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Direct Arylation and Applications of Ruthenium Olefin Metathesis Catalysts - Aldrichimica Acta Vol. 40 No. 2

Direct Arylation and Applications of Ruthenium Olefin Metathesis Catalysts - Aldrichimica Acta Vol. 40 No. 2

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Recent Advances in Intermolecular
Direct Arylation Reactions

Evolution and Applications of Second-Generation Ruthenium Olefin Metathesis Catalysts
Recent Advances in Intermolecular
Direct Arylation Reactions

Evolution and Applications of Second-Generation Ruthenium Olefin Metathesis Catalysts

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Categories:Types, Research, Science
Published by: Sigma Aldrich Chemistry on Feb 12, 2009
Copyright:Traditional Copyright: All rights reserved

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04/18/2012

 
ALDRICH CONGRATULATES THE 2007 ACS AWARD WINNERS
VOL. 40, NO. 2 • 2007
 sigma-aldrich.com
Recent Advances in IntermolecularDirect Arylation ReactionsEvolution and Applications o Second-GenerationRuthenium Olen Metathesis Catalysts
 
33
   V   O   L .   4   0 ,   N   O .   2  •   2   0   0   7
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VOL. 40, NO. 2 • 2007
“PLEASE BOTHER US.”
Proessor Gregory B. Dudley o Florida State University kindly suggested that we make 2-benzyloxy-1-methylpyridinium trilate. This crystalline, neutral, and stable organic salt is anexcellent reagent or the protection o an alcohol as a benzyl ether under mild conditions.Reaction with this reagent can be perormed under near-neutral pH, unlike other benzylationprotocols, which require strongly acidic or basic reaction media (e.g., the use o benzyltrichloroacetimidate or benzyl halides).
1,2
(1) Poon, K. W. C.; Dudley, G. B.
 J.
 
Org. Chem.
 
2006
,
71
, 3923. (2) Poon, K. W. C.; House, S. E.;Dudley, G. B.
Synlett 
 
2005
, 3142.
NCH
3
OCF
3
SO
3
6796742-Benzyloxy-1-methylpyridinium trifate
1 g 5 g
Naturally, we made this useul reagent. It was no bother at all, just a pleasure to beable to help.
Do you have a compound that you wish Aldrich could list, and that would help you in your research by saving you time and money? If so, please send us your suggestion; we will bedelighted to give it careful consideration. You can contact us in any one of the ways shownon this page and on the inside back cover.
TABLE OF CONTENTS
Recent Advances in Intermolecular Direct Arylation Reactions
.....................................................................
35
Louis-Charles Campeau, David R. Stuart, and Keith Fagnou,*
University o Ottawa
Evolution and Applications o Second-Generation Ruthenium Olein MetathesisCatalysts
..........................................................................................................................................................................................................................................
45
Yann Schrodi* and Richard L. Pederson,
Materia, Inc.
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