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PLASTICS
MATERIALS
SEVENTH EDITION
J.
A.
Brydson
Former Head
of
the Department
of
Physical Sciences
and
Technology,Polytechnic
o
North London
(now
known
as the University
of
North London)
f
INEMANN
OXFORD AUCKLAND BOSTON JOHANNESBURG MELBOURNE NEW DELHI
 
Butterworth-HeinemannLinacre House, Jordan Hill, Oxford OX2 8DP225 Wildwood Avenue, Wobum, MA 01801-2041
A
division of Reed Educational and Professional Publishing Ltd
A
member
of
the Reed Elsevier plc groupFirst published by Iliffe Books Ltd 1966Second edition 1969Reprinted 1970Third edition 1975Reprinted with revisions 1977Reprinted 1979
Fourth
edition published by Butterworth-Heinemann 1982Reprinted 1985Fifth edition 1989Reprinted 1991, 1993Sixth edition 1995Reprinted 1995, 1996, 1998Seventh edition 1999
0
J. A. Brydson 1995, 1999
All
rights reserved.
No
part
of
this publicationmay
be
reproduced in any material
form
(includingphotocopying
or
storing in any medium by electronicmeans and whether
or
not transiently
or
incidentallyto some other use
of
this publication) without thewritten permission
of
the copyright holder except inaccordance with the provisions
of
the CopyrightDesigns and Patents Act 1988
or
under the terms
of
alicence issued by the Copyright Licensing Agency Ltd,
90
Tottenham Court Road, London, England WlP 9HE.Applications
for
the copyright holder’s written permissionto reproduce any part
of
this publication should
be
addressedto the publisher
British Library Cataloguing in Publication Data
Brydson, J. A. (John Andrew), 1932-Plastics materials.
-
7th ed.1. Plastics
I.
Title668.4
ISBN
0
7506 4132
0
Library
of
Congress Cataloguing in Publication Data
Brydson,
J.
A.
Plastics materia1slJ.A. Brydson.
-
7th ed.p. cm.Includes bibliographical references and index.ISBN
0
7506 4132
0
(hbk.)1. Plastics.
I.
Title.TP1120 B7 99-30623668.4-dc21 CIPComposition by Genesis Typesetting, Laser Quay, Rochester, KentPrinted and bound in Great Britain by Biddles Lt4 Guildford and King’s Lynn
 
Contents
Preface to the Seventh EditionPreface
to
the First EditionAcknowledgements for the Seventh EditionAbbreviations for Plastics and Rubbers
1
The Historical Development of Plastics Materials1.1 Natural Plastics1.2 Parkesine and Celluloid1.41.5 Developments since 19391.6 Raw Materials for Plastics1.7 The Market for Plastics
1.8
The Future for Plastics1.3 1900-1930The Evolution
of
the Vinyl Plastics2 The Chemical Nature
of
Plastics2.1 Introduction2.2 Thermoplastic and Thermosetting Behaviour2.3Further Consideration
of
Addition Polymerisation2.3.12.3.2 Ionic polymerisation2.3.3 Ziegler-Natta and metallocene polymerisationElementary kinetics of free-radical addition polymerisation2.4 Condensation Polymerisation3States
of
Aggregation in Polymers3.1 Introduction3.2 Linear Amorphous Polymers3.2.13.3 Crystalline Polymers3.3.1 Orientation and crystallisation3.3.2 Liquid crystal polymersOrientation
in
linear amorphous polymers3.4 Cross-linked Structures3.5 Polyblends3.6 Summaryxviixixxxixxiii11346
7
911
15
19192324293337394343434749
52
5353
55
57
V
of 00

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