J. of Nuclear Sci. and Tech.

No. 52, pp. 30-39, 2010

1389 30-39 52

-
-
2

2 4 2 31*

11365-8486 : -1
11365-8486 : -2
- 1913674711 : -3
11365-3486 : -4

. - - :

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.

- :

Sorption of Metal Ions on Synthetic Organoinorganic Ion Exchanger

Polyacrylonitril-Ti(IV) Tungstophosphate
A. Haidary*1,3, S.J. Ahmadi2, M.R. Asadi4, F. Asgharizadeh2, P. Ashtari2
1- Iran Nuclear Waste Management Company, AEOI, P.O. Box: 11365-8486, Tehran - Iran
2- Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, AEOI, P.O.Box: 11365-8486, Tehran Iran
3- Faculty of Chemistry, Islamic Azad University of Tehran, North of Tehran Branch, P.O. Box: 1913674711, Tehran -Iran
4- Nuclear Science Research School, Nuclear Science and Technology Research Institute, AEOI, P.O.Box: 11365-3486, Tehran Iran

Abstract: In this study two Polyacrylonitril-Ti(IV) tungstophosphate organo-inorganic ion exchangers

with different molar ratios have been synthesized. These ion exchangers have been characterized by
FT-IR, X- ray diffraction, TG, SEM and CHNSO techniques and their cation exchange capacity has been
measured by continuous method. Distribution coefficients (Kd) for metal ions and radionuclides were
determined by batch method and with these ion exchangers, separation of metal ions was achieved on a
glass column.

Keywords:

Ion Exchanger, Polyacrylonitrile-Ti(IV) Tungstophosphate, Metal Ions, Cation Exchange

Capacity, Separation, Batch Method, Distribution Coefficient

*email: amhaidary@aeoi.org.ir

89/3/15 : 88/9/1 :

 1389 52

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 1389 52
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. . .

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