HIDROCACBON TRONG CC THI I HC CAO NG (2007-2012) 2007

Cu 1: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C3H4. B. C3H6. C. C2H4. D. C4H8. Cu 2: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. propen v but-2-en (hoc buten-2). B. eten v but-1-en (hoc buten-1). C. 2-metylpropen v but-1-en (hoc buten-1). D. eten v but-2-en (hoc buten-2). Cu 3: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40) A. 30. B. 10. C. 20. D. 40. Cu 4: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16) A. C3H4. B. C3H8. C. C3H6. D. C4H8. Cu 5: Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l: A. anehit axetic, butin-1, etilen. B. anehit fomic, axetilen, etilen. C. anehit axetic, axetilen, butin-2. D. axit fomic, vinylaxetilen, propin. Cu 6: Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l: A. anehit axetic, butin-1, etilen. B. anehit fomic, axetilen, etilen. C. anehit axetic, axetilen, butin-2. D. axit fomic, vinylaxetilen, propin. Cu 7: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l (cho C =12, O = 16) A. C2H5C6H4OH. B. HOCH2C6H4COOH. C. HOC6H4CH2OH. D. C6H4(OH)2. Cu 8: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80) A. 3,3-imetylhecxan. B. 2,2-imetylpropan. C. isopentan. D. 2,2,3-trimetylpentan. Cu 9: Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l (cho H = 1, C = 12, N = 14, O = 16) A. 70%. B. 50%. C. 60%. D. 80%.

2008
Cu 10: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,04 gam. B. 1,32 gam. C. 1,64 gam. D. 1,20 gam. Cu 11: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 2. B. 4. C. 3. D. 5. Cu 12: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 20,40 gam. B. 18,60 gam. C. 18,96 gam. D. 16,80 gam. Cu 13: Cho s chuyn ha: CH4 2H2 2H3 tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 358,4. B. 448,0. C. 286,7. D. 224,0.

Cu 14: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l A. C6H14. B. C3H8. C. C4H10. D. C5H12. Cu 15: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A. 2. B. 3. C. 1. D. 4. Cu 16: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu cl A.2. B. 3. C. 5. D. 4. Cu 17: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A.CH4 v C3H6. B. C2H6 v C3H6. C. CH4 v C3H4. D. CH4 v C2H4. Br2 (1:1)/ Fe, t o NaOH (du)/ p, t o Cu 18: Cho s chuyn ho sau: Toluen X Y HCl (du) Z Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. B. benzyl bromua v o-bromtoluen. C. o-bromtoluen v p-bromtoluen. D. o-metylphenol v p-metylphenol. Cu 18: Hirocacbon mch h X trong phn t ch cha lin k cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A.4. B. 2. C. 3. D. 5. Cu 19: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankin. B. ankan. C. ankaien. D. anken. Cu 20: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 7. B. 5. C. 6. D. 8. Cu 21: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H4. B. CH4. C. C2H6. D. C3H8. Cu 22: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca A. anken. B. ankan. C. ankaien. D. ankin. Cu 23: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A . 11,1. B. 12,9. C. 22,2. D. 25,8. Cu 24: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A . 50% v 50%. B. 75% v 25%. C. 20% v 80%. D. 35% v 65%. Cu 25: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. 2-Metylpropan. C. etan. D. 2,2-imetylpropan

2009
Cu 26: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. xiclohexan. B. xiclopropan. C. stiren. D. etilen. Cu 27: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4.

Cu 28: Hn hp kh X gm H v C H c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A. 20%. B. 25%. C. 50%. D. 40%. Cu 29: Hn hp kh X gm 0,3 mol H v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 16,0. B. 3,2. C. 8,0. D. 32,0. Cu 30: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng vi H (d, xc tc Ni, t ), cho cng mt sn phm l:
2 o 2 2 2 4

A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis-but-2-en v xiclobutan. Cu 31: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=C(CH3)2. B. CH2=CH2. C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3. Cu 32: Cho cc hp cht hu c: (1) ankan; (2) ancol no, n chc, mch h; (3) xicloankan; (4) ete no, n chc, mch h; (5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (1), (3), (5), (6), (8). B. (3), (4), (6), (7), (10). C. (3), (5), (6), (8), (9). D. (2), (3), (5), (7), (9). Cu 33: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. stiren; clobenzen; isopren; but-1-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. buta-1,3-ien; cumen; etilen; trans-but-2-en. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. Cu 34: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l A. 20%. B. 50%. C. 25%. D. 40%. Cu 35: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen. Cu 36: Ngi ta iu ch anilin bng s sau HNO3 a c Fe HCl Benzen Nitrobenzen Anilin 0 H SO a c
2 4 t

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 186,0 gam B. 111,6 gam C. 55,8 gam D. 93,0 gam

2010
Cu 37: un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l

A. 0,585. B. 0,620. C. 0,205. D. 0,328. Cu 38: Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. CH4 v C2H6. B. C2H4 v C3H6. C. C2H6 v C3H8. D. C3H6 v C4H8. Cu 39: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l A. 3-etylpent-3-en. B. 2-etylpent-2-en. C. 3-etylpent-2-en. D. 3-etylpent-1-en. Cu 40: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l A. C3H8. B. C2H6. C. C3H4. D. C3H6. Cu 41: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l A. C3H8. B. C2H6. C. C3H4. D. C3H6. Cu 42: Cho s chuyn ho sau: o o o C2H2 t , xt X +H2, t Pd, PdCO3 Y +Z, t , xt, p Cao su buna-N. Cc cht X, Y, Z ln lt l: A. benzen; xiclohexan; amoniac. B. axetanehit; ancol etylic; buta-1,3-ien. C. vinylaxetilen; buta-1,3-ien; stiren. D. vinylaxetilen; buta-1,3-ien; acrilonitrin. Cu 43: Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh nng lm mt mu nc brom l A. 5. B. 4. C. 6. D. 3. Cu 44: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H
o

(xc tc Ni, t )? A. 3. B. 5. C. 2. D. 4. Cu 45: t chy hon ton 6,72 lt (ktc) hn hp gm hai hirocacbon X v Y (MY > MX), thu c 11,2 lt kh CO2 (ktc) v 10,8 gam H2O. Cng thc ca X l A. C2H4. B. CH4. C. C2H6. D. C2H2. Cu 46: Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3, to), thu c hn hp Y ch c hai hirocacbon. Cng thc phn t ca X l A. C2H2. B. C4H6. C. C5H8. D. C3H4. Cu 47: Cht no sau y c ng phn hnh hc? A. 2-clopropen. B. But-2-en. C. 1,2-icloetan. D. But-2-in.

2011
Cu 48: Hn hp X gm C H v H c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C H , C H , C H v H . Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H l 8. Th tch O (ktc) cn t
2 2 2 4 2 6 2 2 2 2 2 2

chy hon ton hn hp Y l A. 22,4 lt. B. 26,88 lt. C. 44,8 lt. D. 33,6 lt. Cu 49: Cho 13,8 gam cht hu c X c cng thc phn t C H tc dng vi mt lng d dung dch AgNO trong NH , thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn?
3 7 8

A. 2.

B. 5.

C. 4.

D. 6.

Cu 50: t chy hon ton hn hp X gm C H , C H v C H (s mol mi cht bng nhau) thu c 0,09 mol CO . Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO trong NH , th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C H v C H trong X ln lt l: A. CHC-CH , CH =C=C=CH . C. CHC-CH , CH =CH-CCH.
3 2 3 2 2 3 4 4 4 2 3 3 2 2 3 4 4 4

B. CH =C=CH , CH =CH-CCH.
2 2 2

D. CH =C=CH , CH =C=C=CH .
2 2 2 2 2

Cu 51: Cho buta-1,3-ien phn ng cng vi Br theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l A. 2. B. 3. Cu 52: Cho s phn ng: CHCH +HCN X; X Trng hp C. 4.
Y; X + CH =CH-CH=CH
2 2

D. 1.
ng trng hp

polime Z.

Y v Z ln lt dng ch to vt liu polime no sau y? A. T olon v cao su buna-N. B. T nilon-6,6 v cao su cloropren. C. T nitron v cao su buna-S. D. T capron v cao su buna. Cu 53: Cho dy chuyn ho sau: +KOH/C2H5OH to Benzen +C2H4, to, xt X +Br2, as, t l mol 1:1 Y Z(trong X, Y, Z l sn phm chnh). Tn gi ca Y, Z ln lt l A. benzylbromua v toluen. B. 2-brom-1-phenylbenzen v stiren. C. 1-brom-2-phenyletan v stiren. D. 1-brom-1-phenyletan v stiren. Cu 54: Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong hn hp M l A. 30%. B. 40%. C. 50%. D. 20%. Cu 55: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l A. 7,3. B. 6,6. C. 3,39. D. 5,85. Cu 56: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l A. 8. B. 7. C. 9. D. 5. Cu 57: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6 v H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l A. 0,24 mol. B. 0,36 mol. C. 0,60 mol. D. 0,48 mol. Cu 58: Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol 1:1 (c mt bt st) l A. p-bromtoluen v m-bromtoluen. B. benzyl bromua. C. o-bromtoluen v p-bromtoluen. D. o-bromtoluen v m-bromtoluen. Cu 59: Cht no sau y c ng phn hnh hc? A. CH =CH-CH=CH . B. CH -CH=C(CH ) .
2 3 2 3 3 2

C. CH -CH=CH-CH=CH .
2

D. CH =CH-CH -CH .
2 2 3

Cu 60: Cho s phn ng: + X (xt, to) CH4 Y + Z (xt, to) T + M (xt, to) CH3COOH (X, Z, M l cc cht v c, mi mi tn ng vi mt phng trnh phn ng). Cht T trong s trn l A.C H OH. B. CH CHO. C. CH OH. D. CH COONa.
2 5 3 3 3

Cu 61: Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan v xiclopentan. Trong cc cht trn, s cht phn ng c vi dung dch brom l A. 6. B. 4. C. 5. D. 3. Cu 62: Cht X tc dng vi benzen (xt, t) to thnh etylbenzen. Cht X l

A. C H .
2 4

B. C H .
2 2

C. CH .
4

D. C H .
2 6

2012
Cu 63: Hirat ha 5,2 gam axetilen vi xc tc HgSO trong mi trng axit, un nng. Cho ton b cc cht hu c sau phn ng vo mt lng d dung dch AgNO trong NH thu c 44,16 gam kt ta. Hiu sut phn ng hirat ha axetilen l A. 60%. B. 80%. C. 92%. D. 70%. Cu 64: t chy hon ton 3 lt hn hp X gm 2 anken k tip nhau trong dy ng ng cn va 10,5 lt O (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l A. 46,43%. B. 10,88%. C. 31,58%. D. 7,89%. Cu 65: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH) . Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l A. CH . B. C H . C. C H .
4 3 4 4 10 6 5 2 2 3 3 4

D. C H .
2 4

Cu 66: Cho dy cc cht: stiren, ancol benzylic, anilin, toluen, phenol (C H OH). S cht trong dy c kh nng lm mt mu nc brom l A. 5. B. 4. C. 3. D. 2. Cu 67: Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th c ca X l A. 6. B. 7. C. 4. D. 5. Cu 68: Hn hp X gm H v C H c t khi so vi H l 7,5. Dn X qua Ni nung nng, thu c hn hp Y c t khi so vi H l 12,5. Hiu sut ca phn ng hiro ho l
2 2 2 4 2

A. 70%. B. 80%. C. 60%. D. 50%. Cu 69: Cho dy cc cht: cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht trong dy lm mt mu dung dch brom l A. 5. B. 4. C. 2. D. 3. Cu 70: Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H . Nung nng hn hp X (xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi H bng 10. Dn hn hp Y qua dung dch brom d, sau khi phn ng xy ra hon ton, khi lng brom tham gia phn ng l A. 0 gam. B. 24 gam. C. 8 gam. D. 16 gam. Cu 71: t chy hon ton 50 ml hn hp kh X gm trimetylamin v hai hirocacbon ng ng k tip bng mt lng oxi va , thu c 375 ml hn hp Y gm kh v hi. Dn ton b Y i qua dung dch H SO c (d), th tch kh cn li l 175 ml. Cc th tch kh v hi o cng iu kin. Hai hirocacbon l A. C H v C H . B. C H v C H . C. C H v C H . D. C H v C H .
2 4 3 6 3 6 4 8 2 6 3 8 3 8 4 10 2 4 2 2

Cu 72: t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng thc n gin nht khc nhau, thu c 2,2 gam CO v 0,9 gam H O. Cc cht trong X l A. mt ankan v mt ankin. B. hai ankaien. C. hai anken. D. mt anken v mt ankin. Cu 73: Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l A. 2-metylbutan-2-ol. B. 3-metylbutan-2-ol. C. 3-metylbutan-1-ol. D. 2-metylbutan-3-ol.
2 2

Cu 74: Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip (M < M ). t chy hon ton mt lng M cn dng 4,536 lt O (ktc) thu c H O, N v 2,24 lt CO (ktc).
Y 2 2 2 2 X

Cht Y l A. etylamin.

B. propylamin.

C. butylamin.

D. etylmetylamin.