(1

2 Mg O2
(s)

2 MgO

(g )

(s)

-------------------------------(2
6, L3

------------------------------------(3
6-3,6=2,4L
v.
4, L2
1,mol
0
VM 24 L.mol 1
--------------------------------------------------------------------------------------n (o 2 )

(4

v(O2 )
VM
2Mg +
no
no-2x

6L
24 L.mol 1
O2
0,25
0,25-x

25mol
,0
2 MgO
0
2x
x

1,mol
0

x=0,1mol
n(O2)=0,25-x=0,25-0,1=0,15 mol
------------------------------------n (o 2 )
1,mol
0
x max

(5

1,mol
0

2Mg + O2
no
0,25
no-2x
0,25-x
0
0,15

no-2xmax=0
2 MgO
0
2x
0,2
1

(6

-----------------------------------------------------------------------------------no-2xmax=0

(7

no(Mg) =2.xmax=0,2mol
m=n.M=0,2.24=4,8g
----------------------------------------------(8
xmax=0,25mol <= 0,25-xmax=0
no=2xmax=0,5mol
<= no-2xmax=0
0,5mol
m

M .n

24 g / mol

O2
Mg

5, 0. 12 g

(1

(1
3C 2 Fe2 O3
3CO2 4 Fe
------------------------------------------------------------------------------------------------------------------------------(2
m( Fe)
56 g
n( Fe)
1mol
M ( Fe) 56 g / mol

n( Fe) 1mol

4 x max

56 g

x max
25mol
,0
.
m( Fe2 O3 )
16 g
n( Fe2 O3 )
1,mol
0
(3
M ( Fe2 O3 ) 160 g / mol

0,1-2xmax=0
xmax= 0,05mol

Fe2 O3

Fe2 O3 3 CO

2 Fe 3 CO2

(g )

(s)

(s)

(1

(g )

--------------------------------------------------------------------------------------------------------------Fe2 O3
(2
(s)

m
M

no( Fe 2 O3 )
C2H6O
0,02-x
0,02-xmax

2x

3x

2xmax 3xmax

x max
. x3max

n(CO2 ).VM

02mol
,0

06mol
, 0 25L. / mol

5,L1

n( Fe)
m

n.M

Fe2O3
0,02-xmax

CO2

.( 302), 0 06mol
,0

V (CO2 )

02mol
,0

+3O2 -> 2CO2 3H2O

t=0 0,02 mol

n(CO2 )

2,g3
160 g / mol

04 mol
, 0 56 g. / mol

C 2 H 6 O 3O2

24 g, 2

2CO2

3H 2 O

.x2max

04mol
,0

n(O2 )

3x max

m
M

3, g2
46 g / mol

05mol
,0

V (O2 )
VM

5, L1
25L / mol

06mol
,0

n (C 2 H 6 O )

n(O2 )

C2H6O

.( 3 ) 2, 0 6,mol
0

+3O2

2CO2+

3H2O

0,05

0,06

0,05-x

0,06-3x

2x

3x

0,06-3xmax
0,05-xmax=0

2xmax

3xmax

0,05-xmax
xmax=0,05mol

C2H6O

xmax=0,02mol
. xmax=0,02mol

C2H6O

0,06-3xmax=0

+3O2

2CO2+

0,05-0,0,02=0,03mol 0,06-3xmax=0

3H2O

0,04mol 0,06mol

O2
0,02<0,05

(1
.
(2

x 1mol
4 x 4mol
4mol
n(O2 ) 3 x
.(1mol
3 ) 3mol
n( Al 2 O3 )
.x2 .(1mol
2 ) 2mol
--------------------------------------------------------------------------------------------------------------------------x
25mol
,0
4 x 1mol
1mol
n(O2 ) 3 x
.( 325mol
,0 )
75mol
,0
n( Al 2 O3 )
. x2 .( 225mol
,0 )
5,mol
0

x
2,mol
0
n(O2 ) 3 x
n( Al 2 O3 )

4x
8,mol
0
.( 32,mol
0 )
6,mol
0
.x2 .( 22,mol
0 )
4,mol
0

8,mol
0

C3H8 + 5 O2 ------> 3 CO2 + 4 H2O

(1
*

C3H8 5O2 3CO2 4H2O

t=0 2 mol 7 mol
2-x

7-5x
6

3x

4x

(2

2-xmax

3xmax 4xmax

2-xmax =0 --> xmax=2 mol

7-5xmax = 0 --> xmax=1,4 mol

x max

C3H8

4,mol
1

5O2

3CO2

4H2O

2-1,4 = 0,6 mol 0 3*1,4 = 4,2 mol 4*1,4 =5,6 mol

*
C3H8

5O2

t=0 1,5 mol 7 ,5mol

1,5-x

7,5-5x

3CO2 4H2O
0

3x

4x

1,5-xmax =0 --> xmax=1,5 mol

soit 7,5-5xmax = 0 --> xmax=1,5 mol

C3H8 5O2
0

3CO2

4H2O

3.(1,5) = 4,5 mol 4.(1,5) = 6 mol

2 H2S + SO2 -7

3 S + 2 H2 O

(1

----------------------------------------------------------------------------------------------------(2
2H2S SO2 3S 2H2O
5 mol 4 mol 0

5-2 x 4 - x 3 x 2 x
5-2xmax=0 --> xmax=2,5 mol

soit 4-xmax = 0 --> xmax=4 mol

H2S

SO2

. H2S

SO2
.
2H2S

SO2

(3

3S

2H2O

4-2,5 = 1,5 mol 3 2,5) = 7,5 mol 2.(2,5) =5 mol

------------------------------------------------------------------------------------------------------(4
2H2S

SO2

3S 2H2O

n mol 3,5 mol 0

n-2 x 3,5 - x 3 x 2 x
x max

5,mol
3

3,5 xmax=0

n-2 xmax = 0 --> n =2xmax = 7 mol

2H2S SO2
0

3S

2H2O

0 3.(2,5) = 7,5 mol 2.(2,5) =5 mol

VIII

C 2 H 6 O 3O2

2CO2

3H 2 O

(1

-----------------------------------------------------------------------------------------------------------------------(1-2(2
C 2 H 6 O 3O2
0,2
0,2-x

no
no-3x

2CO2

3H 2 O

0
2x

3x

.xmax=0,2mol<=

0,2-xmax =0

no=3xmax=0,6mol

<=

-------------------------------------------------------------------------------

m(CO2 )

M (CO2 ).n

m( H 2 O)

44 g / mol 4,mol
0.
17 6, g <=

n(CO2 )

M ( H 2 O).n 18g / mol 6,mol

0.
10 8, g <=
9

.x2max

n( H 2 O )

4,mol
0 (2-2(2
.x3max

6,mol
0

--------------------------------------------------------------------------------------------------------(3-2

V (O 2 )

n.V M

6,mol
0 25L. / mol 15L

.n=3xmax=0,6mol

----------------------------------------------------------------------------------------------------------------no (C 2 H 6 O )

m
M

n o (O 2 )

3, g2
46 g / mol
v
VM

05mol
, 0 (-1-3(3

5, L1
25L / mol

06mol
,0

--------------------------------------------------------------------------------------------------------(-2-3
C 2 H 6 O 3O2

0,05

2CO2

0,06

0,05-x

0,06-3x

3H 2 O

0
2x

3x

. xmax=0,02mol
------------------------------------------------------------------------------------------------------------(3-3
C 2 H 6 O 3O2

0,03mol

2CO2

0,04mol

10

3H 2 O

0,06mol

xmax=0,1 mol

0,2 -2xmax=0

xmax=0,083mol
. xmax=0,083 mol=83m.mol

0,25 -3xmax=0
0,1 >0,0

11