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MiSty's Compilation:Edexcel Chemistry Practice Test Unit5

MiSty's Compilation:Edexcel Chemistry Practice Test Unit5

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MiSty's Compilation:Edexcel Chemistry A2 Practice Test Unit5
Answer's can be found in Teacher's Guide here:
http://www.scribd.com/doc/111065693/MiSty-s-Compilation-Edexcel-A2-Teachers-Guide
MiSty's Compilation:Edexcel Chemistry A2 Practice Test Unit5
Answer's can be found in Teacher's Guide here:
http://www.scribd.com/doc/111065693/MiSty-s-Compilation-Edexcel-A2-Teachers-Guide

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Published by: MiSty on Oct 24, 2012
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Practice Unit Test 5
Edexcel 
A
2
Chemistry
 
Practice Unit Test 5
 Time allowed:1 hour 40 minutesMaterial required for examination:
Data Booklet 
Answer
all 
questions.In questions indicated by an asterisk,quality of written communication will be taken into account. The total for the paper is 90 marks.Use the periodic table printed at the back of the textbook (page 326).
Section A
 You should aim to spend no more than 30 minutes on this section.For each question, select one answer from A to D and put a cross in the box. If you change your mind, put a horizontal line through the cross and then mark your new answer with across.
1
What is the oxidation number of vanadium in VO
2
+
?
A
+
2
B
+
3
C
+
4
D
+
5
2
Which of the following is
not
a redox reaction?
A
2CrO
42
+
2H
+
Cr
2
O
72
+
H
2
O
B
PbO
2
+
6Cl
+
4H
+
PbCl
42
+
Cl
2
+
2H
2
O
C
H
2
O
2
+
2H
+
+
2I
2H
2
O
+
I
2
D
Mg
+
Cl
2
MgCl
2
3
 A redox reaction will
not
take place if:
A
the standard cell potential is positive
B
the standard cell potential is negative
C
the value of the standard cell potential is less than 0.3
D
the value of the standard cell potential is less than 0.03
4
Consider the standard reduction potentials of sulfur and of iron(
III
) ions:
S(s)
+
2H
+
(aq)
+
2e
H
2
S(g)
°
=+
0.14VFe
3+
(aq)
+
e
Fe
2+
(aq)
°
=+
0.77V
The standard cell potential for the oxidation of hydrogen sulfide, H
2
S, by iron(
III
) ions is:
A
0.63V 
B
+
0.63V 
C
+
0.91V 
D
+
1.4V 
2
Edexcel 
A
2
Chemistry
Practice Unit Test 5
© Philip Allan Updates
Unit 5
 Transition metals,arenes and organic nitrogen chemistry
 
5
The concentration of iodate
(V)
ions, IO
3
, in a solution can be determined by addingexcess potassium iodide and titrating the liberated iodine against standard sodiumthiosulfate solution. The reactions are:
IO
3
+
6H
+
+
5I
3I
2
+
3H
2
OI
2
+
2S
2
O
32–
2I
+
S
4
O
62–
The ratio of iodate(
 V 
) ions to thiosulfate ions in the overall reaction is:
A
1:6
B
6:1
C
1:3
D
3:1
6
Which of the following statements about the reaction below is
false
?
[Cr(NH
3
)
6
]
3+
(aq)
+
EDTA
4–
(aq)
[Cr(EDTA)]
(aq)
+
6NH
3
(aq)
A
The EDTA complex has a higher stability constant than the ammine complex.
B
There is a decrease in the entropy of the system.
C
Both complex ions are octahedral.
D
The complex ions have different colours.
7
There will be a large jump in the successive ionisation energies of manganese, electronconfiguration [Ar] 3
d
5
4
 s
2
, between:
A
the first and second ionisations
B
the second and third ionisations
C
the sixth and seventh ionisations
D
the seventh and eighth ionisations
8
Which of the following species is coloured?
A
CuSO
4
(
s
)
B
[CuCl
2
]
C
[CuCl
4
]
2–
D
[Ti(H
2
O)
6
]
4+
9
Which of the following complex ions is planar?
A
[CrCl
4
]
B
[Pt(NH
3
)
2
Cl
2
]
C
[Cr(en)
3
]
3
+
D
[Cu(H
2
O)
6
]
2
+
10
The electrode potential for the reaction:
Cr
2
O
72–
(aq)
+
14H
+
(aq)
+
6e
2Cr
3+
(aq)
+
7H
2
O(l)
°
=
+1.33V
A
 will be increased by adding H
+
ions
B
 will be increased by adding OH
ions
C
 will not be altered by adding H
+
ions
D
 will be decreased by adding H
+
ions
3
Edexcel 
A
2
Chemistry
Practice Unit Test 5
© Philip Allan Updates

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