Modeling Reactions on Uniform Surfaces

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1/10/2009 1

1/10/2009 1

Chemical

Engineering

126University

of

the

Philippines

Modeling

Reactions

on

Uniform

(Ideal)

Surface

CHEMICAL

ENGINEERING

126:KINETICS

OF

HETEROGENEOUS

REACTION

1/10/2009 2

1/10/2009 2

Chemical

Engineering

126University

of

the

Philippines

CATALYST

123,4,567

What

do

we

know

so

far?



7

Steps

for

converting

reactants

to

products

in

a

catalytic

process



Model

the

rate

of

arrival

to

and

from

the

surface

of

reactants

and

products



Several

isotherms

can

be

written

to

describe

the

adsorption



We

can

characterize/evaluate

some

of

the

important

properties

of

the

catalyst

1/10/2009 3

1/10/2009 3

Chemical

Engineering

126University

of

the

Philippines

Other

Issues

o

Details are still debatable

o

Lack of accurate knowledge of the structure of chemisorbed particles

o

Non‐uniformity of catalyst surface

of 00

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