TRNG THPT THUN THNH S 1

( thi gm c 5 trang)

KHO ST CHT LNG NM HC 2010 LN 1 MN: HA HC Thi gian lm bi: 90 pht; (50 cu trc nghim) M thi 808

H, tn th sinh:.......................................................................... S bo danh:............................................................................... Cho khi lng nguyn t ca cc nguyn t theo vC: C=12, O=16, H=1, Al=27, Mg=24, N=14, Fe=56, Cu=64, S=32, Ag=108, Na=23, K=39, Ba=137, Ca=40, Ba=137, Zn=65, Br=80 v Cl=35,5 Cu 1: Cho cc phn ng sau: a) Cu + HNO3 long b) Fe2O3 + H2SO4 c, nng c) FeS2 + dung dch HCl d) NO2 + dung dch NaOH e) HCHO + H2 f) glucoz + dung dch Br2 g) C2H4 + dung dch KMnO4 h) glixerol + Cu(OH)2 Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l A. a, c, d, e, f, g B. a, b, c, d, e, h C. a, c, d, g, h D. a, d, e, f, g Cu 2: Thm V ml dung dch hn hp gm KOH 1M v Ba(OH)2 0,5M vo cc cha 100 ml dung dch hn hp gm AlCl3 1M, CuSO4 1,5M v Fe2(SO4)3 0,5M th thu c kt ta c khi lng ln nht. gi tr ca V l A. 200 ml B. 550 ml C. 600 ml D. 450 ml Cu 3: Ha tan ht 26,43 gam hn hp bt gm Mg, Al, Al2O3 v MgO bng 795 ml dung dch hn hp gm HCl 0,5M v H2SO4 0,75M (va ). Sau phn ng thu c dung dch X v 4,368 lt kh H2 ( ktc). C cn dung dch X thu c khi lng mui khan l A. 95,92 gam B. 88,18 gam C. 86,58 gam D. 100,52 gam Cu 4: ng vi cng thc C8H8O2, c bao nhiu ng phn este m trong cu to c vng benzen? A. 3 ng phn B. 6 ng phn C. 5 ng phn D. 4 ng phn Cu 5: C 5 l ha cht b mt nhn ng ring bit 5 dung dch khng mu sau y: NH4HS, K2SO3, BaCl2, KHCO3 v NaCl. phn bit cc l dung dch trn thuc th cn dng l A. qu tm B. dung dch NH4Cl C. dung dch KHSO4 D. dung dch NaOH Cu 6: X l hn hp gm mt anken v mt ankin. t chy hon ton m gam X, thu c 1,904 lt CO2 ( ktc) v 1,26 gam H2O. Mt khc, m gam X lm mt mu hon ton dung dch cha 6,4 gam Brom. Cng thc phn t ca anken v ankin c trong X l A. C3H6 v C3H4 B. C4H8 v C3H4 C. C3H6 v C5H8 D. C4H8 v C4H6 Cu 7: t chy hon ton m gam mt amin n chc X bng lng khng kh (va ), thu c 8,96 lt CO2; 12,6 gam hi nc v V lt N2. Gi thit khng kh ch gm nit v oxi trong oxi chim 20% th tch. Cc th tch o ktc. Gi tr ca m, V v cng thc ca X ln lt l A. 7,9 gam; 64,96 lt; C2H5N B. 9,0 gam; 69,44 lt; C2H7N C. 12,4 gam; 91,84 lt; C3H9N D. 7,3 gam; 73,92 lt; C4H9N Cu 8: Nung hn hp M gm x mol Fe v 0,15 mol Cu trong khng kh mt thi gian, thu c 31,2 gam hn hp cht rn N. Ha tan ht hn hp N bng dung dch H2SO4 c, nng, d thu c 6,72 lt kh SO2 duy nht (ktc). Gi tr ca x l A. 0,6 mol B. 0,25 mol C. 0,24 mol D. 0,3 mol Cu 9: Cho cc cp cht sau y tc dng vi nhau: (1) Cl2 + O2 (2) H2S + O2 (3) H2S + Pb(NO3)2 (4) Cl2 + NaOH (5) dung dch NH3 + dung dch AlCl3 (6) dung dch Br2 + FeSO4 (7) dung dch KI + FeCl3 (8) dung dch NaAlO2 + dung dch AlCl3 (9) CuS + HCl c (10) dung dch NaHCO3 + dung dch Ba(OH)2 Cp cht khng xy ra phn ng l
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A. 1, 9 B. 2, 6 C. 6, 9 D. 1, 6, 8 Cu 10: kh hon ton 3,04 gam hn hp X gm FeO, Fe2O3 v Fe3O4 th cn 0,05 mol H2. Mt khc, ha tan hon ton 3,04 gam hn hp X bng dung dch H2SO4 c, nng th thu c V ml kh SO2 (sn phm kh duy nht ktc). Gi tr ca V l A. 448 ml B. 224 ml C. 336 ml D. 112 ml Cu 11: Cc dung dch sau y c cng nng mol (vi dung mi l nc v xt cng iu kin v nhit , p sut): natri hiroxit (1); anilin (2); amoniac (3); metylamin (4); iphenylamin (5); etylamin (6). Dy cc cht c sp xp theo chiu tng dn pH l A. (5); (4); (2); (6); (1); (3) B. (1); (6); (3); (4); (2); (5) C. (1); (4); (2); (5); (3); (6) D. (5); (2); (3); (4); (6); (1) Cu 12: Xenluloz trinitrat l cht d chy v n mnh c dng lm thuc sng khng khi. sn xut 29,7 kg xenluloz trinitrat t xenluloz v axit nitric, hiu sut phn ng 90% th th tch dung dch HNO3 96% (D = 1,52 g/ml) cn dng l A. 13,94 lt B. 14,39 lt C. 14,93 lt D. 19,34 lt Cu 13: T 300 tn qung pirit st cha 20% tp cht tr, sn xut c bao nhiu tn axit H2SO4 98%. Bit rng trong qu trnh sn xut lng axit b hao ht mt 10%? A. 270 tn B. 180 tn C. 360 tn D. 240 tn Cu 14: Dy gm cc cht u tc dng vi dung dch Brom iu kin thng l A. xiclopropan, axit acrylic, phenol, stiren, glucoz B. vinylaxetilen, vinylbenzen, benzen, axit acrylic, axeton C. phenol, toluen, etylen, axetilen, axit acrylic D. axit acrylic, phenol, stiren, fructoz, buta -1,3 ien Cu 15: Thu phn hon ton 0,01 mol mt este mch h ca ancol a chc cn dng va dung dch cha 0,8 gam NaOH. Sau phn ng thu c 0,92 gam ancol v 1,64 gam mui. C bao nhiu ng phn cu to este tho mn iu kin trn? A. 5 ng phn B. 2 ng phn C. 3 ng phn D. 4 ng phn Cu 16: Qu trnh iu ch t no di y l qu trnh trng hp? A. t nilon 6 t axit - aminocaproic B. t nilon - 6,6 t axit hexanioc v hexametyleniamin C. t capron t caprolactam D. t lapsan t etilen glicol v axit terephtalic
KOH ,t CuO ,t HBr Cu 17: Thc hin chuyn ha sau: but 1 en X Y Z (trong X, Y, Z l cc cht hu c ng vi cc sn phm chnh). X, Y, Z ln lt l A. CH3CH2CH2CH2Br; CH3CH2CH2CH2OH; CH3CH2CH2CHO B. CH3CH2CH(Br)CH3; CH3CH2CH(OH)CH3; CH3COCH2CHO C. CH3CH2CH(Br)CH3; CH3CH2CH(OH)CH3; CH3COCH2CH3 D. CH3CH2CH2CH2Br; CH3CH2CH(OH)CH3; CH3CH2CH2COOH Cu 18: Este X c iu ch t amino axit Y (ch cha C, H, O, N) v ancol metylic. t chy hon ton 8,9 gam X thu c 13,2 gam CO2; 6,3 gam H2O v 1,12 lt N2 ( ktc). Bit X c cng thc phn t trng vi cng thc n gin nht. Cng thc cu to ca Y v X ln lt l A. NH2CH2COOH v NH2CH2COOCH3 B. CH3CH(NH2)COOH v CH3CH(NH2)COOCH3 C. NH2CH(CH3)COOH v NH2CH(CH3)COOCH3 D. NH2CH(NH2)COOH v NH2CH(NH2)COOCH3 Cu 19: Hin tng ha hc no sau y c m t khng ng? A. a a thy tinh va nhng vo dung dch HCl m c ln ming l ng dung dch CH3NH2 m c th xung quanh a thy tinh bay ln mt ln khi trng B. Cho t t n d dung dch CH3NH2 vo dung dch FeCl3 th lc u c kt ta nu xut hin, sau kt ta tan dn n ht C. Cho dung dch NaNO2 vo dung dch glyxin, sau thm vi git dung dch axit axetic vo th thy c bt kh khng mu bay ln
0 0

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D. Nh vi git dung dch HNO3 c vo dung dch lng trng trng th thy c kt ta mu vng xut hin Cu 20: Cho V lt CO2 (ktc) hp th ht vo 200 gam dung dch Ba(OH)2 25,65%, sau phn ng thu c 25,61 gam kt ta v dung dch X. un nh dung dch X li thy c kt ta na. Gi tr ca V l A. 6,720 lt B. 2,912 lt C. 10,528 lt D. 12,508 lt Cu 21: Cho 3 phng trnh ion rt gn: (1) Cu2+ + Fe Cu + Fe2+ (2) Cu + 2Fe3+ Cu2+ + 2Fe2+ (3) Fe2+ + Ag+ Fe3+ + Ag Nhn xt no di y l ng A. Tnh oxi ha ca: Ag+ > Fe3+ > Cu2+ > Fe2+ B. Tnh kh ca: Fe > Ag > Fe2+ > Cu C. Tnh oxi ha ca: Fe3+ > Cu2+ > Ag+ > Fe2+ D. Tnh kh ca: Ag > Fe2+ > Cu > Fe Cu 22: Ha tan hon ton m gam hn hp bt gm Fe3O4 v FeCO3 trong dung dch HNO3 d, thu c 8,96 lt hn hp X gm 2 kh (ktc) v dung dch Y. T khi hi ca X i vi hiro bng 22,75. Gi tr ca m l A. 58 gam B. 34,8 gam C. 46,4 gam D. 69 gam Cu 23: Khi nhit phn, dy mui nitrat no sau y u cho sn phm rn l oxit kim loi tng ng? A. Hg(NO3)2, AgNO3, Al(NO3)3 B. Cu(NO3)2, LiNO3, Fe(NO3)2 C. Zn(NO3)2, Fe(NO3)3, Mg(NO3)2 D. Zn(NO3)2, KNO3, Pb(NO3)2 Cu 24: Cho cc cht v ion sau: Cl2, Cl , MnO4 , H2O2, Al3+, SO2, CO2, NO2, Fe, Fe2+, S v Cr3+. Dy gm tt c cc cht v ion va c tnh oxi ha, va c tnh kh l A. SO2, CO2, H2O2, Fe2+, MnO4B. MnO4-, Al3+, Fe, SO2, Cl-, Cl2, Cr3+ C. Cl-, Fe2+, S, NO2, Al3+, CO2 D. SO2, NO2, Fe2+, Cl2, H2O2, S, Cr3+ Cu 25: Cho m gam hn hp bt gm Fe v Mg vo dung dch AgNO3 d, sau khi kt thc phn ng thu c 97,2 gam cht rn. Mt khc, cng cho m gam hn hp 2 kim loi trn vo dung dch CuSO4 d, sau khi kt thc phn ng thu c cht rn c khi lng 25,6 gam. Gi tr ca m l A. 13,5 gam B. 12,8 gam C. 15,2 gam D. 14,5 gam Cu 26: t chy hon ton mt ancol X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l A. C3H8O3 B. C3H4O C. C3H8O2 D. C3H8O Cu 27: C cc dung dch: KCl, CuCl2, Na2SO4, KNO3, NaBr, H2SO4, HCl v NaOH. Tin hnh in phn ln lt cc dung dch trn th s dung dch m khi in phn ch c H2O b in phn c 2 in cc l A. 6 dung dch B. 5 dung dch C. 4 dung dch D. 3 dung dch Cu 28: T enang thuc loi A. t poliamit B. t axetat C. t tm D. t polieste Cu 29: Mun chuyn ha triolein thnh tristearin, ngi ta cho cht bo trn tc dng vi A. dung dch H2SO4 long, un nng B. dung dch NaOH, un nng C. H2 nhit thng D. H2 nhit , p sut cao, xc tc Ni Cu 30: Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, metylamoni axetat, etanol v alanin. S cht trong dy phn ng c vi dung dch NaOH l A. 3 cht B. 2 cht C. 4 cht D. 5 cht Cu 31: X l hn hp gm mt axit cacboxylic no n chc v mt este no n chc. X tc dng va vi 100 ml dung dch NaOH 0,25M un nng. Sau phn ng, c cn dung dch thu c 2,05 gam mt cht rn duy nht v hi ca mt cht hu c Y. Dn hi Y qua CuO nung nng, sau phn ng thu c cht hu c Z. Cho Z tc dng vi dung dch AgNO3/NH3 (d), un nng thu c 6,48 gam kt ta. Bit cc phn ng xy ra hon ton. Cng thc ca axit v este trong X l A. CH3COOH v CH3COOCH3 B. CH3COOH v CH3COOCH2CH2CH3 C. CH3COOH v CH3COOC2H5 D. HCOOH v HCOOCH3 Cu 32: Pht biu no di y v enzim l khng chnh xc?
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A. Mi enzim xc tc cho nhiu chuyn ha khc nhau B. Tc phn ng nh xc tc enzim rt ln, thng gp t 109 n 1011 ln tc ca cng phn ng nh xc tc ha hc C. Enzim l nhng cht hu ht c bn cht protein D. Enzim c kh nng xc tc cho cc qu trnh ha hc Cu 33: Theo Bronster, tt c cc cht v ion trong dy no sau y u c tnh lng tnh? A. HSO4-, H2PO4-, Al2O3, H2O B. Al2O3, HCO3-, H2O, H2PO42C. HPO4 , HCO3 , Zn, Zn(OH)2 D. Al, HS-, Al(OH)3, Al2O3 Cu 34: Cho cc cht sau: ancol etylic (1); axit axetic (2); phenol (3) v axit fomic (4). Th t gim dn linh ng ca nguyn t H trong nhm chc ca cc cht trn l A. (4), (2), (3), (1) B. (1), (3), (2), (4) C. (2), (4), (1), (3) D. (2), (4), (3), (1) Cu 35: S tripeptit ng phn to ra t lysin, alanin v glyxin l A. 3 B. 9 C. 4 D. 6 Cu 36: Nung hn hp bt gm Al v Fe2O3 trong bnh kn chn khng mt thi gian, thu c hn hp X gm Fe, FeO, Fe2O3, Fe3O4, Al v Al2O3. Ha tan ht X bng dung dch HNO3 long d, thu c 6,72 lt (ktc) kh NO l sn phm kh duy nht. Khi lng ca Al c trong hn hp ban u l A. 10,8 gam B. 6,75 gam C. 2,7 gam D. 8,1 gam Cu 37: C nm l mt nhn cha: glixerol, ancol etylic, glucoz, lng trng trng v axit axetic. Thuc th cn dng phn bit cc dung dch trong tng l trn l A. Cu(OH)2 trong mi trng kim B. dung dch HNO3 c C. dung dch AgNO3/NH3 D. qu tm Cu 38: trung ha 50 ml dung dch hn hp gm HCl v H2SO4 cn dng 200 ml dung dch NaOH 1M. C cn dung dch sau khi trung ha thu c 12,95 gam mui khan. Nng mol ca dung dch HCl v dung dch H2SO4 ln lt l A. 1M; 2M B. 1,5M; 2,5M C. 1,4M; 1,6M D. 2M; 1M Cu 39: Nhng mt l st vo dung dch cha mt trong cc cht sau (ly d): Fe2(SO4)3; AgNO3; FeCl3; CuSO4; HCl; HNO3 long; H2SO4 c, nng v Pb(NO3)2. Sau mt thi gian phn ng, ly l st ra khi dung dch. S cc dung dch sau phn ng c cha mui Fe (II) l A. 3 dung dch B. 6 dung dch C. 5 dung dch D. 4 dung dch Cu 40: Kt lun no sau y l sai A. Lin kt trong phn t Cl2, PH3, O2, N2 v CH4 u l lin kt cng ha tr khng c cc B. Lin kt trong phn t NH3, H2O, H2S l lin kt cng ha tr c cc C. Lin kt trong phn t CuS v AlCl3 l lin kt ion v c hnh thnh gia kim loi v phi kim D. Lin kt trong BaF2 v CsCl l lin kt ion Cu 41: un nng hn hp gm anken X v hiro (t l mol tng ng l 2 : 3) vi xc tc Ni, sau khi phn ng hon ton thu c hn hp kh c t khi so vi heli bng 7,5. Cng thc phn t ca X l A. C4H8 B. C5H10 C. C2H4 D. C3H6 Cu 42: Cho 1,792 lt kh CO (ktc) i t t qua ng s ng 3,2 gam mt oxit st nung nng nhit cao n khi phn ng hon ton. Hn hp kh i ra khi ng s c t khi so vi hiro l 20. Cng thc oxit st v % v th tch ca kh CO2 trong hn hp sau phn ng l A. Fe3O4 v 65% B. FeO v 75% C. Fe2O3 v 75% D. Fe2O3 v 25% Cu 43: Cho hn hp gm a mol Zn v b mol Fe vo dung dch cha c mol CuSO4. Kt thc phn ng thu c dung dch X v cht rn Y l mt hn hp kim loi. Kt lun no sau y l khng ng A. c th c a B. trong cht rn Y c c mol Cu C. trong dung dch X lun c a mol Zn2+ D. c th a < c < a + b Cu 44: Cho 27,4 gam hn hp Na2CO3 v NaHCO3 vo 500 ml dung dch HCl 0,81M. Sau khi phn ng xy ra hon ton thu c 6,72 lt CO2 (ktc) v 500 ml dung dch X. Gi tr pH ca dung dch X bng A. 0,4 B. 2 C. 1 D. 1,3
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Cu 45: Glucoz khng c tnh cht no sau y? A. Tnh cht ca ancol a chc B. Tnh cht ca nhm anehit C. Tham gia phn ng thy phn D. Tham gia phn ng ln men to ancol etylic Cu 46: Thu phn 500 gam protein X thu c 89,445 gam alanin. Nu phn t khi ca X bng 1.000.000 vC th s mt xch alanin c trong phn t X l A. 2009 B. 2010 C. 1210 D. 2100 Cu 47: X l dung dch axit cacboxylic n chc. Chia X lm hai phn bng nhau. Phn mt, tc dng ht vi CaCO3 thu c 1,68 lt kh ( ktc). Phn hai, trung ha bng 200 ml dung dch NaOH 1M, sau phn ng c cn dung dch thu c 16,1 gam cht rn. X l A. axit fomic B. axit propionic C. axit axetic D. axit acrylic Cu 48: X l - amino axit, mch cacbon khng phn nhnh c cng thc dng NH2R(COOH)2. X tc dng va vi 100 ml dung dch NaOH 1M, sau phn ng thu c 9,55 gam mui. X l A. axit 2 aminopentanioic B. axit 2 aminopropanioic C. axit 2 aminohexanioic D. axit 2 aminobutanioic Cu 49: Ha tan hon ton 2,38 gam hn hp X gm Mg, Al v Fe bng dung dch HCl d, thu c 1,792 lt kh (ktc). Mt khc, nu ha tan hon ton 7,14 gam hn hp X bng axit HNO3 long d, th thu c 4,032 lt kh NO (ktc) l sn phm kh duy nht. Thnh phn % theo khi lng ca Fe trong hn hp X l A. 30,77% B. 47,06% C. 42,31% D. 24,62% Cu 50: Ha tan ht m gam hn hp X gm FeO, Fe2O3 v Fe3O4 bng dung dch HNO3 c nng, thu c 4,48 lt kh NO2 (ktc). C cn dung dch sau phn ng thu c 145,2 gam mui khan. Gi tr ca m l A. 35,7 gam B. 77,7 gam C. 15,8 gam D. 46,4 gam
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