‫

ود ‬ ‫م ‪2009/1/8‬‬ ‫ا(ض ا&‪ $%‬ا‪#‬ورة ا و  ام ا‬ ‫) ا‪ ,‬ا(*ن ا(*)‬
‫)‪7‬ن(‬ ‫‪ ( I‬اء‪:‬‬
‫‪9 3 V1 = 100mL :* (;9%‬ل ‪7 S1‬ذا آ‪%& 3 m = 68mg 4‬ات ا‪0‬دوم ‪ HCOONa‬ا‪ $. /0‬اء ‪.‬‬
‫)‪ 0,5‬ن(‬ ‫‪ (1‬اآ‪ /4‬د ا=ون‪.‬‬
‫)‪ 0,5‬ن(‬ ‫‪ ( 2‬ا*‪( /‬آ ا‪9‬ل ا‪. C1 >? @09‬‬
‫)‪1‬ن(‬ ‫‪ (3‬ا?‪ (F G‬ا‪=A σ E‬ا ا‪9‬ل ‪ )C C1 #‬ا*‪. A4B /‬‬
‫‪9 3 V2 = 50ml :* M;%‬ل ‪ L9 S 2 $‬ا‪K‬ر‪#‬ر ذي (آ ‪9 C2 = 1,10 mol/L‬ل ا‪(H% )C I‬‬

‫‪ $.‬ا‪4 34. 349E GO‬از‪ L = 1cm . AN @0 34‬وا* ا‪H‬رة ‪.S = 3,21 cm² AN @K‬‬
‫‪( UR%‬ا ‪ 3 U = 1V‬ا‪ 3490‬و‪#S‬ة ‪4‬ر ا‪ I = 38mA : $(AK‬ا‪ 3 QR (F $4‬ا‪9‬ل ‪ 3‬ا‪. 3490‬‬
‫‪ (4‬ا?‪ G‬ادو‪#?B -L* 34V‬ة ا‪4‬ا‪ $. 3#V‬ا‪ 0,5) . GO‬ن(‬
‫‪ (5‬ا?‪ G‬د ا‪#?B-L* @?4‬ة ا‪#9 $4‬ث ‪ $.‬ا‪ M0% ##9 X ، GO‬اد‪#?B -L* 34‬ة ‪ 0,5) .‬ن( ‪.‬‬
‫‪ (6‬ا*‪ /‬آ دة ا‪\?4‬ت ‪ $.‬ا‪ 9‬ا‪ )C #F‬ار[) ‪#V‬ول ‪#R‬م ا‪ @?4‬ا‪1) . @E9‬ن(‬
‫‪ (7‬ا*‪ B /‬ا‪#R4‬م ا‪#* )C . xmax $AN‬د ‪ XV‬ا ‪%‬اع ا‪ K‬ا‪4‬ا‪#V‬ة ‪ $.‬ا‪ A% #N? GO‬ا‪1) . @?4‬ن(‬
‫‪ (8‬ا*‪ B /‬اا‪ 0,5) . G' E‬ن(‬
‫‪(9‬ا[‪ B _N4‬ا‪ GO σ' E‬ب‪ 0,5) . (S/m) :‬ن(‬
‫‪ ( 10‬ا?‪C1, C2, V1, V2 # σ' (F G‬وا‪\E‬ت ا ا ‪%` %‬ت ا‪4‬ا‪#V‬ة ‪ $.‬ا‪9‬ل‪1) .‬ن(‬
‫‪S‬‬
‫‪.G = σ‬‬ ‫‪ ، M ( HCOONa ) = 68 g / mol‬واا‪:E‬‬ ‫‪: $Q%‬‬
‫‪L‬‬

‫‪6):‬ن(‬ ‫‪II‬ء ا اول‬

‫‪ 3 N? ?(.4%‬ا‪0‬دم ‪ Na‬ا‪ $?Se‬ا‪dN‬ط ‪ . β‬آ‪ 4‬ا‪ #N? N‬ا‪ t = 0 b9‬ه‪. mO : $‬‬
‫‪−‬‬ ‫‪24‬‬
‫‪11‬‬

‫‪ 3F‬ا‪ RC‬ا‪(H 4‬ات ‪#?: N‬د ا‪N‬ى ا‪ # RF4‬ا‪. 3‬‬

‫)‪ 0,5‬ن(‬ ‫‪.‬‬ ‫‪16‬‬ ‫‪O ، 9 F ، 10 Ne ،‬‬ ‫‪12‬‬ ‫‪ (1‬اآ‪ /4‬د ه=ا ا‪Mg : $Q%. g44‬‬
‫)‪ 0,5‬ن(‬ ‫‪ Na‬أن ‪ $Q‬إ‪ α ?S‬؟ ?@ ‪V‬ا ‪.‬‬ ‫‪24‬‬
‫‪11‬‬ ‫‪ ( 2‬ه@ ‪#N 3K‬ة ا‪0‬دم‬

‫)‪1‬ن(‬ ‫‪( 5‬ا*‪. mo B /‬‬

‫)‪ 0,5‬ن(‬ ‫‪. 11‬‬
‫‪24‬‬
‫‪Na‬‬ ‫‪(? (6‬ف ?( ا‪#N M0N‬ة ‪ )C . d‬أو‪#N FN >4B #V‬ة ا‪0‬دم‬
‫)‪ 0,5‬ن(‬ ‫‪. 11‬‬
‫‪24‬‬
‫‪ (7‬ا*‪ & B /‬ا‪dN‬ط ا‪#N λ $?Se‬ة ا‪0‬دم ‪Na‬‬
‫‪ ( 8‬أو‪ $. #V‬ا‪ b9‬ا‪ $4‬ر‪: t1 = 45h ، AO‬‬
‫)‪1‬ن(‬ ‫أ( ?‪#‬د ا‪#N‬ات ‪ N 1‬ا‪ )C RF4‬آ‪ 4‬ا‪.N‬‬
‫)‪1‬ن(‬ ‫ب( ‪d%‬ط ا‪ N‬ا‪. d‬‬
‫‪ 4C : $Q%‬أ‪.‬آدرو ‪M ( 11 Na ) = 24 g / mol ، N A = 6,02.10 23 :‬‬
‫‪24‬‬

‫‪1‬‬
 (‫ن‬7): ‫ء ا ا‬ (III
[#? KFd‫ ا‬Mm X;% . a = 4.10 m AQm ( R ) ‫ل‬R4% KFS ? bN λ = 540nm A4V ‫ل‬n o * ‫(د‬
−6

.(@Kd‫( ا‬b%‫)ا‬. [# ‫رة‬0‫ري ا‬pF‫ى ا‬4‫ ا‬$. SS X;%‫ و‬، f ' = 25cm ‫ر‬pF‫ ا‬A4. : RB‫ر‬

(‫ن‬.0.75) .Sd‫@ ?> ? ا‬09‫ ا‬#Ad‫ ا‬ME ‫( ؟‬:4‫(زه ا‬F $4‫ه(ة ا‬b‫@ ؟  ا‬4‫ ا;ء ا‬Fn  ( 1
(‫ن‬0.5 ) . k ∈ Z s* k ‫ و‬λ ‫ و‬a # θ (F #V‫ ( أو‬2
(‫ن‬0.5 ) . k = 1 F(‫ ا; ّذات ا‬RF R.‫ اا‬θ1 ‫ ااو‬#V‫ (أو‬3
(‫ن‬0.5 ) .0R‫ءة ا‬oe‫ ذات ا‬XRF‫د ا‬#? #V‫ ( أو‬4
(‫ن‬0.5 ) .3444 34R 3 E‫ ا‬i .‫ ا‬/*‫( ا‬5
λ
(‫ن‬1 ) . x1 /*‫ أ‬x1 = f ' ‫ أن‬3. k = 1 F(‫ ذات ا‬RF‫ ا(آ و(آ ا‬RF F ' ‫ ا(آ‬3 .‫ ا‬x1 ( 6
a
k = 4 F(‫ ا; ذات ا‬RF‫ (آ ا‬Xo wF0. ، KFd‫ ? ا‬$bN FN θ o ‫ ااردة او‬9‫@ ا‬% (7
(‫ن‬1) . θ o B _4N4[‫ ا‬. F ' : ‫ه‬
(‫ن‬0.5 ) ‫؟‬.‫ل‬Q‫ة ا‬#* (4‫ ا‬KFd‫ق )ا‬RS ‫د‬#?  (8
. L ‫ ا;ء ا‬3 9 R‫ ا‬o 9‫ض ا‬% ( 9
(‫ن‬0.75 ) .Sd‫@ ?> ? ا‬09‫ ا‬#Ad‫ ا‬ME ‫( ؟‬:4‫(زه ا‬F $4‫ه(ة ا‬b‫ ؟  ا‬L ‫ ا;ء ا‬Fn  (‫أ‬
(‫ن‬1) . k = 1 F(‫ ذي ا‬MQ‫د ?(ض ا‬#* ، $b‫( * ارود ا‬F4% (‫ب‬
. λViolet = 400nm : ‫ و‬λ Rouge = 800nm
 400nm ≤ λ ≤ 800nm :‫ل‬:‫ ا‬$. ‫ر‬09 $(‫ا;ء ا‬

#[ y*

. ‫ا ا أ‬

Sbiro abdelkrim
Lycée agricole oulad –taima région d’Agadir Maroc
Mail : sbiabdou@yahoo.fr
msn : sbiabdou@hotmail.fr
pour toute observation contactez moi

2
 : w904‫ا‬
(‫ن‬7) :‫ ( اء‬I

......................................................................................................................................................
m 68.10 −3 g
c1 = = = 0,01mol / L (2
M .V 68 g / mol.0,1L
......................................................................................................................................................
σ = λ( Na + ) .[ Na + ] + λ( HCOO − ) .[ HCOO − ] = c1 .([ Na + ] + [ HCOO − ]) (3

σ = c1 .([ Na + ] + [ HCOO− ]) = 10mol / m 3 .[5,46 + 5,01].10 −3 S.m 2 / mol = 0,1047S / m

......................................................................................................................................................
H 3O + / H 2 O ‫و‬ HCOOH / HCOO − (4
........................................................................................................................................................
HCOO − + H + → HCOOH (5
+ +
H 3O → H + H 2 O
..........................................
HCOO − + H 3O + → HCOOH + H 2 O
............................................................................................................................
n0 ( HCOO − ) = c1 .v1 = 0,01mol / L × 0,1L = 10 −3 mol = 1m.mol (6
n0 ( H 3O + ) = c 2 .v 2 = 1,1mol / L × 0,05 L = 0,055mol = 55m.mol
: ‫م‬#R4‫ول ا‬#V

........................................................................................................................................................................
. G(4 @4 >% HCOO − ‫ات‬%&‫ ه أن ا‬#9‫?@ ا‬4‫(ا‬7
x max = 1m.mol = 10 −3 mol : ‫أي‬ 1 − x max = 0 : ‫إذن‬
:$‫ه‬. @?4‫ ا‬A% #N? GO‫ ا‬$. ‫ة‬#V‫ا‬4‫اع ا‬% ‫ ا‬$4‫و‬
. Cl − ‫ و‬Na + ، H 2 O ، H 3O + ، HCOOH
......................................................................................................................................................
1
G= : ‫و‬R‫ب ا‬R $‫ ه‬E‫) ان اا‬% (8
R
I
G= :‫ إذن‬U = R.I : N#‫و‬
U
I 38.10 −3 S .10 −2 m
G' = = = 38.10 −3 S : G' E‫اا‬
U 1V
..........................................................................................................................................................
(9
−2
L 10 m
σ ' = G '. = 38.10 −3 S . = 1,18.S / m
S 3.21.10 − 4 m 2
........................................................................................................................................................................
.

3
 (10
−
n0 ( HCOO ) = c1 .v1
n0 ( H 3O + ) = c 2 .v 2
. HCOO − :‫ ه‬#9‫?@ ا‬4‫ا‬: ‫ أن‬
x max = c1 .v1 ⇐ c1 .v1 − x max = 0

: GO‫ ا‬E ‫إذن‬

c .v − c .v c .v c .v
σ ' = λ ( H 3O + ) . 2 2 1 1 + λ ( Na + ) . 1 1 + λ ( Cl − ) . 2 2
v1 + v 2 v1 + v 2 v1 + v 2

0000000000000000000000000000000000000000000000000000000000000000000000000000000000
(‫ن‬6): ‫" ا!ول‬#$%‫ء ا‬#&'II
24
11 Na →1224 Mg + −10 e (1
........................................................................................................................................................................
. 200 3 (F‫ أآ‬U A44‫د آ‬#? ‫ ن‬، . α ?S‫ إ‬$Q ‫ أن‬11 24
Na ‫دم‬0‫ة ا‬#N 3K  ( 2
. A > 200 : A44‫د آ‬#? ‫ن‬K 4 α ‫ع‬Se‫ ا‬QdN‫ى ا‬N‫) أن ا‬% s9
........................................................................................................................................................................
...
− λ .t
N = N O .e (3
......................................................................................................................................................................
N O = 10 21 : N9N‫\ل ا‬m 3 (4
.....................................................................................................................................................................
M 10 21.24 m
mo = N O . = 23
= 0,04 g ⇐ N O = o .N A (5
N A 6,02.10 M
........................................................................................................................................................................
. t1 / 2 = 15h ? @09% %F . t1 / 2 :‫ و( إ> ب‬، #F‫ ا‬N‫ى ا‬% M0% g44 ‫ ا\ز‬N‫ة ا‬#‫ ا‬$‫ ه‬M0N‫( ?( ا‬6

................................................................................................................................................................
ln 2 ln 2
λ= = ≈ 1,3.10 −5 s −1 (7
t1 / 2 15.(3600) s
. FR :4N‫ ا‬h −1 : ‫ ب‬λ ? (F4‫ ا‬3K : z9
...............................................................................................................................................................
(‫أ‬ (8
4
 t1
t1 = 3t1 / 2 ⇐ =3 t1 = 45h ‫ و‬t1 / 2 = 15h : N#
t1 / 2
:$‫ه‬ t1 b9‫ ا‬$. RF4‫ ا‬N1 ‫ات‬#N‫د ا‬#? ‫ن‬7. >N‫و‬
ln 2 1
− .3t1 / 2 ln N0 NO
−λ .t1 −3 ln 2
N1 = N 0 .e = N 0 .e t1 / 2
= N O .e = N 0 .e 23
= 3
= = 1,25.1020
2 8
.............................................................................................................................................................
t1 b9‫ ا‬#N? N‫ ا‬4‫ب(آ‬
M 24
m1 = N 1 . = 0,125.10 21. ≈ 0,05 g = 5mg
NA 6,02.10 23

.............................................................................................................................................................
: t1 b9‫ ا‬#N? d‫ ا‬N‫ط ا‬d% (‫ب‬
a1 = λ .N 1 = 1,6.10 s .1,25.10 = 1,6.10 Bq
−5 −1 20 15

. s −1 ‫ [ى ب‬λ 3? (F% ‫ أن‬w0  B\‫ ه={ ا‬$. : z9

000000000000000000000000000000000000000000000000000000000000000000000000000
(‫ن‬7): ()*‫" ا‬#$%‫ء ا‬#&' (III
.lumière monochromatique . ‫@ أ*دي ان‬4‫( ا;ء ا‬1
.KFS Q[‫ *د ا;ء ا‬:(:4‫(زه ا‬F $4‫ه(ة ا‬b‫ا‬
.‫ ا(آ‬RF FN C4‫ و‬AN . .‫و ا‬4 R Sd‫ ? ا‬#‫ه‬d%
......................................................................................................................................................................
k .λ
sin θ = (2
a
.......................................................................................................................................................................
θ 1 = 7 , 76 ° ⇐ sin θ1 = =
λ 540.10 −9
= 0,135 ⇐ k =1 (3
a 4.10 − 6
..................................................................................................................................................................
− 1 ≤ sin θ ≤ +1 :4‫ ا‬B\‫ده ا‬#9 0R‫ءة ا‬oe‫ ذات ا‬XRF‫د ا‬#? (4
a a
− 7 ≤ k ≤ +7 ⇐ − ≤k≤+ : ‫أي‬
λ λ
k ∈ [ − 7 , − 6 , − 5, − 4 , − 3, − 2 , − 1, 0, + 1, + 2, + 3, + 4 , + 5, + 6, + 7 ] : 4‫) ا‬R‫= ا‬m
 ‫ أن‬ANK k F(‫أي ا‬
15: ‫ ه‬0R‫ءة ا‬oe‫ ذات ا‬XRF‫د ا‬#? ‫ن‬7. >N‫و‬
.....................................................................................................................................................................
: $‫ ه‬3444 34R 3 E‫ ا‬i .‫( ا‬5
f '.λ .n (0,25).540.10 −9
i = f '.λ .n = = = 0,03375m = 33,75mm
a 4.10 −6
....................................................................................................................................................
k .λ
θ= : ‫(ة‬H0‫ وا ا‬FN N# (6
a

x
θ= :‫(ى‬m‫ ا‬AV 3‫و‬
f'
x k .λ
= : ‫إذن‬
f' a
f '.k .λ
. k = 1 : ‫ ل‬FN‫و‬ x= :>N‫و‬
a
5
 f '.λ 0,25.540.10 −9
x1 = = = 0,0375m
a 4.10 −6
.......................................................................................................................................................................
⇐ : ‫(ة‬HE ‫ ا وا‬sin θ − sin θ 0 = kλn (7
x4
tgθ = sin θ = θ (rad ) :N#‫ و‬tgθ 4 = : X sin θ 4 = sin θ 0 + 4λn ⇐ k=4
f'
x 4 = f ' (sin θ 0 + 4λn) : ‫إذن‬
x4 = 0 ⇐ F' : ‫ ه‬k = 4 F(‫ ا; ذات ا‬RF‫ (آ ا‬Xo
k .λ 4.540.10 −9
θ 0 = −32,7° ⇐ sin θ 0 = −4λn = − =− = −0,54 ⇐ 0 = f ' (sin θ 0 + 4λn)
a 4.10 −6
.................................................................................................................................................................
1 1
n= = −6
= 25.10 4 m −1 : ‫ل‬Q‫ة ا‬#* (4‫ ا‬KFd‫ق )ا‬RS ‫د‬#? (‫( أ‬8
a 4.10
.......................................................................................................................................................
. L ‫ ا;ء ا‬3 9 R‫ ا; ا‬9‫ض ا‬%(9
.(‫اء أ*د ان‬o‫ة أ‬#? 3 ‫ن‬K4 ‫ )أي‬lumière polychromatique ‫د ا ان‬#4 : L ‫ ا;ء ا‬Fn (‫أ‬
. KFS Q[‫ ا‬L ‫د ا;ء ا‬#F‫ *د و‬: (:4‫(زه ا‬F $4‫ه(ة ا‬b‫ا‬
.‫ (آ ;ء‬R AQ[4 L ‫ف ا;ء ا‬n‫ أ‬3 [ . :Sd‫@ ?> ? ا‬09‫ ا‬#Ad‫ا‬
.................................................................................................................................................................
x λ
θ = : : ‫(ى‬m‫ أ‬AV 3‫ و‬θ = k : ‫(ة‬H0‫ وا ا‬FN >%‫) أ‬% (‫ب‬
f' a
k .λ . f ' x λ
x= ⇐ =k : ‫إذن‬
a f' a
k = 1 F(‫ ذي ا‬MQ‫ ?(ض ا‬، $bN‫ * ارود ا‬$B

λR . f ' λV . f '
xR = :‫و‬ xV =
a a
f' 0,25
i = x R − xV = (λ R − λV ) = −6
(800 − 400).10 −9 = 0,025m = 2,5cm
a 4.10
◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙◙

. ‫ك‬4N‫ *ة أ‬: =4‫@ ?> ا‬0* 19,25 : ‫ ه=ا ا(ض‬$. QR% ?‫أ‬

Sbiro abdelkrim
Lycée agricole oulad –taima région d’Agadir Maroc
Mail : sbiabdou@yahoo.fr
msn : sbiabdou@hotmail.fr
pour toute observation contactez moi