Cu1: Ho tan hon ton 58gam hn hp X gm Fe,Cu v Ag trong dung

dch HNO3 long thu c 0.15 mol NO v 0.0625 mol N2O v dung dch
Y ,khi lng mui khan thu c l:
A.124.4g
B.89.8g
C.116.9g
D.90.3g
Cu2: Ho tan ht 16.3g hn hp X gm 3 kim loi Mg,Al,v Fe trong dung
dch H2SO4 c nng thu c 0.55 mol SO2.C cn dung dch thu c
lng mui khan l:
A.51.8g
B.55.2g
C.69.1g
D.82.9g
Cu3: Nung 8.4g Fe trong khng kh .sau phn ng thu c m g cht rn X
gm Fe v cc oxit st.Ho tan ht cht rn X bng dung dch HNO 3 d, thu
c 0.1 mol NO2 (sn phm kh duy nht ) . Xc nh gi tr ca m:
A.11.2
B.9.8
C.53.2
D.8.8
Cu4 : Ho tan hon ton m g hn hp X gm Fe, FeO,Fe 2O3 v Fe3O4
bng dung dch HNO3 c d , thu c 0.2 mol NO2 (sn phm kh duy
nht). C cn dung dch thu c 145.2g mui khan . Xc nh gi tr ca m:
A.35.7
B.46.4
C.15.8
D.77.7
Cu5: Ho tan hon ton 49.6g hn hp X gm Fe, FeO,Fe 2O3 v Fe3O4bng
dung dch H2SO4 c nng (d), thu c 8.96 lt SO2 (kc) v dung dch
Y .C cn dung dch Y,khi lng mui khan thu c l:
A.88g
B.160
C.132
D.140
Cu6: kh hon ton 3.04g hn hp X gm FeO, Fe 2O3, Fe3O4 th cn
0.05 mol H2.Mt khc , ho tan hon ton hn hp X trong dung dch
H2SO4 c nng, thu c V ml SO2(kc).gi tr ca V l:
A.112
B.224
C.336
D.448
Cu7: Kh hon ton 12 g hn hp X gm FeO, Fe2O3, Fe3O4 thu c
10.08 g Fe .Tnh th tch dung dch HNO 3 2M cn ly ho tan hon ton
12 g hn hp X v to ra sn phm kh duy nht l NO:
A.270ml
B.360ml
C.320ml
D.390ml
Cu8: Cho hn hp gm 2 kim loi Mg va Al tc dng vi dung dch HNO3
2M(ly d 20% so vi lng cn thit ), thu c 1.12 lit hn hp NO v
N2O (kc , khng c sn phm kh no khc ) c t khi so vi H2 l 17.8
.Tnh th tch dung dch HNO3 ly:
A.192ml
B.200ml
C.160ml
D.133ml
Cu9: t chy hon ton 15 gam hn hp gm Al v Mg thu c 26.2 g
hn hp Y.Tnh th tch dung dch hn hp HCl 2 M va H2SO4 1.5 M cn
dng ho tan va ht hn hp Y:
A.140ml
B.280ml
C.70ml
D.210ml

Cu10: Ho tan h hp X gm 0.1 mol MgO; 0.2 mol FeO v 0.3 mol Ag2O
bng dung dch HNO3 d , thu c dung dch ri nung n khi lng
khng i . Xc nh khi lng cht rn thu c sau khi nung:
A.88.0g
B.89.6g
C.84.8g
D.87.7g
PHN GII BI TP 110
Cu1: Ta c :
M
-ne-
Mn+ ( M(NO3)n)nNO3-=nx
x
-nx
n+x(in tch)
M

-ne-

Mn+ ( M(NO3)n) nNO3-=ny

y
-ny
n+y(in tch)
mMUI= mKL + mNO3-(to mui)
nNO3 = ne-(do kim loi nhng ) = ne- (do kim N+5 nhn)
N+5

+ 3e-
N+2
0.45
0.15
N+5 + 4e-
N+4
0.25
0.125
nNO3- to mui = 0.45+0.5 =0.95
m mui = 58 +62*0.95 = 116.9
Lu trong bi ny c th bm my tnh nhanh
c=(0.15*3+0.0625*8)*(14+16*3)+58=116.9g
(nNO3=ne
trao
i(cmt))
Cu2: Tng t cu 1 nhng nSO4=0.5ne trao i
V mui trung ho v in nn : 2nSO42- to mui = n in tch
dng=ne trao i
Cu3: nFe=0.15mol
Khi ta nung Fe th st nhng 1 s e- cho O2- .Sau khi cho hn hp Fe v
cc oxit vo HNO3 th Fe tip tc nhng 1 s e- cho N+5N+4
vy ta c nO2-=3*0.15-0.1=0.35molnO=0.35:2=0.175mol (s mol tng
ca Fe nhng -s mol ca N+5 nhn)
mhn hp=mFe+mO=8.4+0.175*16=11.2g
Cu4: mhn hp=mFe+mO
mui khan y l n Fe(NO3)3=0.6mol
nFe=0.6mol

tng t trn nO2-=0.6*3-0.2=1.6mol nO=1.6:2=0.8mol

(do
O2- -2e- O)
vy
m
hn
hp=
0.6*56+0.8*16=46.4g
0.16 0.8
Cu5: nSO2=0.4mol
Ta c : Fe nhng 1 s e cho O2- sau nhng tip cho S+6 +2e
S+4
gi s mol ca Fe l x v ca O l y ta c h:
56x+16y=49.6
x*3-y*2=0.4*2
gii ra ta c x=0.7;y=0.65 mFe2(SO4)3=0.7:2*400=140g
Bi ny cn c 1 cch gii khc kh hay
gi s ta coi l Fe nhng ht e- cho O tr thnh Fe3+ nh vy
mFe2O3=mX+mO=49.6+0.4*16=56g
nFe2O3=0.35mol
mFe2(SO4)3=0.7:2*400=140g
Cu6:
Ta c H2 + O H2O
0.5 0.05
Do mFe=3.04-0.05*16=2.24g=0.04mol
nSO2=(0.04*3-0.05*2):2=0.01molVSO2=0.01*22.4=0.224lt
Cu7:
t gi thit nFe=0.18mol;mO=12-10.08=1.92g nO=0.12mol
ta c ne- trao i =nNO3- to mui =0.18*3=0.54mol
nNO=(0.54-0.12*2):3=0.1mol(bo ton e-)
bo ton nguyn t Nta c nN (trong HNO3)=nN(trong mui)+nN(trong
NO)
nHNO3=0.54+0.1=0.64molVHNO3=0.64:2=0.32lt
Cu8:
Ta c n hn hp=0.05mol
s dng qui tc ng cho ta c
nNO: 30
8.4
3
35.6
nN2O:44
5.6
2
vy nNO=0.03mol
nN2O=0.02mol
ging nh bi trn ta c nHNO3(lt)l=0.03*3+0.02*8+0.03+0.02*2=0.32mol
vy th tch dung dch HNO3 cn ly l 0.32*120:100:2=0.192lt

Cu9:
Ta c : mO=26.2-15=11.2g nO=0.7mol
bn cht ca phn ng ny l 2H+
+O H2O
0.14 0.7
[H+]=(2+1.5*2)V=0.14
V=0.28
Cu10:
Ta c chui phn ng v sn phm cui cng to thnh nh sau:
MgO Mg(NO3)2
MgO
FeO Fe(NO3)3
Fe2O3
Ag2O AgNO3 Ag
p dng nh lut bo ton nguyn t ta c
nMgO=0.1mol
nFe2O3=0.5nFeO=0.1mol
nAg=2nAg2O=0.6mol

khi
lng
cht
rn
thu
c
sau
phn
ng
=0.1*40+0.1*160+0.6*108=84.8g
Cu11:Ho tan hon ton hn hp X gm 0.02 mol FeS2 va 0.03 mol FeS
bng dung dch H2SO4 c nng(d),kh thu c ch c SO2 .Tnh th tch
dung dch NaOH 1M ti thiu cn hp th ht lng kh SO2 thu c
trn.
A.570ml
B.140ml
C.285ml
D.280ml
Cu12: Cho m gam kim loai M tc dng va vi 150ml dung dch HNO 3
a M, thu c khi N2O ( sn phm kh duy nht ) v dung dch X. C cn
dung dch X , thu c (m+18.6)gam mui khan . Gi tr ca a l.
A.1.5
B.2
C.2.5
D.3
Cu13: Cho 100ml dung dch X cha AgNO3 v Cu(NO3)2 tc dng vi
hn hp bt Y gm 0.03 mol Al v 0.05 mol Fe. Sau khi phn ng hon ton
, lc , thu c 8.12 gam cht rn Z gm 3 kim loi .Cho Z tc dng vi
dung dch HCl d , thu c 0.672 lt H2(ktc).Tnh nng mol AgNO3
trong dung dch X.
A.0.3M
B.0.2M
C.0.9M
D.0.5M
Cu14: Trn 2.7 gam Al vi 20 gam hn hp Fe 2O3, v Fe3O4 ri tin hnh
phn ng nhit nhm , thu c hn hp X.Ho tan X trong dung dch
HNO3 c nng d thu c 0.36 mol NO2 (l sn phm kh duy
nht ).Xc nh khi lng Fe2O3 trong hn hp ban u .
A.6.08g
B.16.36g C.10.72g D.1.44g

Cu15: Tin hnh in phn 200ml dung dch hn hp AgNO3 v

Cu(NO3)2 n khi c kh thot ra 2 in cc th ngng in phn ,thu
c 4.48 lt kh(kc) anot v khi lng catot tng 56 gam .Tng nng
ca 2 mui trong dung dch ban u .
A.2M
B.3M
C.1M
D.2.5M
Cu16: Cho 14.3 gam hn hp Al , Mg , Zn tc dng vi dung dch H 2SO4
long d , thu c 11.2 lt kh (kc).C cn dung dch sau phn ng , khi
lng mui khan thu c l
A.110.3g B.23.9g
C.38.3g
D.62.3g
Cu17: Ho tan hon ton hn hp 2 kim loi bng dung dch HCl d , thu
c dung dch A v V lt kh B (kc).C cn dung dch A thu c 5.71
gam mui khan .Xc nh gi tr ca V.
A.448ml
B.224ml
C.112ml
D.336ml
Cu18: t chy ht 17.4 gam hn hp Al,Fe,Cu thu c 25.4 gam hn
hp X gm 3 oxit .Cho hn hp tc dng vi dung dch HCl d ,c cn dung
dch sau phn ng ,lng mui khan thu c l .
A.35.15g B.26.275g C.52.9g
D.42.8g
Cu19: Cho 24.12 gam hn hp X gm CuO,Fe2O3,Al2O3 tc dng v
vi 350ml dung dch HNO3 4M, c cn dung dch sau phn ng .Xc nh
khi lng mui khan thu c .
A.99.72gamB.86.84gam C.76.34gam D.112.32gam
Cu20: Cho hn hp X gm 1 kim loi kim v 1 kim loi kim th tc
dng ht vi nc ,thu c dung dch Y v 3.36 lt kh H 2(kc) .Cho dung
dch Y tc dng vi 100ml dung dch AlCl 3 0.8M , thu c kt ta Z.Nung
kt ta Z thu c m gam cht rn khan.Gi tr ca m l .
A.2.04
B.1.02
C.4.08
D.0.0
PHN GII BI TP 1020
Cu11:
Ta c FeS2 -11e 2S4+
+Fe3+
0.02 0.22
FeS -7e S4+
+Fe3+
0.3 0.21
Ta c e nhng =0.43 mol
s mol S do H2SO4 to thnh
S+6 +2e S+4
0.43
0.125
vy s mol SO2 to thnh =s mol S do H2SO4 to thnh +s mol lu
hunh do (FeS2;FeS) to thnh=0.125+0.02*2+0.03=0.285mol
Do lng NaOH cn dng l ti thiu nn phi to thnh mui axit

NaOH
+
SO2
NaHSO3
0.285

0.285
Cu12:
Ta c m NO3- to mui=18.6:62=0.3 mol
ne- trao i = nNO3- to mui=0.3 mol
N+5 +4e N+4
0.3
0.075
n HNO3 phn ng =n NO3-to mui +nN(N2O)=0.3+0.075=0.375mol
a =0.375:0.15=2.5
Cu13:
Sau phn ng thu c cht rn gm 3 kim loi nn Al ht v Fe cn d
nH2=0.03 mol n Fe = 0.03 mol ( sau phn ng ch cn Fe phn ng vi
HCl)
vy khi lng ca Ag v Cu trong cht rn sau phn ng =8.12-0.03*56=
6.44gam
gi s mol ca AgNO3 l x v ca Cu(NO3)2 l y
ta c h
x+2y=0.03*3+0.02*2(bo ton e- s mol ca kim loi cho=n
ion kim loi nhn)
108x+64y=6.44
x=0.03mol ; y=0.05 mol M=0.3
Cu14:
Sau phn ng ta thu c Fe3+ v Al3+ , nh vy s mol e do N+5 nhn
tr thnh N+4 l do Al v Fe2+ cho(hn hp ban u ch c FeO v Fe2O3)
N+5 +1e N+4
0.36 0.36
Ta c 3*0.1+x=0.36(vi x l s mol ca FeO)
x= 0.06 molm FeO=0.06*72=4.32 gam
m Fe2O3 = 20-4.32=15.68 gam
Cu 15:
Lu : trong phn ng in phn c cng thc tnh ne- trao i
N=It:96500
Th t cc phn ng xy ra nh sau:

Catot :
Anot :
Ag+
+1e
Ag
2H2O
4H+ + O2
+ 4e
x
x
x
0.2
0.8
Cu2+
+ 2e Cu
y
2y
y
Sau nc in phn nu c
da vo iu kin bi ton ta c h
x+2y =0.8 (trong bnh in phn th s mol e trao i 2 in cc l =
nhau)
108x + 64y = 56
gii ta c x= 0.4 , y = 0.2
a= 0.6:0.2=3M
Cu 16:
S dng nh lut bo ton nguyn t ta c nH2=nH2SO4 =nSO42=11.2:22.4=0.5 mol
m mui khan= m kim loi +m SO42- = 14.3 + 0.5*96=62.3gam
Cu17:
M mui khan =m kim loi + m Clm Cl-=5.71-5=0.71gam=0.02 mol
S dng nh lut bo ton nguyn t ta c nH2 thot ra=0.5n HCl=0.5n Cl=0.01 mol
V=0.01*22.4=0.224 lt
Cu 18 :
mO=25.4-17.4=8gam = 0.5 mol
nhn thy khi tc dng vi dung dch HCl th nguyn t O b thay th
bi Cl-, m in tch O2- =2 Cl- n Otrong mui =0.5 n Cl (pp nh
gi tng ng)
n Cl-=0.5*2=1 mol m mui khan thu c=17.4+35.5=52.9 gam
Cu19:
Tng t cu 18 vi thay th O2-=NO3Cu20:
Ta c X
+ NaOH
XOH
+ H2
Y

+2NaOH

Y(OH)2 +H2
t ptp ta thy rng nOH-=nH+
nOH-=2nH2=3.36:22.4*2=0.3mol
Y tc dng vi dung dch AlCl th th t cc phn ng xy ra nh sau

Al3+ + 3OH0.08
0.3
0.08
0.24
0
0.06

Al(OH)3
B
0
P
0.08
D
0.08
Al(OH)3
+ OH Al(OH)4B 0.08
0.06
0
P 0.06
0.06
0.06
D 0.02
0
0.06
Sau khi nung Al(OH)3 Al2O3
0.02
0.01
m cht rn = 0.01*102=1.02 gam
Cu 21: Dn kh CO qua ng s ng 24 gam hn hp Al2O3,CuO, v
Fe3O4 nung nng, thu c m gam cht rn X v hn hp kh Y .Dn hn
hp kh Y qua bnh ng nc vi trong d , thu c 10gam cht rn .Xc
nh gi tr ca m.
A.20.8
B.16.8
C.22.4
D.12.0
Cu22 : Nung m gam hn hp X gm 2 mui MCO 3 v XCO3 , sau mt
thi gian thu c 3.36 lt kh (kc) v cht rn Y.Cho Y tc dng vi dung
dch HCl d , thu c 3.36 lt kh (kc).C cn dung dch sau phn ng ,
thu c 32.5 gam mui khan .Gi tr ca m l.
A.35.8
B.34.15
C.30.85
D.29.2
Cu 23: Cho 43 gam hn hp BaCl2 v CaCl2 vo 100 ml dung dch hn
hp Na2CO3 1M v (NH4)CO3 2.5M .Sau khi phn ng hon ton , thu
c 39.7 gam kt ta v 100ml dung dch X.Nng ca ion CO32- trong
dung dch X l.
A.0.5M
B.3M
C.3.5M
D.2M
Cu24: X l qung hemantit cha 60 % Fe2O3 v Y l qung manhetit cha
69.6 % Fe3O4 (v khi lng ). Trn a kg qung X vi b gam qung Y , thu
c 1 tn qung Z. T Z sn xut c 500 kg gang cha 96 % st .Xc
nh a.
A.400
B.600
C.714.3
D.285.7
Cu25: Cho 4.04 gam hn hp X gm Fe, FeO v Fe3O4 tc dng vi dung
dch HNO3 d , thu c 336 ml kh NO (kc) sn phm kh duy nht . S
mol HNO3 tham gia phn ng l .
A.0.06
B.0.015
C.0.18
D.0.055
Cu26: Tnh s mol HNO3 trong dung dch HNO3 ti thiu cn dng ho
tan ht 3.36 gam Fe. Bit phn ng to sn phm kh duy nht l NO.
A.0.24
B.0.18
C.0.20
D.0.16

Cu 27: Ho tan hon ton 11.8 ham hn hp Al v Cu bng dung dch hn

hp HNO3 v H2SO4 d , thu c 13.44 lt hn hp kh SO2 v NO2 (kc)
c t khi so vi H2 l 26.C cn dung dch sau phn ng , thu c m gam
cht rn khan v ch cha mui sunfat.Xc nh gi tr ca m.
A.55.6
B.50.2
C.165.4
D.88.6
Cu 28: Dn 2.24 lt kh CO2 (kc) vo bnh ng 1 lt hn hp Ca(OH) 2
0.05 M v NaOH 0.04 M . Tnh khi lng kt ta thu c .
A.5.0g
B.4.0g
C.7.0g
D.3.0g
Cu 29 : Cho 32.8 gam hn hp gm FeS v FeS2 tc dng vi dung dch
H2SO4 c nng , d .Sau phn ng thu c 1.95 mol SO2. Xc nh %
khi lng FeS trong hn hp X.
A.40.24% B.55.36% C.26.83% D.67.07%
Cu 30: Cho hn hp gm 14.4 gam Mg v 10.08 gam Al tc dng va
vi hn hp X gm Cl2 va O2, thu c 66.4 gam cht rn .% khi lng Cl2
trong hn hp X l .
A.68.9% B.50.0%
C.40.3%
D.62.5%
Cu 31: Cho 50 gam CaCO3 tc dng va vi dung dch HCl 20% .Nng
% ca dung dch thu c l:
A.52.7%
B.26.4% C.23.9%
D.39.3%
Cu 32: Sau khi ozon ho mt lng kh oxi, a bnh v nhit ban u
th p sut gim 5% so vi p sut ban u .Thnh phn % th tch ca ozon
trong hn hp sau phn ng l :
A.10.5% B.10.0%
C.5%
D.95.0%
Cu 33 : Hn hp X gm 2 kim loi A,B c ho tr khng i .Cho m gam
X tc dng vi dung dch HCl d , to ra 1.792 lt H2 (kc).Mt khc, t
chy hon ton m gam hn hp X trong oxi d , thu c 2.84 gam hn hp
oxit, xc nh gi tr ca m.
A.2.52
B.2.2
C.1.56
D.1.8
Cu 34: Ho tan 20 gam hn hp 2 mui cacbonat kim loi ho tri 2 v 3
bng dung dch HCl d , thu c dung dch A v 1.344 lt kh CO 2
(kc).C cn dung dch A th khi lng mui khan thu c l
A.18.53g B.21.32g C.24.26g D.20.66g
Cu 35: Cho 19.2 gam Cu tc dng vi 200ml dung dch hn hp NaNO3
2M v H2SO41.5M n khi phn ng hon ton , thu c V lt kh
NO(kc) l sn phm kh duy nht .Xc nh gi tr ca V
A.4.48
B.3.36
C.8.96
D.2.24
Cu36: X l hn hp gm 2 kim loi c ho tr khng i .t chy 1.24
gam hn hp X, thu c 1.56 gam hn hp 2 oxit.Mt khc , ho tan hon

ton 1.24 gam hn hp X bng dung dch HCl d , thu c V lt H2( kc).
Gi tr ca V l.
A.0.896
B.1.792
C.0224
D.0.448
Cu 37: in phn 200 ml dung dch hn hp AgNO3 0.1M v Cu(NO3)2
0.2M vi cng dng in l 10A (in cc tr) .Sau mt thi gian , khi
lng catot tng 3.44 gam.Tnh thi gian in phn.
A.579giy B.386giy C.965giy D.193giy
Cu 38: Cho 1.12 gam bt st v 0.24 gam bt Mg vo mt bnh ng sn
250ml dung dch CuSO4 ri khuy k n khi phn ng kt thc .Khi cc
phn ng xy ra hon ton , khi lng kim loi c trong bnh l 1.88
gam.Vy nng ban u ca dung dch CuSO4 bng .
A.0.15M
B.0.10M
C.0.05M
D.0.20M
Cu 39: Ho tan hon ton hn hp gm a mol FeS 2 v 0.12 mol Cu2S
bng dung dch HNO3 va ,thu c dung dch ch cha 2 mui
sunfat.Gi tr ca a l
A.0.06
B.0.12
C.0.24
D.0.18
Cu40: Cho mt lung CO i qua ng s ng 0.04 mol hn hp X gm
FeO v Fe2O3
t nng .Sau khi kt thc th nghim ta thu c cht rn Y gm 4 cht
,nng 4.784 gam.Khi i ra khi ng s cho hp th vo dung dch Ba(OH) 2
d, th thu c 9.062 gam kt ta .S mol FeO trong X bng
A.0.01 mol B.0.02 mol C.0.025 mol D.0.03 mol
PHN GII BI TP 2140
Cu21 : ta c CO + O CO2 (1)
0.1 0.1
CO2 + Ca(OH)2 CaCO3 +H2O (v Ca(OH)2 d nn ch
to mui trung ho )
0.1
0.1
T (1) m cht rn = 24-0.1*16=22.4gam
Cu22 : ta c MCO3
MO
HCl
MCl2
to
MCO3 d
CO2
CO2
nCO32- = n CO2 = 0.15+0.15=0.2
1 mol MCO3
1 mol Cl2 : m =71-60= 11 gam
0.3 mol m=11*0.3=3.3 gam .vy m = 32.5 3.3 = 29.2 gam

Cu 23: tng t bi tp trn s dng pp tng gim khi lng :

n CO32- ban u = 0.35 mol n CO32- phn ng = (43-39.7 ):( 11*(7160))=0.3 mol
vy n CO32- d = 0.05 mol a= 0.05:0.1=0.5 M
Cu 24 : trong 1 tn qung a c 1*0.6*112:160=0.42 tn Fe
Trong 1 tn qung b c 0.504 tn Fe
Z c 500*96:100= 480kg = 0.48 tn Fe
p dng s ng cho :
m a: 0.42
0.024 2
0.48
m b:0.504
0.06 5
vy m a =1:7*2=0.2857 tn = 285.7 kg
Cu 24: coi nh hn hp ban u gm Fe v O da vo gi tr ta c h
56x + 16y = 4.04
3x - 2y = 0.045
x= 0.055 , y=0.06
n HNO3 = n NO3- trong mui + n N trong NO=0.055*3 + 0.015=0.18 mol
Cu 26: v HNO3 cn dng ti thiu to thnh mui Fe2+
Ptp :
3Fe + 8HNO3 3Fe(NO3)2 +
2NO
+ 4H2O
0.06
0.16
Cu 27:
n SO2 = 0.2 mol
n NO2 = 0.4 mol
S+6 + 2e- S+4
0.4
0.2
N+5
+ 1e- N+4
0.4
0.4
ne- 0.8 mol N SO42- to mui = 0.8:2=0.4 mol
m mui = 11.8 +96* 0.4= 50.2 gam
Cu 28: n CO2 = 0.1 mol
n OH- = 0.14 mol
CO2 + 2OH0.07
0.14

CO32- + H2O
0.07

D 0.03
CO32-

+ CO2
0.03

+ H2O 2 HCO3-

0.03
D0.04
Ca2+ + CO32 CaCO3
0.05
0.04
0.04
vy m kt ta=0.04*100= 4 gam
Cu 29:
FeS
-7e S4+
+Fe3+
x
7x
FeS2-11e 2S4+
+Fe3+
y
11y
S+6 + 2e

S+4
7x +11y
( 7x +11y) ( bo ton e)(s mol SO 2 do H2SO4
to thnh
vy ta c h:
x + 2y + ( 7x +11y) = 1.95 ( SO2 do c H2SO4 v FeS2 , FeS to
thnh)
88x +120y = 32.8
x=0.1 , y= 0.2
% FeS = 0.2*88:32.8% = 53.66 %
Cu 30: Mg2+
+ 2e
0.6
1.2
Al
+ 3e
0.4
0.12
Cl2
+2e
x
2x
O2
+4e
y
4y
T k bi ton ta c h
2x + 4y = 2.4
71x + 32y = 66.4-(14.4 + 10.8)
x = 0.4, y = 0.4
m Cl2 = 0.4*71 =28.4 %m Cl2 trong hn hp X=68.9%
Cu 31: CaCO3 + 2HCl CaCl2 + H2O + CO2
0.5
1
0.5
0.5
m dung dch sau phn ng = m dung dch trc phn ng m kt ta

m bay hi
vy m dung dch sau phn ng trong bi ton ny = 50 + 36.5*100:200.5*44=210.5 gam
vy nng % ca dung dch thu c = 0.5*111:210.5= 26.4 %
Cu 32:
3O2 2O3
3x
2x
gi s n O2 ban u l 100 ml n = 3x 2x = x =5 ml
% sau phn ng = 10: 95 = 10.5 %
Cu 33: pp nh gi tng ng :
AClx A2Ox
BClx B2Ox
2Ta thy n Cl- = 2 n O (cng 1 lng A, B )
Ta c n H2 = 2n HCl = 2n Cl- n Cl- =0.08*2=0.16mol n O trong hp
cht =0.08 mol m A, B = 2.84 0.08*16=1.56gam
Cu 34: tng t bi tp trn nhng thay th CO3 2- = Cl- m bo
mui trung ho v in th n Cl- =2 n CO32Cu 35: phng trnh phn ng
2
3Cu
+ 8H+
+ 2NO3 3Cu + + 2NO
+ 4H2O
0.3
0.6
0.4
0.15
Cu 36:tong t cc cu trn dng pp nh gi tng ng
Cu 37: nh th t cc p xy ra
Cu 38:th t cc phn ng xy ra
Mg
+ CuSO4 MgSO4 + Cu
0.01
0.01
0.01
Fe
+ CuSO4 FeSO4 + Cu
0.015
0.015
gi s Mg phn ng va ht Fe cha ht mkl = 1.12 +64*0.01=1.76 <
1.88 c Fe phn ng
1mol Fe 1molCu tng 8 gam
n Fe phn ng = (1.88 1.76):8 = 0.015 mol
vy n CuSO4 = 0.025 mol [CuSO4] = 0.1 M
Cu 39:FeS2 FeSO4
a
a
( bo ton nguyn t Fe)
Cu2S CuSO4
b
2b
( bo ton nguyn t Cu)

bo ton nguyn t lu hunh

2a + b = a + 2b ( vi b=0.12 mol ) a=
Cu 40: ta c n Ba(OH)2= 0.046 mol n CO2 coi hn hp X ch gm FeO
v Fe2O3
x + y = 0.04
72x + 160y = 4.784+0.046*16
x= 0.01 mol , y = 0.03 mol
Cu 41: Ha tan hon ton 30.4gam hn hp gm Cu, CuS, Cu2S, S vo
HNO3 thu c kh 20,16 lit kh NO duy nht (kc), v hn hp y. Ha tan
hon ton hn hp Y vo Ba(OH)2 thu c m gam kt ta.Tnh m?
Gii:
64x + 96y + 160z + 32k =30.4
2x + 8y + 10z + 6k = 0.9*3
2x + 3y + 5z + k =0.95

2x + 8y + 10z + 6k = 0.9*3

T ta tm c y + z + k = ly 2 -1
=n BaSO4 = n Cu(OH)2
Lu cu ny gii bng phng php qui i nhanh hn
Cu 42: Crackinh C4H10 thu c 5 hidrocacbon c M=232/7. Tnh hiu
sut?
Ly 1 mol
Gi s mol
phn ng l a
=> n kh sau p l 1 + a
=> 58/(1+a) = 232/7 => a = 0.75
=> %H = 75%
Cu 43
Thi hi nc qua than nng thu c X ( ,
,
2) cho X qua dung
dch
th thu c Y( ,
). Mt lng Y tc dng va ht vi
8.96g
to thnh 1.26g nc. Tnh V% CO_2 trong X
cu 44

Ha tan hon ton 20g X(

,
bng
long d to V lt
kh v dd Y. Thm NaOH d vo Y, lc kt ta nung trong kk n khi
lng khng i c 28g rn. Tm V?
Cu 45: Cho 8g Ca tan hon ton trong 200 ml dung dch hh
2M vs
0.75M thu dc kh v dung dch X. c cn dung dch X dc lng
mui khan l:
A 22.2g
B.25.95g
C.22.2g<= m<=25.95g
D. 22.2g<=m<=27.2g
Gii: Theo bi ra ta c
v
Theo phng trnh trn ta nhn thy rng axit cn d v kim loi phn ng
ht. Khi trong dung dch s c cc ion sau:
Khi un nng dung dch sau phn ng th HCl s b bay hi, khi th trong
dung dch s cn li c:
Ta nhn thy rng n va ng theo nh lut bo ton in tch:
vy khi lng ca mui => 25,95 gam
Lu cch gii sai:
Gi s Ca p vi HCl ht trc
Ca+ 2HCl =>
+
0.2----0.4--------0.2
HCl p va ==> m mui=22.2
Ca p vi
ht trc
Ca+
=>
+
0.15-------------------0.15
Ca + 2HCl =>
+
0.05---0.1----------0.05
HCl d ==> m mui=25.95
vy 22.2 =< m =< 25.95
Cu 46: cho m gam Fe vo 0,2l dd X cha HNO3 0,2M v H2SO4 0,1M sau
phn ng cn 0,4m gam kim loi cha tan ht, dd Y v kh NO c cn dd Y
thu c a gam cht rn. tm m v a

Gii:
3Fe +8H+ +2NO3- =>3Fe2+ +2NO+4H2O
0,03...0,08............................0,02
=>0,6m=1,68g=>m=2,8g
=>trong dung dch gm c N03-=0,02mol,SO42-=0,02mol,Fe2+=0,03mol
=>khi lng mui=62.0,02+96.0,02+1,68=4,84g
Cu 47:
1) Hn hp A gm O2 v O3 c t khi so vi hiro l 19,2. Hn hp B gm
H2 v CO . Tnh
th tch kh A (ktc) cn dng t chy hon ton 3 mol kh B.
A. 28 lit B. 22,4 lit C. 16,8 lt D. 9,318 lit
Hng dn gii

Cu 48:
ha tan ht mt mu Al trong dung dch axit HCl 30 C cn 20 pht.
Cng mu Al tan ht trong dung dch axit ni trn 50 trong 5 pht.
ha tan ht mu Al trong dung dch ni trn 80 C th cn thi
gian l:
A:30
B:187.5
C:44,6
D:37,5
Hng dn gii:

Ta c 20=Vo.a((30-t1)/10) (1)
5 =Vo.a((50-t1)/10) (2)
ly (1) chia cho (2) ta tnh c a = 0.5
gi x l thi gian cn tm
x = Vo.a((80-t1)/10)
lp t s vi (1) hoc (2) ta tnh c x = 0.625 pht = 37.5s
Cu 49:
Cu 20: Ho tan a gam oleum H2SO4.3SO3 vo 131gam dung dch H2SO4
40% thu c mt oleum cha 10% SO3 v khi lng. Gi tr ca a l
A. 630,0
B. 570,8
C. 594,0
D. 651,4
Hng dn gii:
n H2O = 131/30 mol
((3.a/338-131/30)*80)/(a+131)=0.1
gii thch t:
3a/338 = s mol ca SO3 trong H2SO4.3SO3
(3.a/338-131/30) = s mol SO3 cn li sau khi phn ng vi nc vi s mol
nc tnh = 131/30
khi lng ca dd sau p = a + 131 (bo ton khi lng)