HNG DN NI DUNG N TP THI HC K 2 HA 11 CB

A. Hoan thanh cac s phan ng sau : 1/. CH3COONa CH4 C2H2 C2H4 C2H5OH C2H4 PE 2/. C4H10 CH4 C2H2 C2H3Cl PVC 3/. CaC2 C2H2 CH2=CH-CCH Buta-1,3-dien poli butadien 4/. Al4C3 CH4 C2H2 C6H6 6.6.6 C6H5-CH3 T.N.T 5/. C2H6 C2H5Cl C2H5OH CH3COOH CH3COOCH3 6/. C2H2 C6H6 C6H5Cl C6H5CH3 C6H5CH2Cl C6H5CH2OH C6H5CHO C6H5COOH. 7/. Tinh bt C6H12O6 C2H5OH CH3CHO C2H5OH CH3COOC2H5 8/. C2H2 C6H6 C6H5Cl C6H5ONa C6H5OH C6H2OHBr3 B. Nhn bit cc l ho cht mt nhn sau bng phng php ho hc: 1/. Etilen, etan, axetilen . 2/. Stiren, benzen, toluen 3/. Benzen, toluen, stiren, hex-1-in. 4/. Andehit axetic, axit axetic, etanol, glixerol 5/. axit axetic, etanol, phenol 6/. dd fomalin, axit fomic, axit axetic, C. Vit cc phng trnh ha hc sau y (nu c) ,cc hp cht hu c phi vit di dng CTCT thu gn ( b sung iu kin phn ng, nu c) 1/. Trng hp CH2=CH-Cl, C6H5-CH=CH2, C2H4 , CH3-CH=CH2 , CH2=CH-CH=CH2 2/. Cho dung dch axit axetic.tc dng ln lt vi : CaCO3, NaOH, CaO, Na, C2H5OH 3/. Cho andehit fomic tc dng ln lt vi vi dung dch AgNO3/NH3 (d), H2 4/. t chy hon tan : ankan, anken, ankin v ancol , anehit, axit cacboxilic (no n chc mch h ) 5/. Cho HCHO tc dng ln lt vi: NaOH, HCl, Na, dd Br2 (d) ,dd HNO3 (d) 6/. Cho ancol etylic tc dng ln lt vi Na , NaOH, HBr , CH 3COOH, CuO D. Vit CTCT cac ng phn va goi tn : 1/. Ankan co 4C, 5C 2/. Anken co 4 C 3/. Ankin co 5 C 4/. Hidrocacbon thm CTPT C8H10 5/. Cac hp cht thm co CTPT C7H8O 6/. ancol no n chc mch h c 3C, 4C 7/. andehit no n chc mch h c 4C 8/. axit cacboxilic no n chc mch h c 4C E. BI TP: 1/. t chy hon ton 0,3 gam cht A (phn t ch cha C, H, O) thu c 0,44 gam kh CO2 v 0,18 gam nc. Th tch hi ca 0,3 gam cht A bng th tch cu 0,16 gam kh oxi (o cng iu kin). Xc nh cng thc phn t ca cht A 2/. Hp cht X c % khi lng C, H v O ln lt l 54,54%, 8,1% v 36,36%. Khi lng phn t ca X l 88g/mol. Lp cng thc phn t ca X. 3/. t chy hon ton a gam mt hirocacbon X th thu c 35,2 gam CO 2 v 10,8 gam H2O. Bit rng X to kt ta mu vng nht vi dung dch AgNO3/NH3 d. a. Tnh a b. Xc nh cng thc cu to ca X?

4/. Cho 3,36 lt hn hp propin v etilen vo dung dch AgNO 3 trong NH3 thy cn 2,24 lit kh thot ra v m gam kt ta. a. Tnh % theo th tch mi kh trong hn hp? b. Tnh m gam kt ta to thnh? c.Tnh th tch khng kh (kc) cn dng t chy hon ton 3,36 lit hn hp trn 5/. t chy hon ton hn hp 2 ankin k tip nhau trong dy ng ng thu c 11, 2 lt ( ktc) kh CO2 v 5,4 gam nc. Xc nh CTPT ca 2 ankan ? 6/. un nng 6,9g ancol etylic vi H2SO4 1800C. Tnh th tch etylen thu c kc bit rng hiu sut phn ng l 85%. 7/. Cho m gam hn hp X gm etanol v phenol tc dng hon ton vi K d th thu c 5,04 lt H2 (kc). Mt khc m gam hn hp X trn tc dng va vi 50 gam dung dch NaOH 20%. Tnh % v khi lng cc cht trong hn hp X. 8/. Kh nc hon ton hn hp hai ancol 180 oC ta thu c hn hp 2 anken ng ng lin tip co t khi hi i vi H2 l 23,8. Xc nh CTPT ca 2 ancol 9/. hidrat ha 14,8g mt ancol thu c 11,2g anken. Xc nh CTPT ca ancol ? 10/. Cho m gam glucoz ln men thnh ancol etylic. Kh sinh ra cho vo nuc vi trong d thu c 120 gam kt ta, bit hiu sut qu trnh ln men t 60%. Gi tr m l 11/. Cho 8,6gam ankanal A phn ng hon ton vi dd AgNO 3/NH3 cho mt axit hu c (C) v 21,6 gam Ag. Xc nh CTPT A. 12/. Cho hn hp A v 1 ng ng B nh hn A 2 nguyn t cacbon tc dng vi H 2 d xc tc Ni c 8,28g ancol. Mt khc nu cng mt lng hn hp trn nu em t chy c 19,8 gam CO2. Tnh khi lng hn hp trn. 13/. 11,6 gam andehit n no A c s cacbon ln hn 1 phn ng hon ton vi dd AgNO3/NH3 d, ton b lng Ag sinh ra cho vo dd HNO 3 c nng sau khi phn ng xy ra hon ton ta thy khi lng dung dch tng ln 24,8gam. Tm CTCT ca A. 14/. Ho tan 6g axit n no A trong 200ml dd Na 2CO3 1M. Sau phn ng ngi ta phi dng 100ml dd HCl 3M tc dng Na2CO3 cn d: a/. Xc nh CTPT A b/. Cho 6g A tc dng vi 6,9g ru etylic, hiu sut phn ng 80%. Tnh lng este thu c 15/. 10,2gam hn hp 2 andehit n no A v B k tip nhau trong dy ng ng tc dng vi dd AgNO3/NH3 cho 43,2gam Ag v 2 axit hu c tng ng. Xc nh CTCT ca A, B.Gi tn 16/. Trung ho 12g axit ankanoic (X) cn 50ml dd KOH aM. em c cn dd sau phn ng trung ho th thu c 19,6g mui khan a/. Tm CTCT (X) b/. Tnh a 17/. Trung ho 14,8g hh (X) gm 2 axit n no A v B c t l mol l 1:1 th cn 400ml dd NaOH 0,5M. a/. Xc nh CTPT, CTCT, gi tn A, B b/. Tnh khi lng mui thu c 18/. Mun trung hoa 0,15mol mt axit cacboxylic (A) cn dung 200ml dd NaOH 1,5M. Mt khac t chay hoan toan 0,05mol (A) trn thi thu c 4,4g CO 2 va 0,9g H2O. Xc nh CTCT A. Goi tn A. 19/. Trung ho mt axit no n chc X cn 50ml dung dch NaOH 1M. C cn dung dch sau phn ng, thu c 4,1 gam mui khan. Xc nh CTCT ca X ?