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KI M TRA MN HO A HO C Th i gian: 60 phu t . M:113

Cu 1: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O 2, thu c 23,52 lt kh CO 2 v 18,9 gam H 2 O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (M y < M z ). Cc th tch kh u o iu kin tiu chun. T l a : b l A. 2 : 3 B. 4 : 3 C. 3 : 2 D. 3 : 5 Cu 2: Cho s phn ng : xuctac (a) X + H 2 O Y (b) Y + AgNO 3 + NH 3 + H 2 O amoni gluconat + Ag + NH 4 NO 3 xuctac (c) Y E + Z anh sang (d) Z + H 2 O X + G chat diepluc X, Y, Z ln lt l: A. Tinh bt, glucoz, etanol. C. Xenluloz, saccaroz, cacbon ioxit. B. Tinh bt, glucoz, cacbon ioxit. D. Xenluloz, fructoz, cacbon ioxit.

Cu 3: Este X c CTPT l C 7 H 12 O 4 . X tc dng vi NaOH un nng thu c mt mui c phn t khi 134 v 2 ancol Y,Z. S CTCT ca X l A.4 B.3 C.6 D.5 Cu 4: Hn hp A gm X, Y (MX < MY) l 2 este n chc c chung gc axit. un nng m gam A vi 400 ml dung dch KOH 1M d thu c dung dch B v (m - 12,6) gam hn hp hi gm 2 anehit no, n chc ng ng k tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn khan. % khi lng ca X trong A l: A. 54,66% B. 45,55% C. 36,44% D. 30,37% Cu 5: Phenol phn ng c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br 2, (CH3CO)2O, CH3COOH, Na, NaHCO3, CH3COCl: A. 4 B. 6 C. 5 D. 7 Cu 6: C bao nhiu cht c th phn ng vi axit fomic trong s cc cht sau: KOH, NH3, CaO, Mg, Cu, Na2CO3, Na2SO4, CH3OH, C6H5OH, AgNO3/NH3? A. 8 B. 9 C. 7 D. 6 Cu 7: Este X c CTPT C 5 H 8 O 2 khi tc dng vi NaOH to ra 2 sn phm u c kh nng tham gia phn ng trng gng. S cht X tha mn iu kin trn l: A. 2 B. 1 C. 3 D. 4 Cu 8: Thy phn 95,76g mantoz trong mi trng axit vi hiu sut phn ng t 75% thu c hn hp X. Trung ha hn hp X bng NaOH thu c hn hp Y. Cho Y tc dng vi dung dch AgNO3/NH3 d un nng thu c m gam Ag kt ta. Gi tr ca m l: A. 120,96 gam B. 60,48 gam C. 105,84 gam D. 90,72 gam Cu 9: Hp cht A c cng thc phn t C4H6Cl2O2. Cho 0,1 mol A tc dng va vi dung dch c cha 0,3 mol NaOH, thu c dung dch hn hp trong c hai cht hu c gm ancol etylic v cht hu c X, c cn dung dch sau phn ng thu c m gam cht rn khan. Khi lng m l: A. 9,6 gam B. 23,1 gam C. 11,4 gam D. 21,3 gam Cu 10: Cho mt s tnh cht: c v ngt (1), tan trong nc (2), tham gia phn ng trng bc (3), ha tan Cu(OH) 2 (4), lm mt mu dung dch brom (5), b thy phn trong dung dch axit khi un nng (6). Cc tnh cht ca fructoz l: A.(1), (2), (4), (6) B.(2), (3), (4), (5) C.(1), (3), (5), (6) D.(1), (2), (3), (4)

Cu 11: Cho m gam hn hp gm mt axit cacboxilic n chc X v mt este n chc Y tc dng hon ton vi 400 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c mt ancol Z v 26,8 gam hn hp rn khan gm hai cht c s mol bng nhau. Cho ton b ancol Z tc dng va vi Na thot ra 0,56 lt kh kc v c 3,4 gam mui to thnh. Y l: A. etyl acrylat. B. Metyl propipnat C.metyl acrylat. D. etyl axetat. Cu 12: Cho 0,15 mol este X tc dng ht vi dd NaOH thu c 21 gam mui. CTPT ca X l: A.C 4 H 6 O 2 B.C 5 H 8 O 2 C. C 4 H 8 O 2 D.C 7 H 14 O 2 Cu 13: Cho s : X
+ H 2 O, as clorophin Y + H, t Z + ,t T. Cho bit X, Y , T ln lt H 2 Ni,
+ o
o

l: A. kh cacbon oxit, tinh bt, sobitol. B. kh cacbonic, glucoz, sobitol. C.kh cacbonic, tinh bt, sobitol. D. kh cacbonic, tinh bt, ancol etilic Cu 14: C cc dung dch sau: (1) glucoz; (2) mantoz; (3) saccaroz; (4) axit axetic; (5) glixerol; (6) axetanehit. S dung dch ha tan Cu(OH)2 nhit thng? A. 6 B. 3 C. 5 D. 4 Cu 15: Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu c 6,72 lt kh CO 2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh H 2 (ktc). Gi tr ca V l A. 3,36 B. 11,20 C. 5,60 D. 6,72 Cu 16: Oxi ha 0,08 mol mt ancol n chc, thu c hn hp X gm mt axit cacboxylic, mt anehit, ancol d v nc. Ngng t ton b X ri chia lm hai phn bng nhau. Phn mt cho tc dng ht vi Na d, thu c 0,504 lt kh H 2 (ktc). Phn hai cho phn ng trng bc hon ton thu c 9,72 gam Ag. Phn trm khi lng ancol b oxi ha l A. 50,00% B. 62,50% C. 31,25% D. 40,00% Cu 17: un nng m gam hn hp X gm cc cht c cng mt loi nhm chc vi 600 ml dung dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit cacboxylic n chc v 15,4 gam hi Z gm cc ancol. Cho ton b Z tc dng vi Na d, thu c 5,04 lt kh H 2 (ktc). C cn dung dch Y, nung nng cht rn thu c vi CaO cho n khi phn ng xy ra hon ton, thu c 7,2 gam mt cht kh. Gi tr ca m l A. 40,60 B. 22,60 C. 34,30 D. 34,51 Cu 18: Co bao nhieu hp chat thm co CTPT C 8 H 10 O tac dung c Na va b oxi hoa vi CuO tao san pham trang gng c: A.4 B.2 C.3 D.5. Cu 19: Hn hp X gm axit panmitic, axit oleic, axit linoleic. t chy hon ton m gam X th thu c 15,68 lt kh CO 2 (ktc) v 11,88 gam H 2 O. Nu hi ro ha hon ton m gam X th cn dng V lt H2 (kc). Gi tr ca V l: A.0,448 B.0,896 C.0,112 D.0,672 Cu 20: Hn hp A gm 3este n chc, to thnh t mt ancol B vi 3 axit hu c trong c hai axit no l ng ng k tip nhau v 1 axit khng no cha 1 lin kt i( mch phn nhnh). X phng ha m gam hh A bng dd NaOH, thu c hn hp mui v p gam ancol B. Cho p gam ancol B vo bnh ng Na d, sau phn ng c 2,24 lt kh thot ra v khi lng bnh ng Na tng 6,2 gam. Mc khc t chy hon ton m gam A thu c 13,44 lt CO 2 v 9,9 gam H 2 O. Phn trm khi lng ca este c khi lng nh nht trong hn hp A l: A.40,82 B. 50,32 C. 41,28 D. 38,46 Cu 21: Cho cc pht biu sau: (1) Fructoz v glucoz u c kh nng tham gia phn ng trng bc; (2) Saccaroz v tinh bt u khng b thy phn khi c axit H2 SO 4 (long) lm xc tc; (3) Tinh bt c to thnh trong cy xanh nh qu trnh quang hp; (4) Xenluloz v saccaroz u thuc loi disaccarit; Pht biu ng l 2

A. (3) v (4).

B. (1) v (3).

C. (1) v (2).

D. (2) v (4).

Cu 22: X phng ha hon ton 1 kg mt loi cht bo c ch s axit l 7 cn 3,125 mol KOH. Khi lng x phng thu c l: A. 1080,75 g B. 1083 g C. 733 g D. 896,75 g. Cu 23: X phng ho 20,2 gam trieste Y bng dung dch NaOH va thu c 9,2 gam glixerol v m gam hn hp hai mui ca hai axit hu c n chc. Cng thc phn t ca hai axit l: A. CH 3 COOH v C 2 H 3 COOH. B. HCOOH v C 2 H 3 COOH. C. HCOOH v C 2 H 5 COOH. D. HCOOH v CH 3 COOH. Cu 24: C cc pht biu sau y: 1)Amilopectin c cu trc mch phn nhnh. 2)Glucoz b kh bi dung dch AgNO3 trong NH3. 3)Xenluloz c cu trc mch phn nhnh. 4)Saccaroz lm mt mu nc brom. 5)Glucoz tn ti dng mch h v dng mch vng. 6) dng mch h, glucoz c 5 nhm -OH k nhau. 7)Glucoz tc dng c vi nc brom. 8)Khi glucoz dng vng th tt c cc nhm -OH u to ete vi CH3OH. S nhn nh ng l A. 6. B. 4. C. 5. D. 7. Cu 25: Cho mt s tnh cht : l cht kt tinh khng mu (1) ; c v ngt (2) ; tan trong nc (3) ; ho tan Cu(OH) 2 (4) ; lm mt mu nc brom (5) ; tham gia phn ng trng bc (6) ; b thu phn trong mitrng kim long nng (7). Cc tnh cht ca saccaroz l A. (1), (2), 3), (4) v (7). B. (1), (2), (3), (4), (5) v (6). C. (1), (2), (3) v (4). D. (2), (3), (4), (5) v (6). Cu 26: Cho s phn ng: + AgNO3 / NH 3 + NaOH + NaOH Este X (C 4 H n O 2 ) Y Z C 2 H 3 O 2 Na. t0 t0 t0 Cng thc cu to ca X tha mn s cho l: A. CH 2 =CHCOOCH 3 B. CH 3 COOCH 2 CH 3 . C. HCOOCH 2 CH 2 CH 3 . D. CH 3 COOCH=CH 2 . Cu 27: t cha y hoa n toa n 4,02 gam h n hp axit acrylic, vinyl axetat va metyl metacrylat r i cho toa n b sa n ph m cha y va o bi n h 1 n g dung di c h H 2 SO 4 c ,bi n h 2 n g dung di c h Ba(OH) 2 d th y kh i l ng bi n h 1 tng m gam,bi n h 2 xu t hin 35,46 gam k t tu a . Gia tri cu a m la : A. 3,6 B. 2,34 C. 3,24 D. 2,7 Cu 28: t chy hon ton m gam hn hp X gm hai ancol, thu c 13,44 lt kh CO 2 (ktc) v 15,3 gam H 2 O. Mt khc, cho m gam X tc dng vi Na (d), thu c 4,48 lt kh H 2 (ktc). Gi tr ca m l A. 12,9 B. 15,3 C. 12,3 D. 16,9 Cu 29: Ngi ta c th iu ch cao su Buna t g theo s sau (vi hiu sut tng ng): H=35% H=80% H=60% Cao su Buna Xenluloz glucoz C 2 H 5 OH Buta-1,3-ien Khi lng xenluloz cn sn xut 1 tn cao su Buna l A. 17,857 tn. B. 37,875 tn. C. 25,625 tn. D. 5,806 tn.

Cu 30: Hn hp M gm ancol no, n chc ,mch h X v ancol khng no , a chc ,mch h Y ( Y cha 1 lin kt trong phn t v X, Y c cng s mol ).t chy hon ton mt lng M cn dng V lt O2 (ktc) sinh ra 2,24 lt CO 2 (ktc) v 2,16g H 2 O.Cng thc ca Y v gi tr ca V ln lt l: A.C 4 H 6 (OH) 2 v 3,584g B.C 3 H 4 (OH) 2 v 3,584 C.C 4 H 6 (OH) 2 v 2,912 D.C 5 H 8 (OH) 2 v 2,912g 3

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