1. An experiment was carried out to determine the molarity of sulphuric acid solution.

20 cm3 of potassium hydroxide solution, 0.5 mol dm -3 is titrated with sulphuric acid
solution using phenolphthalein indicator.
Table 1 shows the result obtained.
Satu eksperimen telah dijalankan untuk menentukan kemolaran larutan asid sulfurik.
20.0 cm3 larutan kalium hidroksida 0.5 mol dm -3 dititratkan dengan larutan asid
sulfurik menggunakan penunjuk fenolftalein.
Jadual 1 menunjukkan keputusan yang diperolehi.

Experiment
1 2 3
Eksperimen
Final reading/cm3
Bacaan akhir buret / cm3 16.10 31.20 25.20

Initial reading/cm3
Bacaan awal buret / cm3 1.20 16.10 10.20

Volume of acid/cm3
Isipadu asid / cm3

TABLE / JADUAL 1

(a) Complete the table above.

Lengkapkan jadual di atas
[1 mark]

(b) Calculate the average of volume of acid used in the titration.

Hitung purata isi padu asid yang digunakan bagi titratan ini

[1 mark]

(c) State the colour change of phenolphthalein in titration.

Nyatakan perubahan warna penunjuk fenolftalein dalam pentitratan ini

.................................................................................................................................
[1 mark]

(d) Write the chemical equation for the reaction.

Tuliskan persamaan kimia bagi mewakili tindak balas yang berlaku.

.................................................................................................................................
[1 mark]

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(e) Calculate the molarity of sulphuric acid.
Hitung kemolaran larutan asid sulfurik.

[3 marks]

(f) (i) If sulphuric acid in the experiment is replaced by hydrochloric acid

with
the same molarity as sulphuric acid, predict the volume of
hydrochloric
acid used to neutralise 20.0 cm3 of potassium hydroxide solution, 0.5
mol
dm -3.
Jika asid sulfurik dalam eksperimen ini digantikan dengan asid hidroklorik
yang mempunyai kemolaran yang sama dengan asid sulfurik, ramalkan
isi padu asid hidroklorik digunakan untuk meneutralkan 20.0 cm3 larutan
kalium hidroksida 0.5 mol dm -3

...........................................................................................................................
[1 mark]

(ii) Explain your answer in (g) (i).

Terangkan jawapan anda di (g) (i)

...............................................................................................................
......

...............................................................................................................
......

. ...............................................................................................................
......
[2 marks]

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2. Diagram 2 shows the flow chart of the change of barium hydroxide solution.
Rajah 2 menunjukkan carta alir perubahan yang berlaku kepada larutan
barium hidroksida.
+ sulphuric acid
asid sulfurik
Barium hydroxide solution Precipitate B
Larutan barium hidroksida Mendakan B

+ phenolphthalein
fenolftalein

Solution A
Larutan A

DIAGRAM 2
RAJAH 2

Based on the above flow chart, answer the questions below:

Berpandukan carta aliran diatas , jawab soalan di bawah .

(a) Element barium is placed in Group 2 of the Periodic Table. Write the formula for
barium hydroxide.
Unsur barium berada dalam kumpulan 2 Jadual Berkala Unsur. Tuliskan formula
bagi barium hidroksida.

….………………..………………………………………………………………………………
[1 mark ]

(b) Write the formula of all ions present in the barium hydroxide solution.
Tuliskan formula semua ion-ion yang terdapat dalam larutan barium hidroksida.

….……………………………….………………………………………………………………
[1 mark ]

(c) What is the colour of solution A?

Apakah warna larutan A ?

……………………………………………………….……………………………………………
[ 1 mark ]

(d) (i) What will be observed when sulphuric acid is added into barium hydroxide
solution?

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 Apakah yang akan diperhatikan bila asid sulfurik ditambah ke dalam larutan
barium hidroksida.

….……………………………………………………………………………………………
[ 1 mark ]

(ii) Name the precipitate B.

Namakan mendakan B .

……………………………………………………………………………………………..
[ 1 mark ]

(iii) Name the type of reaction in (d) (i).

Namakan jenis tindak balas di (d) (i)

………………………………………………………………………………………………..
[ 1 mark ]

(iv) Write the chemical equation in (d) (i)

Tuliskan persamaan tindak balas yang berlaku di d (i)

………………………………………………………………………………………………..
[ 1 mark ]

(e) What is the mass of barium hydroxide in 250 cm3 of barium hydroxide 0.2 mol
dm-3.
Berapakah jisim barium hidroksida yang terkandung dalam 250 cm3 larutan
barium hidroksida 0.2 mol dm-3.
Use information of relative atomic mass; Ba,137 ; O,16 ; H ,1
Gunakan maklumat jisim atom relatif ; Ba,137 ; O,16 ; H ,1

[2 marks ]

(f) Name the suitable apparatus that can be used to prepare 250 cm3 of barium hydroxide
solution 0.2 mol dm-3.
Namakan radas yang boleh digunakan untuk menyediakan 250 cm3 larutan barium
hidroksida 0.2 mol dm-3.

………………………………………………………………………………………………….…
[ 1 mark ]

4
3 Diagram 3 shows the set up of apparatus to investigate the effect of heat to a metal
carbonate P. The powder of metal P carbonate is green in colour. When 12.4 g of
metal P carbonate is heated strongly, a gas Q which turns the lime water chalky.
Residue, a black powder R is produced.

Rajah 3 menunjukkan susunan radas bagi mengkaji kesan haba ke atas suatu
karbonat logam P. Serbuk karbonat logam P berwarna hijau. Apabila 12.4 g
karbonat logam P dipanaskan dengan kuat, suatu gas Q yang mengeruhkan air
kapur. Baki serbuk R yang berwarna hitam dihasilkan.

Metal P carbonate
Karbonat logam P

Heat
Haba
Lime water
Air kapur

Diagram / Rajah 3

(a) Name the metal P carbonate.

Namakan karbonat logam P.

………………………………………………………………………………………....
[1 mark]

(b) Write the formula of gas Q.

Tuliskan formula bagi gas Q.

………………………………………………………………………………………....
[1 mark]

(c) Name the powder R

Namakan serbuk R.

………………………………………………………………………………………....
[1 mark]

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(d) Write the chemical equation for the decomposition of the metal P carbonate.
Tuliskan persamaan kimia bagi penguraian karbonat logam P.

………………………………………………………………………………………....
[1 mark]

(e) State the observations predicted when :

Nyatakan pemerhatian yang dijangkakan apabila :

(i) powder of residue R is dissolved in dilute sulphuric acid.

baki serbuk R dilarutkan ke dalam asid sulfurik cair.

………………………………………………………………………………….
[1 mark]

(ii) ammonia solution is added to the solution in (e) (i) until excess
larutan ammonia ditambah kepada larutan di (e) (i) sehingga
berlebihan.

……………………………………………………………………………….....

………………………………………………………………………………….
[2 marks]

(f) Calculate the volume of gas Q produced at standard temperature and

pressure, STP.
[Given : Relative atomic mass ; C = 12 ; O = 16 ; P = 64 ; 1 mol of gas
occupied 22.4 dm3 at STP]

Hitungkan isipadu gas Q yang dihasilkan pada suhu dan tekanan piawai,
STP.
[Diberi : jisim atom relatif ; C = 12 ; O = 16 ; P = 64 ; 1 mol gas menempati
22.4 dm3 pada STP.]

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 [ 3 marks]
4. Figure 4 shows the flow chart for the reaction of zinc nitrate solution
Rajah 4 menunjukkan carta alir bagi tindak balas yang dijalankan ke atas larutan
zink nitrat.

Reaction/
Zinc nitrate solution Tindak balas I Zinc hydroxide
Larutan zink nitrat Zink hidroksida
+ larutan ammonia

Reaction / + Bahan J
Tindak balas II

Reaction /
Tindak balas III
Zinc carbonate Substance/Bahan K
zink karbonat Heat / + gas L
dipanaskan

RAJAH 4

(a) Name all cations present in zinc nitrate solution

Namakan semua kation yang terdapat dalam larutan zink nitrat.

………………………………………………………………………………………………
[ 1 mark]

(b) State the observation when zinc nitrate is mixed with ammonia solution in
reaction I
Apakah yang dapat diperhatikan apabila larutan zink nitrat dicampur dengan
larutan ammonia dalam Tindak balas I ?

………………………………………………………………………………………………

………………………………………………………………………………………………
[ 2 marks]

(c) (i) Suggest one substance / Cadangkan satu bahan J.

……………………………………………………………………………………..
[ 1 mark]

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 (ii) Write ionic equation for reaction / Tuliskan persamaan ion bagi Tindak
balas II.

……………………………………………………………………………………..
[ 1 mark]

(iii) State the method used to separate precipitate of zinc carbonate from
mixture solution inn reaction II
Nyatakan kaedah yang digunakan untuk mengasingkan mendakan zink
karbonat daripada larutan campuran dalam Tindak balas II.

……………………………………………………………………………………..
[ 1 mark]

(d) (i) Name substance / Namakan bahan K.

……………………………………………………………………………………..
[ 1 mark]

(ii) State the colour of substance K while hot and cold

Nyatakan warna bahan K semasa panas dan semasa sejuk.

……………………………………………………………………………………..
[ 1 mark]

(iii) Describe one chemical test to determine and identify gas L

Huraikan satu ujian untuk mengesahkah kehadiran gas L.

……………………………………………………………………………………..

……………………………………………………………………………………..
[ 2 marks]

5. (a) Table 5 shows the pH values for solutions of acid A and acid B which have
the
same concentration.

Acid pH Value
A 1
B 5
Table 5

By using named example for each acid, explain why the pH values of the acids
are different. [6 marks]

(b) Lead (II) sulphate is insoluble in water. Describe the preparation of lead (II)
sulphate in the laboratory. In your description, include the chemical equation
involved. [10 marks]

8
 (c) The sting of a jelly fish is alkaline and causes pain. Suggest one substance that
can be applied to the skin to relieve the pain without causing further injury. Give
three reasons for your suggestion. [4 marks]

5 Figure 5 shows a monomer for natural rubber

Rajah 5 menunjukkan monomer bagi getah asli.

H CH3 H H

H - C = C - C = C - H

FIGURE/ RAJAH 5

(a) Name the above natural rubber monomer

Namakan monomer bagi getah asli tersebut.

………………………………………………………………………………………………
[ 1 mark]

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(b) Draw a structural formulae for rubber polymer.
Lukiskan formula struktur bagi polimer getah.

[ 1 mark]

(c) Fresh latex is exposed to the air will coagulate within two days
Lateks segar yang dibiarkan akan menggumpal dalam masa 2 hari.

(i) Explain why the latex is coagulate

Terangkan kenapa lateks tersebut menggumpal

………………………………………………………………………………………….

………………………………………………………………………………………….

………………………………………………………………………………………….

………………………………………………………………………………………….
[ 3 marks]

(ii) Suggest one method to prevent coagulate of latex

Cadangkan satu kaedah bagi mengelakkan lateks daripada menggumpal.

………………………………………………………………………………...............
[ 1 mark]

(d) Natural rubber is vulcanised to improve its properties so that it can be widely
used
Getah asli divulkankan untuk memperbaiki sifatnya supaya kegunaanya dapat
diperluaskan.

(i) State two difference between natural rubber and vulcanized rubber
Nyatakan dua perbezaan antara getah asli dengan getah tervulkan.

………………………………………………………………………………………….

………………………………………………………………………………………….
[ 2 marks]

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(ii) Explain why vulcanised rubber has different properties from natural
rubber.
Terangkan mengapa getah tervulkan berbeza sifatnya dengan getah asli.

………………………………………………………………………………………….
[ 1 mark]

(iii) State one function of vulcanized rubber

Nyatakan satu kegunaan getah tervulkan.

………………………………………………………………………………………….
[ 1 mark]

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