Professional Documents
Culture Documents
Grupa: 3156
Anul: IV
Ploiesti
2012-2013
1|Page
Tema proiectului:
Calculul tehnologic al
serpentine cuptorului de
piroliza a benzinei
2|Page
CUPRINS
3|Page
1. OBIECTIVE:
Stabilirea numrului de serpentine n paralel;
Dimensionarea serpentinei: determinarea lunigimii acesteia n ZC, ZR;
numr coturi;
bilanuri masice, termice pe serpentin;
determinarea parametrilor de funcionare (presiune, temperatur) de-a
lungul serpentinei;
estimare VV (LHSV, h-1) i a timpului total de staionare n zona de
reacie.
4|Page
%Vol. distilat
0
5
10
20
30
40
50
60
70
80
90
95
100
Temperatura,
55
63
70
79
87
94
101
108
115
122
130
136
145
Curba ASTM
160
Temperatura,0 C
140
120
100
80
60
40
20
0
0
20
40
60
80
100
120
% vol distilat
Densitate (relativ): d
0,730
79 620
5|Page
Component
1
2
3
4
5
6
7
8
Hidrogen
Metan
Acetilen
Eten
Etan
Propen
Propan
C4
(C3H4; C4H4; 1-C4H6; 1,2-, 1,3-C4H6)
Butene
(1-C4; cis-, trans-2-C4; i-C4)
Butan (n+i)
Benzin
Combustibil lichid greu
9
10
11
12
H2
CH4
C2H2
C2H4
C2H6
C3H6
C3H8
C4H5
Compoziie,
%mas
0,50
5,20
0,40
25,00
4,10
18,40
2,60
7,70
Masmola
r
2,016
16,043
26,038
28,054
30,070
42,081
44,097
53,084
C4H8
7,40
56,108
C4H10
-
4,70
16,00 (xcf)
8,00
58,123
(MP)
250
3) Caracterisitici constructive
Dimensiuni tuburi:
Diametru interior
Diametru exterior
Lungime
di = 80 mm
de = 100 mm
Lu = 8 m
4) Cinetic
Se admite o cinetic aparent (global) de ordin I pentru piroliza benzinei:
C
Unde: R viteza de reacie,
;
Cbz cencentraie materie prim (benzin),
Ecuaia cinetic se poate scrie sub form integrat:
ln (
)
, sau xc 1 e
Unde: xc conversia benzinei;
timp, s;
k constanta de vitez, s-1;
Respect o dependen Arrhenius de temperatura, cu:
6|Page
1,778 10 s
; Ea
210,03
7|Page
INSTALAIA DE PIROLIZ
Schema unei instalaii de piroliz a benzinei,redus la parile component eseniale,este
redat in figura urmtoare ,distingndu-se secia cald i secia rece a instalaiei.
Fig. Schema de principiu,redus a unei instalaii tipice de piroliz,cu indicarea seciei calde
i reci.
1-cuptor
2-generator de abur
3-coloan de fracionare
4-compresor
5-secie de fracionare
8|Page
9|Page
Tabelul 1.
Nr. Crt
1
2
3
4
5
6
7
(d , t
%Vol.distilat
0
10
30
50
70
90
100
)
Temperatura,
55
70
87
101
115
130
145
0,730 (1000
(d , t
0,730 (1000
(d , t
0,730 (1000
(d , t
0,730 (1000
(d , t
0,730 (1000
(d , t
0,730 (1000
(d , t
10 | P a g e
0,730 (1000
2,29
2,29
2,29
2,29
2,29
2,29
2,29
Temperatura, K
T,K(VE)
t,0C(VE)
328.15
352.501
79.351
343.15
358.422
85.272
360,15
359.577
86.427
374,15
363.052
89.902
388,15
373.408
100.258
403,15
380.013
106.863
418,15
380.668
107.518
55 20
) 699.576 g m
6,34 0,730 5,965 0,730
70 20
) 686.537 g m
6,34 0,730 5,965 0,730
87 20
) 671.759 m
6,34 0,730 5,965 0,730
101 20
) 659.591 m
6,34 0,730 5,965 0,730
115 20
) 647.421 g m
6,34 0,730 5,965 0,730
130 20
) 634.382 g m
6,34 0,730 5,965 0,730
145 20
) 621.343 m
6,34 0,730 5,965 0,730
710
700
690
qL,kg/m3
680
670
660
650
640
630
620
610
0
20
40
60
80
100
Temperatura,
120
140
160
oC
Panta: pa
55
tmVf
tmMf
70
tmVf
pa 0,75
87 101 115
5
0,3161379 e
100,6
tmWf
tmVf
130
145
0,3161379 e
2,599348 10
tmVf
0,4388152 e
100,6
11 | P a g e
)
(
0,4388152 e
, )
( ,
100,6 2,599348 10
102.379
tmCf
100.6
,
(
93.54
)
(
) )
. )
( ,
) )
)
(
, )
( ,
98.744
tmMef
tmVf
0,2161448 e
100,6
100.422
tmMf
tmMef
tmCf
0,2161448 e
92.54
98.744
)
(
, )
( ,
) )
95.642
[1,8 (tmMef
d
273,15)]
,
,
11.875
,
,
, TmMef)
42,9654 TmMef
,
e( ,
42,9654 368.729 ,
.
,
e( ,
TmMef
tmMef
273,15
95.642
(d
,
,
,
,
,
,
,
(0,73456)
,
273,15
98.684
368.792 K
Astfel, relaia se poate utilize pentru TmMef cuprins ntre 305 K i 838 K (32-565 ),
d ,, ntre 0,63i 0,97i Mm = 70 700, cu o eroare de max. cca 7%.
12 | P a g e
3.5.Raport
Raportul masic din molecula medie de hidrocarbur se poate determina cu relatia:
Rw
e(
8,7743 10
(d
,
,
,
,
,
,
Tb
)
.
,
,
,
.
,
8,7743 10
e( ,
(0,73456) ,
374.15 ,
6.226
Tb t
273,15 101 273,15 374,15 K
Cunoscnd raportul masic , raportul dintre numrul de atomi de H i cel de C poate fi calculat
cu relatia:
Ra
A
A
1
Rw
12,011
1
1,008 6.642
1.794
13 | P a g e
Tabel 2.Coeficienti din relatie pentru convertirea curbei de distilare ASTM la curba VE.
I
1
2
3
4
5
6
7
%Vol.
distilat
0
10
30
50
70
90
100
T
T
T
T
T
T
T
Ai
Bi
Ci
2,9747
1,4459
0,8506
3,2680
8,2873
10,6266
7,9952
0,8466
0,9511
1,0315
0,8274
0,6871
0,6529
0,6949
0,4209
0,1287
0,0817
0,6214
0,9340
1,1025
1,0737
2,9747
1,4459
0,8506
3,2680
8,2873
10,6266
7,9952
(55 273,15) ,
(70 273,15) ,
(87 273,15) ,
(101 273,15) ,
(115 273,15) ,
(130 273,15)
(145 273,15) ,
0,73456 ,
0,73456 ,
0,73456 ,
0,73456 ,
0,73456 ,
0,73456
0,73456 ,
Domeniu de temperatur
(ASTM),
10 265
60 320
90 340
110 355
130 400
160 520
190 430
352.501 K
358.422 K
359.577 K
363.052 K
373.408 K
380.013 K
380.668 K
Tabel 3
%Vol.
distilat
0
10
30
50
70
90
100
14 | P a g e
Temperatura pe curba VE la
presiunea atmosferic, K
352.501
358.422
359.577
363.052
373.408
380.013
380.668
Temperatura pe curba VE la
presiunea atmosferic,
79.351
85.272
86.427
89.902
100.258
106.863
107.518
120
Temperatura 0C
100
80
60
40
20
0
0
20
40
60
80
100
120
% Volum
Tf
3,2041 (1
1393
1
1393
1
Tf
1393
1
15 | P a g e
Tnf 41 1393 Tf
)
Tf 41 1393 Tnf
log(p)
41
Tnf 1393
(
1)
0,998 3,2041
Tnf 41
log(p)
1
Tnf 1393
0,998 (3,2041 1) Tnf 41
Presiunea: p
Tf
0,998
5,5 bar
log (5,5)
41
352.501 1393
1)
0,998 ( 3,2041
352.501 41
log (5,5)
1
352.501 1393
1)
0,998 ( 3,2041
352.501 41
414.431K
log (5,5)
41
358.422 1393
1)
0,998 ( 3,2041
358.422 41
log (5,5)
1
358.422 1393
1)
0,998 ( 3,2041
358.422 41
426.078 K
Tf
1393
1
Tf
1393
1
Tf
1393
1
Tf
1393
1
Tf
1393
1
log (5,5)
41
359.577 1393
1)
0,998 ( 3,2041
359.577 41
log (5,5)
1
359.577 1393
1)
0,998 ( 3,2041
359.577 41
427.399 K
log (5,5)
41
363.052 1393
1)
0,998 ( 3,2041
363.052 41
log (5,5)
1
363.052 1393
1)
0,998 ( 3,2041
363.052 41
431.301 K
log (5,5)
41
373.408 1393
1) 373.408 41
0,998 ( 3,2041
log (5,5)
1
373.408 1393
1) 373.408 41
0,998 ( 3,2041
443.025 K
log (5,5)
41
380.013 1393
1) 380.013 41
0,998 ( 3,2041
log (5,5)
1
380.013 1393
1) 380.013 41
0,998 ( 3,2041
450.451 K
log (5,5)
41
380.668 1393
1) 380.668 41
0,998 ( 3,2041
log (5,5)
1
380.668 1393
1) 380.668 41
0,998 ( 3,2041
451.335 K
Tabel 4.
%Volum
0
10
30
50
70
90
100
16 | P a g e
Temperatura pe curba VE la
presiunea de 5,5 bar, K
414.431
426.078
427.399
431.301
443.025
450.451
451.335
Temperatura pe curba VE la
presiunea de 5,5 bar,
141.281
152.928
154.249
158.151
169.875
177.301
178.185
200
180
Temperatura, 0C
160
140
120
100
80
60
40
20
0
0
20
40
60
80
100
120
%Volum
3.8.Vscozitti
Vscozitatea cinematic, L, m2/s, a unei fractiuni petroliere lichide la diferite temperaturi
t, , se poate exprima cu relatia:
(d
,
,
, K , t)
101,766
(d
,
,
K )
29,263]
10
xv(d
K
,
,
,K )
,
,
Unde:
(
,
+
,
xv(d ,, , K ) e* ,
xv(d ,, , K ) 779.487
Relatie valabil pentru:
(K
d ,, ) 10,74 (11.875 0,73456) 10,74 8.723 10.74 ( )
(d
,
,
,K ,t
(d
,
,
,K ,t
(d
,
,
,K ,t
17 | P a g e
101,766
(0,73456 11,875) ,
3.376 10 m s
101,766
) [
(0,73456 11,875) ,
3.207 10 m s
101,766
) [
(0,7345 11,875) ,
3.189 10 m s
)
29,263]
29,263]
29,263]
10
11.875 .
e
779.487
10
10
11,875
e
779.487
11,875
e
779.487
(d
,
,
,K ,t
)
3.136
(d
,
,
,K ,t
)
2.990
(d
,
,
,K ,t
)
2.904
(d
,
,
,K ,t
101,766
(0,73456 11,875) ,
10 m s
101,766
[
(0,73456 11.875) ,
10 m s
101,766
[
(0,73456 11,875) ,
10 m s
101,766
[
(0,73456 11.875) ,
10 m s
[
)
2.895
29,263]
29,263]
29,263]
29,263]
10
11,875
e
779.487
10
11,875
e
779.487
10
11,875
e
779.487
10
11,875
e
779.487
Metoda permite determinarea vscozitii cinematice, cSt, a unei fraciuni petroliere lichide pe
baza t50% vol. distilate:
e(
(91,83 Tb
Unde: A
29,263)
,
e ,
Tb este temperatura, K, la 50% vol. distilate.
Tb 374.15 K
e
A
(91,83 374.15
A
e(
18 | P a g e
800.334
11,875
29,263)
800.334
0,0489 e(
0,0489
0,415 cSt
ra
1500
g
g abur
0,62
h
g mp
930
g
h
p
p
,
,
, K , t)
[(2,964 1,332 d ,, ) t
(0,0538 K
0,3544)
Cu originea IL=0 pentru lichid la 0
(0,003074
19 | P a g e
0,001154 d
(0,003074
,
,
) t ]
0,001154 0,73456)
I (d
,
,
,K ,t
)
[(2,964 1,332 0,73456) 141.281 (0,003074 0,001154 0,73456)
141.281 ] (0,0538 11,875 0,3544) 322.775 J g
(h
d
6.332 m
w
2
(d , t )
0,730 (1000
2,29
664.864 g m
(d , t
0,730 (1000
2,29
624.669 g m
664.864
2
95 20
)
6,34 0,730 5,965 (0,730)
141.281 20
)
6,34 0,730 5,965 (0,730)
624.669
2
644.766 gm
G
w
d
4
3600
w
4 G
3600
d
4 G
3600
d
w
20 | P a g e
w
2
3600
0,124
0,133
2
3600
4 1500
(0,08) 664.864
4 1500
(0,08) 624.669
0.1285 ms
0,133 ms
0,124 ms
L
d
p
d
Re
0,0366
6.332
0,08
644.766 0,1285
2
15.421 Pa
Re
t
t
95
141.281 C
t
t
2
t
(d
,
,
141.281
2
118.141
101,766
(0,73456 11.875)
1.025 10 m s
,K ,t
Re
95
0,08 0,1285
1.025 10
d
79620
29,263]
1002926.829
0,1 6.332
10
2300
11,875
e
812,344
1.583 10
Jh
I (d
,K ,t
5,499 bar
)
[(2,964 1,332 0,73456) 141.281 (0,003074 0,001154 0,73456)
141.281 ] (0,0538 11.875 0,3544) 322.775 J g
Pentru fraciuni petroliere vapori, entalpia specific, kJ/kg, se poate calcula cu relaia:
I (d
,
,
, K , t)
21 | P a g e
532,17 210,61 d ,,
(1,8213 0,45638 d ,, ) t
(4,187 t 837)
(0,0023447 0,00059037 d ,, ) t
(0,07 K
0,84)
I (d
,
,
,K ,t
)
532,17 210,61 0,73456 (1,8213 0,45638 0,73456) 178.185
(0,0023447 0,00059037 0,73456) 178.185
(4,187 178.185 837) (0,07 11,875 0,84)
643.054 J g
L
G
(H
h ) 79620
1500 (703.005 322.775) L
Numr de coturi:
L
L
n1C=0
n2C=3
75 d
L
n
p
w
p
75 d
22.802
(w
L
d
624.669 g m
(p
p
M
R T
w
0,1 L
22.802 m
3 75 0,08
40.802m
2
p ) M
R T
w
2
L
3600
G
d
100 M
(p
R T
10
p )
R T
+
(p
100 M
10
p )
0,0366 40.802 1500
3600
0,08
100 102,481 (5,5 10
p )
*624.669
+
8,314 451.185
1
8,314 451.185
[
]
624.669 100 102,481 (5,5 10
p )
*
23827.5 Pa
4 G
d
0.238 bar
3600
4 G
M
R T
4 1500
5,261
102,481
0,083 451.185
22 | P a g e
d
0,08
3600
3600
5.757 ms
(p
0,133
5.757
2
p ) M
R T
624.669
2
t
t
2.945 ms
14.397
2
14.397 gm
319.533 gm
141.281
178.185
t
141.281
2
(d
,
,
,K ,t
d
Re
178.185
159.733
101,766
(0,73456 11,875) ,
3.226 10 m s
w
0,08 2.945
730316.2
3.226 10
79620
29,263]
2300
0,1 22.802
10
11,875
e
812,344
Regim turbulent
5.703 10
Jh
p
d
I (d
,
,
,K ,t
I (d
,
,
,K ,t )
23 | P a g e
5,499
(H
0,238
H
5,261 bar
)
)
532,17 210,61 0,73456 (1,8213 0,45638 0,73456) 178.185
(0,0023447 0,00059037 0,734456) 178.185
(4,187 178.185 837) (0,07 11.875 0,84) 703.729 J g
d
n
L
L
12 coturi
75 d
L
n
p
75 d
G
(H
H ) 79620
1500 (2134.328 703.729) L
85.790
12 75 0,08
28074.9Pa
4 G
d
3600
R T
178.185
650
t
t
2
, T)
M
R T
4 1500
3600
0,08
5,261
102,481
0,083 451.335
178.185
2
650
421,674
3600
5.759 ms
14.392 gm
503.185 K
0,0092696
(0,001383
5,9712 10
) T
V,
la presiuni joase
1,1249 10
M
(M
,T
)
0,0092696
1,1249 10
24 | P a g e
4 G
0,281 bar
5,261
102,481
0,083 451.335
157.79
R G
L
p
p
10
p
(
)
T
T
100 3600
d M
T
T
(
)
p
p
10
p
0,0366 8,314 1500 151.79
5,261
5,261 10
(
100 3600
0,08 102,481 451.335
923,15
451.335
923,15
(
)
5,261
5,261 10
p
t
t
0,1 L
85.790m
(0,001383
102,481
5,9712 10
0.0093 cP
102,481 ) 503.185
0.934 10
gm s
(M
,T )
0,0092696
(0,001383
1,1249 10
(M
,T
102,481
(M
,T )
2
0.9345 10
p
5,261
4 G
d
0.00935 cP
w
(p
R T
4.98 bar
4 1500
i:
e:
6,571
2
0,08
d L
G
H
G
H
d L
G
d
,K ,t
25 | P a g e
79620
6.783 ms
6.27 ms
Q
Q
Q
,
,
3600
p ) M
R T
Q
I (d
5.759
0,08
2
d
3600
5,261
Re
0.935 10
4 G
6.783
gm s
4,98
102,481
0,083 503.185
w
102,481 ) 503.185
0.935 10
0.934 10
gm s
0,281
3600
5,9712 10
6,571 gm
5.916 gm
6.27 5.916
0.9345 10
3969322.63
0,1 151.79
3.797 10
Jh
)
532,17 210,61 0,73456 (1,8213 0,45638 0,73456) 178.185
(0,0023447 0,00059037 0,73456) 178.185
(4,187 178.185 837) (0,07 11,875 0,84) 694.729 J g
H
1500 694.729
0.974 10
J g
I (d
,
,
,K ,t )
532,17 210,61 0,73456 (1,8213 0,45638 0,73456) 650
(0,0023447 0,00059037 0,73456) 650
(4,187 650 837)
(0,07 11.875 0,84) 2134.328 J g
1500 2134.328
3201492 J g
n (x )
g (x )
M
0,005
x
0,84 2,016
0,052
x
0,84 16,043
0,004
x
0,84 26,038
0,250
x
0,84 28,054
0,041
x
0,84 30,070
0,184
x
0,84 42,081
0,026
x
0,84 44,097
0,077
x
0,84 53,084
0,074
x
0,84 56,108
0,047
x
0,84 58,123
1 x
102,481
0,080
x
0,84
12
Comb
250
0,080
0,320
13
H2O
18,015
0,600
(ra)
1,600
(1+ra)
33,305
ra
59,871
1,600
(1+ra)
(xc)
n
M
0,020016 x
1 ra
n (xc)
(xc)
0,080 x
0,84 250
ra
18,015
0,020016 x
0,0430635
n (xc)
M
n (xc)
1 0,62
0,020016 x
0,0430635
1,62
0,020016 x
0,0430635
H (T)
Cp (T)
K
d
Cp (T)
27,7047
b T c
11.8
0.859 d ,,
H (T)
Cp (T)
0.863
3,38985 10
(27,7047
74,52
3,38985 10
(22,3479
228,2
(27,9609
27 | P a g e
8,40652 Jmol
0,0277047 T
T
T) dT
1
1000
60,2362 10 T
6,48921 10 T
217,365 Jmol
10,8667 121,6808 10
1
1000
T) dT
48,1275 10
0,0000240637 T
27,9609 60,2362 10
H (T)
Cp (T)
1,69493 10
T
22,3479 48,1275 10
H (T)
Cp (T)
1
1000
Cp (T) dT
19,46762 10
0,0000301181T
T
37,56525 10
T ) dT
0,0279609 T
T
1
1000
H (T)
Cp (T)
52,51
83,82
19,71
186,11
(10,8549
Cp (T)
(T)
(16,9533
72,91123 10 T ) dT
(15,5790
1
1000
117,823 Jmol
60,87526 10 T ) dT
0,0000928403T
1
1000
0,0246162 T
79,77959 10
258,8119 10 T
3,2724 10
T
147,617 Jmol
28 | P a g e
72,91123 10
185,6805 10 T
1
1000
0,0134925 T
0,000118816T
0,0108549 T
T 60,87526 10
T
2,65932 10 T
15,5790 312,0373 10
129,985
59,16355 10 T ) dT
237,6317 10 T
(24,6162
1
1000
0,0102338 T
0,0000954863T
T
45,56065 10 T ) dT
59,16355 10
190,9726 10 T
2,02918 10 T
171,067 Jmol
16,9533 258,8119 10
9,01
45,56065 10
0,0000790615T
T
1
1000
0,0108667 T
158,1230 10 T
2,43037 10 T
24,6162 185,6805 10
H (T)
(13,4925
104,68
H (T)
Cp (T)
1,97212 10 T
7,73156 Jmol
10,8549 237,6317 10
H (T)
Cp (T)
(10,2338
37,56525 10 T ) dT
0,0000608404T
1,51869 10 T
93,4888 Jmol
13,4925 190,9726 10
H (T)
Cp (T)
121,6808 10 T
1,25217 10 T
44,2002 Jmol
10,2338 158,1230 10
H (T)
Cp (T)
(10,8667
79,77959 10 T ) dT
0,000129406T
0,0169533 T
T 98,17201 10
T
1
1000
24,8501 Jmol
312,0373 10 T
98,17201 10 T ) dT
0,000156019 T
0,015579 T
1
1000
(T)
(T)
M
1000
100
C (t) dT
100
M
( 1,69578
1000
10
(4,6894
0,29309K
1,18074d
,
,
0,45638d
)(T
,
,
) dT
M
1000
273) dT
100
102,481
( 1,69578
1000
102,481
10
1000
H
(T)
M
1000
100
10
Cp
Q
1
M
(4,6894
0,000450552 T
34,4 0,62775 10
0,29309K
1,18074d
250
( 1,69578
1000
273) dT
128,94 Jmol
0,0389407 T
(4,6894
0,45638 0,745)dT
1,18074 0,745)(T
M
( 1,69578
1000
250
10
1000
(T)
(4,6894
0,000195213 T
H (T)
100
0,29309 11,791
,
,
0,45638d
)(T
0,45638 0,9189) dT
273) dT
C (T) dT
1
(34,4
18,015
0,62775 10
5,6079 10
T ) dT
1,03764 10
T
0,000017423 T
1,90952 T
10
T
0,000017423 T
1,90952 T J g
Comp
29 | P a g e
) dT
273) dT
0,29309 11,1685
1,18074 0,9189)(T
,
,
H (T)
1,03764
Jmol
1,69493 10
0,0000240637
6,48921 10
Jmol
T
0,0277047 T 8,40652
T
0,0223479 T 83,3166
T
0,0000301181T
0,0279609 T
217,365
T
0,0000608404T
0,0108667 T
44,2002
T
0,0000790615T
0,0102338 T
93,4888
T
0,0000954863T
0,0134925 T
7,73156
T
0,000118816T
0,0108549 T
117,823
T
0,0000928403T
0,0246162 T
171,067
T
0,000129406T
0,0169533 T
24,8501
T
0,000156019 T
0,015579 T
147,617
T
0,0389407 T 128,94
1
2
3
H2
CH4
C2H2
0
-74,52
228,2
C2H4
52,51
1,25217 10
C2H6
-83,82
1,51869 10
C3H6
19,71
1,97212 10
C3H8
-104,68
2,43037 10
C4H5
186,11
2,02918 10
C4H8
-9,01
2,65932 10
10
C4H10
-129,985
3,2724 10
11
-100
0,000195213
12
13
MP
benzin
Comb
H2O
100
-241,814
0,000450552 T
Comp
H2
CH4
C2H2
C2H4
C2H6
C3H6
30 | P a g e
0,0435555 T
47,0096
1000 n (x )
x
J g MP reacionat
H
5
[1,69493 10
0,84 2,016
52
[0,0000240637
0,84 16,043
4
[( 6,48921) 10
0,84 26,038
217,365]
250
[( 1,25217) 10
0,84 28,054
44,2002]
41
[( 1,51869) 10
0,84 30,07
93,4888]
184
[( 1,97212) 10
0,84 42,081
7,73156]
0,0277047 T
8,40652]
0,0223479 T
0,0000301181T
0,0279609 T
0,0000608404T
0,0108667 T
T
T
0,0000790615T
0,0000954863T
83,3166]
0,0102338 T
0,0134925 T
C3H8
C4H5
C4H8
10
C4H10
11
MP
benzin
Comb
12
13
26
[( 2,43037) 10 T
0,000118816T
0,0108549 T
0,84 44,097
117,823]
77
[( 2,02918) 10 T
0,0000928403T
0,0246162 T
0,84 53,084
171,067]
74
[( 2,65932) 10 T
0,000129406T
0,0169533 T
0,84 56,108
24,8501]
47
[( 3,2724) 10
T
0,000156019 T
0,015579 T
0,84 58,123
147,617]
1000
(0,000195213 T
0,0389407 T 128,94)
102,481
80
(0,000450552 T
0,0435555 T 47,0096)
0,84 250
H2O
3,86691 10
(T)
Comp
H2
CH4
C2H2
C2H4
C2H6
C3H6
C3H8
31 | P a g e
3,86691 10 T
0,000238042 T
0,000238042 T
0,10363 T
0,10363T
1358,52
1358,52
(x , T) 1000 n (x )
H
H
J g MP alim sau J g prod de reacie
5 x
[1,69493 10
0,84 2,016
52 x
[0,0000240637
0,84 16,043
4 x
[ 6,48921 10
0,84 26,038
217,365]
250 x
[ 1,25217 10
0,84 28,054
44,2002]
41 x
[ 1,51869 10
0,84 30,070
93,4888]
184 x
[ 1,97212 10
0,84 42,081
7,73156]
26 x
[ 2,43037 10
0,84 44,097
117,823]
0,0277047 T
8,40652]
0,0223479 T
83,3166]
0,0000301181T
0,0279609 T
0,0000608404T
0,0108667 T
0,0000790615T
0,0102338 T
0,0000954863T
0,0134925 T
0,000118816T
0,0108549 T
C4H5
C4H8
10
C4H10
11
MP
benzin
Comb
12
13
77 x
[ 2,02918 10 T
0,0000928403T
0,0246162 T
0,84 53,084
171,067]
74 x
[ 2,65932 10 T
0,000129406T
0,0169533 T
0,84 56,108
24,8501]
47 x
[ 3,2724 10
T
0,000156019 T
0,015579 T
0,84 58,123
147,617]
1000 (1 x )
[0,000195213 T
0,0389407 T 128,94]
102,481
80 x
[0,000450552 T
0,0435555 T 47,0096]
0,84 250
H2O
3,86691 10
T x
0,00023804 T x
0,00190487 T
0,10363 T x
0,37998 T 1358,52 x
1258,18
650 923,15 K
6,571 bar
1500 gh
0,62
32 | P a g e
725
Presupunem:
xc
xc
H
0,106382
xc
H
xc
0,106382
(xc , T )
1500
( 3,86691 10
998,15 0,106382 0,00023804 998,15
0,106382 0,00190487 998,15
0,10363 998,15 0,106382
0,37998 998,15 1358,52 0,106382 1258,18)
1,738158 10 Jh
,
ra
(T) dT
C
,
1500 0,60
( 1,03764 10
T
0,000017423 T
1,90952 T
1,03764
10
T
0,000017423 T
1,90952 T )
1500 0,60
( 1,03764 10
923,15
0,000017423 923,15
1,90952 923,15
1,03764 10
998,15
0,000017423 998,15
1,90952 998,15)
150553,08 J h
Q
xc
650
(
725
273,15)
2
1500 0,106382
( 3,86691 10
960,65
0,000238042 960,65
1358,52) 213019,42 Jh
0,10363 960,65
1,07391004 10
Q
1,738158 10
1,02782 10 Jh
Q
L
d
H
213019,42
L
Q
d
1,738158 10
10,273 m
33 | P a g e
150553,08
150553,08 213019,42
0,1 318470
1,07391004 10
n
L
(xc )
(xc )
75 d
10,273 1 75 0,08 16,273 m
1,6
37,154
0,020016 0 0,0430635
1,6
35,403
0,020016 0,106382 0,0430635
R L
(1
ra)
d 3600
100 M (xc ) (10 p
p ) M (xc )
+
T
1000 T
T
1000 T
[
]
p
100 M (xc ) (10 p
p ) M (xc )
8,314 16,273 1500 (1 0,62)
0,0366
3600
0,08
4,913 100 37,154 (10 4,913
p ) 35,403
*
+
923,15
1000 998,15
923,15
1000 998,15
[
]
4,913 100 37,154 (10 4,913
p ) 35,403
p
*
74692 Pa
p
0.746 bar
M (0)
R T
(p
6,571 37,154
0,083 923,15
p ) M
R T
(xc )
3.186
2
w
w
w
1,968
2
3.186 gm
1.781 gm
2.577 gm
(1 ra)
4 G
4 1500 (1 0,62)
42.149 ms
3600 3.186
0,08
3600
d
(1 ra)
4 G
4 1500 (1 0,62)
75.399 ms
3600 1.781
0,08
3600
d
w
w
42.149 75.399
58.774 ms
2
2
L
w
34 | P a g e
10.273
58.774
0.175s
725
2
lg(K)
11,25
xc
1 e
Presupus: xc
273,15
10970
T
(
960,65 K
K(T
1
0,106382
)
e
0,677
,
0,106297
1500 gh
998,15 K
1,738158 10 Jh
p
p
4,913 0.746 4.167bar
0
xc
0 0,106382 0,106382
761
xc
0,430083
xc
xc
xc
0,106382 0,430083 0,536465
Bilan termic pe sector:
i:
H
G
H (xc , T )
H
G
H (xc , T )
1500
( 3,86691 10
998,15 0,106382 0,00023804 998,15
0,106382 0,00190487 998,15
0,10363 998,15 0,106382
0,37998 998,15 1358,52 0,106382 1258,18)
1,738158 10 Jh
H
G
H (xc , T )
1500
( 3,86691 10
1034,15 0,536465 0,00023804 1034,15
0,536465 0,00190487 1034,15
0,10363 1034,15 0,536465
0,37998 1034,15 1358,52 0,536465 1258,18)
2,798098 10 Jh
Presupunem:
35 | P a g e
ra
(T) dT
C
,
1500 0,60
( 1,03764 10
T
0,000017423 T
1,90952 T
1,03764
10
T
0,000017423 T
1,90952 T )
1500 0,60
( 1,03764 10
998,15
0,000017423 998,15
1,90952 998,15
1,03764 10
1034,15
0,000017423 1034,15
1,90952
1034,15) 73431,04 Jh
xc
725
(
761
273,15)
2
1500 0,430083
( 3,86691 10
1016,15
0,000238042 1016,15
1016,15 1358,52) 841168,85 Jh
0,10363
n
L
d
2,798098 10
2
(xc )
(xc )
De continuat
36 | P a g e
75 d
73431,04 841168,85
0,1 318470
19,73
1,6
0,020016 0,106382
1,6
0,020016 0,536465
2 75 0,08
0,0430635
0,0430635
1,738158 10
31,73 m
35,403
29,739
19,73 m
R L
(1
ra)
3600
p
100 M (xc ) (p
10
*
T
T
T
[
p
100 M (xc ) (p
10
8,314 31,73 1500 (1
0,0366
3600
0,08
4.167 100 35,403 (10 4,606
*
998,15
1000
998,15
1000
[
4.167 100 35,403 (10 4,606
848032.2 Pa
(p
(xc )
(xc )
(xc )
p ) M
R T
2
1.781 29,739
0,083 1034,15
0.617
2
1.781 gm
0.617 gm
1.199 gm
4 G
3600
(1
ra)
d
4 1500 (1
3600 1.781
0,62)
0,08
75.399 ms
4 G
3600
(1
ra)
d
4 1500 (1
3600 0.617
0,62)
0,08
217.645 ms
75.399
2
L
w
217.645
2
19.73
184.2215
0.1065 s
725
37 | P a g e
761
2
p ) 29,739
+
1034,15
1034,15
]
p ) 29,739
(xc )
1.781
0,848 bar
p ) M
R T
(p
p ) M
1000
T
p ) M
0,62)
273,15
1016,15 K
184.2215 ms
lg(K)
10970
T
11,25
K(T
2,846
(1 xc ) (1 e
xc
Presupus: xc
0,430083
(1
0,106382) (1
0,431876
1500 gh
1034,15 K
2,798098 10 Jh
p
p
1.781 0,848
0
xc
xc
0,106382
t
Presupunem:
t
828,622
xc
828,622
xc xc
828,622
0.933 bar
0,430083
0,84
273,15
0,536465
0,536465
0,303535
1101,772 K
H (xc , T )
1500
( 3,86691 10
1101,772 0,84 0,00023804 1101,772 0,84
0,00190487 1101,772
0,10363 1101,772 0,84 0,37998
1101,772 1358,52 0,84 1258,18) 3,777234 10 Jh
,
ra
C
,
(T) dT
1500 0,60
( 1,03764 10
T
0,000017423 T
1,90952 T
1,03764
10
T
0,000017423 T
1,90952 T )
1500 0,62
( 1,03764 10
1034,15
0,000017423 1034,15
1,90952
1034,15 1,03764 10
1101,772
0,000017423 1101,772
1,90952 1101,772) 140092,80 Jh
38 | P a g e
828,622
273,15)
2
1500 0,303535
( 3,86691 10
1067,961
0,000238042 1067,961
1067,961 1358,52) 578088,14 Jh
xc
761
(
0,10363
d
3,777234 10
n
L
(xc )
75 d
16,964
2 75 0,08
2,798098 10
28,964 m
1,6
0,020016 0,536465
29,739
0,0430635
1,6
M (xc )
26,721
0,020016 0,84 0,0430635
R L
G (1 ra)
d 3600
p
100 M (xc ) (p
10
p ) M (xc )
*
+
T
T
1000
T
T
[
]
p
100 M (xc ) (p
10
p ) M (xc )
8,314 28,964 1500 (1 0,62)
0,0366
3600
0,08
3,754 100 29,739 (10 3,754
p ) 26,721
*
+
1034,15
1000 1101,772
1034,15
1000 1101,772
[
]
3,754 100 29,739 (10 3,754
p ) 26,721
101291 Pa
(p
p
R
p
R
(p
1.013 bar
) M (xc ) (4.167 0,848 ) 29,739
1.149 gm
T
0,083 1034,15
) M (xc ) (3.754 1.149) 26,721
0.76118 gm
T
0,083 1101.772
1.149
2
39 | P a g e
140092,80 578088,14
0,1 318470
0.76118
2
1.5296 gm
16,964 m
4 G
3600
4 G
3600
(1
(1
ra)
d
4 1500 (1
3600 1.149
ra)
d
4 1500 (1
3600 0.76118
116.873
2
L
w
176.419
2
16,964
146.65
0.62)
0.08
116.873 ms
0.62)
0,08
176.419 ms
146.65 ms
0.115 s
761
11,25
828,622
2
10970
T
273,15
K(T
9,508
(1 xc ) (1 e
xc
Presupus: xc
0,303535
40 | P a g e
1067,961 K
(1
0,536465) (1
0,303725
Anexe
Nr. Crt
1
2
3
4
5
6
7
I
1
2
3
4
5
6
7
%Vol.distilat
0
10
30
50
70
90
100
%Vol.
distilat
0
10
30
50
70
90
100
%Vol.
distilat
0
10
30
50
70
90
100
41 | P a g e
Temperatura,
55
70
87
101
115
130
145
Ai
Bi
Ci
2,9747
1,4459
0,8506
3,2680
8,2873
10,6266
7,9952
0,8466
0,9511
1,0315
0,8274
0,6871
0,6529
0,6949
0,4209
0,1287
0,0817
0,6214
0,9340
1,1025
1,0737
Temperatura pe curba
VE la presiunea
atmosferic, K
352.501
358.422
359.577
363.052
373.408
380.013
380.668
Temperatura, K
328.15
343.15
360,15
374,15
388,15
403,15
418,15
T,K(VE)
352.501
358.422
359.577
363.052
373.408
380.013
380.668
t,0C(VE)
79.351
85.272
86.427
89.902
100.258
106.863
107.518
Domeniu de temperatur
(ASTM),
10 265
60 320
90 340
110 355
130 400
160 520
190 430
Temperatura pe curba
VE la presiunea
atmosferic,
79.351
85.272
86.427
89.902
100.258
106.863
107.518
%Volum
0
10
30
50
70
90
100
Temperatura pe curba VE la
presiunea de 5,5 bar, K
414.431
426.078
427.399
431.301
443.025
450.451
451.335
Temperatura pe curba VE la
presiunea de 5,5 bar,
141.281
152.928
154.249
158.151
169.875
177.301
178.185
Sector
Parametru
ti,
pi, bar
p, bar
L, m
nc, coturi
Lech, m
Rem
Qf, kJ/h
95
5,5
1.542
6.332
0
141.281
5,499
0.238
22.802
3
40.802m
730316.2
5.703*105
178.185
5,261
0,281
85.790
12
157.79
3969322.63
3.797*106
650
6,571
0.746
10.273
1
16,273
0.175
0,106382
0,106297
725
1.781
0,848
19,73
2
31,73
0.1065
0,430083
0,431876
761
0.933
1.013
16,964
2
28,964
0.115
0,303535
0,303725
1002926.829
1.583*105
42 | P a g e