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Homework 3

Homework 3

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Homework 1: Advanced polymer physic
 Profs: Lee Jun Young  Student: Luu xuan Dinh1. Chemical reactions
CH
2
=CH-COOHCOOH(-CH
2
-CH-)n
Polyvinyl acetate, addition polymer 
OCH
2
CH
2
CH
2
(-CH
2
-CH
2
-CH
2
-O-)n
H
2
N-(CH
2
)
5
-NH
2
ClO-(CH
2
)
5
-COCl(-HN-(CH
2
)
5
-NH-O-(CH
2
)
5
-CO-)n+
 Non mane: Nylon 66, condensation polymer 
HO-(CH
2
)
5
-COOH (-O-(CH
2
)
5
-CO-)n
Condensation polymer 
HO-CH
2
CH
2
-OHCH
3
NCONCOH
3
C
n 
HN-C(O)-OCH
2
CH
2
-O-C(O)-NH+
Condensation polymer 
CH
2
=CH-F(-CH
2
-CH-)nF
Vinyl flour, addition polymer 
2. Polystyren
FractionWeight fraction(w
i
)Molecular weight Mi Number of molecules Ni Number of fraction n
i
A0.0112.10
3
8.3.10
-4
0.03B0.1921.10
3
90.5.10
-4
0.37C0.2435.10
3
68.6.10
-4
0.28D0.1849.10
3
.36.7.10
-4
0.15E0.273.10
3
27.4.10
-4
0.11F0.08102.10
3
7.8.10
-4
0.03G0.06122.10
3
4.9.10
-4
0.02H0.04146.10
3
2.7.10
-4
0.01
 g  M 
3
10
=
 
iii
 M  M w N 
=
mol  g  M w M 
iiii
/57250
==
mol  g  M n M 
iiin
/40270
==
00.050.10.150.20.250.30.350.40 20 40 60 80 100 120 140 160
Mi 10-3Number fraction
3. Osmotic pressure
 
π
(1) fill out the osmotic pressureConcentration, c (g/l)2.004.006.008.00Osmotic pressure
π
(cm, xylene)2.5855.9659.66013.9535Osmotic pressure
π
(g/cm.sec
-2
)2030.9724684.7447586.69410944.159
π
/c (cm
2
/sec
-2
1.0151.1711.2641.368(2) Draw the graph showing relationship between concentration and
π
/c
y = 5.76x + 91.650601201800 2 4 6 8 10
Fig 1: the influence of 
π
/c on concentration(3) Calculate the number average molecular weightApplication the formula:
65.91
=
n
 M  RT 
And R = 8.315J/mol.K, T = 273 + 90 = 363K 
mol  g  M 
n
/000,33 65.91363*315.8
==
4. GPC of PMMA

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