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Assignment 4 Better

Assignment 4 Better

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Published by Anshu Kumar Gupta

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Published by: Anshu Kumar Gupta on Nov 23, 2012
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05/13/2014

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Assignment
1.
 
Assuming Ag-Au is a random mixture of gold and silver atoms .Calculate the entropyincrease when 10 gm of gold are mixed with 20 gms of silver to form an idealhomogenous alloy. The atomic weight of Au and Ag are 197 and 107.88gm,respectively. (Ans:1.02 J/K)2.
 
A mixture of Fe
2
O
3
and Al, present in the molar ratio 1:2 is adiabatically contained alongwith some Fe at 25°C. If the Thermit reaction ( Fe
2
O
3
+ 2 Al Al
2
O
3
+2Fe) isallowed to proceed to completion, calculate molar ratios of Fe to Fe
2
O
3
in the initialmixture which, on completion of reaction, will give
liquid 
Fe and
solid 
Al
2
O
3
at1600°C. (Ans: 6.57)mol / J196300x2.4)OFe(H
32298
=
mol / J400000x2.4)OAl(H
32298
=
 mol / J)T10x82.6T10x25.448.25(2.4)OAl(Cp
25332
+=
K in
1879T298
 Fe Cp, J/mol K K?T?
<<
 
α
)T10x92.518.4(2.4
3
+
 
273-1033
β
0.9x2.4 1033-1181
γ 
)T10x66.484.1(2.4
3
+
 
1181-1674
δ
5.10x2.4
 
1674-1808Liquid 42 1808-1873
)(Fe)(Fe
βα
1200x2.4H
=
at 1033K)(Fe)(Fe
β
220x2.4H
=
J/mol K at 1181 K)(Fe)(Fe
δγ 
210x2.4H
=
at 1674 K)liquid(Fe)(Fe
δ
3300x2.4H
m
=
at 1808 K

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