BAI TP PHENOL CTTQ CnH2n-7(OH) I.

ng ng - ng phn - danh php

Bi 1. Hp cht thm X c CTPT l C7H8O a, S ng phn ca hp cht thm X l: A. 2 B. 3 C. 4 D. 5 b, S ng phn ca X c phn ng vi Na l: A. 2 B. 3 C. 4 D. 5 c, S ng phn ca X va phn ng vi Na va phn ng vi NaOH l: A. 3 B. 1 C. 2 D. 4 Bi 2. Hp cht thm X c CTPT l C8H10O a, S ng phn khng tc dng vi Na v NaOH l: A. 4 B. 5 C. 6 D. 7 b, S ng phn X tha mn s sau l: X + NaOH khng phn ng
(1) (2) Y Y1 polime

A. 1 B. 2 C. 3 D. 4 Bi 3. Hp cht hu c X c cng thc C6H6O2. Bit X tc dng vi KOH theo t l s mol 1:2, Vy s ng phn cu to ca X l: A. 1 B. 2 C. 3 D. 4 Bi 4. Cho phenol (X), p-crezol (CH3-C6H4-OH) (Y), ru benzylic (Z). Cp cht no sau y l ng ng ca nhau ? A. X v Y B. X v Z C. Y v Z D. X,Y v Z Bi 5. Tn ca hp cht CH3 l: Cl OH A. 2-clo-4metyl phenol C. 4-metyl-2-clo phenol

B. 1-metyl-3-clo phenol 4 D. 1-clo-3-metyl phenol-4

II. Tnh cht vt l Bi 1 . Cu no sau y khng ng ? A. Phenol cng c lin kt hidro lin phn t B. Phenol c lin kt hidro vi nc C. Nhit si ca phenol thp hn nhit si ca etylbezen D. Phenol t tan trong nc lnh Bi 2. Th t tng dn ta trong nc ca dy no sau y ng ? A. bezen < phenol < etanol B. benzen < etanol < phenol C. phenol <benzen < etanol D. etanol < benzen < phenol Bi 3. Cht no sau y c lin kt hidro ni phn t ? A. o-nitrophenol B. m-nitrophenol C. p-nitrophenol Bi 4. Xt lin kt hidro c trong cc ng phn ca F-C6H4-OH 1. O O H F 2. OH
... ...

D. C A v B

F O - H...

F O H...F

3.

...

OH

...

Lin kt no c biu din ng ? A. 1 B. 2 C. 2 v 3 D. 1, 2 v 3 Bi 5. Cho cc cht: benzen, o-nitro phenol, p-nitro phenol. Nhit si ca cc cht tng dn theo th t no sau y ? A. benzen < o-notro phenol < p-nitro phenol B. benzen < p-nitrophenol < o-nitro phenol C. p-nitrophenol < o-nitro phenol < benzen D. o-nitro phenol < bnzen < p-nitrophenol

III. Tnh cht ha hc A. S chuyn ha - PTHH Bi 1. Cho dy chuyn ha sau: Br2 / Fe NaOH / t 0 , p HCl Toluen B C D .Vy D l: A. Benzyl clorua B. m-Metyl phenol C. o-Metyl phenol v p-metyl phenol D. o-clotoluen v p-clotoluen Bi 2. Cht hu c Y c CTCT: C8H10O. Y phn ng vi CuO, to to sn phm c kh nng phn ng trng gng v tha mn s :
(1) (2) Y Y1 polistiren. Vy CTCT ca Y l:

CH2-OH

A. C6H5-CH2CH2OH

D. C6H5-O-CH2-CH3 CH3 Bi 3. Hp cht hu c X c iu ch t etylbenzen theo s :

KMnO4 HNO3 / H 2 SO4 +C2 H 5OH C6 H 5C2 H 5 A B X . Vy CTCT ca X l: H 2 SO4 H 2 SO4 ,t 0

B. H3C-CH-OH

C.

A. o-NO2-C6H4-COOC2H5 B. m-NO2-C6H4-COOC2H5 C. phn ng-NO2-C6H4-COOC2H5 D. C A v C Bi 4. Cho cc phn ng sau: (A) + (B) (C) + (D) ; (C) + (E) Nha phenol fomanhit (E) + O2 (H) ; (I) (J) + (K) (J) (L) ; (L) + Cl2 (M) + (B) (M) + (N) (C) + (D) ; Na + (F) (N) + (K) Vy A, I, M c th l: A. C2H5ONa, C2H6, C2H5Cl B. C6H5OH, C3H8, C3H7Cl C. C6H5ONa, CH4, C6H5Cl D. p n khc Bi 5. Cho s sau: OH CH4 X1 X2 X3 X4 Vy X2, X3, X4 ln lt l: A. C6H6, C6H5Br, C6H5ONa B. C2H2, C6H6, C6H5Br C. CH3OH, HCHO, C6H6 D. C6H6, C6H5Br, C6H5Br2 Bi 6. Phn ng no sau y khng ng ?

A.

OH + OH 3Br2 (dd) Br

OH Br + 3HBr Br OH Br CH3 OH CH3 + 2Br2 (dd) Br Br + 2HBr CH3 OH + 2Br2 (dd) Br CH3 + 2HBr

B. CH3 C. OH

2Br2 (dd)

Br

+ 2HBr

D.

OH CH3

Br Bi 7. Cho s bin ha: C6H6 X C6H5OH Y C6H5OH . Vy X, Y ln lt l: A. C6H5Cl, C6H5NO2 B. C6H5NH2, C6H5ONa C. C6H5Cl , C6H5ONa D. C6H5COOH, C6H5Br Bi 8. Phenol khng phn ng vi cht no sau y ? A. Na v dd NaOH B. Nc Br2 C. dd NaCl D. Hn hp HNO3 v H2SO4 c Bi 9. Phenol c th phn ng vi cht no sau y ?5 A. dd NaOH, Na B. dd Br2, dd HNO3 C. dd C2H5COOH, dd H2SO4 D. A, B ng Bi 10. Ly 11,75g phenol cho phn ng ht vi nc brom d, hiu sut phn ng 64%. Khi lng kt ta trng thu c bng bao nhiu (trong cc gi tr sau): A. 26,48g B. 64,65g C. 41,375g D. C A, B, C u sai

Bi 11. Cho 18,8 gam phenol tc dng vi 45 gam dung dch HNO3 63% (H2SO4 c lm xc tc v un nng; hiu sut 100%). Hi khi lng axit picric (2,4,6-trinitro phenol) thu c l bao nhiu (trong cc gi tr sau): A. 50g B. 34,35g C. 35g D. 45,85g Bi 12. t chy hon ton hn hp (X) gm 2 phenol (Y) v (Z) ng ng k tip nhau thu c 83,6g CO2 v 18g H2O. Tng s mol ca (Y) v (Z) thu c bng bao nhiu (trong cc gi tr sau): A. 0,3 mol B. 0,25 mol C. 0,2 mol D. 0,15 mol Bi 13. Trung ha ht 9,4 gam phenol bng V ml dung dch NaOH 1M (ly d 10% so vi lng cn dng). Hi V c gi tr bao nhiu ( trong cc s sau): A. 80ml B. 90ml C. 110ml D. 115ml Bi 14. Ln lt cc cht C2H5Cl, C2H5OH, C6H5OH vo dung dch NaOH n nng. Hi my cht c phn ng ? A. Khng cht no B. Mt cht C. Hai cht D. C ba cht Bi 15. Thuc th duy nht c th dng phn bit ba cht lng: phenol, stiren v ru benzylic l: A. Na B. dd NaOH C. dd Br2 D. Qu tm Bi 16. phn bit phenol v ru benzylic c th dng thuc th no ? A. dd Br2 B. Na C. dd NaOH D. C A v C Bi 17. Phenol phn ng c vi dy cht no sau y: A. CH3COOH, Na2CO3, NaOH, Na, dd Br2, HNO3 B. HCHO, Na2CO3, dd Br2, NaOH. Na C. HCHO, HNO3, dd Br2, NaOH, Na D. C A, B, C Bi 18. Cho 15,5g hn hp 2 phenol A v B lin tip nhau trong dy ng ng ca phenol tc dng va vi 0,5 lt dung dch NaOH 0,3M. Cng thc phn t ca 2 phenol v % khi lng ca hn hp l: A. C7H7OH (69,68%) v C8H9OH (30,32%) B. C6H5OH (69,68%) v C7H7OH (30,32%) C. C6H5OH (30,32%) v C7H7OH (69,68%) D. Kt qu khc

chuyn luyn thi i hc -tn -gv-t-q-t BAI TP PHENOL

CTTQ CnH2n-7(OH) I. ng ng - ng phn - danh php Bi 1. Hp cht thm X c CTPT l C7H8O a, S ng phn ca hp cht thm X l: A. 2 B. 3 C. 4 D. 5 b, S ng phn ca X c phn ng vi Na l: A. 2 B. 3 C. 4 D. 5 c, (H-C-KB-2007) S ng phn ca X phn ng c vi NaOH l: A. 3 B. 1 C. 2 D. 4 Bi 2. Hp cht thm X c CTPT l C8H10O a, S ng phn khng tc dng vi Na v NaOH l: A. 4 B. 5 C. 6 D. 7 b, S ng phn X tha mn s sau l: X + NaOH khng phn ng
(1) (2) Y Y1 polime

A. 1 B. 2 C. 3 D. 4 Bi 3. Hp cht hu c X c cng thc C6H6O2. Bit X tc dng vi KOH theo t l s mol 1:2, Vy s ng phn cu to ca X l: A. 1 B. 2 C. 3 D. 4 Bi 4. Cho phenol (X), p-crezol (CH3-C6H4-OH) (Y), ru benzylic (Z). Cp cht no sau y l ng ng ca nhau ? A. X v Y B. X v Z C. Y v Z D. X,Y v Z Bi 5. Tn ca hp cht CH3 l: Cl OH A. 2-clo-4-metyl phenol B. 1-metyl-3-clo phenol- 4 C. 4-metyl-2-clo phenol D. 1-clo-3-metyl phenol-4 II. Tnh cht vt l Bi 6 . Cu no sau y khng ng ? A. Phenol cng c lin kt hidro lin phn t B. Phenol c lin kt hidro vi nc C. Nhit si ca phenol thp hn nhit si ca etylbezen D. Phenol t tan trong nc lnh Bi 7. Th t tng dn tan trong nc ca dy no sau y ng ? A. bezen < phenol < etanol B. benzen < etanol < phenol C. phenol <benzen < etanol D. etanol < benzen < phenol Bi 8. Cht no sau y c lin kt hidro ni phn t ? A. o-nitrophenol B. m-nitrophenol C. p-nitrophenol D. C A v B Bi 9. Cho cc cht: benzen, o-nitro phenol, p-nitro phenol. Nhit si ca cc cht tng dn theo th t no sau y ? A. benzen < o-nitro phenol < p-nitro phenol B. benzen < p-nitrophenol < o-nitro phenol C. p-nitrophenol < o-nitro phenol < benzen D. o-nitro phenol < bnzen < p-nitrophenol Bi10.(TN-2007) Phnol lng v ru etylic u phn ng c vi A. dd NaOH B.dd Br2 C.dd Na2CO3 D. kim loi Na III. Tnh cht ha hc A. S chuyn ha - PTHH Bi 11. Cho dy chuyn ha sau: Br2 / Fe NaOH / t 0 , p HCl Toluen B C D .Vy D l: A. Benzyl clorua B. m-Metyl phenol C. o-Metyl phenol v p-metyl phenol D. o-clotoluen v p-clotoluen Bi1 2. Cht hu c Y c CTCT: C8H10O. Y phn ng vi CuO, to to sn phm c kh nng phn ng trng gng v tha mn s :
(1) (2) Y Y1 polistiren. Vy CTCT ca Y l:

CH2-OH D. C6H5-O-CH2-CH3 CH3

A. C6H5-CH2CH2OH

B. H3C-CH-OH

C.

Bi 13. Hp cht hu c X c iu ch t etylbenzen theo s :

KMnO4 HNO3 / H 2 SO4 +C2 H 5OH C6 H 5C2 H 5 A B X . Vy CTCT ca X l: H 2 SO4 H 2 SO4 ,t 0

A. o-NO2-C6H4-COOC2H5 B. m-NO2-C6H4-COOC2H5 C. phn ng-NO2-C6H4-COOC2H5 D. C A v C Bi14. Cho cc phn ng sau: (A) + (B) (C) + (D) ; (C) + (E) Nha phenol fomanhit (E) + O2 (H) ; (I) (J) + (K) (J) (L) ; (L) + Cl2 (M) + (B) (M) + (N) (C) + (D) ; Na + (F) (N) + (K) Vy A, I, M c th l: A. C2H5ONa, C2H6, C2H5Cl B. C6H5OH, C3H8, C3H7Cl C. C6H5ONa, CH4, C6H5Cl D. p n khc Bi 15. Cho s sau: OH CH4 X1 X2 X3 X4 Vy X2, X3, X4 ln lt l: A. C6H6, C6H5Br, C6H5ONa B. C2H2, C6H6, C6H5Br C. CH3OH, HCHO, C6H6 D. C6H6, C6H5Br, C6H5Br Bi 16. Cho s bin ha: C6H6 X C6H5OH Y C6H5OH . Vy X, Y ln lt l: A. C6H5Cl, C6H5NO2 B. C6H5NH2, C6H5ONa C. C6H5Cl , C6H5ONa D. C6H5COOH, C6H5Br Bi 17. Phenol khng phn ng vi cht no sau y ? A. Na v dd NaOH B. Nc Br2 C. dd NaCl D. Hn hp HNO3 v H2SO4 c Bi 18. Phenol c th phn ng vi cht no sau y ? A. dd NaOH, Na B. dd Br2, dd HNO3 C. dd C2H5COOH, dd H2SO4 D. A, B ng Bi 19. Cho ln lt cc cht C2H5Cl, C2H5OH, C6H5OH vo dung dch NaOH un nng. Vy my cht c phn ng ? A. Khng cht no B. 1 cht C. 2 cht D. C 3 cht Bi 20. Phenol phn ng c vi dy cht no sau y: A. CH3COOH, Na2CO3, NaOH, Na, dd Br2, HNO3 B. HCHO, Na2CO3, dd Br2, NaOH. Na C. HCHO, HNO3, dd Br2, NaOH, Na D. C A, B,C
B. nhn bit- bi tp v phnol

Bi 21. phn bit phenol v ru benzylic c th dng thuc th no ? A. dd Br2 B. Na C. dd NaOH D. C A v C Bi 22. Thuc th duy nht c th dng phn bit ba cht lng: phenol, stiren v ru benzylic l: A. Na B. dd NaOH C. dd Br2 D. Qu tm Bi 23. phn bit phenol v ru benzylic c th dng thuc th no ? A. dd Br2 B. Na C. dd NaOH D. C A v C Bi 24. Ly 11,75g phenol cho phn ng ht vi nc brom d, hiu sut phn ng 64%. Khi lng kt ta trng thu c bng bao nhiu (trong cc gi tr sau): A. 26,48g B. 64,65g C. 41,375g D. C A, B, C u sai Bi 25. Cho 18,8 gam phenol tc dng vi 45 gam dung dch HNO3 63% (H2SO4 c lm xc tc v un nng; hiu sut 100%). Hi khi lng axit picric (2,4,6-trinitro phenol) thu c l bao nhiu (trong cc gi tr sau): A. 50g B. 34,35g C. 35g D. 45,85g Bi 26. t chy hon ton hn hp (X) gm 2 phenol (Y) v (Z) ng ng k tip nhau thu c 83,6g CO2 v 18g H2O. Tng s mol ca (Y) v (Z) thu c bng bao nhiu (trong cc gi tr sau): A. 0,3 mol B. 0,25 mol C. 0,2 mol D. 0,15 mol Bi 27. Trung ha ht 9,4 gam phenol bng V ml dung dch NaOH 1M (ly d 10% so vi lng cn dng). Hi V c gi tr bao nhiu ( trong cc s sau): A. 80ml B. 90ml C. 110ml D. 115ml Bi 28. Cho 15,5g hn hp 2 phenol A v B lin tip nhau trong dy ng ng ca phenol tc dng va vi 0,5 lt dung dch NaOH 0,3M. Cng thc phn t ca 2 phenol v % khi lng ca hn hp l: A. C7H7OH (69,68%) v C8H9OH (30,32%) B. C6H5OH (69,68%) v C7H7OH (30,32%) C. C6H5OH (30,32%) v C7H7OH (69,68%) D. Kt qu khc