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Rr210802 Organic Chemistry

Rr210802 Organic Chemistry

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Published by Srinivasa Rao G

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Published by: Srinivasa Rao G on Jan 18, 2008
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Code No: RR210802
Set No. 1
II B.Tech I Semester Supplimentary Examinations, November 2007ORGANIC CHEMISTRY(Chemical Engineering)Time: 3 hours Max Marks: 80Answer any FIVE QuestionsAll Questions carry equal marks
⋆⋆⋆⋆⋆
1. (a) Define and explain Inductive effect.(b) Explain why aniline is less basic in comparison with methyl amine. [10+6]2. What is alkylation and acylation? Give at least three different examples of each.[16]3. (a) Describe the chlorination of methane in the presence of peroxides.(b) Discuss the chlorination of ethane in the presence of heat. [8+8]4. (a) Discus the methods of resolution of recemic mixtures.(b) What is the criterion of enantiomerism? [10+6]5. Write a note on conformational analysis of cyclothexane. [16]6. (a) What are Polymers? How are they Classified?(b) Discuss the importance of Synthetic high polymers.(c) Describe the preparation of nylon(6) from cyclohexanone. [6+5+5]7. (a) How will you prepare Quinoline? How does it react with the following reagents?i.
HNO
3
/
2
SO
4
ii.
2
SO
4
iii. KMn
O
4
.(b) Give two methods of synthesis of pyridine. [11+5]8. (a) What are dyes?(b) Explain the classification of dye based on their chemical structure. [6+10]
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Code No: RR210802
Set No. 2
II B.Tech I Semester Supplimentary Examinations, November 2007ORGANIC CHEMISTRY(Chemical Engineering)Time: 3 hours Max Marks: 80Answer any FIVE QuestionsAll Questions carry equal marks
⋆⋆⋆⋆⋆
1. (a) Explain the following applications of Inductive effecti. Effect of bond lengthsii. Dipole momentiii. reactivity of alkyl halide(b) Discuss the strength of carboxylic acid based upon Inductive effect. [9+7]2. Write a detailed note on Perkin reaction with mechanism. [16]3. Formulate and give mechanism for the following reactions :-(a) NBS and isobutylene(b) Ditorane and isobutylene followed by treatment with
2
O
2
. [8+8]4. (a) Which of the following compounds exhibit optical isomerism?i. Nitromethaneii. Methyl chlorideiii. Glyceraldehydeiv. Ethylene glycol(b) Describe a method to determine the optical activity of an organic compound.[8+8]5. (a) How maleic acid and fumaric acid react with acetyl chloride? What inferenceyou get from this reaction?(b) Write a note on E and Z configurations of geometrical isomens. [8+8]6. (a) What is natural wool? How is it obtained?(b) Explain the difference between natural and artificial silk. How are they dis-tinguished? [8+8]7. (a) Compare the basic nature of the following pairs of compounds and justify yourcomparison.i. Pyridine and pyrroleii. Pyridine and trimethylamine.(b) How will you prepare Quinoline from aniline? [8+8]8. Give a brief account of the chemistry of Diphenylamine and Triphenylamine dyes?[16]
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Code No: RR210802
Set No. 3
II B.Tech I Semester Supplimentary Examinations, November 2007ORGANIC CHEMISTRY(Chemical Engineering)Time: 3 hours Max Marks: 80Answer any FIVE QuestionsAll Questions carry equal marks
⋆ ⋆ ⋆ ⋆ ⋆
1. Discuss about polar effects briefly such as inductive, hyperconjugation and reso-nance eects. [16]2. Show the reaction mechanism of aldol condensation and describe its uses. [16]3. (a) Describe the chlorination of methane in the presence of peroxides.(b) Discuss the chlorination of ethane in the presence of heat. [8+8]4. Explain the following(a) Chiral center(b) Plane polarised light(c) Meso compound(d) Conformational isomers [4
×
4]5. How will you assign E-Z notations to geometrical isomers? Explain with suitableexamples. [16]6. (a) Describe the preparation of natural rubber from latex.(b) What are bakelite resins and how are they made. [8+8]7. (a) How will you obtain the following heterocyclic compounds.(Mention any twomethods)i. Pyrrole andii. Quinoline.(b) In pyridine, electrophilic substitution reaction occurs chiefly at C-3. Why?[8+8]8. Explain what are(a) Direct dyes(b) Mordant dyes(c) Vat dyes(d) Ingrain dyes with examples. [16]
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