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2, Mt hp cht c cng thc phn t l C8H8O (X) v ph IR (hnh 1). Hy cho bit cng thc
cu to ca X. (tn hiu 3013 cm-1 l ca C-H bo ha)
Hnh 1
3, Dao ng chun l g? Tnh dao ng chun ca cc phn t HCHO, C2H2, CO2
4, Mt hp cht c cng thc phn t l C7H8O (X) v ph IR (hnh 1). Hy cho bit cng thc
cu to ca X.
5, Mt hp cht c cng thc phn t l C7H8O (X) v ph IR (hnh 1). Hy cho bit cng thc
cu to ca X.
6, Mt hp cht c cng thc phn t l C6H6O (X) v ph IR (hnh 1). Hy cho bit cng thc
cu to ca X.
7, Mt hp cht c cng thc phn t l C8H8O (X) v ph IR (hnh 1). Hy cho bit cng thc
cu to ca X. (tn hiu 3013 cm-1 l ca C-H bo ha)
Hnh 1
CH3
CH
CH3 8 17
CH
CH3 9 19
CH3
CH3
CH3
CH3
CH3COO
CH3COO
HO
CH3COO
CH3
CH3
O
O
C8H17
C8H17
CH3
CH3
2. Mt hp cht ha tan trong n-hexan c max=305 nm. Khi cng hp cht ha tan trong
etanol th c max=307 nm. Hp th ny gy nn bi bc chuyn n* hay *, gii thch.
3. Mt hp cht ha tan trong n-hexan c max=306 nm. Khi cng hp cht ha tan trong
etanol th c max=309 nm. Hp th ny gy nn bi bc chuyn n* hay *, gii thch.
4. i vi hp cht sau c bao nhiu nhm th gn vi lin kt i C=C, bao nhiu lin kt i
ngoi vng ca h lin hp. Cho bit n c cc bc chuyn di electron no?
c, CH3 C CH3
b, CH3CH2OH
d, CH2 CH CH2OH
O
Bi tp MS
1, Benzanamit (C6H5CONH2) c ph khi lng nh hnh 2, cho bit c ch phn mnh ca n.
Hnh 2
2, Phenyl metyl ete (Anisol), c ph MS nh hnh 2. Cho bit c ch phn mnh ca n.
Hnh 2
3, Hp cht Y c cng thc phn t l C7H8O. Khi bn ph Y bng chm electron (70 eV) thu
c cc mnh ph: m/z=93 (C6H5O+), 78 (C6H6+), 77 (C6H5+), v 65 (C5H5+). Cho bit cng
thc cu to ca Y v s phn mnh Y to thnh cc mnh ph trn.
4. Hp cht Y c cng thc phn t l C7H7ON. Khi bn ph Y bng chm electron (70 eV) thu
c cc mnh ph: m/z=105 (C6H5CO+), 77 (C6H5+) v 44 (CO=NH2+). Cho bit cng thc cu
to ca Y v s phn mnh Y to thnh cc mnh ph trn
Bi tp 1H-NMR
1. Tnh hng s J (Hz) ca mt tn hiu proton duplet c H=7,7135; 7,7295 ppm c o trn
my c tn s 500 MHz. Da vo dch chuyn ha hc cho bit proton trn l proton ca loi
hp cht no, hng s J c trng cho tng tc spin g.
2, Mt hp cht c cng thc phn t l C8H10 (X), c ph 1H-NMR (hnh 2). Cho bit cng thc
cu to ca X.
(Hnh 2)
6. Tnh hng s J (Hz) ca mt tn hiu proton duplet c H=7,7135; 7,7295 ppm c o trn
my c tn s 500 MHz. Da vo dch chuyn ha hc cho bit proton trn l proton ca loi
hp cht no, hng s J c trng cho tng tc spin g. Cho bit ngha ca hng s J
7, Trnh by c trng v ngha ca cc phng php ph HSQC v HMBC.
Ph X-ray
1. Cho bit cc thng tin thu c khi nghin cu vt liu bng phng php nhiu x tia X.
2. Cho bit ng dng ca phng php nhiu x tia X trong nghin cu kch thc ht ca vt
liu.
3. Trnh by ngn gn s hiu bit v qu trnh pht sinh tia X, cho bit tn cc ng dng trong
nghin cu vt liu bng nhiu x tia X.
Gii ph tng hp
1. Xc nh cu to ca hp cht c cng thc phn t C12H16O2, ph IR cho cc nh hp th
3000, 2950, 2850, 1666, 1600, 1500, 1260, 840 cm-1, ph 1H-NMR cho =1,4 (s); 3,8 (s); 6,9 (d)
v 7,8 (d) ppm, ph khi lng cho ion phn t M=192 dvC (hnh di).
6. Xc nh cng thc cu to ca hp cht c cng thc cng C8H14O4, ph hng ngoi cho
nh hp th mnh 1743, 1200 cm-1, ph 1H-NMR cho =1,2 (t); 2,4 (q); 4,4 (s) ppm, ph 13CNMR cho = 10; 30; 52 v 174 ppm, ph khi lng cho ion phn t M=174, ph UV khng
hp th trong vng ln hn 220 nm