Welcome to Scribd. Sign in or start your free trial to enjoy unlimited e-books, audiobooks & documents.Find out more
Standard view
Full view
of .
Look up keyword
Like this
2Activity
0 of .
Results for:
No results containing your search query
P. 1
IIT MAIN PAPER 2013

IIT MAIN PAPER 2013

Ratings: (0)|Views: 122|Likes:
Published by Apex Institute

Apex institute for IIT-JEE is the institution of making IITians in the Ghaziabad. It is the Institute in Indirapuram to making IITians (Eng..). Its mission is to upgrade the teaching profession by providing high quality education and training to students who will be the industry's future engineers.

Apex institute for IIT-JEE is the institution of making IITians in the Ghaziabad. It is the Institute in Indirapuram to making IITians (Eng..). Its mission is to upgrade the teaching profession by providing high quality education and training to students who will be the industry's future engineers.

More info:

Published by: Apex Institute on Feb 03, 2013
Copyright:Attribution Non-commercial

Availability:

Read on Scribd mobile: iPhone, iPad and Android.
See more
See less

09/17/2013

 
 
JEE - MAIN
CHEMISTRY
(Part-A)
 
1.
Consider the following statements :I. Atomic hydrogen is obtained by passing hydrogenthrough an electric arc.II. Hydrogen gas will not reduce heated aluminiumoxideIII. Finely divided palladium adsorbs large volumeof hydrogen gasIV. Pure nascent hydrogen is best obtained byreacting Na with C
2
H
5
OHWhich of the above statements is/are correct ?(1) I alone (2) II alone(3) I, II and III (4) II, III and IV
2.
When ethanal reacts with CH
3
MgBr and C
2
H
5
OH/dryHCl, the product formed are -(1) ethyl alcohol and 2-Propanol(2) ethane and hemi-acetal(3) 2-propanol and acetal(4) propane and ethyl acetate
3.
How many moles of CH
3
I will react with one mole of the ethylamine to form a quarternary salt ?(1) 2 (2) 3 (3) 4 (4) 5
4.
26.8 g of Na
2
SO
4
nH
2
O contains 12.6 g of water .The value of ‘n’ s(1) 1 (2) 10 (3) 6 (4) 7
5.
The concentration of oxalic acid is‘x’ mol litre
 –1
40mL of this solution reacts with 16 mL of 0.05 Macidified KMnO
4
. What is the pH of '
 x
' M oxalic acidsolution (Assume that oxalic acid dissociatescompletely)(1) 1.3 (2) 1.699 (3) 0.05 (4) 2
6.
Which pair of species given below produce bakelite?(1) phenol, methanol(2) phenol, NaOH(3) phenol, urea(4) phenol, formaldehyde
7.
A drug that is antipyretic as well as analgesic is-(1) Chloroquin(2) Penicillin(3) Paracetamol(4) Chloropromazine hydrochloride
8.
Which of the following can possibly be used asanalgesic without causing addiction andmodifications ?(1) Morphine(2) N-Acetyl-para-aminophenol(3) Diazepam(4) Tetrahydrocatenol
9.
 Na
2
HPO
4
is used to test -(1) Ca
+2
(2) Ba
+2
 (3) Ni
+2
(4) Mg
+2
 
10.
1 mole of N
2
& 3 mole of H
2
filled in one litre bulbwere allowed to reaction when the reaction attainedequilibrium, two third of N
2
converted to NH
3
. If ahole is then made in the bulb, the mole ratio of thegases N
2
, H
2
& NH
3
effusing out initially would berespectively -
 
(1) 1 : 3 : 4 (2)28:2:17 (3)281:21:171(4)281:23:174 
11.
Which of the following is not a state function -
 
(1) q + w (2) Q/T(3) E + PV (4) Q/W
12.
The relative rate of acid catalysed dehydration of following alcohols would be -
 
Ph – CH – CH – CH
3
CH
3
OH{P}
 
Ph – CH – CH
2
– CH
2
– OHCH
3
{Q}
 
Time : 3 Hours Total Marks : 360Instructions :
There are three parts in question paper A, B, C consisting of chemistry, Physics & Mathematics having30 questions in each part of equal weightage. Each question is allotted
four marks
for each correct response.
1/4 (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from thetotal score will be made if no response is indicated for an item in the answer sheet.
 
 
Ph – C – CH
2
– CH
3
 CH
3
 {R}OHPh – C – CH
2
– OHCH
3
 {S}CH
3
(1) R > P > Q > S (2) P > R > S > Q(3) R > S > P > Q (4) R > S > Q > P
13.
The ether 
OCH
2
when treated withHI produces – [I]
CH
2
I
[II]
CH
2
– OH
 [III]
I
[IV]
OH
(1) I and III (2) Only II(3) I and IV (4) Only III
14.
40% of a mixture of 0.2 mole of N
2
and 0.6 mole of H
2
react to give NH
3
according to the equation, N
2
(g)+ 3H
2
(g) 2NH
3
(g) at constant temperature and pressure. Then the ratio of the final volume to theinitial volume of gases are :(1) 4 : 5 (2) 5 : 4 (3) 7 : 10 (4) 8 : 5
15.
for the reaction, X + Y Z is 4.606 kcal. Theequilibrium constant for the reaction at 227ºC is(1) 100 (2) 10 (3) 2 (4) 0.01
16.
According to Bronsted Lowry concept, the correctorder of strength of bases follows the order :(1) CH
3
COO
 – 
> OH
 – 
> Cl
 – 
 (2) OH
 – 
> CH
3
COO
 – 
> Cl
 – 
 (3) CH
3
COO
 – 
> Cl
 – 
> OH
 – 
 (4) OH
 – 
> Cl
 – 
> CH
3
COO
 – 
 
17.
The element having the highest ionization energy hasthe outer shell configuration as -(1) ns
2
np
3
(2) ns
2
np
6
(3) ns
2
(4) ns
2
np
5
18.
Which of the following processes is exothermic ?(1) EA of N (2) IE of O
 – 
(3) EA of Cl (4) IE of Cl
19.
Which of the following is not correct ?(1) XeO
3
has pyramidal shape(2) The hybrid state of Xe in XeF
4
is sp
3
d
2
(3) In calcium carbide, between carbon atoms onesigma and two
π
-bonds are present(4) In silica(SiO
2
), one Si atom is attached with twooxygen atoms
20.
Which of the following contains minimum number of lone pairs around Xe atom ?(1) XeF
4
(2) XeF
6
 (3) XeOF
2
(4) XeF
2
 
21.
The two isomers
 X 
and
with the formulaCr(H
2
O)
5
CIBr 
2
were taken for experiment ondepression in freezing point. It was found that onemole of 
 X 
gave depression corresponding to 2 molesof particles and one mole of 
gave depression due to3 moles of particles. The structural formulae of 
 X 
and
respectively are -(1) [Cr(H
2
O)
5
Cl]Br 
2
; [Cr(H
2
O)
4
Br 
2
]Cl
H
2
O(2) [Cr(H
2
O)
5
Cl]Br 
2
; [Cr(H
2
O)
3
CIBr 
2
]
⋅2
H
2
O(3) [Cr(H
2
O)
5
Br]BrCl; [Cr(H
2
O)
4
CIBr] Br 
H
2
O(4) [Cr(H
2
O)
4
Br 
2
]Cl
H
2
O; [Cr(H
2
O)
5
Cl]Br 
2
22
Rates of addition of Cl
2
/H
2
O of the following alkenesare
H
2
C=CH
2
(P)H
2
C=CH–C–H(Q)O
 
CH
3
 –CH
2
 –HC=CH
2
(R)CH
3
 –C=CH
2
(S)
 
CH
3
 (1) S > R > P > Q (2) S > P > Q > (3) P > Q > R > S (4) P > Q > S >
23.
(i) Na/ NH
3
(
l
)(ii) C
2
H
5
OH(i) O
3
(ii) H
2
O-Zn(A)
 ProductProduct will be -(1) CHO–CHO(2) CHO–CH
2
 –CHO(3)
CH
3
 –C–C–CH
3
OO
 (4) CHO–CHO & CHO–CH
2
 –CHO
24.
In the reaction
CH
3
 –CH–CH
2
 –Br 
(i) X mole NaNH
2
(ii) C
2
H
5
Br 
Br CH
3
 –C
C–C
2
H
5
 The value of [
 X 
] is(1) One (2) Two (3) Three (4) Four 
25.
Relate the following compounds -
CFClBr CClFBr CFBr ClCBr FClS
 
 
 
(1) Identical (2) Enantiomer (3) Diastereomers (4) Meso
26.
The correct order of acidic strength of following acidis -
COOHOH(I)COOHOH(II)HOCOOHCH
3
(III)COOH(IV)OH
 
(1) II > I > III > IV (2) I > II > III > IV(3) II > I > IV > III (4) II > IV > I > III
27.
In the phenomenon of osmosis, the semipermeablemembrane allows the passage of (1) solute particles(2) solvent molecules only(3) both solute and solvent(4) none
28.
What is the contribution of the atom present at theedge centre to the cubic unit cell ?(1) 1/2 (2) 1/4(3) 1/8 (4) 1
29.
In the cell, Zn | Zn
2+
| | Cu
2+
| Cu, the negativeterminal is -(1) Cu (2) Cu
2+
 (3) Zn (4) Zn
2+
 
30.
Assign double bond configuration of the following -
COOHCH
2
OH NCH
2
 N–H
2
CCN
(1) E, Z (2) Z, Z(3) E, E (4) Z, E
MATHEMATICS
(Part-B)
 
31.
 f 
(
 x
) = log25
2
 x
and
 g 
(
 x
) = log
x
5
 
then
 f 
(
 x
) =
 g 
(
 x
)holds for 
 x
 belonging to -(1)
 R
(2) (0, 1)
(1,
)(3)
φ
(4) none
32.
The area enclosed by the parabola
 y
2
= 4
ax
betweenthe ordinates
 x
= a and
 x
= 9
a
is -(1) 8
a
2
(2) 1083
2
a
(3) 2083
2
a
(4)
a
2
33.
If S
λ
 
=
=
λ
0
1
, then
λ=λ
λ
n
1
)1(=(1)2)1(
nn
(2)2)1(
+
nn
 (3)2)2(
+
nn
(4) none of these
34.
If 
    π    π    π    π
72cos72sin72sin72cos=
1001, Then the least positive integral value of k is -(1) 6 (2) 7 (3) 3 (4) 4
35.
The number of 2 digit numbers , which are of theform
 xy
with
 y
<
 x
are given by(1) 45 (2) 55 (3) 17 (4) None
36.
Let
 A
,
 B
,
be three independent events such that
 P 
(
 A
) =31,
 P 
(
 B
) =21,
 P 
(
) =41. Then probability of exactly two events occuring out of three events is -(1) 1/2 (2) 1/3(3) 1/4 (4) none of these
37.
If a variable
 x
takes values
 x
i
such that
a
 
 
 x
i
 
 
b
, for 
i
= 1, 2, ----
n
, then -
 
(1)
a
 
Var (
 x
)
 
b
(2)
a
2
 
Var (
 x
)
 
b
2
(3)4
2
a
 
Var (
 x
) (4) (
b
– 
a
)
2
 
Var (
 x
) 
38.
A variable line has it's intercepts on the coordinateaxes
e
,
e
' where2
e
,2'
e
are eccentricies of hyperbola and it's conjugate hyperbola then the linealways touches the circle
 x
2
+
 y
2
=
2
, where
= ?(1) 1 (2) 2(3) 3 (4) cannot be decided
39.
If it is possible to draw a line which belongs to all thegiven family of lines
 y
– 2
 x
+ 1 +
λ
1
(2
 y
– 
 x
– 1) = 0, 3
 y
  – 
 x
 – 6 +
λ
2
(
 y
3
 x
+ 6) = 0 and
ax
+
 y
– 2 +
λ
3
(6
 x
+
ay
– 
a
) = 0 , then -
 
(1)
a
= 4 (2)
a
= 3(3)
a
= 2 (4)
a
= 2
40.
If (
α
, 0) is an interior point of 
 ABC 
formed by thelines
 x
– 
 y
= 0, 4
 x
+ 3
 y
– 12 = 0 and
 y
+ 2 = 0 thenintegral values of 
α
are
 
(1) 1 (2) 2(3) 4 (4) 8

You're Reading a Free Preview

Download
scribd
/*********** DO NOT ALTER ANYTHING BELOW THIS LINE ! ************/ var s_code=s.t();if(s_code)document.write(s_code)//-->