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Residual Properties by Equations of State

Residual Properties by Equations of State

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Published by: hameed1966 on Jan 04, 2013
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10/19/2013

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University of Babylon /College Of EngineeringElectrochemical Engineering Dept.Second Stage /Thermodynamics
1
Residual Properties by Equations of State
An attractive alternative to the numerical evaluation of integrals in below equations is theiranalytical evaluation by equations of state.
(1) )1(
0
PdP Z  Rt G
P R
 
(2) 
0
PdP Z  RT  H 
PP R
    
 
(3) 1
00
PdP Z PdP Z  R
PPP R
    
 
Residual Properties from the Virial Equations of Sate
 R BP Z 
1
 Equation (1) reduces to
 RT  BP RT G
 R
 
        
2,
1) / (
 BdT dB RP RT G RT  H 
 xP R R
 Or
    
dT dB B RP RT  H 
 R
 
dT dB RP R
 R
 
P = Z ρ RTdP = RT ( Zd ρ+ρ dZ ) constant T
 Z dZ PdP
    
 
 Z  Z  Z  RT G
P R
ln1)1(
0
   
 

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