M p M

n
163
49
7
1
B
21

p
n

22

P N V GII TM TT MN HO HC
Gii tm tt.

Gi x, y ln lt l s mol ca C2H5OH v H2O.

C2H5OH H2
H2O
H2 => h pt: x/2 + y/2 = 0,1145
46.x/0,8 + y.18 = 10 => x = 0,1488 (mol) =>
0
D ru = (0,1488.46.100)/(0,8.10) = 85,556 => chn B.
Gi x, y ln lt l s mol ca H2NC3H5(COOH)2 (axit glutamic) v
(H2N)2C5H9COOH (lysin).

3
4
5

C
A
B

23
24
25

C
A
B

26

7
8

C
D

27
28

C
D

29

10
11

A
A

30
31

A
A

12

32

13

33

14

34

C th coi 0,4 mol NaOH th c 0,2 mol phn ng vi 0,2 mol HCl => cn li
0,2 mol phn ng vi hh trn nn ta c hpt:
2x + y = 0,2
x + y = 0,15 => x = 0,05 mol. => chn C.
3Br2 + 8NaOH + 2NaCrO2 2Na2CrO4 + 6NaBr + 4H2O.
(C4H9ClO)n = C4nH9nClnOn . Ta c 9n + n 2.4n + 2 => n 1 => n =1.
Kt lun ng: (2); (3).
Lu : Fe khng phi l cht xc tc m Fe l cht to nn cht xc tc. Cht
xc tc ca phn ng ny l FeCl3 (bn cht ca cht xc tc l khng thay
i thnh phn, khi lng sau phn ng).
Theo lbt khi lng: mO = 11,1 6,3 = 4,8 (gam).
O-2 2e O
0,3 0,6 (mol)
12,6 gam X tc dng vi HCl th s mol e cho l 1,2 mol. => 2H+ + 2e > H2
=> nH2 = 0,6 (mol) => V = 13,44 (lt).
nH2C2O4 = 0,0095 (mol) => %tp cht = (0,95 0,0095.87).100/0,95 = 13%.
RCOONa + NaOH Na2CO3 + RH
28,8/(R + 67) = 0,2 => R = 77 => C6H5COONa.
C 0,15 (mol) C7H8 phn ng vi AgNO3/NH3 tng 32,1 (gam)
1 (mol)
tng 32,1/0,15 = 214 (gam)
=> trong sn phm c 2 nguyn t Ag => c 2 lin kt 3 u mch => c 4
p.
Theo lbt e: 0,14. 5 = 0,03.4 + neCl-cho. 2Cl- -2 e Cl2
0,58 0,29 (mol).
Gi x, y ln lt l s mol ca X v Y =>
23,5x + yMY = 107,5
23,5y + xMY = 91,25
y x = 0,5
=> M = 56 => C4H8.
Gi a, b, c ln lt l s mol Al3+, OH-( TN1), OH-( TN2)
Al3+ + 3OH- Al(OH)3
a
3a
a
Al(OH)3 + OH AlO2- + H2O
b
b
c
c
3a + b = 0,51
3a + c = 0,57
a -b = 3x/78
a - c = x/78 => a = 0,15 => m = 31,95 (gam).
Theo s phn ng:
C2H5OH CH3CHO + H2O H2
C2H5OH CH3COOH + H2O H2

15
16

B
C

35
36

B
C

17
18

C
B

37
38

C
B

19
20
21

C
D
C

39
40
1

C
D
C

22
23
24
25
26
27
28
29
30

B
D
C
B
A
B
C
B
B

2
3
4
5
6
7
8
9
10

B
D
C
B
A
B
C
B
B

31

11

32

12

33

13

34

14

C2H5OH C2H5OH
H2
S chnh lch s mol H2 l do sinh ra axit. nCH3COOH = 0,2.2 -0,3 = 0,1
(mol) => khi lng etanol b oxi ho to axit l 0,1.46 = 4,6 (gam).
CH4 C2H2 CH3CHO CH3COOH CH3COOCH=CH2 PVA.
nCH2=C(CH3)COOCH3 (CH2-C(CH3)COOCH3)n
150/ 100
(150.0,9.100n)/(100n) = 135.
(1), (2), (3), (5)
F1: Gi x, y ln lt l s mol Fe, Cu trong mt phn.
56x + 64y = 15,2.
3x + 2y = 0,6
=> x = 0,1 mol; y = 0,15 mol.
+
F2: Fe + 2Ag 2Ag + Fe2+
0,10,2
0,1
Cu + 2Ag+ 2Ag + Cu2+
0,15 0,3
Fe2+ + Ag+ Ag + Fe3+
0,1 0,05
CM(Fe(NO3)2) = 0,05/0,55 = 0,091(M).
Cu, Fe, MgO
Ta c 0,5<a/1,5a < 1 => to hh mui, SO2 v CO2 tan ht to hn hp mui.
Gi cng thc chung 2 oxit l RO2 => RO2 + 2OH- RO32- + H2O
x
2x
x
RO2 + OH- HRO3y
y
x+y=a
2x + y = 1,5a => x = 0,5a. Theo lbt khi lng: mA + mKOH = mMui +
mH2O => m mui = 54a + 56.1,5a 0,5a.18 = 129a.

C12H22O11 --> C6H12O6 CH3-CH(OH)-COOH CH2=CH-COOH.

NaOH, NH3, Ba(OH)2.
(1); (4).
Nn th ngc p n l nhanh nht.

2H2O - 4e O2 + 4H+
0,032 <--0,008 => It/F = 0,032 => t = 1600(s).
Cu CuO => tng 0,25m gam =>1,25 m + a (v a > 0) c c CuO, MgO
=> sau phn ng vi axit Mg d => HCl ht => CMHCl = 0,15.2/0,2 = 1,5(M).
Khi lng Fe trong hh = 2,688.56/22,4 = 6,72 (gam) = 7m/17 => m = 16,32
gam => mCu = 9,6 (gam).
V HNO3 t nht cn ho tan hon ton m gam X nn Fe-2e Fe2+, Cu 2e
Cu2+ , 4H+ + NO3- + 3e NO + 4H2O => nHNO3 = 4.(2.0,12 + 2.0,15)/3
= 0,72 (mol) => V = 0,72 (lt).
nCO2 = 0,6mol. Khi lng dung dch gim = m(kt ta) mCO2 mH2O
=> mH2O = 60 44.0.6 24,6 = 9 gam. => nH2O = 0,5 mol. S chn lch s
mol CO2 v s mol nc l do axit acrylic gy ra. nCO2-nH2O = nCH2=CHCOOH = 0,1 (mol).
Fe - 3 e Fe3+
Cu 2e Cu2+
x 3x
0,15 0,3
2+6
O2
+
4e O
S + 2e S+4
(63,2-56x 64.0,15)/32
0,6 < --0,3
Theo lbt e ta c: 0,6 + (63,2-56x 64.0,15)/32 = 3x + 0,3 => x = 0,7 (mol).

35

15

36
37

D
B

16
17

D
B

38

18

39

19

40
41

B
A

20
46

B
A

42
43
44
45

D
D
B
C

47
48
49
50

D
D
B
C

46
47
48
49
50

A
D
B
C
C

41
42
43
44
45

A
D
B
C
C

51

55

52
53
54
55
56
57
58
59

B
B
A
C
B
B
A
B

56
57
58
51
52
53
54
59

B
B
A
C
B
B
A
B

60

60

H+ + CO32- HCO3-. Khi bt u c kh thot ra th dng li tc cha xy ra

phn ng H+ + HCO3- CO2 + H2O
=> t.z/1000 = 0,3x => z.t = 300y.
H2SiO3; HCl; HClO; NaCl.
Gi s A ch c SO2 SO2 + Ca(OH)2 CaSO3 + H2O.
nSO2 = 5,1/120 = 0,0425 (mol) => R - ne Rn+; S+6 + 2 e S+4
Theo lbt e: 0,0425.2 = 0,18n/R => R = 2,11n => khng c n cht tho
mn. Vy A ngoi SO2 cn c kh khc => R l phi kim. thu c hh kh
R c th l C. Thay cc d kin trn thy tho mn.
C + 4HNO3 CO2 + 4NO2 + 2H2O.
0,015
0,015 0,015.4 => V = 0,075.22,4 = 1,68 (lt).
Theo lbt khi lng ta c:
m(C2H2+H2) = m(bnh brom tng) + m(hh Z) => m(hh Z) = 0,15.26 + 0,3.2
3 = 1,5 (gam) => n(hh Z) = 1,5/(20.2/6) = 0,225 (mol) => V = 5,04 (lt).
nKOH =5,6.5/56 = 0,5 (mmol) = nNaOH => mct(NaOH) = 0,5.40 = 20 (mg).
mddNaOH = 20.100/30 = 66,67 (mg).
(3); (4); (5).
Cho hh FeS v CuS vo dd HCl ch c FeS phn ng => nFeS = nH2S = 0,1
mol.
FeS 9e Fe3+ + S+6
CuS 8e Cu2+ + S+6
0,1 0,9
x
8x
+5
+2
N +3eN
2,1 <-- 0,7 => 8x + 0,9 = 2,1 => x = 0,15 mol
=> m = 23,2.2 = 46,4 (gam).
SO2; H2S.
(2); (3); (4).
H3PO4 + xNaOH NaxH3-xPO4 + xH2O
0,2
0,2x
0,2
0,2x => 0,2.(23x + 98 x ) = 26,2 => x
= 1,5 => a = 0,2.1,5 = 0,3 (mol).
NH4Cl; Na2CO3; KNO3; KClO.
V thm 100 ml dung dch H2SO4 trn th nng khng thay i.
Xiclopropan; stiren; axit acrylic; andehit axetic; glucoz; vinyl axetat.
Gi x, y ln lt l s mol ca Al3+; Fe3+.
Theo lbt in tch: 3x + 3y = 0,2.2 + 0,3.1 0,1.1 = 0,6 mol. thu c
lng kt ta ti a th ton b Al3+ v Fe3+ ta ht => nOH- = 3x + 3y = 0,6
mol => V = 0,6 (lt).
Gi cng thc ca hchc (theo d kin ca ) l CnH2nOx => theo ptp t
chy: 4 = (3n x)/2 => 8 = 3n x => n =3; x = 1 (x khng th = 3, 4v n
chc). => c 3 ctct: CH2=CH-CH2-OH; CH3-CO-CH3; CH3-CH2-CHO.
Cht no c tnh axit cng yu th dd mui ca n c tnh bazo cng mnh.
Theo ptp: mAg = (2.0,01 + 4.0,02 + 2.0,01).108 = 12,96 (gam).
(2); (3); (5).
Gi n l s mt xch: n = 2232/72 = 31.
KCB = ([H2O].[este])/([ancol].[axit]) = 2.2/1.1 = 4.
O3; Cl2.
PTP: (C6H7O2(OH)3)n + 3n(CH3CO)2O (C6H7O2(OOC-CH3)3)n +
3nCH3COH
(C6H7O2(OH)3)n + 2n(CH3CO)2O (C6H7O2 OH(OOC-CH3)2)n +
2nCH3COH
Lp h pt; gii => % ln lt: 77,84%; 22,16%.

Chc cc em mt ma thi thng li!