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Halogenation
 
σ
(s)
σ
* (s)
π
(p)
σ
(p)
π
* (p)
σ
* (p)Diatomic MOs for Br
2
LUMOHOMO
A
Br
2
 
ππ
*
HOMOLUMO
SC
2
H
4
LUMOHOMO
ASA
Br
2
Side on Br
2
addition is symmetry forbidden.End on addition is allowed.
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