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V . A D I T Y A V A R D H A N

H T T P : / / W W W . A D I C H E M A D I . C O M

1

Prepared by V. Aditya vardhan adichemadi(at)gmail.com

WARANGAL

You will get key to this paper and more model papers at

http://www.adichemadi.com

AIEEE-2009MODEL PAPER - 2(CHEMISTRY)

Note: This paper is not only for AIEEE(indeed more advanced)but equally useful for other competitive exami-nations like IIT-JEE, EAMCET, KCET, CSIR-NET, JAM, M.Sc CHEMISTRY entrance examinations of vari-ous universities and institutions.

1)The IUPAC name of the product formed during the alkaline hydrolysis of the followingcompound is

CH

3

ClCl

1) 1-[3-carboxycyclopentyl]-4-methylbenzene2) 1-[3-(formyl)cyclopentyl]-4-methylbenzene3) 3-(4-methylphenyl)cyclopentanecarbaldehyde4) 3-(4-methylphenyl)cyclopentanecarboxylic acid2)Graphite is considered as the ultimate of fused benzene rings. On the same lines, which of thefollowing can be considered as the ultimate of fused

‘inorganic benzene’

rings?1) boran carbide2) borazole3) boron nitride4) carborundum3)If either

ooDD

α-D-Glucose([]= +111) or β-D-Glucose([]=

+19.2)

 

is dissolved separately inwater and allowed to stand, their specific rotations,

D

[]



, gradually change and reach to aspecific constant value +52.5

o

. Which of the following equilibrium best represents thismutarotation?1)

OOHHHHOHOHH OHHOHOOHHHOHHHOH OHHOH

2)

OOHHHHOHOHH OHHOHOHHHOHHHOH OHOHOH

3)

OHHHHOHOHH OHOHOHOHOHHOHHOHHOHOH

4)

OOHHHHOHOHH OHHOHOHHHHOHOHH OHOHOH

4)Following sequence of reactions occur during Mac Arthur Forrest process of extraction of

V . A D I T Y A V A R D H A N

H T T P : / / W W W . A D I C H E M A D I . C O M

2

Prepared by V. Aditya vardhan adichemadi(at)gmail.com

WARANGAL

silver from argentite ore.

2

224

NaCN O Zn

Ag S A Na SO A B Ag

    

Consider the following statements about ‘A’ and ‘B’.a) The geometries of the complexes ‘A’ and ‘B’ are respectively linear and square planar.b) The central metal ions in ‘A’ and ‘B’ exhibit ‘sp’ and ‘sp

3

’ hybridisations respectively.c) The IUPAC name of ‘A’ is Sodium dicyanoargentate(I) and that of ‘B’ is Sodiumtetracyanozincate(II).d) Both ‘A’ and ‘B’ are paramagnetic and colorless substances.Choose the

INCORRECT

statment(s)1) a & c2) a, c & d3) b & c4) a & d5)When 2.0 mol O

2

(g) is heated at a constant pressure of 4.25 atm, its temperature increasesfrom 260 K to 285 K. Given that the isobaric molar heat capacity of O

2

is 29.4 J.K

-1

mol

-1

, thechange in the internal energy during the process will be1) 1054 J.K

-1

mol

-1

2) 416 J.K

-1

mol

-1

3) 1470 J.K

-1

mol

-1

4) 1887 J.K

-1

mol

-1

6)In the following reaction sequence,

CH

3

1) O

3

2) H

2

O, Zn,



A

conc. NaOD

products

the product mixture contains,1) both

CH

3

COO-DOH

and

CH

3

COO-OHD

2) both

CH

3

COO-OHH

and

CH

3

COO-OHH

3) both

CH

3

COO-HOH

and

CH

3

COO-OHH

4) only

CH

3

COO-HOH

7)Consider the following reactions and their differential rate expressions.

V . A D I T Y A V A R D H A N

H T T P : / / W W W . A D I C H E M A D I . C O M

3

Prepared by V. Aditya vardhan adichemadi(at)gmail.com

WARANGAL

12

dxXproducts ; -[]dtdyYproducts ; -dt

k X k

   

These reactions are started with the 2 M solutions of ‘X’ and ‘Y’ each. It is found that theirinitial concentrations are halved in 5 minutes. The respective concentrations of ‘X’ and ‘Y’after 10 minutes will be1) 0.5 M & 0.5 M2) 0.5 M & 0.0 M3) 0.5 M & 0.25 M4) 0.125 M & 0.5 M8)The correct increasing order of the acidic strength of the following compounds isa) 3-Nitrophenol, b) 2-Nitrophenol, c) water, d) Ethyl alcohol, e) 2-Propanol, f) para cresol1) e < d < f < a < b < c2) c < e < d < f < a < b3) e < d < c < f < b < a4) e < d < c < f < a < b9)A beaker contains 100 mL of 0.02 M aqueous solution of methylamine. In first step, 50 mL of 0.02 M HCl solution is added to this and the p

H

of the resulting solution is found to be 10.6. Inthe next step, 50 mL of the 0.01 M H

2

SO

4

solution is added to the beaker. The p

H

of finalsolution will be1) 4.32) 9.73) 2.74) 11.310)As shown below, a graph of log x/m against log P values are plotted for adsorption of hydrogengas over 2 gr of finely powdered nickel. ( where x = amount of adsorbate adsorbed, m = weightof adsorbent and P = equilibrium pressure). What is the amount of hydrogen adsorbed overnickel at 2 atm pressure?1) 2 gr2) 4 gr3) 0.25 gr4) 0.27 g11)Which among a) PHBV, b) Buna-S, c) Dacron, d) Neoprene, e) Nylon-6, are the condensationcopolymers?1) b,d & e2) a,c & e3) a & c4) b,c & e12)A 0.2 molar KCl solution is found to be isotonic with 3% glucose solution. The van’t Hoff factor of KCl solution is (the density of glucose solution is 1 g cm

-3

)1) 1.3342) 0.3343) 1.6674) 0.66713)The reaction that occurs at anode of lead storage battery during its charging by external supply

of 00

Leave a Comment

thankkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkksssssssssssssssssssssssssss

reply04 / 03 / 2010

xz

reply02 / 11 / 2010

You can get the key from my site http://www.adichemadi.com

reply12 / 12 / 2009

uploaded a new revision for this document (#2)

12 / 12 / 2009

kopparapukranthi7117

this is very good

reply06 / 05 / 2009

vishalgupta0792

can u send me the merit list of VJTI of 2008

reply05 / 21 / 2009

i didn't find any download link. can you tell me how to download thanks

reply04 / 23 / 2009

Now try to download! Some times the site becomes busy.

reply04 / 08 / 2009

Aieee 2009 Model Paper 2

This is a model paper for AIEEE 2009. Also useful for IIT-JEE, AIEEE, EAMCET, KCET, GATE, CSIR-UGC NET, JAM, UPSC, AIIMS, VITEE, COMBINED BIOTECHNOLOGY ENTRANCE, M.Sc Chemistry ... (More)

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Category:	School Work > Essays & Theses
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Upload Date:	01/12/2009
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Tags:	Chemistry practice jam upsc mock gate AIEEE aiims IGCSE eamcet IISc model paper (more tags) Chemistry practice jam upsc mock gate AIEEE aiims IGCSE eamcet IISc model paper andhra university iit jee bitsat kcet m.sc chemistry kakatiya university osmania university hyderabad central university ncl pune aieee 2009 aieee 09 aieee2009 aieee 2009 solved aieee 2009 solutions aieee 2009 solved paper aieee sample paper aieee previous paper aieee solved paper aieee chemistry jipmer csir ugc net combined biotechnology entrance mock test aieee 2009 mock test aieee mock test aieee practice paper practice paper sciencechemistry vitee (fewer)

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