MA TRN RA KIM TRA 1 TIT - Ha hc 11 CB

I/ HIDROCACBON THM (5 cu) Bit: (2 cu) Cu 1: Cng thc chung ca dy ng ng ankylbenzen l: A.CnH2n-6( n 6) B. CnH2n-3 ( n 6). C. CnH2n-6( n 1). D. CnH2n+6( n 1) Cu 2: Hin tng g xy ra khi un nng toluen vi dung dch KMnO4 ? A. Dung dch KMnO4 b mt mu. B. Xut hin kt ta trng C. Si bt kh D. Dung dch KMnO4 khng b mt mu. Hiu: (2 cu) Cu 3: Thuc th no di y c dng phn bit cc cht lng: benzen, toluen, vinylbenzen (stiren)? A. Dung dch KMnO4 long lnh. B. Dung dch KMnO4 un nng C. Dung dch Brom. D. Dung dch NaOH Cu 4: Nguyn liu no dng iu ch 2,4,6- trinitrotoluen ( thuc n TNT)? A. C6H6 v HNO3 m c B. C7H8 v HNO3 m c C. C7H8 v HNO3 m c, H2SO4 m c D. C6H6 v HNO3 m c, H2SO4 m c Vn dng: (1 cu) Cu 5: Ankylbenzen X c phn trm nguyn t cacbon l 92,30%. Cng thc phn t ca X l: A. C6H6 B. C7H8 C. C8H10 D. C9H12 II/ Bi tp ( 2 cu) Bit: (1 cu) Cu 6: S ng phn hidrocacbon thm ca C8H10 l? A. 3 B. 4 C. 5 D. 6 Hiu: (1 cu) Cu 7: t chy ht m gam 2 ng ng ca benzen A, B thu c 8,1 gam H2O v 15,456 lt kh CO2. Cng thc phn t ca A, B v m ln lt l: A. C6H6, C7H8, 12,6 gam. B. C7H8, C8H10, 10,8 gam. C. C8H10, C9H12, 9,18 gam. B. C8H10, C8H8, 10,8 gam III/ANCOL (8 cu) Bit: (3 cu) Cu 8: Phng php sinh ha iu ch ancol etylic l: A. ln men glucoz B. hidrat ha anken C. thy phn dn xut halogen D. Axetilen hp nc Cu 9: Oxi ha ancol X bng CuO, to thu c andehid n chc. X l: A. Ancol n chc bc 1 B. Ancol n chc bc 2 C. Ancol n chc bc 3 D. Ancol n chc bc 1 v bc 2 Cu 10: Dy cht no di y u tc dng c vi metanol ? A. Na, HBr, C2H5OH B. Na, Br2 , C3H7OH C. NaOH, HBr, C2H5OH D. NaOH, HBr, Cu(OH)2 Hiu: (3 cu) Cu 11: phn bit 2 l dung dch cha glixerol v propan-1-ol b mt nhn, ngi ta dng : A. Cu(OH)2 B. Dung dch AgNO3/ NH3 C. Na kim loi D. Nc brom Cu 12: S ng phn ancol X c cng thc phn t C4H10O b oxi ha bi CuO, to to thnh andehid l: A. 2 B. 3 C.4 D.5 Cu 13: Tn gi ca ancol: (CH3)2CHCH2 CH2 CH(OH)CH3 l: A. 5-metyl hexan-2-ol B. 2-metyl hexan-5-ol C. 1,1-imetyl pentan-2-ol D. 2-metyl hexan-1-ol Vn dng: (2 cu) Cu 14: Cho 1,38 gam glixerol phn ng vi Na d thu c bao nhiu mililit kh H2 (kc)? A. 504. B. 336 C. 224 D. 448 Cu 15: Cho 6,4 gam ancol X no, n chc, mch h phn ng vi Na d thu c 2,24 lit kh H2 (kc). Cng thc phn t ca X l: A. CH3OH B. C3H7OH C. C2H5OH D. C4H9OH Vn dng mc cao hn: ( 1 cu) Cu 16: Thc hin tch H2O ca hn hp X gm 2 ancol thu c hn hp Y gm cc anken . t chy hon ton hn hp Y thu c 11 gam CO2 . Khi lng H2O thu c trong phn ng t chy Y l: A. 4,5 gam B. 11 gam C. 5,4 gam D. 15,5 gam

IV/ PHENOL ( 4 cu) Bit: (2 cu) Cu 17: Nh nc brom vo dung dch phenol hin tng quan st c l: A. Nc brom mt mu, xut hin kt ta trng B. Nc brom mt mu, xut hin kt ta vng C. Nc brom chuyn sang mu xanh D. Nc brom khng b mt mu Cu 18: Chn cu ng nht? A. Phenol tan trong dung dch NaOH ch l s ha tan bnh thng. B. Phenol l ancol thm . C. Phenol tc dng vi NaOH , Na , dung dch brom, HNO3 c D. C6H5CH2OH l ng ng ca phenol. Hiu: (1 cu) Cu 19: Phn ng no di y chng minh phenol c tnh axit yu hn axit cacbonic: A. 2C6H5OH + 2Na 2C6H5ONa + H2 B. C6H5OH + NaOH C6H5ONa + H2O C. C6H5ONa + CO2 + H2O C6H5OH + NaHCO3 D. C6H5OH + 3Br2 C6H3OBr3 + 3HBr Vn dng: (1 cu) Cu 20: Cn bao nhiu phenol tc dng va vi 300 ml dung dch brom 1M ? A. 9,4 B. 9,2 C. 10,4 D. 8,6 TNG HP ( 10 cu) Bit: (2 cu) Cu 21 : Cht no sau y c nhit si cao nht? A. C6H5OH B. C2H5OH C. CH3OCH3 D. C4H10 Cu 22 : Dy cht no sau y u lm mt mu dung dch brom? A. Axetilen, etilen, stiren, phenol B. Axetilen, etanol, stiren, phenol C. Etanol, etan , stiren, phenol D. Toluen, benzen, etanol Hiu: ( 3 cu) Cu 23: Dng thuc th no phn bit 3 l dung dch b mt nhn cha : phenol, stiren, ancol benzylic? A. Dung dch brom B. Na C. NaOH D. Qy tm Cu 24: Cho HOC6H4CH2OH ln lt tc dng vi Na, dd NaOH, dd HBr, dd CuSO 4, dd AgNO3/NH3. C my phn ng xy ra? A. 3 B.4 C.5 D. 2 Cu 25: Cht thc hin phn ng thay th nguyn t Halogen bng nhm OH to sn phm ancol l: A. Vinyl clorua B. Phenyl bromua C. 1,1- iclopropan D. 1,2- icloetan Vn dng: ( 4 cu) Cu 26: Khi un ancol X vi H2SO4c, 170oC thu c anken Y c t khi so vi X l 0,6. Cng thc phn t ca ancol X l: A. C2H6O B. C3H8O C. C4H10O D. C5H12O Cu 27: Trong day bien hoa sau: CH4
1500 C
0

H 2 , Ni ,t

Cl 2 , as

C2H5Cl

ddNaOH , t

CuO ,t

Cac chat A,B,C,D lan lt la: A. C2H2, C2H6 , C2H5OH, CH3CHO B. C2H2, C2H4 , C2H4, HCHO C. C2H4, C2H6 , C2H5OH, CH3CHO D. C2H2, C2H4 , C2H5OH, CH3CHO Cu 28: Cho 18,6 gam hn hp A gm etanol v phenol tc dng vi Na d thu c 0,336 lt kh H2 ( kc). Phn trm khi lng ca etanol v phenol trong hn hp ln lt l: A.49,46% v 50,54% B. 38,68% v 61,32% C. 40,53% v 59,47% D. 60,24% v 39,76% Cu 29 : un nng m gam hn hp hai ancol n chc tc dng vi H2SO4 c 140oC thu c 21,6 gam H2O v 72 gam hn hp 3 ete c s mol bng nhau v bng x mol .Ga tr ca m v x ln lt l: A. 93,6 v 0,4 B. 50,4 v 1,2 C. 93,6 v 1,2 D. 50,4 v 0,3 Vn dng mc cao hn: ( 1 cu) Cu 30: Cho 34,6 gam hn hp gm phenol, etanol v metanol tc dng va vi 50 ml dung dch NaOH 2M . Cng lng hn hp trn tc dng ht vi Na thu c 0,8 gam kh H2. Phn trm khi lng ca metanol trong hn hp l: A. 46,20 % B. 27,17% C. 26,63% D. 34,60%