Table of PCB Species

by CAS Registry Number

U. S. Environmental Protection Agency, Region 5
www.epa.gov/toxteam/pcbid/
5 November 2003
Descriptor*

CASRN

Congener
Number

1336-36-3

IUPAC Name

Type

Polychlorinated biphenyl (PCB)

Category

CP0_---_--_2M

2050-67-1

11

3,3'-Dichlorobiphenyl

Congener

CP0_---_PP_--

2050-68-2

15

4,4'-Dichlorobiphenyl

Congener

---_---_--_--

2051-24-3

209

Decachlorobiphenyl

Congener

CP1_---_--_--

2051-60-7

2-Chlorobiphenyl

Congener

CP0_---_--_--

2051-61-8

3-Chlorobiphenyl

Congener

CP0_---_--_--

2051-62-9

4-Chlorobiphenyl

Congener

---_4CL_--_2M

2136-99-4

202

2,2',3,3',5,5',6,6'-Octachlorobiphenyl

Congener

---_4CL_PP_--

2437-79-8

47

2,2',4,4'-Tetrachlorobiphenyl

Congener

CP0_---_--_--

2974-90-5

13

3,4'-Dichlorobiphenyl

Congener

CP0_---_--_--

2974-92-7

12

3,4-Dichlorobiphenyl

Congener

CP1_---_PP_--

7012-37-5

28

2,4,4'-Trichlorobiphenyl

Congener

11096-82-5

Aroclor 1260

Mixture

11097-69-1

Aroclor 1254

Mixture

11100-14-4

Aroclor 1268

Mixture

11104-28-2

Aroclor 1221

Mixture

11141-16-5

Aroclor 1232

Mixture

12672-29-6

Aroclor 1248

Mixture

12674-11-2

Aroclor 1016

Mixture

12767-79-2

Aroclor (unspecified)

Mixture

---_---_--_--

13029-08-8

2,2'-Dichlorobiphenyl

Congener

CP1_---_--_--

15862-07-4

29

2,4,5-Trichlorobiphenyl

Congener

---_4CL_--_--

15968-05-5

54

2,2',6,6'-Tetrachlorobiphenyl

Congener

CP1_---_--_--

16605-91-7

2,3-Dichlorobiphenyl

Congener

CP1_---_--_--

16606-02-3

31

2,4',5-Trichlorobiphenyl

Congener

---_4CL_--_2M

18259-05-7

116

2,3,4,5,6-Pentachlorobiphenyl

Congener

25323-68-6

Trichlorobiphenyl

Homolog

25429-29-2

Pentachlorobiphenyl

Homolog

Table of PCB Species by CAS Registry Number

Descriptor*

CASRN

Congener
Number

25512-42-9
CP1_---_--_--

11/5/2003
IUPAC Name

Page 2
Type

Dichlorobiphenyl

Homolog

2,3'-Dichlorobiphenyl

Congener

26601-64-9

Hexachlorobiphenyl

Homolog

26914-33-0

Tetrachlorobiphenyl

Homolog

27323-18-8

Monochlorobiphenyl

Homolog

28655-71-2

Heptachlorobiphenyl

Homolog

25569-80-6

CP1_4CL_PP_2M

31508-00-6

118

2,3',4,4',5-Pentachlorobiphenyl

Congener

CP1_4CL_PP_--

32598-10-0

66

2,3',4,4'-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

32598-11-1

70

2,3',4',5-Tetrachlorobiphenyl

Congener

---_4CL_PP_--

32598-12-2

75

2,4,4',6-Tetrachlorobiphenyl

Congener

CP0_4CL_PP_2M

32598-13-3

77

3,3',4,4'-Tetrachlorobiphenyl

Congener

CP1_4CL_PP_2M

32598-14-4

105

2,3,3',4,4'-Pentachlorobiphenyl

Congener

CP1_4CL_PP_--

32690-93-0

74

2,4,4',5-Tetrachlorobiphenyl

Congener

CP0_4CL_PP_2M

32774-16-6

169

3,3',4,4',5,5'-Hexachlorobiphenyl

Congener

CP1_4CL_PP_--

33025-41-1

60

2,3,4,4'-Tetrachlorobiphenyl

Congener

---_4CL_PP_2M

33091-17-7

197

2,2',3,3',4,4',6,6'-Octachlorobiphenyl

Congener

---_---_--_--

33146-45-1

10

2,6-Dichlorobiphenyl

Congener

CP1_---_--_--

33284-50-3

2,4-Dichlorobiphenyl

Congener

CP0_4CL_--_2M

33284-52-5

80

3,3',5,5'-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

33284-53-6

61

2,3,4,5-Tetrachlorobiphenyl

Congener

---_4CL_--_2M

33284-54-7

65

2,3,5,6-Tetrachlorobiphenyl

Congener

---_4CL_PP_--

33979-03-2

155

2,2',4,4',6,6'-Hexachlorobiphenyl

Congener

CP1_---_--_--

34883-39-1

2,5-Dichlorobiphenyl

Congener

CP0_---_--_2M

34883-41-5

14

3,5-Dichlorobiphenyl

Congener

CP1_---_--_--

34883-43-7

2,4'-Dichlorobiphenyl

Congener

---_4CL_PP_2M

35065-27-1

153

2,2',4,4',5,5'-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

35065-28-2

138

2,2',3,4,4',5'-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

35065-29-3

180

2,2',3,4,4',5,5'-Heptachlorobiphenyl

Congener

---_4CL_PP_2M

35065-30-6

170

2,2',3,3',4,4',5-Heptachlorobiphenyl

Congener

---_---_--_--

35693-92-6

30

2,4,6-Trichlorobiphenyl

Congener

---_4CL_--_2M

35693-99-3

52

2,2',5,5'-Tetrachlorobiphenyl

Congener

USEPA Region 5

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Table of PCB Species by CAS Registry Number

Descriptor*

CASRN

11/5/2003

Congener
Number

IUPAC Name

Page 3
Type

---_4CL_--_2M

35694-04-3

133

2,2',3,3',5,5'-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

35694-06-5

137

2,2',3,4,4',5-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

35694-08-7

194

2,2',3,3',4,4',5,5'-Octachlorobiphenyl

Congener

---_4CL_--_--

36559-22-5

42

2,2',3,4'-Tetrachlorobiphenyl

Congener

37234-40-5

Aroclor 1231

Mixture

37324-23-5

Aroclor 1262

Mixture

---_---_--_--

37680-65-2

18

2,2',5-Trichlorobiphenyl

Congener

---_---_--_--

37680-66-3

17

2,2',4-Trichlorobiphenyl

Congener

CP1_---_--_2M

37680-68-5

34

2,3',5'-Trichlorobiphenyl

Congener

CP0_---_--_2M

37680-69-6

35

3,3',4-Trichlorobiphenyl

Congener

---_4CL_--_2M

37680-73-2

101

2,2',4,5,5'-Pentachlorobiphenyl

Congener

---_4CL_--_2M

38379-99-6

95

2,2',3,5',6-Pentachlorobiphenyl

Congener

---_4CL_PP_--

38380-01-7

99

2,2',4,4',5-Pentachlorobiphenyl

Congener

---_4CL_--_2M

38380-02-8

87

2,2',3,4,5'-Pentachlorobiphenyl

Congener

---_4CL_--_2M

38380-03-9

110

2,3,3',4',6-Pentachlorobiphenyl

Congener

---_4CL_--_2M

38380-04-0

149

2,2',3,4',5',6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

38380-05-1

132

2,2',3,3',4,6'-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

38380-07-3

128

2,2',3,3',4,4'-Hexachlorobiphenyl

Congener

CP1_4CL_PP_2M

38380-08-4

156

2,3,3',4,4',5-Hexachlorobiphenyl

Congener

---_4CL_--_2M

38411-22-2

136

2,2',3,3',6,6'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

38411-25-5

174

2,2',3,3',4,5,6'-Heptachlorobiphenyl

Congener

---_---_--_--

38444-73-4

19

2,2',6-Trichlorobiphenyl

Congener

---_---_--_--

38444-76-7

27

2,3',6-Trichlorobiphenyl

Congener

---_---_--_--

38444-77-8

32

2,4',6-Trichlorobiphenyl

Congener

---_---_--_--

38444-78-9

16

2,2',3-Trichlorobiphenyl

Congener

CP1_---_--_2M

38444-81-4

26

2,3',5-Trichlorobiphenyl

Congener

CP1_---_--_2M

38444-84-7

20

2,3,3'-Trichlorobiphenyl

Congener

CP1_---_--_--

38444-85-8

22

2,3,4'-Trichlorobiphenyl

Congener

CP1_---_--_--

38444-86-9

33

2,3',4'-Trichlorobiphenyl

Congener

CP0_---_--_2M

38444-87-0

36

3,3',5-Trichlorobiphenyl

Congener

CP0_---_--_2M

38444-88-1

39

3,4',5-Trichlorobiphenyl

Congener

USEPA Region 5

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Table of PCB Species by CAS Registry Number

Descriptor*

CASRN

Congener
Number

11/5/2003
IUPAC Name

Page 4
Type

CP0_---_PP_--

38444-90-5

37

3,4,4'-Trichlorobiphenyl

Congener

---_4CL_--_2M

38444-93-8

40

2,2',3,3'-Tetrachlorobiphenyl

Congener

---_4CL_PP_--

39485-83-1

100

2,2',4,4',6-Pentachlorobiphenyl

Congener

CP1_4CL_PP_2M

39635-31-9

189

2,3,3',4,4',5,5'-Heptachlorobiphenyl

Congener

CP1_4CL_--_2M

39635-32-0

111

2,3,3',5,5'-Pentachlorobiphenyl

Congener

CP0_4CL_--_2M

39635-33-1

127

3,3',4,5,5'-Pentachlorobiphenyl

Congener

CP1_4CL_--_2M

39635-34-2

162

2,3,3',4',5,5'-Hexachlorobiphenyl

Congener

CP1_4CL_--_2M

39635-35-3

159

2,3,3',4,5,5'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

40186-70-7

175

2,2',3,3',4,5',6-Heptachlorobiphenyl

Congener

---_4CL_--_2M

40186-71-8

201

2,2',3,3',4,5',6,6'-Octachlorobiphenyl

Congener

---_4CL_PP_2M

40186-72-9

206

2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl

Congener

---_4CL_--_2M

41411-61-4

142

2,2',3,4,5,6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

41411-62-5

160

2,3,3',4,5,6-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

41411-63-6

166

2,3,4,4',5,6-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

41411-64-7

190

2,3,3',4,4',5,6-Heptachlorobiphenyl

Congener

---_4CL_--_2M

41464-39-5

44

2,2',3,5'-Tetrachlorobiphenyl

Congener

---_4CL_--_--

41464-40-8

49

2,2',4,5'-Tetrachlorobiphenyl

Congener

---_4CL_--_--

41464-41-9

53

2,2',5,6'-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

41464-42-0

72

2,3',5,5'-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

41464-43-1

56

2,3,3',4'-Tetrachlorobiphenyl

Congener

---_4CL_--_--

41464-46-4

71

2,3',4',6-Tetrachlorobiphenyl

Congener

---_4CL_--_--

41464-47-5

46

2,2',3,6'-Tetrachlorobiphenyl

Congener

CP0_4CL_--_2M

41464-48-6

79

3,3',4,5'-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

41464-49-7

58

2,3,3',5'-Tetrachlorobiphenyl

Congener

---_4CL_--_2M

41464-51-1

97

2,2',3,4',5'-Pentachlorobiphenyl

Congener

---_4CL_PP_2M

42740-50-1

196

2,2',3,3',4,4',5,6'-Octachlorobiphenyl

Congener

---_4CL_--_2M

51908-16-8

146

2,2',3,4',5,5'-Hexachlorobiphenyl

Congener

---_4CL_--_--

52663-58-8

64

2,3,4',6-Tetrachlorobiphenyl

Congener

---_4CL_--_--

52663-59-9

41

2,2',3,4-Tetrachlorobiphenyl

Congener

---_4CL_--_2M

52663-60-2

84

2,2',3,3',6-Pentachlorobiphenyl

Congener

---_4CL_--_2M

52663-61-3

92

2,2',3,5,5'-Pentachlorobiphenyl

Congener

USEPA Region 5

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Table of PCB Species by CAS Registry Number

Descriptor*

CASRN

11/5/2003

Congener
Number

IUPAC Name

Page 5
Type

---_4CL_--_2M

52663-62-4

82

2,2',3,3',4-Pentachlorobiphenyl

Congener

---_4CL_--_2M

52663-63-5

151

2,2',3,5,5',6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

52663-64-6

179

2,2',3,3',5,6,6'-Heptachlorobiphenyl

Congener

---_4CL_--_2M

52663-65-7

176

2,2',3,3',4,6,6'-Heptachlorobiphenyl

Congener

---_4CL_--_2M

52663-66-8

130

2,2',3,3',4,5'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

52663-67-9

178

2,2',3,3',5,5',6-Heptachlorobiphenyl

Congener

---_4CL_--_2M

52663-68-0

187

2,2',3,4',5,5',6-Heptachlorobiphenyl

Congener

---_4CL_PP_2M

52663-69-1

183

2,2',3,4,4',5',6-Heptachlorobiphenyl

Congener

---_4CL_--_2M

52663-70-4

177

2,2',3,3',4,5',6'-Heptachlorobiphenyl

Congener

---_4CL_PP_2M

52663-71-5

171

2,2',3,3',4,4',6-Heptachlorobiphenyl

Congener

CP1_4CL_PP_2M

52663-72-6

167

2,3',4,4',5,5'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

52663-73-7

200

2,2',3,3',4,5,6,6'-Octachlorobiphenyl

Congener

---_4CL_--_2M

52663-74-8

172

2,2',3,3',4,5,5'-Heptachlorobiphenyl

Congener

---_4CL_--_2M

52663-75-9

199

2,2',3,3',4,5,5',6'-Octachlorobiphenyl

Congener

---_4CL_PP_2M

52663-76-0

203

2,2',3,4,4',5,5',6-Octachlorobiphenyl

Congener

---_4CL_--_2M

52663-77-1

208

2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl

Congener

---_4CL_PP_2M

52663-78-2

195

2,2',3,3',4,4',5,6-Octachlorobiphenyl

Congener

---_4CL_PP_2M

52663-79-3

207

2,2',3,3',4,4',5,6,6'-Nonachlorobiphenyl

Congener

---_4CL_--_2M

52704-70-8

134

2,2',3,3',5,6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

52712-04-6

141

2,2',3,4,5,5'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

52712-05-7

185

2,2',3,4,5,5',6-Heptachlorobiphenyl

Congener

---_4CL_--_2M

52744-13-5

135

2,2',3,3',5,6'-Hexachlorobiphenyl

Congener

Aroclor 1242

Mixture

3,4,5-Trichlorobiphenyl

Congener

Nonachlorobiphenyl

Homolog

53469-21-9
CP0_---_--_2M

53555-66-1

38

53742-07-7
---_4CL_--_--

54230-22-7

62

2,3,4,6-Tetrachlorobiphenyl

Congener

---_4CL_--_--

55215-17-3

88

2,2',3,4,6-Pentachlorobiphenyl

Congener

---_4CL_--_2M

55215-18-4

129

2,2',3,3',4,5-Hexachlorobiphenyl

Congener

---_4CL_--_2M

55312-69-1

86

2,2',3,4,5-Pentachlorobiphenyl

Congener

---_---_--_--

55702-45-9

24

2,3,6-Trichlorobiphenyl

Congener

CP1_---_--_--

55702-46-0

21

2,3,4-Trichlorobiphenyl

Congener

USEPA Region 5

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Table of PCB Species by CAS Registry Number

Descriptor*

CASRN

Congener
Number

11/5/2003
IUPAC Name

Page 6
Type

CP1_---_--_--

55712-37-3

25

2,3',4-Trichlorobiphenyl

Congener

CP1_---_--_2M

55720-44-0

23

2,3,5-Trichlorobiphenyl

Congener

Octachlorobiphenyl

Homolog

55722-26-4
---_4CL_PP_--

56030-56-9

139

2,2',3,4,4',6-Hexachlorobiphenyl

Congener

---_4CL_--_--

56558-16-8

104

2,2',4,6,6'-Pentachlorobiphenyl

Congener

---_4CL_PP_--

56558-17-9

119

2,3',4,4',6-Pentachlorobiphenyl

Congener

---_4CL_--_2M

56558-18-0

121

2,3',4,5',6-Pentachlorobiphenyl

Congener

CP0_4CL_PP_2M

57465-28-8

126

3,3',4,4',5-Pentachlorobiphenyl

Congener

---_4CL_PP_--

59291-64-4

140

2,2',3,4,4',6'-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

59291-65-5

168

2,3',4,4',5',6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

60145-20-2

83

2,2',3,3',5-Pentachlorobiphenyl

Congener

---_4CL_--_--

60145-21-3

103

2,2',4,5',6-Pentachlorobiphenyl

Congener

---_4CL_PP_--

60145-22-4

154

2,2',4,4',5,6'-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

60145-23-5

182

2,2',3,4,4',5,6'-Heptachlorobiphenyl

Congener

---_4CL_--_--

60233-24-1

69

2,3',4,6-Tetrachlorobiphenyl

Congener

---_4CL_--_--

60233-25-2

98

2,2',3,4',6'-Pentachlorobiphenyl

Congener

---_4CL_--_2M

61798-70-7

131

2,2',3,3',4,6-Hexachlorobiphenyl

Congener

---_4CL_--_--

62796-65-0

50

2,2',4,6-Tetrachlorobiphenyl

Congener

CP1_4CL_PP_2M

65510-44-3

123

2,3',4,4',5'-Pentachlorobiphenyl

Congener

---_4CL_PP_--

65510-45-4

85

2,2',3,4,4'-Pentachlorobiphenyl

Congener

---_4CL_--_--

68194-04-7

51

2,2',4,6'-Tetrachlorobiphenyl

Congener

---_4CL_--_--

68194-05-8

91

2,2',3,4',6-Pentachlorobiphenyl

Congener

---_4CL_--_--

68194-06-9

102

2,2',4,5,6'-Pentachlorobiphenyl

Congener

---_4CL_--_2M

68194-07-0

90

2,2',3,4',5-Pentachlorobiphenyl

Congener

---_4CL_--_--

68194-08-1

150

2,2',3,4',6,6'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

68194-09-2

152

2,2',3,5,6,6'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

68194-10-5

113

2,3,3',5',6-Pentachlorobiphenyl

Congener

---_4CL_--_2M

68194-11-6

117

2,3,4',5,6-Pentachlorobiphenyl

Congener

CP1_4CL_--_2M

68194-12-7

120

2,3',4,5,5'-Pentachlorobiphenyl

Congener

---_4CL_--_2M

68194-13-8

147

2,2',3,4',5,6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

68194-14-9

144

2,2',3,4,5',6-Hexachlorobiphenyl

Congener

USEPA Region 5

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Table of PCB Species by CAS Registry Number

Descriptor*

CASRN

11/5/2003

Congener
Number

IUPAC Name

Page 7
Type

---_4CL_--_2M

68194-15-0

143

2,2',3,4,5,6'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

68194-16-1

173

2,2',3,3',4,5,6-Heptachlorobiphenyl

Congener

---_4CL_--_2M

68194-17-2

198

2,2',3,3',4,5,5',6-Octachlorobiphenyl

Congener

CP1_4CL_PP_2M

69782-90-7

157

2,3,3',4,4',5'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

69782-91-8

193

2,3,3',4',5,5',6-Heptachlorobiphenyl

Congener

CP1_4CL_--_2M

70362-41-3

108

2,3,3',4,5'-Pentachlorobiphenyl

Congener

---_4CL_--_--

70362-45-7

45

2,2',3,6-Tetrachlorobiphenyl

Congener

---_4CL_--_2M

70362-46-8

43

2,2',3,5-Tetrachlorobiphenyl

Congener

---_4CL_--_--

70362-47-9

48

2,2',4,5-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

70362-48-0

76

2,3',4',5'-Tetrachlorobiphenyl

Congener

CP0_4CL_--_2M

70362-49-1

78

3,3',4,5-Tetrachlorobiphenyl

Congener

CP0_4CL_PP_2M

70362-50-4

81

3,4,4',5-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

70424-67-8

57

2,3,3',5-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

70424-68-9

107

2,3,3',4',5-Pentachlorobiphenyl

Congener

CP1_4CL_--_2M

70424-69-0

106

2,3,3',4,5-Pentachlorobiphenyl

Congener

CP1_4CL_--_2M

70424-70-3

124

2,3',4',5,5'-Pentachlorobiphenyl

Congener

Aroclor 1240

Mixture

71328-89-7
CP1_4CL_--_2M

73575-52-7

68

2,3',4,5'-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

73575-53-8

67

2,3',4,5-Tetrachlorobiphenyl

Congener

---_4CL_--_--

73575-54-9

96

2,2',3,6,6'-Pentachlorobiphenyl

Congener

---_4CL_--_2M

73575-55-0

94

2,2',3,5,6'-Pentachlorobiphenyl

Congener

---_4CL_--_2M

73575-56-1

93

2,2',3,5,6-Pentachlorobiphenyl

Congener

---_4CL_--_--

73575-57-2

89

2,2',3,4,6'-Pentachlorobiphenyl

Congener

---_4CL_--_2M

74338-23-1

73

2,3',5',6-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

74338-24-2

55

2,3,3',4-Tetrachlorobiphenyl

Congener

---_4CL_--_2M

74472-33-6

59

2,3,3',6-Tetrachlorobiphenyl

Congener

CP1_4CL_--_2M

74472-34-7

63

2,3,4',5-Tetrachlorobiphenyl

Congener

---_4CL_--_2M

74472-35-8

109

2,3,3',4,6-Pentachlorobiphenyl

Congener

---_4CL_--_2M

74472-36-9

112

2,3,3',5,6-Pentachlorobiphenyl

Congener

CP1_4CL_PP_2M

74472-37-0

114

2,3,4,4',5-Pentachlorobiphenyl

Congener

---_4CL_PP_--

74472-38-1

115

2,3,4,4',6-Pentachlorobiphenyl

Congener

USEPA Region 5

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Table of PCB Species by CAS Registry Number

Descriptor*

CASRN

11/5/2003

Congener
Number

IUPAC Name

Page 8
Type

---_4CL_--_2M

74472-39-2

125

2,3',4',5',6-Pentachlorobiphenyl

Congener

---_4CL_--_--

74472-40-5

145

2,2',3,4,6,6'-Hexachlorobiphenyl

Congener

---_4CL_--_2M

74472-41-6

148

2,2',3,4',5,6'-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

74472-42-7

158

2,3,3',4,4',6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

74472-43-8

161

2,3,3',4,5',6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

74472-44-9

163

2,3,3',4',5,6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

74472-45-0

164

2,3,3',4',5',6-Hexachlorobiphenyl

Congener

---_4CL_--_2M

74472-46-1

165

2,3,3',5,5',6-Hexachlorobiphenyl

Congener

---_4CL_PP_2M

74472-47-2

181

2,2',3,4,4',5,6-Heptachlorobiphenyl

Congener

---_4CL_PP_--

74472-48-3

184

2,2',3,4,4',6,6'-Heptachlorobiphenyl

Congener

---_4CL_--_2M

74472-49-4

186

2,2',3,4,5,6,6'-Heptachlorobiphenyl

Congener

---_4CL_PP_2M

74472-50-7

191

2,3,3',4,4',5',6-Heptachlorobiphenyl

Congener

---_4CL_--_2M

74472-51-8

192

2,3,3',4,5,5',6-Heptachlorobiphenyl

Congener

---_4CL_PP_2M

74472-52-9

204

2,2',3,4,4',5,6,6'-Octachlorobiphenyl

Congener

---_4CL_PP_2M

74472-53-0

205

2,3,3',4,4',5,5',6-Octachlorobiphenyl

Congener

---_4CL_--_2M

74487-85-7

188

2,2',3,4',5,6,6'-Heptachlorobiphenyl

Congener

CP1_4CL_--_2M

76842-07-4

122

2,3,3',4',5'-Pentachlorobiphenyl

Congener

89577-78-6

Aroclor 1252

Mixture

147601-87-4

Aroclor 1210

Mixture

151820-27-8

Aroclor 1216

Mixture

165245-51-2

Aroclor 1250

Mixture

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Table of PCB Species by CAS Registry Number

11/5/2003

Page 9

*Key to Table Columns

Descriptors
CP0 / CP1

These 68 "Co-Planar" congeners include 20 with chlorine substitution at none

(CP0, non-ortho) and 48 with chlorine substitution at only one (CP1, mono-ortho)
of the 2, 2', 6, or 6' positions.

4CL

These 169 congeners have a total of four or more chlorine substituents

(regardless of position).

PP

These 54 congeners have both para positions (4 and 4') chlorinated.

2M

These 140 congeners have two or more of the meta positions (3, 3', 5, and 5')
chlorinated.

NOTE: The 12 "Dioxin-like" congeners are those that display all four of the above Descriptors.

CASRN
Chemical Abstracts Service (CAS) Registry Number.

Congener Number
The numbering presented in the table is identical to that published by Ballschmiter et al., 1992.
It should be noted that there is currently no disagreement between the congener numbers
assigned by Ballschmiter ("BZ Numbers") and those assigned by CAS. In the complete dataset
(pcbcong8.dbf) available on the Download page, these congener numbers are found in column
(field) BZ_1992.

IUPAC Name
The names presented in the table are the IUPAC names. Ballschmiter currently differs from
CAS (and the IUPAC naming rules) on 10 congeners. Please see the BZ v. IUPAC Table for a
summary of these name differences, as well as the changes adopted since the seminal
publication on congener nomenclature by Ballschmiter and Zell, 1980. In the complete dataset
(pcbcong8.dbf) available on the Download page, these names are found in column (field)
IUPAC_NAME.

Type
The type of the PCB entity: Congener, Homolog, Mixture, Category. For more on these terms,
see the Definitions page.

USEPA Region 5

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Table of PCB Species by CAS Registry Number

11/5/2003

Page 10

Table Revision History

November 1998 -- Table Created
September 2000 -- Column titles revised; "PCB-" removed from
congener numbers; font changed; no change in table data.
May 2003 -- Column title "Current BZ & IUPAC Number" changed
to "Congener Number" to clarify lack of direct IUPAC role in
congener numbering. Other minor edits to page title, headers, and
footers. No change in table data.
October 2003 -- Table Key revised to clarify the sources of the data
in each column. No change in table data.

Please direct any comments or corrections to:

Jonathan Barney
USEPA (WQ-16J)
77 W Jackson Blvd
Chicago IL 60604-3590
barney.jonathan@epa.gov
312.886.6102

USEPA Region 5

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PCB Congener Weight%s in Aroclors of 5 Types

IUPAC
No.
1

2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40

Structure
Ring Cl Pos.
2
3
4
2-2
23
2-3
24
2-4
25
26
3-3
34
3-4
35
4-4
23-2
24-2
25-2
26-2
23-3
234
23-4
235
236
24-3
25-3
26-3
24-4
245
246
25-4
26-4
34-2
35-2
34-3
35-3
34-4
345
35-4
23-23

Lot
A2
A1016

Mean
3 Lots
A1242

Lot
A3.5
A1248

.52
.02
.15
3.62
.17
1.64
.29
8.29
.58
.23

.54
.03
.18
3.08
.14
1.43
.26
7.05
.50
.20

.05

.07
.24

.06
.22

2.40
3.88
3.98
10.86
.99
.88
NM
3.50
.01
.16
.72
1.57
.51
8.50
.10
.00
9.32
2.37
6.21
.03
.05

2.10
3.14
3.13
8.53
.80
.72
NM
2.84
.01
.13
.59
1.28
.41
6.86
.08
7.34
1.90
5.01
.02
.08

5.07
.88
2.23
.00
.00

1.02

2.03

.58

.76

Lot
G3.5
A1248

Lot
A4
A1254

Lot
G4
A1254

Mean
3 Lots
A1260

.02

.02

.04

.02

.06

.02

.00

.01

.02

.01

.26

.05

.13

.04

.22
1.04
1.05
4.29
.22
.14

.06
.71
.93
3.29
.14
.08

.01
.02
.02
.08

.03
.09
.08
.25

.01
.01
.02
.05

1.33

1.38
.00

.02

.04

.01

.01
.32
.00
.13
.02
.81
.04

.02

.02

.01
.11
.40
.12
3.59
.00

.04
.23
.07
5.57
.01

.03
.06

.19

.03

5.47
.93
2.21
.00

.11
.01
.05

.28
.05
.16

.04
.01
.03

.79

.95

.01

.07

.01

1.13

.92

.15

.12

PCB Congener Weight%s in Aroclors of 5 Types

IUPAC
No.
41
42
43
44
45
46
47
48
49

50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80

Structure
Ring Cl Pos.
234-2
23-24
235-2
23-25
236-2
23-26
24-24
245-2
24-25
246-2
24-26
25-25
25-26
26-26
234-3
23-34
235-3
23-35
236-3
234-4
2345
2346
235-4
236-4
2356
24-34
245-3
24-35
246-3
25-34
26-34
25-35
26-35
245-4
246-4
345-2
34-34
345-3
34-35
35-35

Lot
A2
A1016
.76
1.59
.28
4.47
1.23
.49
1.26
1.61
3.35
.01
.32
4.63
.95
.01

Mean
3 Lots
A1242

Lot
A3.5
A1248

Lot
G3.5
A1248

.77
1.67
.30
6.31
1.09
.47
1.49
1.66
4.12

.75
1.79
.19
5.09
.91
.39
2.41
1.54
4.17

.30
6.93
1.05

.07
.01

.68
1.19
.18
3.55
.89
.36
.93
1.18
2.53
.00
.23
3.53
.71
.01
.10
1.81
.02

.06
3.16
.02

.31
5.58
.88
.01
.05
3.19
.02

.41
.04

.32
1.18

.37
1.85

.06
1.87

.12
1.70

.39
.06
.00
.59
1.16
.00
.00
.33
.06

Lot
A4
A1254

Lot
G4
A1254

Mean
3 Lots
A1260

.02
.09

.01
.15

.67
.02

2.31
.05

.07
.05
.26

.14
.12
1.10

.83
.04

5.38
.12

.24

1.70

.55

.02

.23
2.67

.01
.95

.02
.18

.04

.17
3.01

.19
3.32

.07
.36

.02
.59

.01

3.39
.16

5.84
.13

7.22
.10

3.56
.01

1.01

.02

3.73
1.03
.01
.00
1.81
.04
.08
.31

7.28
1.67
.02

7.39
1.86
.01

6.83
.11

3.49
.15

.04
.01

3.14
.08
.13
.41

4.67
.08
.13
.52

2.19

.84

.05

.03
.20

.02
.03

.01
.03

.01

PCB Congener Weight%s in Aroclors of 5 Types

IUPAC
No.
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120

Structure
Ring Cl Pos.
345-4
234-23
235-23
236-23
234-24
2345-2
234-25
2346-2
234-26
235-24
236-24
235-25
2356-2
235-26
236-25
236-26
245-23
246-23
245-24
246-24
245-25
245-26
246-25
246-26
234-34
2345-3
234-35
2346-3
235-34
236-34
235-35
2356-3
236-35
2345-4
2346-4
23456
2356-4
245-34
246-34
245-35

Lot
A2
A1016

Mean
3 Lots
A1242

Lot
G3.5
A1248

Lot
A4
A1254

Lot
G4
A1254

Mean
3 Lots
A1260

.02
.62
.20
.91
1.14
.09
1.11
.02
.17
NM
.56
.25
.03
.02
1.43
.06
.97

.00
1.53
.56
1.58
2.49
.10
3.41

1.11
.48
2.32
1.28
.06
3.99

.21
.09
.00
.01
.61
.03
.38

.01
.81
.26
1.26
.98
.11
1.45
.02
.20
NM
.63
.38
.04
.03
1.96
.08
1.22

.11
NM
.53
.57

.09
NM
.93
1.29

.01
1.84
.01
2.78

.02
6.25
.04
2.62

.01

.46

1.47

1.81

4.53

3.02

.04

.04
.04

.69
.07

2.22
.19
.02

1.89
.17
.01

5.49
.09

8.02
.15
.03

3.13

.00

.47

1.60

1.45

7.37

2.99

.22

.06
.83

.18
2.97

.13
2.55

.78
8.42

.37
9.29

.01
1.33

.04
.04

.12
.11

.12
.11

.01
.50
.37

.18
.20

.03
.66

.09
2.29
.06

.10
2.35
.06

.19
13.59
.12

.23
7.35
.08

.05

.06

.31
.04

.01
.26
.11
.41
.31
.03
.46
.00
.09

Lot
A3.5
A1248

.01
.11
.01
.41

.01
.30

2.45
.09

.48

PCB Congener Weight%s in Aroclors of 5 Types

IUPAC
No.
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160

Structure
Ring Cl Pos.
246-35
345-23
345-24
345-25
345-26
345-34
345-35
234-234
2345-23
234-235
2346-23
234-236
235-235
2356-23
235-236
236-236
2345-24
234-245
2346-24
234-246
2345-25
23456-2
2345-26
2346-25
2346-26
235-245
2356-24
235-246
236-245
236-246
2356-25
2356-26
245-245
245-246
246-246
2345-34
234-345
2346-34
2345-35
23456-3

Lot
A2
A1016

Mean
3 Lots
A1242

Lot
A3.5
A1248

Lot
G3.5
A1248

Lot
A4
A1254

Lot
G4
A1254

Mean
3 Lots
A1260

.01
.03
.03
.02

.06
.07
.10
.04
.00

.05
.08
.07
.03
.00

.25
.32
.47
.03
.02

.10
.15
.29
.02
.00

.02

.12
.02
.04

.08

.04

.15

.14

1.71
.39
.50
.14
1.50

.10

.04
.05
.03
.38

.01
.04
.06
.02
.41

.20
.28
.24
.52
5.95
.14

1.42
.38
.60
.19
2.29
.11
.37
.61
.70
.42
5.80
.15

.53
.14
.22
.07
2.90
.07
.34
1.08
1.46
.02
6.54

.01

.07

.09

.69

.98

2.62

.01

.12

.24

.61

.04

.05

.45
.02

.67
.10

1.15

.24

.33

1.82

3.65

8.75

.04

.08

.22

.69

3.04

.06

.23

.43

3.29
.02

3.77
.04

9.39

.01

.06
.01
.04

.04
.00
.04

1.13
.30
.90

.82
.19
.81

.52
.02
.58

.06

.01

.01

.01

PCB Congener Weight%s in Aroclors of 5 Types

IUPAC
No.
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200

Structure
Ring Cl Pos.
2346-35
235-345
2356-34
236-345
2356-35
23456-4
245-345
246-345
345-345
2345-234
2346-234
2345-235
23456-23
2345-236
2346-235
2346-236
2356-234
2356-235
2356-236
2345-245
23456-24
2345-246
2346-245
2346-246
23456-25
23456-26
2356-245
2356-246
2345-345
23456-34
2346-345
23456-35
2356-345
2345-2345
23456-234
2345-2346
2346-2346
23456-235
2345-2356
23456-236

Lot
A2
A1016

Mean
3 Lots
A1242

.01

Lot
A3.5
A1248

Lot
G3.5
A1248

Lot
A4
A1254

Lot
G4
A1254

Mean
3 Lots
A1260

.06
.02

.08
.03

.70
.31

1.03
.40

2.42
.69

.01

.01

.05
.35

.05
.27

.19

.08

.35
.08
.03

.52
.14
.07

.08

.14

.34

.03

.01
.08

.02
.21

.02
.42

.04
.20
.03
.10
.67

.06

.09

.18

.02

4.11
1.11
.70
.10
4.96
.17
.59
2.57
.83
2.03
11.38
.01
2.41
.55

.09

.09

.25

5.40

.01
.05

.01
.07

.10
.82
.17

.03
.01

.53
2.07
.84
1.09
.07
.10
1.78
.25

.01

PCB Congener Weight%s in Aroclors of 5 Types

IUPAC
No.

Structure
Ring Cl Pos.

Lot
A2
A1016

Mean
3 Lots
A1242

Lot
A3.5
A1248

Lot
G3.5
A1248

Lot
A4
A1254

Lot
G4
A1254

201

2346-2356
202
2356-2356
23456-245
203
204
23456-246
205
23456-345
206
23456-2345
207
23456-2346
208
23456-2356
209
23456-23456
Sum of Wt%s =
Homolog % Dist.

mono-Cl
di-Cl
tri-Cl
tetra-Cl
penta-Cl
hexa-Cl
hepta-Cl
octa-Cl
nona-Cl
N.B.

.02

100.0
A2
A1016
.70
17.53
54.67
22.07
5.07
.00
.00
.00
.00

100.0
Mean
A1242
.75
15.04
44.91
20.16
18.85
.31
.00
.00
.00

100.2
A3.5
A1248
.07
1.55
21.27
32.77
42.92
1.64
.02
.00
.00

100.2
G3.5
A1248

IUPAC#s 107, 108, & 109 here correspond to BZ #s 108, 109 & 107.
IUPAC#s 199, 200, & 201 here correspond to BZ #s 201, 199 & 200.
NM indicates congener not measured but present at trace level.
Underlined PCB # indicates present at > 1.0 Wt% in some Aroclor.
Italicized PCB# indicates not present at > 0.10 Wt% in any Aroclor;
these "non-Aroclor congeners" generally have major imbalance in
no. of Cls/ring and/or less probable 3-, 35- or 246- substituted rings

Data condensed from: Frame, G. M., Cochran, J. W., and Boewadt, S.S.,
J. High Res. Chromatogr.,
Vol. 19, pp 657-668 (1996)

.03

.01

.01

100.2

100.4

A4
A1254

.02
.36
22.02
31.12
44.09
1.97
.57
.00
.00

** Lot A4 Aroclor 1254 from abnormal late production ( 1974-1977 ) made by

chlorinating A1016 distillate residue and contains elevated percentages of
non- and mono-ortho chlorinated congeners relative to "normal" G4 Lot

.03

.02
.09
.39
4.86
71.44
21.97
1.36
.00
.04

G4
A1254
.00
.24
1.26
10.25
59.12
26.76
2.66
.04
.04

Mean
3 Lots
A1260
.24
.33
1.40
.10
.53
.05
.13
NM
100.3
Mean
A1260
.02
.08
.21
.35
8.74
43.35
38.54
8.27
.70