5 5 \ ‘\ X x YAK 621,791.92. $546,741.06 : 006.354 Tpynna B09 TOCYMAPCTBEHHB A CTAHMRAPT COW3A CCP a rOctT 11930.5—79* Hard-facing materials. 7 Methods of manganese determination roc hip idaede B uacTH pasa. 3 MATEPHASIbI HATJSIABOYHBIE Meropbi onpegenenna apranya OKCTY 1709 Nocranosneunem [ocyaapcrsenHoro Komureta CCCP no cranqapram or 21 mapta 1979 r. Ne 982 cpok sRefeRNA ycraHoBnen ¢ 01.07.80 Mponepen s 1984 r. Moctatosnennem Foccraupapta or 13.12.84 Ne 4262 ¢pok Aedicrana npoanen Ro 01.07.90 Heco6niogenne crangapra mpecnepyerca no 3aKoHy Hactoamuit crafapT yctTavapnupaet oToKosopuMerpuyuecknii MeTOL ONpeeneHuaA Mapranila (pH Maccopol oe Mapranua oT 0,4 Ho 4%) 4 oGnemupiit Merox onpegereHya Mapranya (npH maccoBoit one Mapranua oT 6 go 85%) B HanaaBoUHbIx MaTepHaaax, 4. OBLIWE TPEBOBAHHA 1.1. OOujwe tpeGopanna xK MeTOnam ataausa — mo TOCT 11930.0—79. Sy 2, DOTOKONOPHMETPAYECKMA METOX OMPEAENEHKA MAPFAHUA ‘2.1. CymtHocTp Metona 7 Metoa mpeHasHayed Jun aHalv3a MpyTKOB 2aA HalllaBKu Ma- pox: IIp-C27, Mp-Cl, Ip-C2, Mp-B3K-P no TOCT 21449—-75, no- POWKOB 43 CN1aBOB AWA HansaBKH Mapok: IIT-C27, Ml-Cl, MIl-YC25, NI-@BX6-2, NIT-AH1 no TOCT 21448—75. Merog ocHoBaH Ha OKHCeHHH MapraHua B cepHotbocopHoKncaoa cpeqe NepHO_uTOM Kalua AO MapraHlleBol KHCMOTH, MHTEHCHBHOCTD OKpackH KOTOpOi H3MepsIOT Ha oTOSMeKTpoKOTOpuMeTpe. 22, Anmnmapatypa, peakTHBh H pacTBOph @otoanextpoxoiopuMerp Tunop ®SK-56, PIK-56M nau mo6oro apyroro tuna. . Kucnota cepHaa no TOCT 4204—77, pasOapnennaa 1:1 a 1:4. Viaganne odmunanbioe Tepeneyarxa socnpewena. * Mepeusdanue (anaapo 1986 2.) ¢ Hamenenuem NM 1, yraepxdennsin @ GekaGpe 1984 2. (HVC 385). 26TOCT 11930.5—79 Crp. 2 Kucaota oproocpopuasx no TOCT 6552—80. Kamit fognoKucabiit. Kucnora cenenuctan no TOCT 11081—75, 2%-nnii pacrsop. Mapraneu, Meranauyeckuli 10 TOCT 6008—82. CraufapTHbiit pacrBop Maprailla; roToBaT cjiezyiuluM O6pasom: 0,1 r Merasmmueckoro MapraHiia pacTBopaioT B 25 cM® a30THOM KH- cnoThl, pasOaBrennoh 1:1, KHNATAT oO yaseHua’ OxHCOB asoTa H TlepeHocst B MepHyl0 KonGy BMectTuMocTbio 1000 cm*. PactBop pa3- 6aBAAWT BOAO HO MeTKH M NepemMeliMBaicT. 1 em? pacrsopa cogepxut 0,0001 r mapranua. 2.3. [popemenue ananusa 2.3.1. Mapranen onpezersioT B @uAbTpaTe Mocae OTAeTeHHA KPeM- nus no TOCT 11930.3—79. V3 mepxoi Kon6i1 BMectumoctpio 200 cm? oT6upair or 5 2O 50cm® anaiH3HpyeMoro pacTBOpa (B 3aBHCHMOCTH OT coxepxKaHHA Maprawua) B cTakaH BMecTaMocTbIO 100 cm’, no6aBanior cepHyl0 KHcaoTy (c TaKHM pacueTOM, 4TOGE OKpalenHbiit pacTBop 6bI1 2—3%-nEIM lo cepHoi KucaoTe), 1 cm? dociopHo KucHoTH, 0,5 Fr fionwoKucroro Kanna. ConepxKuMoe KoNOpl pasOaBasioT no 50 cM? JMCTHIMpOBaHHOK BOLO H HarpeBaior no Kunenua. Topaani pact- BOP OcTaBaAnoT Ha 30 MHH Ha TemJOll MWTKe MO NoAHOrO pasBHTHA oxpackH. OxaaxfexHbili pactBop mepenocaT B Mepnyio KoN6y BMe- cTuMocTbO 100 cm’, pas6aBIAOT AHMCTHIMPOBaHHOK BOLO AO MeTKH, MepeMeluBaloT H U3MepHIOT ONTHYECKYIO IIOTHOCTh OkpallleHHoroO PacTBopa Ha (oTOsTeKTpoKONOpHMeTpe Cc 3eTeHbIM CBeTOpHAD- tpom (4=490 uM) B xKloBeTe Cc TOAMLMHO! mornoujatourerq cron 50 MM. [na npuroTopmeHia pacTBopa cpaBHeHist HCnO/b3yI0T COOTBETCTBYIOULYIO YaCTb HccyeL_yemMoro pacTBOpa, B KOTOpoM Majp- TaHuoBy!0 KHCIOTY BOCCTaHaBlMBaloT npHOaBrenHem (pH mMepeMe- WHBaHHH) HeCKOJbKHX Kaleb pacTBopa cejenucTOl KHCAOTDI. 2.3.2. [ocrpoenue epadyuposounozo epaduka B math MepHbix KOw6 BMecTHMocTHIO 10 100 cm? nomemawr |, 2, 3, 4, 5 cm? crangzapTHoro pacTBopa Mapranua, 2—3 cm* cepHoii KHC- OTH H asec aHaHs BesyT, Kak ykasaHo BM. 2.3.1. 24. O6pa6oTKa pesyabTaToB 2.4.1. Maccosyio omo Mapranua (X) B MpoleHTax BEIYHCIAIOT WO opmyvie xa. 200- 100 mV , rie m— acca Maprauua, Haliqenvaa no rpaayupopownomy rpadi- Ky, Ty m,— Macca Hapecky, Tr; — aJIMKBOTHAA UaCTb aHasIM3upyeMoro pacTBopa, cM’. 27Crp. 3 FOCT 11930.5—79 2.4.2. A6comorTHBe JomyckaeMble pacxoxKsenua pesyAbTaToB Ma- PaJJeNbHBIX ONpedeTeHH MPH AOBepHTeTbHO BepoatHocTH P=0,95 He JOMKHM OpeBbilaTh 3HayeHHit, yKasaHHbIx B Taba. 1. Ta6auua 1 AGcomoTaue zonycKaeune Maccosas foam mapranua, % packomkreuna, Or 0,4 a0 1,5 0,05 Ce. 1,5 20 4,0 0,10 3. OBBEMHBIM METOA ONPEAENIEHKA COAEPKAHHA MAP AHA 3.1. CymHocTbh MeTOna Metoy npeqvasnayen Ja aHamH3a CMeCH NOpoliKOB Aa HanmaB- ku MapkH C-2M mo TOCT 11546—75. Metox ocHoBaH Ha OKHCNeHHM MapraHla MO ceMMBaeHTHOTO ¢ TocaeayiouLiM THTPOBaHHeM ero pacTBopom cou Mopa. Xpom mpea- BapHTeIbHO OTACAHOT OKHCbIO WHHKa. 3.2. PeaxTuBbl H pacTBOpbl yKasaHB BM. 2.2 c AONOTHeHHEM: Kouro Kpacupiii. Iuka ouch no TOCT 10262—73, ssmyyennyio B Bowe OKHCb WHHKa FOTOBAT caegxyioulum o6pa3om: 20—25 r MeaKOW3MenbueHHOR OKHCH MHHKa pacTHpaloT B dapdopozolt crymke c 50 cm® ropsyelt (50—60°C) BogbI yo macToobpasHoro cocTOAHHA H MepenocaT B cTa- KaH BMecTHMOcTHIO 200 cm’, Zo6aBaaa eme 25 cm? son. Tepex npa- MeHEHHeEM CMeCb XOPOMO pasMelUBaIOT CTeKAAHHOM nano¥KoH AAA TIpHAanna ef ORHOPOLHOH KOHCHCTeHIMH. 3.3. TIpopeqenne anasusa Vis mepHoii Kon6u1 sMectumoctbio 200 cm? no FOCT 11930.3—79 or6upaioT B cTakaH oT 50 30 100 cm® aHaausupyemoro pacTBopa K BbITapHBaioT Jo 25 em’. Pacrsop Helitpanusyior no 6yMaxKKe KOHTO PacTBOPOM FHAPOOKHCH HaTpa AO Hayada BbilakeHuA OCasKa, KOTO- pail saTem pacTBopslor mpHOaBseHHemM HeCKOAbKHX Kame.lb CepHolt KHCHOTL, pas6apseHHo 1:4. PacTsop HarpeBalor 4o TeMNepaTypbr 65—70°C, nepeHocsT B MepHyio Koa6y BMecTuMocTbIO 100 cm? u mpH- JIMBaIOT. HEOONbUIMMH KOJHYeCTBAMH XOPOUIO BSMYYeHHyIO B BOE OKHCb QHHKA, TIWAaTeIbHO B3GaTHBaA KaKAbIit pas Coxep2xXHMOe KOA- Obl, NOKa Ha AHe KON6bI OKaxKeTcA HEOOAbIUON H3ObITOK OKHCH WHHKa. Conepxumoe Kon6n HarpeBalor 20 70—80°C H BbIqepAMBaloT B Te- uenne 5 MuH. SaTem pacTBOp OxJaxKAaloT, pasbaBrAOT BOOM NO MeT- Ku H nepemewmsaior. Pactsop dbusprpywr, or6upaior 50 cm’ B KOHH- yeckyio Ko6y BMecTHMOCTb10 250—300 cM°, HeliTpanu3yior cepHol KucHOTOH, pas6aBnenHon 1:4, H BBOMAT B U36EITOK 25 cm°. Tpu6as- 28