CU 1.

C2H5OH + Na C2H5ONa + H2 C2H5OH +HCl C2H5Cl+ H2O i vi Br v NaOH th ru etanol k phn ng

PHENOL C6H5-OH C6H5-OH C6H5-OH + Na C6H5ONa + H2 + H2O ( 2,4,6 tri brom phenol) + 3HBr

+ NaOH C6H5ONa + 3/2Br 2

C6H2OH(Br3)

Phenol k p vi HCl CU 2. a) cho hn hp etanol v glixerin vo dd Cu(OH)2 , hn hp no p vi dd Cu(OH)2 to dd mu xanh lam th l glixerin, cn li l etanol Cu(OH)2 + 2C3H5(OH)3 (C3H5(OH)2O)2 Cu + H2O

b) ln lt cho tng cht etanol v phenol vo NaOH, hn hp no sau p to kt ta trng chnh l phenol, cn li l etanol. C6H5-OH + 3/2Br 2 C6H2OH(Br3) ( 2,4,6 tri brom phenol) + 3HBr

Cu 3) 1 ancol X t hon ton m c nH2O > nCO2 => ANCOL ny no 1mol X + Na H2 => X l ancol n chc => Gi CTPT X l CnH2n+1OH Ta c ptpu l: CnH2n+1OH + Na CnH2n+1ONa + H2 0.1mol 1,12/22.4=0.05mol <_________________ Khi lng phn t X : 7,4/ 0.1 = 74 => n = 4 Vy ctpt X C4H9OH Butanol Cng thc CU TO

CH3-CH2-CH2-CH2-OH CH3-CH2-CH(OH)-CH3 CH3-CH(CH3)-CH2(OH) CH3-C(OH)(CH3)-CH3 Cu 4) Ctct C3H8O CH3-CH2-CH2-OH propannol-1 CH3-CH(OH)-CH3 propanol -2 CH3-O-C2H5 metyl, etyl -ete

BUTANOL-1 BUTANOL-2 2-metyl , propanol-1 2-metyl , propanol-2

CTCT C4H10O CH3-CH2-CH2-CH2-OH BUTANOL-1 CH3-CH2-CH(OH)-CH3 BUTANOL-2 CH3-CH(CH3)-CH2(OH) CH3-C(OH)(CH3)-CH3 2-metyl , propanol-1 2-metyl , propanol-2

CH3-O-CH2-CH2-CH3 metyl, propyl ete CH3-O-CH(CH3)-CH3 C2H5-O-C2H5 di etyl ete THE END Ch c em gi hok????hjhjhj