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Trng THPT Chuyn Vnh Phc

THI KHO ST I HC LN III NM 2011-2012 MN Ho 12 - Ban A, B

Thi gian lm bi: pht; (50 cu trc nghim)

M thi 109

H, tn th sinh:.......................................................................... S bo danh:...............................................................................
Cu 1: hn hp c 0,36(gam) Mg v 2,8(gam) Fe cho vo 250 ml dung dch CuCl , khuy u phn 2 ng xy ra hon ton thu c dung dch B v 3,84(g) cht rn B , Cho B tc dng vi dung dch 1 2 1 NaOH d, lc kt ta nung n khi lng khng i c 1,4(gam) 2 oxit. tnh C ca CuCl M 2 A. 0,15M B. 0,05M C. 0,1M D. 0,5M Cu 2: Phng php no sau y iu ch c Al t Al 2O3 A. p dung dch B. in phn nng chy C. Nhit luyn D. Thu luyn + CH OH / HCl khan + HCl NaOH du X3 . Hy cho bit trong s trn Cu 3: Cho s sau: alanin X1 X2 + c bao nhiu cht c kh nng lm i mu qu tm? A. 0 B. 3 C. 2 D. 1 Cu 4: t chy hon ton 0,1 mol hirocacbon A cho 0,5 mol CO 2. Mt khc 0,1 mol A phn mg va vi 0,2 mol Br2 trong dung dch. Cng thc phn t ca A? A. C5H8 B. C5H10 C. C3H4 D. C4H6
3

Cu 5: t chy hon ton mt lng hirocacbon trong bnh kn bng mt lng va oxi 120 0C. Sau phn ng nhit p sut bnh khng thay i. Hirocacbon trn c c im. A. Ch c s H = 4 B. Ch c th l anken C. Ch c th l ankan D. Ch c s C = 3. Cu 6: Cho cc phn ng oxi ho - kh sau? 2H2O2 (1) HgO (2) 2H2O + O2 Hg + O2 Cl2 + KOH KClO3 (4) KCl + KClO + H2O (3) KCl + O2 NO2 + H2O (5) HNO3 + NO FeS + H2SO4 Fe2(SO4)3 + SO2 + H2O (6)
Trong cc phn ng trn c bao nhiu phn ng t oxi ho - kh ? A. 3 B. 1 C. 2 D. 4 Cu 7: Ch c dung dch nc Brm v cc dng c th nghim c th phn bit c my cht trong s cc dung dch sau: Benzen, C2H6; C2H4; C2H2, phenol, ng trong cc ng nghim ring bit. A. 4 B. 2 C. 3 D. 5 Cu 8: Cho s sau: C4H10 X1 X2 X3 X4 CH3COOH Bit rng X1, X2, X3, X4 c cng s nguyn t cacbon v t chy thu c CO 2 v H2O. Vy X1 ; X2 ; X3 ; X4 l : A. CH3-CH3 ; CH2=CH2 ; CH3-CH2OH ; CH3CH=O B. CH3-CH3 ; CH2=CH2 ; CH2=CH-OH ; CH3-CH2OH C. CH3-CH3 ; CH2=CH2 ; CH3-CH2Cl ; CH3CH2OH D. CH2=CH2 ; CH3-CH3 ; CH3-CH=O ; CH3CH2OH Cu 9: Trong ba kim loi kim th Mg, Ca, Ba ch c Mg khng phn ng vi H 2O iu kin thng l do nguyn nhn no? A. Mg km hot ng hn Ca v Ba B. MgO khng tan trong H2O C. Tnh baz ca Mg(OH)2 km hn Ca(OH)2 v Ba(OH)2 D. Mg(OH)2 khng tan trong H2O cn Ca(OH)2 tan c Trang 1/5 - M thi 109

Cu 10: Cho a mol CO hp th ht vo dung dch cha b mol NaOH thu c dung dch A . Cho BaCl 2 2 d vo dung dch A thu c m(g) kt ta. Nu cho Ba(OH) d vo dung dch A thu c m (g) kt ta 2 1 ( m m ). T s T = b/a c gi tr ng l? 1 A. T 2 B. 0<T<1 C. T>0 D. 1<T<2 Cu 11: Nung mt lng mui Cu(NO3)2 sau mt thi gian dng li ,thy khi lng gim i 5,4gam. Kh thot ra hp th hon ton vo 100ml H2O thu c dung dch X (th tch coi nh khng i). Nng mol/l ca dd X l: A. 0,5mol/l B. 1mol/l C. 2 mol/l D. 0,1mol/l Cu 12: Mt ru no, n chc c % H = 13,04% v khi lng. Cng thc phn t ca ru l? A. CH3OH B. C4H9OH C. C2H5OH D. C3H7OH Cu 13: C bao nhiu ru bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? A. 2 B. 3 C. 4 D. 5 Cu 14: Hp cht hoc cp hp cht no sau y khng th tham gia phn ng trng ngng? A. axit -amino caproic B. hexa metyleniamin v axit aipic. C. phenol v anehit fomic D. butaien-1,3 v stiren. Cu 15: Khi hnh thnh lin kt trong phn t Cl theo phng trnh Cl + Cl --> Cl th h 2 2 A. Thu nng lng B. Qua hai giai on: To nng lng ri thu nng lng C. To nng lng D. Khng thay i nng lng Cu 16: Polime X c phn t khi 420 000 vC v h s trng hp n = 10 000. X l A. PVC B. ( - CF2 CF2 - )n C. P.P D. PE Cu 17: iu no l sai trong cc iu sau? A. ru a chc c nhm OH cnh nhau ho tan Cu(OH)2 to dung dch xanh lam B. CH3COOH ho tan Cu(OH)2 to thnh dung dch xanh nht C. Anehit tc dng vi Cu(OH)2 to kt ta gch D. Phenol ho tan Cu(OH)2 to dung dch xanh nht Cu 18: in phn 100 ml dung dch A cha ng thi HCl 0,1M v NaCl 0,2M, vi mng ngn xp, in cc tr ti khi anot thot ra 0,224 lt kh (ktc) th ngng in phn. Dung dch sau in phn c pH l bao nhiu? ( coi th tch dung dch khng thay i) A. 7 B. 12 C. 13 D. 6 Cu 19: Cho cc cht: etyl axetat, anilin, ru etylic, axit acrylic, phenol, phenylamoni clorua, ru benzylic, p-crezol v ietyl sunfat. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l: A. 6 B. 5 C. 4 D. 7 Cu 20: Cn phi trn hai dung dch H 2SO4 0,02M v dung dch KOH 0,035M theo t l th tch nh th no thu c dung dch c pH = 2 A. 1:2 B. 2:1 C. 2:3 D. 3:2 Cu 21: Cho m(gam) NaOH rn ho tan trong H2O thu c 100 ml dung dch NaOH c pH = 13. m = ? A. 0,6(g) B. 0,4(g) C. 0,2(g) D. 0,8(g) Cu 22: Khi in phn cc dung dch sau, dung dch no cho pH tng? A. Dung dch AgNO3 B. Dung dch BaCl2 C. Dung dch Na2SO4 D. Dung dch CuCl2 Cu 23: Pht biu no sau y khng ng? A. Kim loi cng mnh th m in cng ln. B. Kim loi ch th hin tnh kh trong cc phn ng ho hc C. Nguyn t kim loi c t electron lp ngoi cng. D. Cc phn nhm ph ca bng HTTH ch gm cc kim loi
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Cu 24: Ln men glucoz thu c ru etylic v kh CO 2. Hp th ht kh CO2 trong 500 ml dung dch NaOH 1M thu c dung dch c cha 16,8 gam NaHCO 3. Xc nh th tch ru nguyn cht thu c (d = 0,8 gam/ml) A. 20,125 ml B. 16,1 ml C. 25,76 ml D. 8,05 ml Cu 25: t chy hon ton mt hn hp gm ankan v anken thu c 4,14(g) H 2O v 6,16(g) CO2. Tnh khi lng ankan trong hn hp u? A. 2,7(g) B. 1,44(g) C. 3,69(g) D. Khng xc nh c Cu 26: tn gi no sau y l tn gi khc ca thu tinh hu c. A. polimetylacrilat B. polimetacrilic C. axit picric D. polimetylmetacrilat Cu 27: Lin kt cng ho tr l lin kt c hnh thnh gia hai nguyn t bng A. Mt hay nhiu cp electron chung B. Nhiu cp electron chung C. S cho - nhn prton D. Mt cp electron dng chung Cu 28: Cho 14(gam) hn hp 2 anken k tip, i qua dung dch Br 2 thy phn ng va vi 320(gam) dung dch Br2 20%. Cng thc phn t ca anken? A. C5H10; C6H12 B. C3H6; C4H8 C. C4H8; C5H10 D. C2H4; C3H6 Cu 29: iu no l ng trong cc iu sau: A. Baz kim tc dng vi mui tan khng bao gi to kh bay ra. B. Ch c cc oxit th kh nh CO2;SO2;NO2 mi tc dng vi cc baz kim. C. Baz tc dng vi axit lun l phn ng trung ho. D. cc hiroxit khng tan b nhit phn Cu 30: Dy cc cht c xp theo chiu tng dn s phn cc lin kt? A. NaCl; Cl ; HCl B. HCl; N ; NaCl C. Cl ; HCl; NaCl D. Cl ; NaCl; HCl 2 2 2 2 Cu 31: Khi un nng n ru n chc c H 2SO4 c 1400C th thu c s ete ti a l? A. 2n B. n2 C. n(n+1)/2 D. 3n Cu 32: nh ngha no sau y l ng khi ni v Hircacbon no? A. L hp cht hu c ch cha lin kt n trong phn t B. l hircacbon ch cha lin kt n trong phn t C. L hircacbon c cha t nht mt lin kt n trong phn t D. L hircacbon c cha cc lin kt n trong phn t Cu 33: Cho cc cht sau: phenol, etanol, axit axetic, etyl amin, phenyl amoni clorua, natri phenolat, natrihiroxit. S cp cht tc dng c vi nhau l A. 9 B. 8 C. 7 D. 6 Cu 34: t chy hon ton hn hp 3 ankin thu c 3,36(l) CO 2 (ktc) v 1,8(g) nc. Xc nh khi lng ca 0,1(mol) hn hp ban u? A. 4(g) B. 3,2(g) C. 5,2(g) D. 2,6(g) Cu 35: Cho 1 ming Fe vo cc ng dung dch H 2SO4 long. Bt kh H2 s bay ra nhanh hn khi ta thm vo cc trn dung dch no trong cc dung dch sau? A. Na2SO4 B. MgSO4 C. Al2(SO4)3 D. HgSO4 Cu 36: Khi in phn cc dung dch cha hn hp a mol NaCl v b mol CuSO 4 (m.n.x) kt thc qu trnh in phn ta thy dung dch c pH tng so vi ban u. Mi quan h gia a v b ? A. 2b> a> b B. a = 2b C. a > 2b D. a b Cu 37: Crackinh 560 lt C4H10 thu c hn hp kh X c th tch 1010 lt ( cc kh o cng iu kin). xc nh th tch C4H10 cha b crckinh? A. kt qu khc B. 90 lt C. 110 lt D. 80 lt Cu 38: Cho cc phn ng sau? 1. HCl + MnO2 2. HCl + Cu + O2 MnCl2 + Cl2 + H2O CuCl2 + H2O
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3. HCl + Fe FeCl2 + H2 H2O

4. HCl + KMnO4 KCl + MnCl2 + Cl2 +

C bao nhiu phn ng trong HCl ng vai tr l cht b kh? A. 3 B. 2 C. 1 D. 4 Cu 39: Dy cc cht c xp theo chiu tng tnh axit? A. HF, HCl, HBr, HI B. HF, HBr, HCl, HI C. HI, HCl, HBr, HF D. HI, HBr, HCl, HF Cu 40: X l 1 mui ca Fe .X ho tan trong HCl c kh A bay ln .t chy X trong O 2 c kh B bay ln .BitA v B u lm mt mu dung dch nc Brom .X l: A. FeS B. FeCO3 C. FeSO4 D. Fe3C Cu 41: un nng mt ru A vi H 2SO4 c nhit thch hp thu c 1 olefin duy nht. Cng thc tng qut ca X l? A. CnH2n+1OH B. ROH C. CnH2n+1CH2OH D. CnH2n + 2O Cu 42: Cho s phn ng: A --> B --> TNT, Cu tr li no sau y l ng v A, B? A. A l hexan, B l toluen B. A l toluen, B l heptan C. Tt c iu sai D. A l benzen, B l toluen Cu 43: Cho hn hp gm 0,14 mol Mg v 0,01 mol MgO tan hon ton trong dung dch HNO 3 ch thu c 0,02 mol N2 v dung dch. Xc nh khi lng mui khan thu c nu c cn dung dch? A. Khng xc nh c. B. 23(g) C. 22,2(g) D. 23,2(g) Cu 44: Cho 1 gam bt Fe tip xc vi oxi mt thi gian thy khi lng bt vt qu 1,41gam. Nu ch to thnh mt oxit st duy nht th l oxit no? A. FeO B. Fe3O4 C. Fe2O3 D. Khng xc nh c Cu 45: Thy phn hon ton mt tripeptit thu c hn hp gm alanin v glyxin theo t l mol l 2: 1. Hy cho bit c bao nhiu tri peptit tha mn? A. 1 B. 3 C. 2 D. 4 Cu 46: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H 2SO4 lm xc tc) thu c hn hp Z gm hai ru X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (th tch dung dch thay i khng ng k). A. C3H7OH v C4H9OH B. C4H9OH v C5H11OH C. CH3OH v C2H5OH D. C2H5OH v C3H7OH Cu 47: Lp N c bao nhiu phn lp? A. 3 B. n C. 2n D. 4 Cu 48: Cho cc cht (X): n Butan; (Y): n Hexan; (Z): isohexan , (T) : neohexan. Cc cht c xp theo chiu gim dn nhit si? A. Y, Z, X, T B. Y, Z, T, X C. T, Z, Y, X D. Y, X, Z, T Cu 49: Ho tan mt ming Al vo dung dch cha 0,05 mol NaOH ,thy c 0,672 (ktc) H 2 bay ln v cn li dung dch A .Cho vo dung dch A dung dch cha 0,065mol HCl th lng kt ta sinh ra l: A. 1,56g B. 2,34g C. 1,17g D. 0,78g Cu 50: Lin kt trong phn t no c hnh thnh nh s xen ph p - p A. Cl B. H C. NH D. HCl 2 2 3
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made 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109 109

cauhoi 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

dapan C B B A A A C A D D B C B D C C D C A D B B A A B D A D D C C B B A D C C C A A C D B C B D D B C A

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