9.

Grafik Volume Campuran vs Fraksi Air dan Fraksi Aseton

Grafik Volum Molar Campuran

terhadap Fraksi Air
70.0000
y = 630.5x6 - 2485.6x5 + 3955.8x4 3226.2x3 + 1412.4x2 - 369.29x + 100.46
R = 0.9999

60.0000
50.0000
40.0000
30.0000

Grafik Volum Molar

Campuran terhadap
Fraksi Air
Poly. (Grafik Volum
Molar Campuran
terhadap Fraksi Air)

20.0000
10.0000
0.0000
0

0.5

1.5

Grafik Volume Molar Campuran

terhadap Fraksi Aseton
70.0000
60.0000

Grafik Volume Molar

Campuran terhadap
Fraksi Aseton

50.0000
40.0000
30.0000
20.0000
10.0000

y = 630.5x6 - 1297.4x5 + 985.31x4 351x3 + 70.065x2 + 44.917x + 18.068

R = 0.9999

0.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

Poly. (Grafik Volume

Molar Campuran
terhadap Fraksi
Aseton)

LAMPIRAN B
DATA PERCOBAAN DAN HASIL ANTARA

1. Kalibrasi Piknometer

T(K)

300
305
310
316
321

massa
piknometer
kosong (gram)

massa
piknometer+air
(gram)

I
11.79
11.79
11.79
11.79
11.79

I
21.8
21.8
21.79
21.78
21.75

II
11.79
11.79
11.79
11.79
11.79

II
21.81
21.79
21.78
21.78
21.75

massa air (gram)

I
10.01
10.01
10
9.99
9.96

II
10.02
10
9.99
9.99
9.96

Rata-rata
10.015
10.005
9.995
9.99
9.96

air
(gr/ml)

Volume
piknometer
(ml)

0.9966
0.9951
0.9934
0.991
0.9889

10.0492
10.0543
10.0614
10.0807
10.0718

2. Penentuan Densitas Gliserin

Gliserin 1gr/100ml
T(K)

305
310
316
321

vol pikno
(ml)

10.0543
10.0614
10.0807
10.0718

m pikno+gliserin (gram)
I
21.8
21.81
21.8
21.73

II
21.79
21.8
21.78
21.72

Rata-rata
21.795
21.805
21.79
21.725

m gliserin
(gram)

gliserin
(gr/ml)

10.005
10.015
10
9.935

0.9950966
0.9954
0.9920
0.9864

m gliserin
(gram)

gliserin
(gr/ml)

10.025
10.005
9.99
9.98

0.9971
0.9944
0.9910
0.9909

Gliserin 0.5gr/100ml
T(K)

305
310
316
321

vol pikno
(ml)
10.0543
10.0614
10.0807
10.0718

m pikno+gliserin (gram)
I
21.82
21.79
21.78
21.77

II
21.81
21.8
21.78
21.77

Rata-rata
21.815
21.795
21.78
21.77

Gliserin 0.25gr/100ml
T(K)

vol pikno
(ml)

305
310
316
321

10.0543
10.0614
10.0807
10.0718

m pikno+giserin (gram)
I
21.81
21.8
21.78
21.79

II
21.81
21.79
21.78
21.77

Rata-rata
21.81
21.795
21.78
21.78

m gliserin
(gram)

gliserin
(gr/ml)

10.02
10.005
9.99
9.99

0.9966
0.9944
0.9910
0.9919

m gliserin
(gram)

gliserin
(gr/ml)

9.995
9.995
9.985
9.975

0.9941
0.9934
0.9905
0.9904

(gr/cm.s)

ln

1/T

0.0076
0.0069
0.0061
0.0054

-4.883979
-4.977704
-5.095049
-5.21319

0.00328
0.00323
0.00316
0.00312

Gliserin 0.125gr/100ml
vol pikno
(ml)

T(K)

305
310
316
321

10.0543
10.0614
10.0807
10.0718

m pikno+giserin (gram)
I
21.78
21.78
21.77
21.77

II
21.79
21.79
21.78
21.76

Rata-rata
21.785
21.785
21.775
21.765

3. Penentuan Viskositas Gliserin

Viskositas Air
T(K)

mo
(gr/cm.s)

t(s)

305
310
316
321

9.66
9.44
9.4
9.25

o air
(gr/ml)

0.00765
0.00692
0.00618
0.00566

0.9951
0.9934
0.991
0.9889

Gliserin 1gr/100ml
T(K)

305
310
316
321

gliserin
(gr/ml)
0.9951
0.9954
0.992
0.9864

t(s)
I
9.68
9.38
9.25
8.97

II
9.43
9.38
9.37
8.87

Rata-rata
9.555
9.38
9.31
8.92

Gliserin 0.5gr/100ml
T(K)

305
310
316
321

gliserin
(gr/ml)
0.9971
0.9944
0.991
0.9909

t(s)
I
9.53
9.32
9.09
8.94

II
9.47
9.5
9.09
9.22

(gr/cm.s)

ln

1/T

0.0075
0.0069
0.0060
0.0056

-4.887744
-4.975516
-5.119972
-5.19086

0.00328
0.00323
0.00316
0.00312

(gr/cm.s)

ln

1/T

0.0077
0.0070
0.0060
0.0055

-4.863809
-4.967578
-5.113939
-5.203714

0.00328
0.00323
0.00316
0.00312

(gr/cm.s)

ln

1/T

0.0077
0.0070
0.0061
0.0056

-4.861709
-4.967004
-5.101408
-5.179868

0.00328
0.00323
0.00316
0.00312

Rata-rata
9.5
9.41
9.09
9.08

Gliserin 0.25gr/100ml
T(K)

305
310
316
321

gliserin
(gr/ml)
0.9966
0.9944
0.991
0.9919

t(s)
I
9.72
9.4
9.16
8.84

II
9.75
9.57
9.13
9.07

Rata-rata
9.735
9.485
9.145
8.955

Gliserin 0.125gr/100ml
T(K)

305
310
316
321

gliserin
(gr/ml)
0.9941
0.9934
0.9905
0.9904

t(s)
I
9.72
9.54
9.25
9.16

II
9.84
9.46
9.28
9.21

Rata-rata
9.78
9.5
9.265
9.185

4. Penentuan Viskositas Intrinsik

T=305 K
C(gr/100ml)
1
0.5
0.25
0.125

(gr/cm.s)
0.0076
0.0075
0.0077
0.0077

o(gr/cm.s) s(gr/cm.s)
0.00765
-0.0065
0.00765
-0.0196
0.00765
0.0065
0.00765
0.0065

s/C
-0.0065
-0.0392
0.0261
0.0523

(gr/cm.s)
0.0069
0.0069
0.007
0.007

o(gr/cm.s) s(gr/cm.s)
0.00692
-0.0029
0.00692
-0.0029
0.00692
0.0116
0.00692
0.0116

s/C
-0.0029
-0.0058
0.0462
0.0925

T=310 K
C(gr/100ml)
1
0.5
0.25
0.125

T=316 K
C(gr/100ml)
1
0.5
0.25
0.125

(gr/cm.s)
0.0061
0.006
0.006
0.0061

o(gr/cm.s) s(gr/cm.s)
0.00618
-0.0129
0.00618
-0.0291
0.00618
-0.0291
0.00618
-0.0129

s/C
-0.0129
-0.0583
-0.1165
-0.1036

T=321 K
C(gr/100ml)
1
0.5
0.25
0.125

(gr/cm.s)
0.0054
0.0056
0.0055
0.0056

o(gr/cm.s)
0.00566
0.00566
0.00566
0.00566

s(gr/cm.s)
-0.0459
-0.0106
-0.0283
-0.0106

s/C
-0.0459
-0.0212
-0.1131
-0.0848

5. Penentuan Harga E dan A (Metode Grafis)

C(gr/100ml)
1
0.5
0.25
0.125

y=ax+b
2000.5x-11.436
1917.4x-11.172
2118.4-11.808
1978.5x-11.351

a
2000.5
1917.4
2118.4
1978.5

b
-11.436
-11.172
-11.808
-11.351

R
8.314
8.314
8.314
8.314

A
1.08E-05
1.4062E-05
7.4448E-06
1.1758E-05

6. Penentuan Berat Molekul

T(K)
305
310
316
321

y=ax+b
6.0008x+0.5178
6.7062+0.6868
7.8771x+1.0423
5.7886x+0.8523

[] saat
x=0
0.5178
0.6868
1.0423
0.8523

ln[]
-0.6582
-0.3757
0.0414
-0.1598

ln (BM)
10.3408
10.7125
11.2613
10.9965

BM
30971.5702
44912.6627
77757.1708
59667.8133

7. Penentuan Densitas Aseton

T(K)

305
310
316
321

massa piknometer+aseton
(gram)
I
19.6
19.65
19.57
19.56

II
19.6
19.63
19.58
19.56

Rata-rata
19.6
19.64
19.575
19.56

Volume
piknometer
(ml)

massa
aseton
(gram)

aseton
(gr/ml)

10.0543
10.0614
10.0807
10.0718

7.81
7.85
7.785
7.77

0.777
0.780
0.772
0.771

E
16632.157
15941.264
17612.378
16449.249

8. Penentuan Densitas Campuran dan Volum Molar Campuran

Vol
air
(ml)
1
2
3
4
5
6
7
8
9
10
11
12
13
14

Vol
aseton
(ml)
14
13
12
11
10
9
8
7
6
5
4
3
2
1

massa
piknometer+campuran
(gram)
I
19.88
20.12
20.28
20.51
20.61
20.89
21.02
21.08
21.21
21.41
21.51
21.58
21.68
21.75

II
19.88
20.1
20.27
20.5
20.61
20.89
21.02
21.07
21.21
21.39
21.5
21.58
21.67
21.74

massa
campuran
(gram)

r
campuran
(gr/ml)

massa
total
(gr)

vol total
(ml)

8.09
8.32
8.485
8.715
8.82
9.1
9.23
9.285
9.42
9.61
9.715
9.79
9.885
9.955

0.805
0.828
0.844
0.867
0.878
0.905
0.918
0.924
0.937
0.956
0.967
0.974
0.984
0.991

11.946
12.1605
12.375
12.5895
12.804
13.0185
13.233
13.4475
13.662
13.8765
14.091
14.3055
14.52
14.7345

14.8402
14.6891
14.6575
14.518
14.5896
14.3776
14.4086
14.5555
14.5757
14.5118
14.5769
14.6854
14.7624
14.8751

Rata-rata
19.88
20.11
20.275
20.505
20.61
20.89
21.02
21.075
21.21
21.4
21.505
21.58
21.675
21.745

mol air
(mol)

mol aseton
(mol)

mol total
(mol)

X air

X
aseton

vol molar
campuran
(ml/mol)

0.0554
0.1107
0.1661
0.2215
0.2768
0.3322
0.3876
0.4429
0.4983
0.5537
0.6090
0.6644
0.7198
0.7751

0.1888
0.1753
0.1618
0.1483
0.1348
0.1214
0.1079
0.0944
0.0809
0.0674
0.0539
0.0405
0.0270
0.0135

0.2441
0.2860
0.3279
0.3698
0.4117
0.4536
0.4954
0.5373
0.5792
0.6211
0.6630
0.7049
0.7467
0.7886

0.2268
0.3871
0.5065
0.5989
0.6725
0.7324
0.7823
0.8243
0.8603
0.8914
0.9186
0.9426
0.9639
0.9829

0.7732
0.6129
0.4935
0.4011
0.3275
0.2676
0.2177
0.1757
0.1397
0.1086
0.0814
0.0574
0.0361
0.0171

60.7833
51.3547
44.6992
39.2595
35.4393
31.6994
29.0823
27.0887
25.1649
23.3652
21.9872
20.8347
19.7692
18.8623

dVm
camp/dXaseton

Vm air

Vm
aseton

dVm
camp/dXair

Vm air

Vm
aseton

72.49251
54.44997
57.28132
57.41345
55.93836
54.46129
53.46181
52.8593
52.41845
51.91802
51.19946
50.16799
48.77929
47.02435

4.7302
17.9843
16.4329
16.2303
17.1168
17.127
17.4418
17.803
17.8428
17.7292
17.8217
17.9554
18.0075
18.0582

77.2227
72.4343
73.7142
73.6438
73.0551
71.5883
70.9036
70.6623
70.2613
69.6472
69.0212
68.1234
66.7868
65.0825

-72.5011
-54.4567
-57.2841
-57.4119
-55.9329
-54.4523
-53.4496
-52.8444
-52.4011
-51.8986
-51.1781
-50.145
-48.7548
-46.9985

4.7235
17.9802
16.4316
16.2309
17.1185
17.1294
17.4444
17.8056
17.8452
17.7313
17.8235
17.9568
18.0084
18.0586

77.2247
72.4369
73.7156
73.6429
73.0514
71.5817
70.8940
70.6500
70.2464
69.6299
69.0016
68.1018
66.7632
65.0572

LAMPIRAN A
DATA FISIK DAN LITERATUR

1. Data Densitas dan Viskositas Air

2. Data Densitas Aseton