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6CH01_01_que_20120515

6CH01_01_que_20120515

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Published by Kajana Sivarasa

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Published by: Kajana Sivarasa on Dec 08, 2012
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07/15/2013

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Centre NumberCandidate NumberWrite your name here
SurnameOther names
 Total Marks
Paper Reference
Edexcel GCE
P39306A
©2012 Pearson Education Ltd.
7/7/5/5/5/
*P39306A0124*
Chemistry
Advanced SubsidiaryUnit 1: The Core Principles of Chemistry
 Tuesday 15 May 2012 – Afternoon
Time: 1 hour 30 minutes
6CH01/01
Candidates may use a calculator.
Instructions
t
 
Use
black 
ink or ball-point pen.
t
 
Fill in the boxes
at the top of this page with your name,centre number and candidate number.
t
 
Answer
all
questions.
t
 
Answer the questions in the spaces provided
there may be more space than you need 
.
Information
t
The total mark for this paper is 80.
t
The marks for
each
question are shown in brackets
– use this as a guide as to how much time to spend on each question.
t
Questions labelled with an
asterisk 
(
*
) are ones where the quality of yourwritten communication will be assessed
– you should take particular care with your spelling, punctuation and grammar, aswell as the clarity of expression, on these questions.
t
A Periodic Table is printed on the back cover of this paper.
Advice
t
 
Read each question carefully before you start to answer it.
t
Keep an eye on the time.
t
Try to answer every question.
t
Check your answers if you have time at the end.
Turn over 
 
2
*P39306A0224*
SECTION AAnswer ALL the questions in this section. You should aim to spend no more than 20 minutes onthis section. For each question, select one answer from A to D and put a cross in the box .If you change your mind, put a line through the box and then mark your new answer witha cross .1
A solution contains 66 ppm of a solute. The mass of the solute dissolved in 1 kg of thissolution is
A
66 g
B
0.66 g
C
0.066 g
D
0.000066 g
(Total for Question 1 = 1 mark)2
Complete combustion of 50 cm
3
of a hydrocarbon vapour gave 350 cm
3
of carbondioxide, both gas volumes being measured at the same temperature and pressure. Theformula of the hydrocarbon could be
A
C
8
18
B
C
16
C
C
6
14
D
C
5
12
(Total for Question 2 = 1 mark)3
hich of the following statements is true? The Avogadro constant is the number of 
A
grams of any element which contains 6.02 × 10
23
atoms of that element.
B
atoms contained in one mole of any element.
C
atoms contained in one mole of any monatomic element.
D
 particles (atoms, molecules or ions) required to make one gram of a substance.
(Total for Question 3 = 1 mark)
 
3
*P39306A0324*
Turn over 
 
4
n an experiment to determine the enthalpy change of combustion of an alcohol, a spirit burner containing the alcohol was weighed, lit and placed under a copper can containinga known volume of water. The temperature rise of the water was measured and the burner reweighed. The enthalpy change calculated from the results was much lessexothermic than the value reported in the literature.hich of the following factors is
most
likely to be the cause of this error?
A
eat loss around the side of the copper can.
B
The use of a thermometer with a range of 0 – 110 °C rather than 0 – 50 °C.
C
The use of a measuring cylinder for measuring the water rather than a pipette.
D
vaporation of the alcohol during the weighing.
(Total for Question 4 = 1 mark)5
The standard enthalpy changes of formation of carbon dioxide and of methanoic acid areíN-PRO
 –1
DQGíN-PRO
 –1
respectively. Calculate the enthalpy change for thereaction
2
(g)  C
2
(g)
o
C(l)
A
íN-PRO
 –1
B
íN-PRO
 –1
C
N-PRO
 –1
D
N-PRO
 –1
(Total for Question 5 = 1 mark)6
or which of the following changes is the value of 
ǻ
 H 
negative?
A
(g)
o
 
(g)  e
 – 
B
 
Cl
 – 
(s)
o
 
(g)  Cl
 – 
(g)
C
Cl(g)  e
 – 
o
Cl
 – 
(g)
D
Cl
2
(g)
o
2Cl(g)
(Total for Question 6 = 1 mark)

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