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Materials@Sheffield 2012
Contents
1 2 3 4 5 Head of Department Introduction Staff in the Department of Materials Science and Engineering Industrial Liaison Committee Academic Staff Profiles Research Highlights 2011
5.1. 5.2. 5.3. 5.4. 5.5 5.6 Biomaterials and Tissue Engineering Functional Materials and Devices Nuclear Energy Advanced Structural Materials Multiscale Materials Modelling Nanomaterials and Nanoengineering
Content
Page No 5 7 11 13 21
22 28 34 40 48 52
6 7 8 9 10 11 12
Publications, 2011 PhD Awards, 2011 Current Research Sponsors Grants and Contracts Awarded 2011 Personal Highlights 2011 Retired Academic Staff Profiles Appendix: Annual Report 2012 (separate report)
56 66 67 70 71 80
Production Team: Wendy Dutton and Vanessa Dalton Editor: Professor W M Rainforth Department of Materials Science and Engineering The University of Sheffield Sir Robert Hadfield Building Mappin Street Sheffield S1 3JD United Kingdom Tel: +44 (0)114 222 5941 Fax: +44 (0)114 222 5943 www.shef.ac.uk/materials
Materials Science & Engineering, The University of Sheffield
Materials@Sheffield 2012
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Introduction
Materials@Sheffield 2012
1 Introduction
The Department of Materials Science and Engineering at the University of Sheffield is one of the largest departments in the UK and internationally renowned for its research and teaching. The Department has its origins in the last 19th century, and indeed was one of the founding departments of the University (which received its Royal Charter in 1905). In the early days key subjects such as metallurgy underpinned the huge industrial strength of Sheffield, particularly in the world dominant steel industry. Today, the Department has internationally recognised research is a wide range of topics, including biomaterials, tissue engineering, functional ceramics, magnetics, surface engineering, tribology, glass, nuclear waste immobilisation, cements and geopolymers, multiscale materials modelling, thermomechanical processing of metals, additive layer manufacturing, manufacturing, high temperature materials, energy materials, polymer composites, functional polymers, nanocharacterisation, nanomaterials and nanorobotics. We group ourselves into 6 broad themes, namely, Biomaterials and Tissue Engineering; Functional Materials and Devices; Nuclear Engineering; Multiscale Materials Modelling; Nanomaterials and Nanoengineering; Advanced Structural Materials. Research highlights from each of these themes forms the largest part of this report. The subject of Materials is ubiquitous and underpins technology that enters everyones daily lives, for example, from transport to mobile devices to healthcare to the energy sector. The vision of the Materials Science and Engineering team at Sheffield is to produce worldclass research that impacts directly on society and industrial processing. Our research is often guided by industrial need, which is shown by the 120 companies and Government agencies who sponsor our work. Equally, we undertake fundamental research, which frequently impacts in later years. The impact of our research is widely publicised and there have been many examples over the last year. For example, Prof Sheila MacNeil has developed a wound dressing that glows to indicate an infection through a gel containing molecules that bind to bacteria and activate a fluorescent dye. Doctors can then make the best decision about how to treat the wound. As well as shining a spotlight on bacteria, the gel can rid a wound of up to 80% of surface bugs in around three hours. This work was highlighted in all of the mainstream national press. Dr Fred Claeyssens was highlighted by the BBC for his work on a miniature honeycomb - or scaffold - that could one day be used to encourage damaged nerves to grow and recover. The scaffold can channel clusters of nerves through its honeycomb of holes, eventually healing a severed nerve, which could one day make a huge difference to patients suffering severe nerve damage. Our work in nuclear waste immobilisation is known around the globe. Following the Tohoku earthquake and tsunami on 11 March 2011, Prof Neil Hyatt gave over 20 media interviews to national newspapers and television channels in relation to the Fukushima Dai-ichi incident, including live appearances on BBC News 24. He was also a key note speaker and panellist at the special The Future of Nuclear Power Post Fukushima session of the Green Party National Conference, Sheffield, 11 September 2011. Antenna (i.e. aerials) are ubiquitous in devices we use in everyday life from radios, televisions, cell phones, satellites, bluetooth devices, wireless computing networks and so on. The efficiency of the antenna is critical, as anyone trying to use a cell phone with a weak signal will know. Prof Ian Reaney has developed new materials for the core of antennas that boost their efficiency. By introducing a radically different manufacturing route, replacing the traditional solid state synthesis by a route where a glass is formed, followed by heat treatment to give controlled crystallisation to form a glass ceramic, antennae with higher efficiency have been produced and the knowledge transferred to industry. Following the announcement of the 5m ERDF grant to Prof Mark Rainforth and Prof Iain Todd to fund the Mercury Centre for Innovative Materials and Manufacturing, the Centre was formally opened in 2011. Benefiting from a long overdue 300k refurbishment of the Quarrell Laboratory, the Centre focuses on the demand for more sophisticated products made with radically improved resource-efficiency. Powder-based manufacturing encompasses a range of new processes such as high-speed sintering, additivelayer, and entrained-jet manufacturing. Equipment at the centre includes Additive Layer Manufacture, Deep Repair, Aerosol Jet Deposition, Spark Plasma Sintering, Metal Injection Moulding and Advanced Materials Characterisation. These new manufacturing technologies have attracted substantial interest from industry, from SMEs to large organisations such as Rolls-Royce. We continue to be a leading force in grant capture. Of the many grants won, it was particularly pleasing to see Dr Tom Hayward win a prestigious EPSRC Career Acceleration fellowship. Tom is currently working with Dr Dan Allwood developing novel techniques for manipulating ultra-cold paramagnetic atoms using the magnetic fringing fields created by ferromagnetic nanostructures. The award is entitled Magnetism You Can Rely On: Understanding Stochastic Behaviour in Nanomagnetic devices and has a total value of 700k. Profs Sheila MacNeil and John Haycock along with Prof R Smallwood, have been awarded 500k for P&G: coupled in vitro and computational models of immune reactions in skin, from Proctor and Gamble, while Prof Sheila MacNeil is also part of a consortium who have been awarded 2.9M for E-TERM, Engineering Tissue Engineering and Regenerative Medicine. Dr Russell Goodall led a team, along with Prof Panos Tsakiropoulos and Dr Iain Todd as part of a large European Consortium to win a 440k FP7 grant Accelerated Metallurgy. Our staff are regularly recognised with awards in recognition of their outstanding work. This year, Prof Allan Matthews was awarded the IOM3 Gold Medal. The award is given for a company, team or individual who has made a significant contribution to the industrial application of materials, in Allans case it was for transferring laboratory-based surface engineering technologies to industry. This is a remarkable achievement while also leading the Department as Head for the four years 2007-2011, arguably the most
Materials Science & Engineering, The University of Sheffield
Introduction 1
Materials@Sheffield 2012
successful in the Departments history. In the same year, Dr Brad Wynne has been awarded the IOM3 Harvey Flower Titanium Prize for his ground breaking work on crystallographic texture evolution and phase transformation behaviour in aerospace titanium alloys. We were delighted for Iain Todd and Russell Hand, who were both promoted to Personal Chairs, for Dr Steve Matcher who was promoted to Reader and to Dr Russell Goodall and Dr Martin Jackson who were promoted to Senior Lecturer. After years of steady academic staff numbers, we have made a number of key strategic appointments. We welcome John Provis from Melbourne University as Professor of Geopolymers. Johns research is primarily based around the design, synthesis and characterisation of durable, low CO 2 materials for applications in construction, waste management and as low cost ceramics. Dr Karl Whittle joins us from ANSTO, Australia, as Senior Lecturer in Nuclear Materials. Karls research is concerned with the development of materials that have applications as first wall materials, and materials that have applications as both nuclear fuels and waste form. Dr Biqiong Chen has joined us from Trinity College, Dublin as Senior Lecturer in Functional Polymers. Her research is wide ranging, encompassing polymer chemistry, nanocomposites, biocomposites, biomimetics and nanofabrication. We are also delighted to appoint Dr Julian Dean as Teaching Fellow in January, to assist with Cross-Faculty
Introduction
teaching, other parts of the curriculum and to continue his impressive research focused on modeling. Julian is a previous winner of the Kroto Prize for Excellence in the Science Education of Young People. One of our key roles is the training of the next generation scientists and engineers at all levels from undergraduate to postgraduate. The last year has seen a substantial increase in numbers of research staff, research students and postgraduate Masters students. The total number of research students in the department is just short of 200, almost double the number 3 years ago. The same is true for the Masters students, with an intake of around 66 being more than double the numbers of three years ago. We now struggle for space for all the staff and students, but an ambitious multi-million pound new build and refurbishment programme in the Faculty of Engineering will help us build the infrastructure in-line with our plans for growth. Our success has been recognised with the Department being ranked the 2nd best Materials Department in the UK in both the Guardian and the Independent league tables, and of course we are proud to be part of 2011 University of the Year. Prof WM Rainforth, Head of Department.
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Materials@Sheffield 2012
Department Staff
m.r.gibbs@ 0114 2224261 r.hand@ 0114 2225465 j.harding@ 0114 2225957 j.w.haycock@ 0114 2225972 n.c.hyatt@ 0114 2225470 Beverley.inkson@ 0114 2225925 s.macneil@ 0114 2225995 a.matthews@ 0114 2225466 (from 1st June 2012) i.m.reaney@ 0114 2225471 d.c.sinclair@ 0114 2225974 i.todd@ 0114 2226011 p.tsakiropoulos@ 0114 2225960 g.ungar@ 0114 2225457 a.r.west@ 0114 2225501 d.allwood@ s.j.matcher@ g.moebus@ e.j.palmiere@ i.u.rehman@ biqiong.chen@ c.k.chong@ r.goodall@ martin.jackson@ a.leyland@ k.travis@ k.r.whittle@ b.wynne@ f.claeyssens@ c.l.freeman@ s.a.hayes@ g.hrkac@ h.kinoshita@ n.a.morley@ g.reilly@ c.rodenburg@ r.thackray@ x.zeng@ j.dean@ j.foreman@ p.kapranos@ m.c.stennett@ 0114 2225938 0114 2225994 0114 2225512 0114 2225978 0114 2225946 0114 2225958 0114 2225984 0114 2225977 0114 2225474 0114 2225486 0114 2225483 0114 2225929 0114 2226026 0114 2225513 0114 2225965 0114 2225516 0114 2226028 0114 2225930 0114 2225935 0114 2225986 0114 2225921 0114 2225963 0114 2225948 0114 2225928 0114 2225517 0114 2225509 0114 2225504 0114 2225499
Materials@Sheffield 2012
Emeritus Professors: Associate Professors: Prof B B Argent Prof P V Hatton Prof M Cable Prof R van Noort Prof H A Davies, FREng Prof F G F Gibb Associate Senior Lecturer: Prof G W Greenwood, FRS, FREng Dr D H Kirkwood Prof F R Jones Prof H Jones Associate Reader: Prof J M Parker Dr D H Warrington Professor C M Sellars, FREng Professor J H Sharp Associate Lecturers: Professor P V Wright Dr A W Bryant Dr A J Devlin Visiting Lecturers: Dr E Maddrell (1 January 2007-31 December 2012) Senior Experimental Officers Dr V Royds Dr P Korgul (Sorby Centre) Departmental Technical Manager: Dr S J Mason Financial Administrator: Mr D M Binns Short Course Director: Dr P A Kapranos Manager, Mercury Centre: Dr M I Highett Marketing and Administration Officer/ Mercury Project: Mrs S Hollely Project Manager Metals DTC: Dr C Hinchliffe Learning Technologist Metals DTC: Mrs K Thomson E-Futures DTC Programme Manager: Dr N J Lowrie Visiting Academic Staff: Prof N A Chapman, Independent Consultant in Radioactive Waste Management Prof P T Curtis, DSTL Prof S Franklin, Philips, The Netherlands Prof K Holmberg, Technical Research Centre of Finland (VTT) Prof A A Howe, Tata Steel Prof D Jiles, Dept of Electrical & Computer Engineering, Iowa State University Prof P T McGrail, Composites and Polymers Consultant Dr S Owens, National Nuclear Laboratory Prof D Porter, Dept of Zoology, University of Oxford Prof S Stipp, University of Copenhagen, Denmark Prof W Smith, CCLRC Daresbury Laboratory (retired February 2011) Prof J Talamantes Silva, Sheffield Forgemasters Ltd Prof J Thomason, Strathclyde University Prof B S Yilbas, King Fahd University of Petroleum and Minerals, Saudi Arabia Associate Professor Qi-Long Zhang, Materials Science and Engineering, Zhejiang University Prof dr ir Sybrand van der Zwaag, Technische Universiteit Delft, The Netherlands Experimental Officers: Dr L Ma Dr N Reeves-McLaren Dr C Shaw Dr P Zeng Teaching Administrator: Mrs T V Sampson The Nanolab Project Administrator: Mrs J Simpson Project Engineer: Dr F Derguti Research Manager: Mr G Brown IMMPETUS Administrator: Ms M Szofer
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Technical Staff: Support Staff: Dr J Bates Mrs V M Dalton (PA to Head of Department) Miss D Bussey Mrs K A Burton Mr M Carter Ms W B Dutton Mr M G Cooper Miss R D Fearon (p-t) Mr F G Fletcher Miss K L Heard Mr P Hawksworth Miss F E Kirk Mr D Haylock Mrs L C Mason Dr L Holland Mrs A Newbould (p-t) Miss C Johnson Mrs S Nixon (p-t) Mr R Kangley Miss K Orgill Ms B C Lane Mrs A E Sargent Mr A G Mould Mr B G Palmer Coffee Bar Staff: Mr P Staton Mrs A Marquis Mr M J Wagner Mr I P Watts Research Fellows and Research Assistants: Dr M Audronis EPSRC and Technology Strategy Board (AL) 20 Feb 2012-19 Feb 2013 Dr A J Beck - BBSRC (AM) 1 Apr 200631 March 2012 Mr U Bhatta EPSRC (GM) 30 April 2010-14 March 2013 Dr P Bingham KTA (RJH) 1 Aug 201031 Dec 2011 Dr K Briston EPSRC (BJI) 01 Oct 201030 Sept 2012 Dr M Bryan EPSRC (DA) 1 March 200931 March 2012 Dr A Bullock Sheffield Teaching Hospitals Trust (SMN) 25 April 2000-22 April 2011 Mr K Butler European Union (JHH) 1 Dec 200931 May 2012 Dr B Christiansen EPSRC (JHH) 1 Oct 2010-30 Sept 2013 Dr C Corkhill EU REDDUP (NCH) 1 Sept 2011-31 March 2014 Dr D Cumming EPSRC (IMR) 1 March 2010-31 Oct 2012 Mr R Delaine-Smith P/T (SMN) 1 Oct 2011-27 April 2012 Ms P Deshpande Wellcome Trust (SMN) 16 July 2010-15 July 2013 Dr R Dost EPSRC (DA) 1 Dec 2011-20 July 2012 Dr M Faraji EPSRC (PT) 1 Jan 2009-31 Dec 2012 Dr M Ferrarelli Feb 2009-Feb 2012 Dr H Foxhall EPSRC (JHH) 1 July 2010-30June 2013 Dr A Gandy EPSRC (NCH) 1 Oct 2011-30 Sept 2013 Mr J Ghatak EPSRC (GM) 10 Jan 2011-31 Dec 2011 Dr W Guan - EPSRC (BJI) 1 July 2009-15 Jan 2012 Dr E Hadzifejzovic EPSRC (ARW) 1 Dec 2011-30 Sept 2012 Dr J S Hinton EPSRC (WMR) 1 April 2009-31 March 2012 Dr C Huang Mercury Project (WMR/IT) 7 Feb 2011-30 Sept 2013 Mr J Hunt Mercury Project (WMR/IT) May 2011-Swept 2013 Dr YN Kok EPSRC (AL & AM) 1 June 2010-30 Nov 2011 Dr M Krzyzanowski EPSRC (WMR) 1 Aug 2002-31.12.2012 Dr H Li TST (AL) 6 Feb 2012-5 Feb 2014 Dr M Li EPSRC (DCS) 1 April 2010-1 Setp 2012 Dr F Liu FP7-Nanogold (GU) 2 Oct 2009-31 Aug 2012 Mr Y Liu EPSRC (ARW) 1 Nov 2009-31 May 2012 Mr Z Liu Mandeville of London (FRJ) 1 Dec 2010-31 May 2011 Dr A Lockwood EPSRC (BJI) 1 Oct 2010-30 Sept 2012 Dr Z Lu EPSRC (SJM) 16 June 2008-31 May 2012 Dr N Maso Carcases EPSRC (ARW) 1 March 2009-30 Sept 2012 Dr S Mittar EU Cascade (SMN) 1 Feb 2011-31 Dec 2011 Dr A Nogiwa Valdez Mercury Project (WMR/IT) 1 March 2011-31 Sept 2013 Dr I Ortega Wellcome Trust (SMN) 10 Jan 2011-9 Jan 2012 Dr J Pokorny EPSRC (IMR) p/t 1 Feb 2008-31 Jan 2012 Mr A Rana Mercury Project (WMR/IT) 1 May 2011-30 Sept 2013 Mr T Sebastian KTA (IMR) 1 April 2011-31 May 2012 Dr F Sefat Wellcome Trust (SMN) 5 Jan 20114 Jan 2014 Dr J Sharp EPSRC (WMR) 1 Dec 201030 Sept 2012
Department Staff 2
Materials@Sheffield 2012
Dr W Shen EPSRC (IMR) 20 March 2010-19 March 2012 Dr A Sidambe ERDF (WMR & IT) 8 Sept 2010-07 Sept 2013 Mr T Simm EPSRC (WMR) 31 Oct 2011-31 Dec 2012 Dr D Stapleton Mercury Project (WMR/IT) 1 Oct 2011-30 Sept 2012 Dr I Sterianou EPSRC (IMR) 1 Oct 2009-30 Sept 2012 Dr T Swait Airbus (SAH) 1 Feb 2010-27 July 2012 Dr M Thomas EPSRC/UoS Doctoral Prize Fellowship 1 Oct 2011-30 Sept 2012 Dr C Utton EPSRC (PT) 8 June 2010-30 April 2014 Dr A Yerokhin EPSRC (AM) 1 July 2003-31 March 2013 Dr H Zhang (IMR/WMR) 12 Dec 2011-31 Aug 2014 Dr Y Zhang Mercury Project (IT/WMR) 1 Aug 2011-31 Sept 2013 KTP Associates: Dr T Biggs KTP Rolls Royce (RG) Dr M Darby KTP from Ilika Technologies Ltd (IMR) 1 Feb 2009-31 Jan 2012 Dr R Deffley KTP from LPW Technology Ltd (IT) 1 Aug 2010-31 July 2012 Mr L Jiranek KTP from William Beckett Plastics (IT & RG) 1 Nov 2010-30 Oct 2012 Mr S Saeidi KTP from Cutting & Wear Ltd (AL) 17.01.2011-16.04.2013 Dr P Travaglia KTP from DPG Ltd (SAH) 1 March 2010-29 Feb 2012 Miss B Zalinska KTP from Sarantel Group plc (IMR) 1 Oct 2009-30 Sept 2012
Department Staff
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Committee 3
Materials@Sheffield 2012
Dr B Rickinson [Bernie] Chief Executive Institute of Materials 1 Carlton House Terrace London SW1Y 5DB Tel: 020 7451 7367 Bernie.Rickinson@iom3.org Dr R Ricks [Ricky] Technology Strategy Consultants Unit 16, Blackwell Business Park Blackwell Shipston-on-Stour Warwickshire CV36 4PE Tel: 01608 682199 M: 07739 862812 Ricky.ricks@tecstrat.co.uk Dr E G Shahidi [Ebby] Advanced Composites Group Ltd Composites House Sinclair Close Heanor Gate Industrial Estate Heanor Derbyshire DE75 Tel: +44(0) 1773 766200 Mobile: +44 (0) 7887 535520 eshahidi@acg.co Dr M W Stow [Martin] Vice President R&D WW, Ethicon Products c/o DePuy International Ltd St. Anthonys Road Leeds LS11 8DT Tel: +44 (0) 113 272 4110 Fax:+44 (0) 113 387 6218 Mobile: +44 (0) 7768 555 707 Email: mstow@its.jnj.com
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Committee
Materials@Sheffield 2012
Academic Staff
Dr Frederik Claeyssens
Licentiate PhD Member RSC MRS Lecturer in Biomaterials Current research is focussed on biomaterials manufacture with laser based techniques. This research broadly falls into three categories: Coatings for biology: Biocompatible surface coatings of semiconductors to be integrated into cellsilicon interfaces for biosensors. Bioprinting: Laser based techniques for printing biomolecules/cells for producing biomolecule arrays and biosensors. Biomaterials manufacture via microstereolithography: Production of microstructured biomaterials for usage as tissue engineering scaffolds, via a laser based photocuring technique. Via scanning the laser through a photocurable resin, user-defined microstructures can be produced from a biocompatible polymer. This technique can be combined with self-assembly approaches to achieve hybrid biomaterials as 3D scaffolds for implants, tissue engineering and pharmaceutical testing.
Dr Biqiong Chen
BSc, MSc, PhD Senior Lecturer in Functional Polymers Research focuses on synthesis, processing, characterisation and properties of polymers and polymer nanocomposites with particular emphasis on the structure-property relationships. Current research activities include fundamental studies of polymer-clay and polymer-graphene nanocomposites; plastics recycling; development of biomimetic polymer nanocomposite foams as potential tissue scaffolds; novel nanocomposite hydrogels for engineering applications; biodegradable microneedles for transdermal drug delivery; functionalised nanoparticles for cancer imaging and treatment; and stimulus-responsive nanocomposites.
Dr Chuh K Chong
BSc PhD Senior Lecturer in Biomedical Engineering Main research interest centres on cardiovascular fluid mechanics, focusing on understanding the role of haemodynamics in the pathogenesis of arterial diseases in normal and reconstructed vessels, the pharmacokinetics of drug-eluting stents, with the aim of designing betterperforming customised vascular implants and bypasses. Another interest is in tissue engineering, particularly the cardiovascular system, focusing on the mechanics of soft tissues, developing functional cell-seeding device and bioreactors, scaffolds and matrices with desired architecture and material properties, with the aims of understanding the effects of materials, mass transport, biochemical cues and mechanical stresses on cell activities in purpose-designed bioreactors to develop better tissue constructs.
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Academic Staff
Dr Russell Goodall
MEng PhD CEng MIMMM Senior Lecturer in Metallurgy Principal research interests are in the processing, mechanical and thermal properties and applications of open-celled porous metals. This includes aluminium, which with a relatively high thermal conductivity, combined with low density and low cost is interesting for applications requiring heat transfer from or to a fluid medium. Opencell foams made from other metals such as titanium can have applications as electrodes or as surgical implants, amongst many others. As well as foams (with pores or cells in random locations), he is also interested in porous structures with varying degrees of order, such as 3D lattice structures. Current challenges are the assessment of the suitability of processes for practical fabrication of foam parts, the development of methods to allow production of novel foam architectures, the characterisation of both the mechanical and thermal performance of the material and the further optimisation of the properties for certain applications.
Dr Simon A Hayes
BEng PhD Lecturer in Aerospace Engineering Research interests encompass smart materials, nanocomposites and nanomechanical property determination. He is involved in the development of sensors for damage detection, cure monitoring and through-life environmental condition monitoring in polymer-matrix composites. He has also developed a patented technology for the healing of damage within composite structures. He has projects examining the mechanical properties of clay and nanotube-based nanocomposites. He is also involved in the development of nanoindentation for the analysis of soft viscoelastic materials.
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Materials@Sheffield 2012
Dr Gino Hrkac
Dr techn Dipl INg Royal Society University Research Fellow Main research area is computational and theoretical magnetism, and especially the development of a numerical model to investigate and predict the behaviour of magnetic spin valve systems and the effect of eddy currents in nano-scale materials. He is working on the theoretical and numerical description of spin electronic devices on a length scale ranging from the computation of the local spin current density and magnetization dynamics with a sub-nm resolution in micron size devices (magnetic nano pillars and Magnetic Tunnel Junctions). A prominent example for his work is the theoretical explanation of the angular dependency of phase locking phenomena in point contacted spin valves and His work on the simulation of spin current induced magnetization dynamics that explained the low frequency oscillations found in point contact devices that were explained by vortex oscillations. His latest research includes ab initio simulations of atomic structures, solid state molecular dynamics for the simulation of the transition of amorphous to crystalline grain boundaries in NdFeB magnets within the framework of an industrial funded project on permanent magnets (EuropeanJapanese consortium).
Academic Staff 4
Dr Martin Jackson
MEng PhD DIC Royal Academy of Engineering/ EPSRC Research Fellow and Lecturer Elect Research interests centre on solid state processing, microstructural/ textural evolution and phase transformations in light alloys. Major research focus is development of low cost non-melt consolidation routes for particulate titanium-based feedstock from emerging reduction processes. Current research in titanium also includes; (i) microstructural evolution during isothermal forging of high strength alloys used in airframe forgings; (ii) alpha case formation/crack initiation in alloys used in aeroengine gas turbine compressors. Other research interests include the superplastic behaviour of aluminium and magnesium alloys during processing for automotive applications.
Dr Hajime Kinoshita
BEng MEng DEng Lecturer in Materials Chemistry and Geochemistry Current researches focus on the environmental-friendly applications of mineral-based materials, extending from nuclear waste management to CO2 storage. Current projects include low temperature synthesis of ceramics for nuclear waste immobilisation, CO2 storage in recycled cementitious waste materials using molten salt media. Based on thermodynamics, both experimental and computational techniques are used to improve their capacity to host the aiming compounds and the compatibility of the products to the environment.
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Academic Staff
Dr Adrian Leyland
BSc PhD MInstP Senior Lecturer in Surface Technology Research interests are focused on Surface Engineering and Tribolog y, specialising in plasma-assisted Physical Vapour Deposition (PVD) of nanostructured ceramic coatings (for wear resistance and/or adaptive behaviour in extreme environments), metallic nanocomposite/glassy-metal coatings (for combined wear and corrosion protection), duplex plasma-diffusion/ PVD-coating treatments (to improve the load-bearing capacity of light alloys and stainless steels in sliding wear applications) and the development of tribological testing/ property evaluation techniques for coatings.
Dr Gnter Mbus
DiplPhys Dr rer nat (PhD) Reader in Microscopy and Materials Science Research is focussed on the characterisation of materials on the atomic and nanoscale, including development of quantitative electron microscopy techniques for 3D-mapping of microstructure, composition, strain, and retrieval of crystal defect structures. Within the context of immobilisation science, modern characterisation techniques, such as tomography, 3D reconstruction, and fine structure spectroscopy are used to detect the local composition and microstructure in glasses and ceramics, and to determine local coordination and oxidation states of cations.
Dr Nicola A Morley
MPhys PhD MemInstP Lecturer in Materials Physics Current research includes: manipulating the anisotropy and magnetostriction of thin Fe-based magnetic films and multilayers; novel spintronic devices, which include organic polymer spacer layers; spinterface investigations at organicmagnetic interfaces; organic intrinsic magnetoresistance of conjugated polymers and small-molecules; using muons to measure the intrinsic transport properties of polymers.
Dr Stephen J Matcher
BSc, PhD, Member SPIE, OSA, BMS, ESM. Reader in Biomedical Engineering. Current research interests: development of optical imaging and spectroscopy to characterize bioengineered tissues in vitro and in situ. Main techniques are optical coherence tomography and microscopy, elastic scattering spectroscopy, secondharmonic and two-photon microscopy. He is particularly interested in the collagen structure of connective tissue and how this is altered in disease, in techniques to assess tissue perfusion and cellular bioenergetics in vivo and in Doppler techniques to study the microcirculation.
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Dr Eric J Palmiere
BSc MSc PhD CEng Reader in Metallurgy Research involves the microstructural evolution, and the subsequent development of mechanical properties, during the thermomechanical processing of both ferrous and nonferrous alloys with a primary focus on ferrous alloys such as stainless, microalloyed steels and associated model alloy steels. He is particularly interested in developing a basic understanding between those softening (i.e. recovery, recrystallisation) and strengthening (i.e. solid solution formation, precipitation) mechanisms which occur either in austenite or in ferrite.
Academic Staff 4
Dr Ihtesham ur Rehman
BSc MSc PhD Reader in Biomedical Materials The focal point of his research has been the identification and understanding of the fundamental mechanisms by which chemical responses are mediated by nanto micro-scale variations in biomaterials, with the main emphasis on the development of synthetic inorganic bone analogue materials and characterisation of natural tissues. Current research covers the following themes: Analysing Cancer with Spectroscopy: FTIR and Raman spectroscopy of cancer tissues and cells with the aim of developing diagnostic techniques for cancer. Polymers and Bioactive Composites: Development of an auxetic biodegradable drug-eluted stent-graft in the palliation of oesophageal cancer Bioactive composite materials: Development of improved ceramic/polymer composites for osteological and dental applications Dental Materials: Glass -ionomers, nano-ceramics and nano-composites for dental restoration.
Dr Gwendolen Reilly
BSc DPhil Lecturer in Tissue Engineering Background: bone biomechanics; transduction of mechanically induced signals in bone cells; bioactive glasses as a scaffold for bone tissue engineering; skeletal cell differentiation. Research aims: investigating the use of mechanical stimuli to enhance strength of tissue engineered bone and cartilage; examining the effect of biomaterial scaffolds on skeletal cell mechanical responses; mechanical manipulation of tissue engineered matrix structures. Our laboratory is particularly interested in using tissue engineering to create 3D bone models for use as an alternative to animal experiments in the testing of orthopaedic pharmaceuticals and devices.
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Academic Staff
Dr Karl P Travis
BSc PhD CChem MRSC Senior Lecturer in Modelling Materials Research interests cover Theoretical and Mathematical Physics, particularly of condensed phases; structure-property relationships of materials; and the thermodynamic behaviour of nana-confined fluids. Research is currently focussed on applying atomistic, mesoscale and continuum modelling techniques to problems connected with the storage of nuclear waste. Some current topics under investigation include: modelling radiation damage in ceramic wasteforms, modelling the conductive flow of heat in very deep geological disposal scenarios and developing Dissipative Particle Dynamics for predicting phase behaviour and rheology in complex mixtures.
Dr Richard Thackray
BEng PhD DIC Tata Steel Lecturer in Steelmaking Research interests are in continuous casting of steel, in particular the role of mould powders in the processing route, where models have been developed which relate the viscosity, break temperature, and crystallinity of the powder to the successful performance of the casting operation. New research into evaluating the suitability of F-free fluxes to replace existing fluxes will also be carried out in the near future. In addition, work to understand the complex flow of metal during the casting process, and the associated heat transfer effects and product quality implications, using process modelling techniques is also ongoing.
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Dr Bradley P Wynne
BEng PhD Senior Lecturer in Metallurgy Research interests focus on the thermomechanical processing of metals and alloys, particularly the interrelationship between the constraints imposed by the deformation conditions and the constraints on flow behaviour generated by crystal structure and crystallographic texture, which in turn determines deformation microstructure evolution. Currently his major focus is on the effects of non-linear strain paths on microstructure evolution. The overall aim of this research is to develop true internal state models for microstructure evolution to replace our current empirically based models which are often inadequate when deformation conditions are complex.
Academic Staff 4
Dr Xiangbing Zeng
BSc MSc PhD Lecturer in Polymers Current research concerns 1-d, 2-d, 3-d ordered nano-structures (1 100 nm) in macromolecular and supramolecular systems, with potential applications for molecular electronics, photonics etc. The main methods used are small angle x-ray and neutron scattering (SAXS and SANS). These experiments are often carried out in real-time in order to catch transient structures and rapid transformations such as occur in real-life, industrial processing of polymers.
Dr Karl Whittle
BSc MSc PhD Senior Lecturer Research focusing radiation effects and how they can be mitigated in the development of new materials for use within nuclear reactors (fission and fusion), and the next generation of nuclear waste forms. An approach using experimental investigations coupled with computer simulations are used holistically. Current topics include order/disorder in systems and how it can be used to tailor radiation effects, transmutation effects, and new materials resistant to 400 dpa (displacements per atom) of damage.
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5.1
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Research Themes
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5.1
Biomaterials
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5 Research Highlights
5.1 Biomaterials and Tissue Engineering
Bioengineering peripheral nerve
Three-dimensional in vitro cell culture models are seeing a rapid rate of development, principally driven by the need for conducting studies in a more relevant environment compared to the culture of cells in two dimensions, against a background of the 3Rs (replacement refinement, reduction) in regards to animal usage and scientific experimentation (reviewed by John Haycock (Methods Mol Biol 2011;695:1-15). While an increasing number of mammalian tissues have been reconstructed using three dimensional techniques, often by combining scaffolds and the co-culture of cells, little work has been conducted on peripheral nerve. The development of such models holds considerable value for a breadth of studies, from a basic understanding of neuronal-glial development through to the design of improved scaffolds for nerve tissue reconstruction following injury. It is known that an intimate relationship exists between neurons and glia, both in development and following the response to injury. However, a number of specific requirements exist for making 3D in vitro models. Thus, the design of scaffolds for controlling neuronal and glial cell movement requires an understanding of the cellular response to physical stimuli. Previous studies report that fibre diameter can alter cellular morphology and proliferation, as well as migration. In this respect, the use of electrospinning, while a commonplace technique for fabricating scaffolds, is attractive for studying the relationship between physical dimensions and cellular response. Fibre diameters can be controlled between nanometer and micrometer length scales by manipulation of the electrospinning processing parameters. Aligned fibres can be readily fabricated via a number of fibre collection strategies, which is of particular importance for peripheral nerve studies. In recent research from John Haycock and colleagues (Muhammad Daud, Kiran Pawar, Frederik Claeyssens and Tony Ryan) we have developed a controlled process for producing aligned polycaprolactone (PCL) microfibers with discrete diameters ranging from 1 m to 8 m. The response of neuronal cells and primary Schwann cells were evaluated separately in single culture and as glialneuronal co-cultures. This was then extended to using dorsal root ganglion cultures for forming aligned 3D neuronal-glial co-cultures. Taken together, the models formed a basic but organised peripheral nerve structure and we suggest this approach has the potential for use in a breadth of studies, from basic cell biology through to injury, in disease studies (e.g. de-myelinating disorders), but also in the improved design of biomaterial scaffolds for peripheral nerve regeneration and in bridging the gap between simple in vitro cultures and in vivo implantation studies.
Figure 5.1.1. Left. Confocal microscopy images of neuronal cells (beta-III tubulin - red) and primary Schwann cell (S100 - green) co-cultures on aligned PCL fibres of 1 m (A, D, G, J), 5 m (B, E, H, K) and 8 m (C, F, I, L) diameter after 4-days co-culture. Images are shown as both separate channels - neuronal cells alone (A, B, C), primary Schwann cells alone (D, E, F) and neuronal / primary Schwann cell co-cultures (G, H, I). Corresponding 3D composite images are presented (J, K, L). Neurite growth and Schwann cell organization was guided in the direction of fibre alignment for all fibre diameters. Scale bar = 50 m. Right - Confocal microscopy images of isolated DRGs grown on 1 m (A-D), 5m (E-H) and 8m (I-L) aligned PCL fibres. Fibre direction is from left to right in all micrographs (A-L). (A, E, I) S100 expressing Schwann cells (green); (B, F, J) -III tubulin expressing neurites (red) and (C, G, K) overlaid images showing co-localisation of -III tubulin expressing neurites and S100 expressing Schwann cells. (D, H, L) shows high magnification selected regions of interest identifying close physical association of Schwann cells and neurites (yellow). Arrows for (A, E, I) indicate the furthest identified position of migratory Schwann cells. Arrows for (B, F, J) indicate the furthest position of neurite extension. Asterisks (*) mark the position on the left of each micrograph of where ganglion bodies were placed for culture. Scale bar = 100 m. (M, N, O) shows isolated DRGs cultured on a flat (control) TCP surface for reference with no directional organisation, labelled for S100 (M), -III tubulin (N) and S100 plus -III tubulin (O). Sale bar = 200 m. (P) Quantification of neurite length and Schwann cell migration on each of the fibre scaffolds.
Figure 5.1.2. This shows the before and after on a patient treated with a combination of their own tissue delivered as very small pieces from the other (undamaged) eye to the damaged eye on a substrate of human amniotic membrane. This is an example of a simple idea being translated into clinical practice.
Sheila MacNeil working with colleagues at the LV Prasad Eye Institute, Hyderabad, India, with funding supported by the Wellcome Trust has had the pleasure of seeing an idea going rapidly into clinical practice to benefit man. The project funded by the Wellcome Trust (Sheila MacNeil is PI and Frederik Claeyssens (Department of Materials Science and Engineering) and Professor Tony
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Ryan (Department of Chemistry) are co-applicants on this) is seeking to develop a synthetic carrier membrane to use as an alternative to the biological donor membrane of the human amnion which is currently used to deliver laboratory expanded limbal stem cells to the cornea. While The use of the human amnion to deliver cells can work reasonably well, this project seeks to design a synthetic off-the-shelf safer alternative to the human amnion and work is proceeding well. However, during the initial planning phase of this research Sheilas idea of using small explants of tissue rather than laboratory cultured cells was shared with her colleagues in India who quickly took the idea into progress putting very small explants of tissue onto the human amnion and the above picture shows an example of the clinical results. The relevance and impact of this technique is that it simplifies how these patients can be managed so that on no longer needs to laboratory expand the cells but may be able, for certain conditions to simply use finely diced explants of the contralateral undamaged eye. This is an example of an international research partnership benefiting patients.
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(b)
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Figure 5.1.3. (a) Bone cells in 3D glass scaffolds imaged by confocal microscopy. (b) Cross-section through glass scaffolds with bone matrix stained in red. (c) Oscillating fluid flow bioreactor to apply shear stress to bone cells.
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thus yielding estimates for these parameters which are consistent with the known structural properties of this type of cartilage. With further development we believe that this technique could become a unique tool for the in-vivo characterising of cartilage structure.
Figure 5.1.4. Comparison of measured (symbols) and calculated (red line) depth-resolved optical retardance curves for bovine cartilage.
the cells are cultured (Figure 5.1.5c) can be extracted and used predict these stresses and to ensure that the EC cultured in the system are subjected to welldefined and quantified mechanical forces (Figures 5.1.5d, 5.1.5e). In parallel to this, we have developed a dedicated automated image processing/segmentation programme which is being used to aid the analysis of EC response to mechanical stimulation (Figure 5.1.5e). This system not only allows us to perform experiments to better understand the effects of different mechanical stimuli in the development of atherosclerosis, its modular design and simple set-up allows easy incorporation of further modifications for extending its applications and the range of experiments which can be performed. These modifications include incorporating a library of atheroprone and atheroprotective shear stress profiles, culturing EC in monolayer or co-culture with smooth muscle cells (and fibroblasts) on flexible substrates, or excised tissues, and subjected to physiological cyclic stretch and circumferential deformation to the cells to understand their interactions, in normal and pathological events, while it also allows for mechanical stimulation of vascular cells for engineering vascular tissues. It is also expected to be useful in anastomotic engineering, design of vascular devices e.g. stents, understanding cells and biomaterials interactions, as well as developing vascular disease models, angiogenesis and vascular networks formation. In the future, we aim towards developing a flow-bioreactor system with feedback control/autoregulation and with capabilities for live cells imaging and continuous online monitoring and assessment of cell profile as well as mechanical/structural properties/ profiles of engineered vascular tissues/network. a b c
Figure 5.1.5. (a) Comparing requested physiological flow waveforms and those reproduced by FBS. (b) Some examples of physiologically normal or hypo/hypertensive pressure waveforms obtained in the FBS. (c) Map of WSS showing distributions within 1% to 5%. (d) Morphology of EC cultured under static condition for 13 hours. (e) Morphology of EC cultured under steady flow condition in FBS for 13 hours. (f) Image of mmunostained EC segmented to extract cell number, aspect ratio, cell alignment, nucleus, centroid.
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Figure 5.1.7. PLS1- PLS-DA model applied to the training and test sets. The high-dimensional spectral space has been reduced to a two-dimensional space of PLS scores (T1 and T2); the classifier is shown as the dashed line.
Figure 5.1.8. FTIR and Raman spectra of Normal, DCIS (HNG), and IDC (GIII) Breast Tissues.
Figure 5.1.6. Infrared image of cancer tissue with associate spectroscopic analysis.
In recent research from Ihtesham ur Rehman and colleagues (Sheila MacNeil, Rob Coleman, Martin Thornhill, Jonathan Bury, Helen Coley and Ingunn Holen), we are developing a spectroscopic process that can help in precisely identifying the chemical structural differences between the normal and cancerous cells an in addition differentiating the sub type of cancers. Raman spectroscopic chemical imaging is employed for tissue (normal and cancerous) sample analysis, focusing on key criteria that need to be considered in clinical diagnosis including resolution, accuracy, robustness, speed, cost and how easy it is to use. Advanced novel signal and image analysis techniques are employed to develop a decision support system that can provide quantitative assessment of every single pixel of a tissue, as well as a subsection of an image frame and a whole image frame on the degree of abnormality, with confidence levels of the assessment of between 97 to 99%. This involves investigation of multi-scale signal and image-processing methods using wavelets, multi-mode multivariate statistical control based on principal and independent component analysis, as well as genetic programming based tree classification.
Raman and FTIR spectra of the normal breast tissue were compared with malignant tissue. Different grades of ductal carcinoma in situ (DCIS) and invasive ductal carcinoma (IDC) were analysed with the aim to evaluate precisely how spectroscopy could differentiate between these grades and any biochemical changes taking place. The research work on breast cancer tissue samples to develop an approach of early diagnosis of various histopathological subtypes and monitoring changes in response to treatment is continuing. Another project is focusing on differentiating between benign moles and metastatic melanoma employing well developed in-vitro models (by Sheila MacNeil) which in turn will help with early, non-invasive detection of metastatic melanoma. We are also working on analysis of oral squamous cell carcinoma, the commonest cause of head and neck cancer (in collaboration with Martin Thornhill) in an attempt to develop an early and non-invasive diagnostic technique using recently developed a 3D tissue-engineered human models that accurately replicate normal oral mucosa, dysplastic epithelium and invasive Oral squamous cell carcinoma (OSCC). OSCC, a primary cause of HNC, evolves from normal epithelium through mild, moderate and severe dysplasia to carcinoma in-situ before invading into the connective tissue to form carcinoma. We believe that this work will ultimately expand to incorporate all cancers, and not only cancer, other diseases as well. We believe exploitation of this data has the potential to revolutionise clinical medicine and fulfil the promise of the spectroscopy of biological molecules era to impact positively on human health.
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Neural Tissue Engineering: direct laser writing of 3D scaffolds for neural tissue engineering applications
John Haycock and co-workers have produced highresolution 3D structures of polylactide-based materials via multi-photon polymerization and explores their use as neural tissue engineering scaffolds. To achieve this, a liquid polylactide resin was synthesized in house and rendered photocurable via attaching methacrylate groups to the hydroxyl end groups of the small molecular weight prepolymer. This resin cures easily under UV-irradiation, using a mercury lamp, and under femtosecond IR irradiation. The results showed that the photocurable polylactide (PLA) resin can be readily structured via Direct Laser Write (DLW) with a femtosecond Ti:sapphire laser and submicrometer structures can be produced (Figure 5.1.10). The maximum resolution achieved is 800 nm. Neuroblastoma cells were grown on thin films of the cured PLA material, and cell viability and proliferation assays revealed good biocompatibility of the material. Additionally, PC12 and NG108-15 neuroblastoma growth on bespoke scaffolds was studied in more detail to assess potential applications for neuronal implants of this material. The study revealed that the PLA-based photocurable resin supports well neuronal cell growth and that these structures can be used to study aligned cell growth (Figure 5.1.10) and cell ingrowth in scaffolds.
Corneal tissue engineering: development of a microfabricated artificial limbus with artificial stem cell niches for corneal repair
This project focuses on the development of an artificial limbus incorporating stem cell niches. These niches act as well-defined microenvironments for limbal stem cells development and protection. In accidents or diseases where the surface of the cornea is damaged, stem cells are crucial for corneal regeneration. These corneal problems caused by chemical burns, Aniridia or Steven Johnson syndrome can result in the formation of scar tissue over the cornea and lead to permanent blindness. Providing synthetic microenvironments for limbal stem cells is a novel approach which is envisaged to aid in the regeneration process. In this project Sheila MacNeil and co-workers build artificial microenvironments or niches via microstereolithography (microSL) to mimic the structure of the natural stem cell niches. MicroSL allows the building up of user-defined structures via a layer-bylayer photocuring of the material. Photocurable polymers such as polyethylene glycol diacrylate (PEGDA) are used in this application due to their well-known properties for tissue engineering applications and biomedical uses. We have been able to build different prototypes of limbal rings incorporating stem cell niches (Figure 5.1.9), and we have been able to selectively tune the surface chemistry of the stem cell niches (Figure 5.1.9). We are currently studying these rings in a rabbit corneal organ culture (Figure 5.1.9) to assess the efficiency of these scaffolds for corneal tissue engineering.
Figure 5.1.10. (left) Detail of a Direct Laser Written scaffold and (middle and right) NG108-15 neuronal cell growth on a line pattern of PLA.
Figure 5.1.9. (left) photograph of a corneal tissue engineering scaffold, (middle) scanning electron micrograph highlighting a stem cell niche incorporated within this scaffold and (right) scaffold incorporated in a rabbit corneal organ culture.
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ab initio data including the cohesive energy and lattice parameters of BaTiO3, BaO and rutile TiO2. This procedure provides internal consistency to the potential model for studying the energetics of the defect chemistry of BaTiO3. This is tested by examining trivalent rare-earth cation doping in BaTiO3 and considering all possible compensation (doping) schemes. Our simulations are in agreement with experiment and predict small rareearth cations to dope exclusively on the Ti site (so-called acceptor doping), see Figure 5.2.1(a); medium sized rareearth cations to dope on both the Ti and Ba sites and large rare-earth cation doping (eg La) exclusively on the Ba-site. For Ba-site substitution the simulations predict electron compensation (so called donor-doping) to be energetically unfavourable compared to the formation of Ti vacancies, i.e. Ba1-xRExTi1-x/4O3, see Figure 5.2.1(b). The apparent disagreement with electrical conduction of these ionic doped compositions is explained by subsequent Oxygen-loss which leads to the creation of Ti3+ cations, i.e. Ba1-xRExTi1-x/4O3- where = oxygen loss. Our simulations show that oxygen-loss is much more favourable in the ionic-doped system than pure BaTiO3 due to the unique local structure created around the defect site, see Figure 5.2.1(b). These findings resolve the so-called donor-doping anomaly in BaTiO3. There is no need to invoke a magic switch in doping mechanism and our results explain the source of semiconductivity in positive temperature coefficient of resistance (ptcr) BaTiO3 thermistors. We have also developed a potential model for the hexagonal polymorph of BaTiO3 (Dawson, Freeman, Ben, Harding, and Sinclair, J Applied Physics, 109 (2011) 084102). Again, excellent agreement with experimental results on the defect chemistry has been obtained. These studies show the power of combined work between experimentalists and modellers in the Ceramics and Composites Laboratory (CCL) to unravel the defect chemistry of complex but important electroceramics.
Figure 5.2.1. Lowest binding energy defect clusters for (a) B-site (acceptor doping) BaTi1-xRExO3-x/2 with the creation of oxygen vacancies and (b) A-site doping Ba1-xRExTi1-x/4O3 with the creation of B-site vacancies. Code: oxygen red, barium green, rare earth (RE3+) blue, titanium vacancy silver.
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where Cmax and Cmin are the capacitances at the maximum and minimum dc bias fields, low insertion losses at the operating frequency and range of dc biases, moderate relative permittivity (r < 500, depending on applications) to enable device impedance matching and a crack-free, smooth surface morphology.
that can potentially make things invisible when cloaked. This is in contrast to earlier work on metamaterials which focused on top-down (lithographic) methods. In an attempt to control the self-assembly of gold nanoparticles (GNP) into ordered arrays, the Goran Ungar and Xiangbing Zeng set out to place them into the center of a soft dendritic (tree-like) corona of controllable radial density profile (Kanie et al, J Am Chem Soc,134, 808, 2012). It has been shown previously that RDP is the key determinant of the type of packing adopted by spherical supramolecular dendrimers (Ungar et al, Science, 299, 1208, 2003). As shown in Figure 5.2.4b, each GNP is covered with a double-shell corona. In the inner shell are alkylthiols, some of which are end functionalized with COOH groups. The outer shell is formed by subsequent attachment of dendrons to those groups. By adjusting the number and type of dendrons, precise control of the RDP can be achieved. With the help of grazing incidence small angle X-ray scattering on oriented thin films, the formation of a highly ordered simple cubic lattice of self-assembled GNPs is established. This is the first simple cubic liquid crystal, thermo- or lyotropic, and is the first example of SC selfassembly in spherical NPs.
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Figure 5.2.2. Three-dimensional atomic force micrographs of the typical as-deposited film along with the post-annealing films of various compositions, illustrating their relative root mean square (r.m.s.) surface roughness.
In 2001, research at Sheffield by Ian Reaney demonstrated that Pb1.5Nb2O6.5 had ultra low dielectric loss (0.0002) and a high r (260) which suggested that compositions based on PbO-Nb2O5 were potential candidates for tunable dielectrics. In a collaborative study, Ian Reaney with Brian Hayden of Southampton University have developed a new generation of tunable dielectric thin films using a high throughput combinatorial approach. A range of PbO-Nb2O5 thin compositions, Figure 5.2.2, were deposited using a bespoke Physical Vapour Deposition technique on a single chip and the dielectric properties and tunabilities measured. The tunability peaked in the cubic pyrochlore phase at ~37%Pb, Figure 5.2.3. These compositions have the best combination of tunability (26%), low dielectric loss (0.0009) and high permittivity (420) discovered to date and have great potential for the fabrication of tunable electronic devices which can be used to modify the filtering frequency of circuits.
(c)
Figure 5.2.4. (a) 3D electron density map of a unit cell of the simple cubic phase of gold nanoparticles coated with an organic double shell of hydrocarbon chains (inner) and dendrimer (outer). Isoelectron surface delimits the spherical region of highest density, i.e. gold; organic matter fills the continuum. (b) Schematic of a part of a GNP surface with double corona. (c) (110) section through the unit cell.
Figure 5.2.3. Dielectric tunability versus dc bias field and composition measured at 10 kHz and -60 C.
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Furthermore, a 2D hexagonal superlattice is also found, made up of dense and sparse strings of nanoparticles, as shown by the electron density map in Figure 5.2.5a. For every two densely packed column there is a diluted one, containing half the number of NP (Figure 5.2.5b). Further studies utilizing quantum dots and magnetic NPs are now in progress.
Figures 5.2.7f,g hint that it is likely that a phase with the forbidden 12-fold rotational symmetry may be found soon in these systems. This would be the first example of a honeycomb quasicrystal. We note that quasicrystals have won D Schechtman the Nobel Prize for 2011.
Figure 5.2.5. The superlattice of hexagonally arranged dense and sparsely populated columns of gold nanoparticles coated with a paraffinic-dendritic double corona. (a) 2D electron density map. (b) 3D model.
Figure 5.2.6. (a) T-shaped molecules and (b,c)single-colour LC honeycombs. (d) X-shaped tetraphiles and (e,f) two-colour honeycombs.
Figure 5.2.7. (a,b) GISAXS patterns of a thin film of an X-shaped LC compound in the low- and high-temperature phases. (c,f) Corresponding electron density maps (purple high, red low), with schematic molecules partly superposed (red and green side-groups are carbosilane and perfluoroalkyl chains). (d,g) Representation of the honeycombs as tilings. (e,h) Tile types constituting the two phases and their number in a unit cell.
Axial-bundle phases - new modes of 2D, 3D, and helical columnar liquid crystals
Liquid crystals have transformed our daily lives, with the LCD industry currently being worth 300 B per year worldwide. The nematic phase, the most common LC phase used in displays, is formed by rod-like aromatic molecules bearing a flexible chain at one or both ends. In recent years a new type of LC molecules gained prominence, having flexible chains attached to the side rather than the ends. Such T-shaped molecules were
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found to form honeycomb structures e.g. as shown in Fig. 5.2.8(a,b). An increase in side chain volume, e.g. by attaching two instead of one side chain, honeycombs give way to layered structures (Figure 5.2.8(c)). In a recent study by the Goran Ungar and Xiangbing Zeng (Prehm, Liu, Zeng, Ungar and Tschierske, J Am Chem Soc, 133, 4906, 2011), the linear side-chains were replaced with branched swallow-tail ones (Figures 5.2.8d and 2a). Interestingly, such compounds exhibit the hexagonal columnar phase again. However, this time the structure is an inverted honeycomb, with the columns having a hard aromatic core and a soft aliphatic sheath. Unlike the classical discotic columnar phases, the new phase is made up of bundles of around 10 rod-like molecules in cross-section, with the rods aligned parallel to the column (Figure 5.2.8d). At high temperatures the rod-like molecules are distributed evenly along the column length. At lower temperatures they gradually group together forming periodic modulation of the columns, as clearly seen in the electron density map in Figure 5.2.9b (pink). In fact the structure changes from 2D periodic to 3D periodic, with the columns shifted by 1/3 of a molecule longitudinally relative to their neighbours. This is coupled with segregation of the two branches of the swallow tails one being an aliphatic hydrocarbon, the other fluorinated Teflon-like (RF in Figure 5.2.9a). The fluorinated regions are found to condense into right- and left-handed helices (Figure 5.2.9c). This work opens the way to creating novel nanopatterned organic semiconductors, and illustrates the fact that there is much more yet to be discovered in liquid crystals. There has been a flurry of discoveries of new and ever more complex structures with great promise of new nanomaterials for optics and molecular electronics, photovoltaic, LED, ceramics templating and other applications.
Figure 5.2.9. (a) The compounds. (b) 3D electron density map of the rhombohedral phase: blue-purple are regions of highest density (fluoroalkyl), pink are regions of low density, i.e. the aromatic bundles. (c) Schematic representation showing RF helices, green: RF regions, grey: aromatic.
Figure 5.2.8. Representative LC structures in T-shaped molecules with increasing volume of the side chains. Blue: hydrogen-bonding groups; grey: rod-like cores; green: laterally attached chains.
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Nuclear
Engineering
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The basic idea is of DBD involves the construction of large diameter holes (~0.5m) in diameter drilled to a depth of > 4 km into a suitable host rock (usually the granitic basement of the continental crust), with waste packages emplaced in the bottom 1 km of the hole. DBD takes advantage of a geological barrier that is an order of magnitude greater than that of a standard repository, utilizes the very low hydraulic conductivities found at these depths and benefits from the chemical and physical isolation (over millennia) of intrarock fluids from near surface mobile groundwaters resulting from density stratification (see Figure 5.3.2).
Figure 5.3.2. Diagram showing relationship between a deep geological borehole and local geology.
Using numerical computation (finite differences) we have solved the heat conduction equation and determined temporal and spatial dependence of the temperature for a wide variety of disposal scenarios. These calculations have established that disposal of higher burn-up spent fuel by DBD is feasible. Furthermore, they have enabled us to explore a wide area of the parameter space which includes: the number of fuel pins per container, age and type of the waste, and number of containers per borehole. Our results have enabled the construction of a phase field diagram (see figure 5.3.3) which can be used to determine the best support matrix to use down-hole either a special lead alloy or geothermal grout. The criteria upon which this is based is the maximum temperature reached on the surface of the waste containers, whether this exceeds the liquidus of the lead alloy and the time taken to reach this temperature. For spent MOX at 65 GWD/t shown in the figure, our results suggest that most combination of pin number and age are compatible with the preferred support matrix (lead alloy). Plots such as these are significant as they allow manipulation of the parameters to achieve a desired outcome. Our work on DBD is recognised as internationally leading and we are currently part of a consortium involving Sandia National Labs and MIT looking to develop a version of DBD for disposal of US spent fuel.
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Figure 5.3.3. Engineering field diagram for spent MOX at 65 GWD/t burnup.
Figure 5.3.4. The crystal structure of stoichiometric Pb5(VO4)3I prepared by microwave heating.
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damage healing in ion beam implanted perovskite, CaTiO3, which functions as an actinide host in the Synroc ceramic wasteform. Remarkably, this leads to a buried amorphous layer located between two recrystallised and partly damaged regions, as shown by electron diffraction. This work is clearly important in establishing and explaining the inherent radiation instability of titanate ceramics, with implications for materials selection in the context of actinide immobilisation (Reid et al, Nuclear Instruments and Methods in Physics Research B, 268, 1847-1852, (2010); Davoisne, Stennett, Hyatt, Peng, Jeynes and Lee, J Nuclear Materials, 415, 67-73 (2011); Gilbert, Davoisne, Stennett, Hyatt, Peng, Jeynes and Lee, J Nuclear Materials, 416, 221-224 (2011)).
Figure 5.3.7. pH of wet cement slurries of various cementing systems: CAP 1 and CAP2 have been developed at ISL.
Figure 5.3.6. Cross sectional TEM and electron diffraction analysis of buried amorphous zone in CaTiO3 .
Calcium aluminate phosphate cement for encapsulation of aluminium containing nuclear wastes
Paul Swift, Claire Utton and Hajime Kinoshita have been developing calcium aluminate phosphate cement (CAP) systems as an alternative cementing system for the encapsulation of aluminium-containing wastes from the UKs legacy radioactive waste, in collaboration with National Nuclear Laboratory. Through a series of investigations, a formulation envelope was developed to fulfill the processing requirements defined by industry. X-ray diffraction, thermogravimetric analysis, and scanning electron microscopy incorporating energy dispersive spectroscopy, were used to characterise the phase composition and microstructure of the CAP system, and the effect of a supplementary material (pulverised fuel ash) on the processing characteristics of various CAP systems i.e., setting time, fluidity, compressive strength, density and porosity. The potential for encapsulation of aluminium metal was assessed by encapsulating aluminium waste simulant in two CAP cementing systems and inspecting after 90 days curing and measuring the amount of hydrogen gas generated by corrosion of the encapsulated aluminium. The obtained results revealed that CAP systems was able to suppress the corrosion of aluminium specimens encapsulated and the hydrogen gas generation owing to the pH lower than conventional OPC systems, which demonstrated potential as an alternative cementing system for the encapsulation of aluminium metal.
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Figure 5.3.8. Hydrogen gas generation over 7 days from aluminium encapsulated in various cementing systems.
Materials@Sheffield 2012
phase formation, microstructure, porosity, compressive strength in order to optimize the wasteform formulation. The obtained results revealed that the particle size is the key factor to maximise the BaSO4 loading without a loss of integrity of wasteform in terms of microstructure and compressive strength. Both increase in water content and BaSO4 loading reduced the mechanical strength of the products causing the increase in porosity and suppression in formation of strong binding phases.
Figure 5.3.9. BSE image of OPC-BaSO4 system after 28 days of curing: granule 36 wt%, w/c = 0.53.
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Advanced
Structural Materials
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titanium to improve the tribological performance. Previously, a wide variety of surface treatments (anodising, thermal, plasma, ion- beam, electron-beam, laser, etc.) have been studied and explored in the scientific literature. Generally, such studies have involved attempts to incorporate (small) interstitial species (i.e. O, N, C, B) into the near-surface, to provide combinations of i) solution strengthening ii) precipitation hardening and iii) surface ceramic compound layer formation. Processes receiving most research attention are thermal oxidation gas nitriding and plasma nitriding. At the commencement of our research, the challenges still to be addressed were (in oxidation treatments) build-up of high growth stresses in the oxide compound layer with resulting stratification, brittleness and poor adhesion; and (in nitriding treatments) slow inward nitrogen diffusion leading to a need for long treatment times at high temperature. Our research has sought to overcome these drawbacks, whilst incorporating beneficial surface characteristics (such as an appropriate level of in-plane compressive residual stress to enhance fatigue performance). Processes investigated have included low voltage (LV) and high voltage (HV) triode (ie. hot-filament enhanced) plasma nitriding (TPN), low then high voltage (LHV) TPN at high temperature (HT)and low- then high-voltage triode plasma oxy-nitriding (TPON) where the nitriding treatment is preceded by an oxidation stage, to boost treatment depth. Our studies have shown that, as well as an appropriate diffusion case depth, thicker compound layers also contribute to the global compressive state and that an oxygenated diffusion case although improving sliding wear performance, reduces the overall compressive stress effect.
Figure 5.4.1. Neural network approach for identification of Plasma Electrolytic Oxidation process.
Figure 5.4.2. Surface stresses for Ti-6Al-4v samples using XRD sin2 method (Cassar, Avelar-Batista Wilson, Banfield, Housden, Fenech, Matthews and Leyland, Int J Fatigue, 33 (2011) 1313-1323).
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The overall effectiveness of nitriding treatments (in terms of the hardness-depth profile) is improved by applying a low voltage for most of the process time (to prevent nitride compound layer growth from blocking nitrogen diffusion) and following this with a short high voltage stage (to introduce a compound layer at the end of the process and take advantage of its superior hardness and wear characteristics).
The annealed substrate provides a benchmark against which the various triode plasma treatments can be measured (ie. its bulk microstructure is similar to them). It is clear that the combined low- and high-voltage (LHV) nitriding treatment gives a major improvement in fatigue life (more so than low-voltage (LV) nitriding alone). Despite a larger overall treatment depth the high-temperature (HT) TPN and oxy-nitriding (TPON) treatments are less effective. Triode plasma oxidation treatments provide more rapid diffusion case formation. However the oxide compound layer doesnt favour the application of a subsequent PVD coating, since interfacial adhesion is poor (as assessed by the critical load for debonding in a controlled scratch test) and the oxide layer is excessively brittle. However, a sequential oxidation + nitriding treatment can be used to remove the oxide layer and change the surface chemistry to improve the coating adhesion (and aid lubricant performance). The best results in this regard are obtained if the nitriding treatment duration is at least twice that of the prior oxidation treatment. The process technologies described above have been used to take weight out of bearings used in Airbus aircraft.
Figigure 5.4.3. Hardness depth profile of Ti-6Al-4V sample diffusion treated for 4 hours (Cassar, Banfield, Avelar-Batista Wilson, Housden, Matthews and Leyland, Surf Coat Technol, 206 (2012) 2645-2654).
Figure 5.4.4. Log-Log (Basquin) plots of fatigue performance of (a) diffusion treated Ti-6Al-4V, and (b) diffusion treated and TiN coated Ti-6Al-4V (Cassar, Avelar-Batista Wilson, Banfield, Housden, Fenech, Matthews and Leyland, Int J Fatigue, 33 (2011) 1313-1323).
Low-to-moderate temperature (ie. 700C) plasmaassisted diffusion treatments provide a significant improvement in fatigue behaviour. PVD TiN alone has a tendency to shorten fatigue life, but duplex TPN/TiN remains superior to the untreated (annealed) substrate material.
Figure 5.4.5. Critical loads for failure of 2.8 m TiN coating deposited on LV-TPO and LBV-TPON treated Ti-6Al-4V (Cassar, Banfield, Avelar-Batista Wilson, Housden, Matthews and Leyland, Surf Coat Technol, 206 (2011) 395-404).
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osteolysis and joint rejection. Three types of wear debris were seen from the worn surface, namely: granular wear debris, nanocrystalline wear debris and needle shaped wear debris. Wear debris was shown to arise from grain pull-out, severe plastic deformation at the surface and from a tribochemical reaction between the alumina and the calf bovine serum. The observations allow a mechanistic model of the damage accumulations leading to wear and ultimately failure in ceramic on ceramic hip joints (Zeng, Inkson, Stewart and Rainforth Acta Materialia, 60 20612072 (2012)).
the laboratory using the replication process, where liquid aluminium is forces between salt grains using gas pressure, with the salt grains being dissolved to leave behind a foam. Different coating treatments produce different amounts of oxide, Figure 5.4.8, and have also been found to alter the structure and composition of the coating. The effect on mechanical properties has been assessed, and is found to be significant, Figure 5.4.9 demonstrates the results looking at the effect of frequency in the process, and it is seen that increases in the yield strength of up to a factor of 8 or so have been obtained. Of course, there is an increase in weight, but as shown in Figure 5.4.10, significant improvements in the specific strength are also possible. Related research is currently examining how great an effect can be achieved through optimisation of the PEO process conditions for foams, and how to minimise the process time and costs. Also under investigation is how the composition and properties of the coatings vary with thickness, to understand why a thicker coating does not necessarily mean a better performance.
Figure 5.4.6. (a) AFM image shows small (5-30 nm) height differences between grains on the worn surface; (b) Bright field TEM micrograph of a back-thinned samples of the worn surface showing an intergranular crack that runs between grains with a high dislocation density and low dislocation density.
Figure 5.4.8. Alminium replicated foams with (left) no coating, and PEO processed using frequencies of 50, 250, 1250, and 6250 Hz respectively.
Figure 5.4.7. Bright field TEM image of a FIB cross-section of the high wear stripe region showing intergranular cracking in the outer grains and an associated high dislocation density. The dark surface layer is a gold film used to label the original surface.
Eight fold increase in compressive strength of aluminium foam by use of a plasma electrolytic oxidation coating
In the porous metals research group, work as been carried out looking at the effect of applying a Plasma Electrolytic Oxidation (PEO) coating to open celled aluminium foams. These materials already possess very good strength to weight ratios, and can be used as sandwich panel cores in lightweight structures, but this research seeks to boost these capabilities even further. It is well known that in foams deformation occurs by bending of the struts, and so if a stiff, strong phase can be introduced at the strut surface it should be a very efficient way of reinforcing it. To attempt to achieve this PEO coatings have been applied to the foams by Taha Abdulla, Alexi Yerokhin and Russell Goodall; this is an electrochemical process that applies a large alternative voltage to a sample placed in an electrochemical bath. The microdischarge arcing events that occur result in the surface being transformed into oxides, and strong, well adhered coatings are regularly achieved on flat components. The foams are made in
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Figure 5.4.9. Stress-strain curves for foams with different PEO coatings tested in compression.
Figure 5.4.10. Log-log plot of yield stress against density for coated foam samples, with lines of equal specific strength marked. Even with the increase in weight, the increase in strength leads to overall favourable properties.
Materials@Sheffield 2012
to the same total strain, multiple strain path reversal significantly retarded the DIFT mechanism. A very plausible explanation of this phenomenon can be drawn by comparison with the observed strain path effect on austenite grain subdivisions using the Fe-30wt%Ni model alloy in early study (Sun, Muszka, Wynne and Palmiere, Scripta Materialia, 64 280-283 (2011)). As the 2-pass test produced a large amount of HABs within the austenite grains, these boundaries could act as ferrite nucleation sites for DIFT. On the contrary, after the 8-pass test a very limited amount of HABs was produced by the texture mechanism. Without these intragranular nucleation sites for the ferrite, the onset of the DIFT process was significantly retarded. Further examination on the misorientation distribution of the dislocation boundaries (shown in Figure 5.4.13) reveals the different phase transformation mechanisms taking place after the 8-pass and 2-pass tests. It can be seen that the density of HABs in the 2-pass deformed microstructure are much higher than that in the 8-pass deformed one. This is believed to come from the reconstructive phase transformation during DIFT process. DIFT is believed to be a reconstructive phase transformation involves diffusional nucleation and growth (Bhadeshia, Materials Science and Technology, 15 22-29(1999)) of the ferrite, therefore producing HABs with higher disorientation. Meanwhile, the displacvie transformation of the martensitic transformation experienced by the 8-pass deformed test does not involve any diffusion producing much lower levels of HABs.
Figure 5.4.11. SEM Microstructures of the X-70 steel showing significantly different extents of DIFT ferrite due to the effect of strain path reversal.
Figure 5.4.12. EBSD Microstructures of the X-70 steel showing significantly different extents of DIFT ferrite due to the effect of strain path reversal.
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Figure 5.4.14. Inverse pole figure EBSD images of alpha grains (a,c) and reconstructed beta grains (b,d) for forward + forward and forward + reverse deformation.
Figure 5.4.13. The disorientation angle distribution of the HABs after 2-pass and 8-pass test as absolute frequencies per unit area (square mm).
Figure 5.4.15. Examples of basketweave (left) and spheroidised (right) microstructure in Ti-6Al-4V after deformation at 815 oC followed by 4 hours annealing. The graph shows the fraction of spheroidised grains as a function of annealing time.
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case formation and subsequent surface embrittlement after prolonged exposure. The implications are that the benefits of the peening process which is designed to enhance surface mechanical properties, in particular fatigue resistance, could in fact be negated during thermal exposure, due to the increased propensity for oxygen enrichment and associated microcracking. Secondly, the fact that silicon comes out of solid solution within the highly deformed twinned region (Fig 5.4.16(b)), thus draining the primary alpha matrix of creep-enhancing silicon atoms, implies that there is a localized loss of creep strength near the surface. The effect of workpiece temperatures; 77 K, 298 K and 553 K on the on subsurface microstructure and mechanical properties of CP-Ti is illustrated in figure 5.4.18. The corresponding microhardness data as a function of temperature are presented in figure 5.4.18d). At all temperatures investigated, peening leads to localised subsurface hardening, with the magnitude of hardening considerably greater than twice the standard deviation of the bulk hardness measurements. The degree of subsurface hardening increases commensurately with the temperature of the workpiece during shot peening, with both the depth of hardening and peak hardness being the least for the CP-Ti coupon that was shot peened at cryogenic temperatures. The increase in subsurface hardening with higher peening temperatures can be explained by the interaction of dislocations with twin boundaries. There is strong evidence of strain hardening of CP-Ti due to deformation twinning, a result of both a reduction in effective slip length (HallPetch effect) and the conversion of glissile dislocations within the twinned volume into sessile dislocations as a result of the twinning shear transformation (i.e. the Basinski mechanism).
Figure 5.4.17. Oxygen content (normalized to wt.%) of as-machined and shot-peened (1200% coverage) Ti-834 exposed to air for 1800 h at 973 K. Data collected using secondary ion mass spectrometry (SIMS).
Figure 5.4.18. The effect of workpiece temperature on the microstructural response and subsurface mechanical properties of CP-Ti to shot peening. Cross-section polarized light micrographs of CP-Ti shot peened at 77, 298and 553 K are shown in (a)(c), respectively (the direction of the shot stream is approximately vertical). Microhardness data and twin lineal fraction measurements are presented in (d).
Figure 5.4.16. Backscatter electron micrographs of shot-peened Ti-834: (a) before thermal exposure, and (b) 973 K, 1800 h, showing the silicide precipitation along twin boundaries.
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5.5
Multiscale
Materials Modelling
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Figure 5.5.2. Energy as a function of domain wall position for two voltage configurations and resulting minimum energy magnetic structures.
Electric voltages applied to local contacts induce a stress distribution in the piezoelectric layer, which couples to the magnetostrictive wire. Our calculations showed how the stress gradients create energy minima and maxima for the position of domain walls that can be used to move and position domain walls (Figure 5.4.2). Domain walls can be passed between stable locations with very little energy (100s keV) on a nanosecond timescale. Alternate voltage configurations can be used to create a bistable RAM type operation (Figure 5.4.2) or sequential sequences can be used to propagate streams of domain walls for shift register type operation. If successful, this development promises to overcome the existing challenges with magnetic nanowire technology of high power consumption and unreliable switching. We have also developed an analytical description of stresscontrol of domain walls in nanowires (Bryan, Dean and Allwood, Phys Rev B, in press). This analysis has shown that the axial strain gradients are responsible for domain wall motion in magnetostrictive nanowires.
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Figure 5.5.3. (a) Simple voronoi model of a heterogeneous ceramic material with grain boundary. (b) and (c) show the calculated local electric field in the sample for high and low frequencies respectively corresponding to the excitement of the grain core and grain boundaries. (Red indicating a high region of electric field). (d) The simulated spectroscopic plot of Z* resulting from the differing time constants of the grain cores and grain boundaries.
Figure 5.5.5. Binding of ovocleidin-17 to a planar surface (left), acute steps (centre) and obtuse steps (right). Water is not shown for clarity.
Topological connectivity analysis of accumulated radiation damage from multiple molecular dynamics recoil cascades
At present, it seems likely that much of the stored plutonium in the UK is destined for reuse as MOx fuel, but some will be unsuitable for this purpose and require immobilisation. The current waste management option for these arisings is a ceramic phase material based on the SYNROC C concept. Pyrochlore structures such as Gd2Ti O and Gd2Zr2O7 are of interest in radiation 2 7 damage research. The phases have been shown to exist as stable metamict materials over geological timescales. Amorphisation occurs because many atoms are displaced in successive collision cascades. Simulations by Henry Foxhall, John Harding and Karl Travis of radiation damage are often analysed by identification of vacancy, interstitial and anti-site defects as a measure of damage. Topological connectivity analysis takes into account only connectivity, and so is suitable for crystalline, disordered or distorted material. Comparing Gd2Ti2O7 and Gd2Zr2O7 (see Figure 5.5.4) the former amorphises readily while the latter does not, forming a defective fluorite phase upon irradiation. We have used topological analysis to give a robust method of analysing for point defects. Zr-pyrochlore systems exhibited defect fluorite motifs upon radiation damage due to randomisation of oxygen ions over the anion sub-lattice. Ti-pyrochlores do not show this behaviour, with localised volumes of damage showing increased disorder, and primitive rings up to order-14. Both materials retain crystalline-type topological motifs.
Ovocleidin-17 has been identified as a protein involved in the formation of eggshells, although the role and function it performs is still not clear. Colin Freeman, John Harding and David Quigley and Mark Rodger (University of Warwick) have performed classical molecular dynamics simulations for the adsorption of the whole protein onto the {10.4} surface and also onto the acute and obtuse steps of calcite in several different configurations. The simulation show that binding is a competition between the protein and the strongly bound surface water. The protein is fairly rigid and the arginine residues are the most important binders to the calcite surface. The protein can bind to all three kinds of surface, but significant differences in the binding energy for the three surfaces were observed. This is likely to be due to the differences in water structure observed between the surfaces. However, this protein does not show the same degree of selectivity as found for other molecules such as the polysaccharides, which suggests that it is less likely to be involved in the control of crystal morphology. Previous simulations demonstrated that this protein can alter the energetic stability of the different phases of calcium carbonate, removing the barrier between amorphous calcium carbonate and the crystalline calcite phase. This implies that the protein may facilitate the crystallisation of calcium carbonate. These results do not suggest that it could function as a step binder to prevent the growing out of a face. This suggests that any function in crystallisation could be earlier in the growth process i.e. before large calcite planes are formed.
Figure 5.5.4. Snapshots of the final configurations of the simulation, showing all atoms that have moved more than 1.0 from their initial positions (a) Gd2Ti2O7 (b) Gd2Zr2O7 .
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5.6
Nanomaterials
and Nanoengineering
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Figure 5.6.2. Real-time imaging of the compression of an aluminium single crystal to form new grains.
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The observations have been greatly facilitated by an exceptional electron-beam ablation of carbon support film, which allows background and noise-free observation of finest contrast details. The wide-ranging and fast carbon ablation is dependent on the materials loaded on the film and therefore a chemical rather than a straight beam drilling effect. In collaboration with the theory group of D Sayle at Cranfield University, the experimental findings have been explained using molecular modelling and derivation of a charge-quenching model for the {100} surface caps involving linear Ce-O-Ce-O chains. Furthermore atomic hopping sequences triggered by high temperature during the molecular dynamics simulations have been compared to the irradiation-induced experimental hopping processes to explore similarities and differences.
Figure 5.6.3. Fabrication and electrical characterisation of 55nm diameter CoPt/Pt multilayer magnetic nanowires.
Figure 5.6.4. Ce ion hopping on CeO2 (100) (Mbus, Saghi, Sayle, Bhatta, Stringfellow and Sayle, Advanced Functional Materials, 21(11) 1970 (2011)).
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In a two-part study, at first the generation of nanostructures by materials removal using focused electron beams is described starting from either a homogeneous and freestanding nickel thin film, or starting from a nickel nanotip (Gnanavel, Yajid, Saghi, Peng, Inkson, Gibbs and Mbus, Applied Physics A: Materials Science and Processing, 102(1) 205-211 (2011)). Results achieved comprise arrays of nanoholes, nanobridges, and 3D sharpening of nickel tips down to sub-5nm radius. To exploit the full capability of modern TEM/STEM instruments, a variety of beam shapes (focused, astigmatic, field emission and thermionic guns) are applied for the first time, combining drilling with cutting and thinning actions, equivalent to an electron scalpel. In combination with tomographic large angle specimen tilt systems, it is shown how innovative sculpting in 3D can be achieved step-wise by ablation in different viewing directions. In the second part (Gnanavel, Kumar and Mbus, J Nanoscience and Nanotechnology, 11(2) 1019-1024 (2011)) pure Ni is replaced by NiF2 as a precursor material and the electron beam is used as a tool to preferentially ablated fluorine, leaving pure Ni behind. The nanoparticulate structures achieved are synthesised by nucleation and growth and therefore classify as bottom-up nanofabrication, complementing the earlier sculpting approach. In detail, the electron beam converts the original salt crystal into an intermediate nanoporous/ nanocomposite (metal-salt) material, before further irradiation leads to rather sudden collapse of the pores and growth of dense spherical metal particles (beads) of 10-600 nm size, under the influence of minimising surface tension.
Research Themes
for tomography and in-situ TEM. For computed axial tomography (CAT) it is important that projection images of the 3D object are available for every viewing direction. One problem of traditional goniometers is a limitation in tilt range to far below 180, which causes distortions in tomographic reconstructions. We present acquisition series of a W-tip test object exceeding the important 180 limit, and also present an innovative magnetic sensor feedback mechanism as measure of tilt angle.
Figure 5.6.6. [4]: W tip (surface rendering left, and central cross section right) reconstructed from piezo-goniometric full tilt series free of missing wedge artefacts.
Our goniometer allows for two specimens to be placed into different mounts, one piezo-moveable and one fixed position, with both together movable by the TEM goniometer. This unique setup allowed us for the first time in the history of TEM to rotate one specimen against a second specimen (Differential Tilt) while at the same time translating one against the other. This is important for experiments with overlapping specimens, holographic and magnetic imaging modes, and especially for crystallography-specific contacting experiments (mechanical or electrical).
Figure 5.6.5. Ni-fluoride salt to Ni-metal bead conversion under electron irradiation [3].
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6 7 8 9 10 11 12
Publications, 2011 PhD Awards, 2011 Current Research Sponsors Grants and Contracts Awarded 2011 Personal Highlights 2011 Retired Academic Staff Profiles Appendix: Annual Report 2012 (separate report)
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Publications
6 Publications 2011
1. T Abdulla, A Yerokhin and R Goodall Effect of Plasma Electrolytic Oxidation coating on the specific strength of open-cell aluminium foams, Mate Des 32(7) (2011) 3742-3749. M M Z Ahmed, B P Wynne, W M Rainforth and P L Threadgill Through-thickness crystallographic texture of stationary shoulder friction stir welded aluminium, Scripta Mat, 1(64) (2011) 45-48. M N Ali and I U Rehman An Auxetic structure configured as oesophageal stent with potential to be used for palliative treatment of oesophageal cancer; development and in vitro mechanical analysis, J Mater Sci-Mat in Medicine, 22(11) (2011) 2573-2581. K Anantheshwara, A J Lockwood, R K Mishra, B J Inkson and M S Bobji Dynamical Evolution of Wear Particles in Nanocontacts, Tribology Letters (2011) 1-7. G S E Antipas, C Lekakou and P Tsakiropoulos Microstructural characterisation of Al - Hf and Al Li - Hf spray deposits, Mater Charact, 62(4) (2011) 402-408. M Ascenzi and G C Reilly Bone tissue: Hierarchical simulations for clinical applications, J Biomech, 44(2) (2011) 211/212. I Atkin, R H Elder, G H Priestman, D C Sinclair and R W K Allen High temperature oxygen separation for the sulphur family of thermochemical cycles Part I: Membrane selection and flux testing, Intl J of Hydrogen Energy, 36(17) (2011) 10614-10625. 13. L Ben and D C Sinclair Anomalous Curie temperature behavior of A-site Gd-doped BaTiO3 ceramics: The influence of strain, Appl Phys Lett, 98(9) (2011) 092907. 14. I Betancourt, G Hrkac and T Schrefl Magnetic domain structure and magnetization reversal in amorphous microwires with circular anisotropy: A micromagnetic approach, J Appl Phys, 109(1) (2011). 15. I Betancourt, G Hrkac and T Schrefl Micromagnetic study of magnetic domain structure and magnetization reversal in amorphous wires with circular anisotropy, J Magn Magn Mats, 323(9) (2011) 1134-1139. 16. S Bhakta, K H Gillingham, M Mirsaneh, C A Miller, I M Reaney, I M Brook, R van Noort R and P V Hatton In vitro biocompatibility of modified potassium fluorrichterite and potassium fluorrichterite-fluorapatite glass-ceramics, J Mat Sci-Mats Med, 22(9) (2011) 2065-2070. 17. R Bhattacharya and B P Wynne Hot working and crystallographic texture analysis of magnesium AZ alloys, Mat Sci Technol, 27(2) (2011) 461-477.
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18. J J Biendicho and A R West Thermally-induced cation disorder in LiFePO4, Solid State Ionics 203(1) (2011) 33-36. 19. P A Bingham, A J Connelly, N J Cassingham and N C Hyatt Oxidation state and local environment of selenium in alkali borosilicate glasses for radioactive waste immobilisation, J Non-Cryst Solids, 357(14) (2011) 2726-2734. 20. P A Bingham, A J Connelly, N C Hyatt and R J Hand Corrosion of glass contact refractories for the vitrification of radioactive wastes: A review, Intl Mater Rev, 56(4) (2011) 226-242. 21. A J Bullock, A Mangera, S MacNeil and C R Chapple Development of aseptically produced scaffolds for substitution urethroplasty, British Journal of Surgery, 98 (2011) 54. 22. K T Butler, P E Vullum, A M Muggerud, E Cabrera and J H Harding Structural and electronic properties of silver/silicon interfaces and implications for solar cell performance, Phys Rev B (Condensed Matter and Materials Physics) 83(23) (2011) 235307. 23. G Cassar, S Banfield, J C A B Wilson, J Housden, A Matthews and A Leyland Tribological properties of duplex plasma oxidised, nitrided and PVD coated Ti-6Al-4V, Surf Coat Technol, 206(10) (2011) 12771287. 24. G Cassar, J C A B Wilson, S Banfield, J Housden, M Fenech, A Matthews and A Leyland Evaluating the effects of plasma diffusion processing and duplex diffusion/PVD-coating on the fatigue performance of Ti-6Al-4V alloy, Intl J of Fatigue, 33(9) (2011) 1313-1323.
8. K M Au, Z Lu, S J Matcher and S P Armes Polypyrrole Nanoparticles: A Potential Optical Coherence Tomography Contrast Agent For Cancer Imaging, Adv Mats, 23(48) (2011) 57925795. 9. M Audronis, S J Hinder, P Mack, V BellidoGonzalez, D Bussey, A Matthews and M A Baker A comparison of reactive plasma pre-treatments on PET substrates by Cu and Ti pulsed-DC and HIPIMS discharges, Thin Solid Films, 520(5) (2011) 1564-1570.
10. S Banfield, J C Avelar-Batista Wilson, G Cassar, A Leyland, A Matthews and J Housden An investigation into the effect of Triode Plasma Oxidation (TPO) on the tribological properties of Ti6Al4V, Surf Coat Technol, 206(7) (2011) 19551962. 11. J H Bell and J W Haycock Next Generation Nerve Guides: Materials, Fabrication, Growth Factors, and Cell Delivery, Tissue Eng Part B: Reviews, 8th December 2011.
12. H Beltran, M Prades, N Maso, E Cordoncillo and A R West Enhanced Conductivity and Nonlinear Voltage-Current Characteristics of Nonstoichiometric BaTiO3 Ceramics, J Am Ceram Soc, 94(9) (2011) 2951-2962.
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25. A A Chaudhry, H Yan, K Gong, F Inam, G Viola, M J Reece, J B M Goodall, I Ur Rehman, F K McNeil-Watson, J C W Corbett, J C Knowles and J A Darr High-strength nanograined and translucent hydroxyapatite monoliths via continuous hydrothermal synthesis and optimized spark plasma sintering, Acta Biomat, 7(2) (2011) 791-799. 26. M A Chavda, M I Ojovan and S Zhang Immobilization of Nuclear Waste Graphite Using the SiC Synthesis Route, Proc WM11 Conference, 27th February 3rd March 2011, Phoenix, Arizona, WM 11484, 12 p (2011). 27. G Chen, J Di, M Li, I M Reaney, Y Lei, H Xu, C Zhou, M Jiang, X Liu Synthesis, microstructure and microwave dielectric properties of Ca4-xMgxLa2Ti5O17 ceramics, J Mat Sci: Mats Elects (2011).
36. A J Connelly, K P Travis, R J Hand, N C Hyatt and E Maddrell Composition-Structure Relationships in Simplified Nuclear Waste Glasses: 2. The Effect of ZrO2 Additions, J Am Ceram Soc, 94(1) (2011) 137-144. 37. J Corrochano, J C Walker, M Lieblich, J Ibanez and W M Rainforth Dry sliding wear behaviour of powder metallurgy Al-Mg-Si alloy-MoSi2 composites and the relationship with the microstructure, Wear, 270(9-10) (2011) 658-665. 38. J Corteen, W M Rainforth and I Todd A mathematical approach to transformation toughening in bulk metallic glasses, Scripta Mat, 65(6) (2011) 524-527. 39. A Covill, N C Hyatt, J Hill and N C Collier Development of magnesium phosphate cements for encapsulation of radioactive waste, Adv Appl Ceram, 110(3) (2011) 151-156. 40. P S Davies, B P Wynne, W M Rainforth, M J Thomas and P L Threadgill Development of Microstructure and Crystallographic Texture during Stationary Shoulder Friction Stir Welding of Ti-6Al4V, Metall Mater Trans A, 42A(8) (2011) 2278-2289. 41. C Davoisne, M C Stennett, N C Hyatt, N Peng, C Jeynes and Lee WE Krypton irradiation damage in Nd-doped zirconolite and perovskite, J Nuclear Mats, (2011) 67-73. 42. J A Dawson, C L Freeman, L Ben, J H Harding and D C Sinclair An atomistic study into the defect chemistry of hexagonal barium titanate, J Appl Phys, 109(8) (2011) 084102. 43. J Dean, M T Bryan, N A Morley, G Hrkac, A Javed, M R J Gibbs and D A Allwood Numerical study of the effective magnetocrystalline anisotropy and magnetostriction in polycrystalline FeGa films, J Appl Phys, 110(4) (2011) 043902. 44. J Dean, A Kohn, A Kovacs, A Zeltser, M J Carey, G Hrkac, D A Allwood and T Schrefl The formation mechanism of 360 degrees domain walls in exchange-biased polycrystalline ferromagnetic films, J Appl Phys, 110(7) (2011) 073901. 45. R M Delaine-Smith and G C Reilly The effects of mechanical loading on mesenchymal stem cell differentiation and matrix production, Vitam Horm: Adv Res Appl, 87 (2011) 417-480. 46. F Diologent, R Goodall and A Mortensen Activation volume in microcellular aluminium: Size effects in thermally activated plastic flow, Acta Mat, 59(18) (2011) 6869-6879. 47. M Elawayeb, Y Peng and B J Inkson Nanostructure and chemical characterisation of individual NiFe/Pt multilayer nanowires, J Nanosci Nanotech, 11(9) (2011) 7777-7782.
Publications 6
28. H Chen, C L Freeman and J H Harding Charge disproportionation and Jahn-Teller distortion in LiNiO2 and NaNiO2: A density functional theory study, Phys Rev B (Condensed Matter Mat Phys), 84(8) (2011) 085108. 29. X Cheng, F Liu, X Zeng, G Ungar, J Kain, S Diele, M Prehm and C Tschierske Influence of flexible spacers on liquid-crystalline self-assembly of T-shaped bolaamphiphiles, J Am Chem Soc, 133(2) (2011) 7872-7881. 30. F Claeyssens, K E Ranaghan, N Lawan, S J Macrae, F R Manby, J N Harvey and A J Mulholland Analysis of chorismate mutase catalysis by QM/MM modelling of enzyme-catalysed and uncatalysed reactions, Organic and Biomol Chem, 9(5) (2011) 1578-1590. 31. H E Colley, V Hearnden, A V Jones, P H Weinreb, S M Violette, S Macneil, M H Thornhill and C Murdoch Development of tissue-engineered models of oral dysplasia and early invasive oral squamous cell carcinoma, British Journal of Cancer, 105(10) (2011) 1582-1592. 32. A J Connelly, R J Hand, P A Bingham and N C Hyatt Mechanical properties of nuclear waste glasses, J Nuclear Mats, 408(2) (2011) 188-193. 33. A J Connelly, N C Hyatt, K P Travis, R J Hand and E R Maddrell Predicting the preference for charge compensation in silicate glasses, Phys Chem Glasses B, 52(2) (2011) 64-67. 34. A J Connelly, N C Hyatt, K P Travis, R J Hand, E R Maddrell and R J Short The structural role of Zr within alkali borosilicate glasses for nuclear waste immobilisation J Non-Cryst Solids, 357(7) (2011) 1647-1656. 35. A J Connelly, K P Travis, R J Hand, N C Hyatt and E Maddrell Composition-Structure Relationships in Simplified Nuclear Waste Glasses: 1. Mixed Alkali Borosilicate Glasses, J Am Ceram Soc, 94(1) (2011) 151-159.
48. T El-Sayed and R J Hand Fractographic analysis of epoxy coated glass, Ceram Intl (2011) available online.
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Publications
49. T El-Sayed and R J Hand Modelling the strengthening of glass using epoxy based coatings, J Europ Ceram Soc, 31(15) (2011) 2783-2791. 50. N J Emerson, M J Carr, G C Reilly and A C Offiah Geometrically accurate 3D FE models from medical scans created to analyse the causes of sports injuries, Procedia Eng, 13 (2011) 422-427. 51. PC Eves, M Baran, NA Bullet, L Way, D Haddow and S MacNeil Establishing a transport protocol for the delivery of melanocytes and keratinocytes for the treatment of vitiligo, Tissue Engineering (2011) Available online. 52. M C Ferrarelli, D Nuzhnyy, S Kamba, D C Sinclair and A R West Microwave dielectric properties of Na1/2Bi1/2Cu2.82Mn0.18Ti4O12 ceramics, IOP Conference Series: Mater Sci Eng, 18 (2011) 092004. 53. M C Ferrarelli, C C Tan and D C Sinclair Ferroelectric, electrical, and structural properties of Dy and Sc co-doped BaTiO3, J Mater Chem, 21(17) (2011) 6292-6299. 54. A Feteira, D Iddles, T Price, D Muir and I M Reaney High-permittivity and low-loss microwave dielectric ceramics based on (x)RE(Zn1/2Ti1/2)O3-(1-x) CaTiO3 (RE=La and Nd), J Am Ceram Soc, 94(3) (2011) 817-821. 55. P Fiorenza, V Raineri, M C Ferrarelli, D C Sinclair and R Lo Nigro Nanoscale electrical probing of heterogeneous ceramics: The case of giant permittivity calcium copper titanate (CaCu3Ti4O 12), Nanoscale, 3(3) (2011) 1171-1175. 56. C Fiorica, R A Senior, G Pitarresi, F S Palumbo, G Giammona, P Deshpande and S MacNeil Biocompatible hydrogels based on hyaluronic acid cross-linked with a polyaspartamide derivative as delivery systems for epithelial limbal cells, Intl J Pharmaceutics, 414(1-2) (2011) 104-111. 57. C L Freeman, J A Dawson, H R Chen, J H Harding, L B Ben and D C Sinclair A new potential model for barium titanate and its implications for rareearth doping, J Mater Chem, 21(13) (2011) 48614868. 58. C L Freeman, J H Harding, D Quigley and P M Rodger Simulations of ovocleidin-17 binding to calcite surfaces and its implications for eggshell formation, J Phys Chem Part C: Nanomaterials and Interfaces, 115(16) (2011) 8175-8183. 59. N F Garza-Montes-de-Oca, R Cols and W M Rainforth On the damage of a work roll grade high speed steel by thermal cycling, Engineering Failure Analysis, 18(6) (2011) 1576-1583. 60. N F Garza-Montes-de-Oca, R Cols and W M Rainforth Failure Modes of the Oxide Scale Formed on a Work Roll Grade High Speed Steel, Oxidation of Metals: an international journal of the science of gas-solid reactions, 76(3-4) (2011) 149-160.
61. N F Garza-Montes-de-Oca, R Cols and W M Rainforth High temperature oxidation of a work roll grade high speed steel, Oxidation of Metals: an international journal of the science of gas-solid reactions, 76(5-6) (2011) 451-468. 62. N F Garza-Montes-de-Oca, R Cols and W M Rainforth On the damage of a work roll grade high speed steel by thermal cycling, Engineering Failure Analysis, 18(6) (2011) 1576-1583. 63. A T Giddings, M C Stennett, D P Reid, E E McCabe, C Greaves and N C Hyatt Synthesis, structure and characterisation of the n=4 Aurivillius phase Bi5Ti3CrO15, J Solid State Chem, 184(2) (2011) 252-263. 64. M Gilbert, C Davoisne, M C Stennett, N C Hyatt, N Peng, C Jeynes and W E Lee Krypton and helium irradiation damage in yttria-stabilised zirconia, Materials Research Society Symp Proc, 1298 (2011) 197-202. 65. M Gilbert and J H Harding Energetics of Ce and Pu incorporation into zirconolite waste-forms, Phys Chem Chem Phys, 13(28) (2011) 13021-13025. 66. A A Gill and F Claeyssens 3D structuring of biocompatible and biodegradable polymers via stereolithography, Methods in Molecular Biology, 695 (2011) 309-321. 67. T Gnanavel, S Kumar and G Mbus In-situ fabrication of three dimensional nickel nanobeads by electron beam induced transformation, J Nanosci Nanotech, 11(2) (2011) 1019-1024. 68. T Gnanavel and G Mbus Tomographic nanofabrication with electron beams, Proc Microsc Conf. (MC2011), DGE pub,W Jger et al, eds, Kiel, Germany, IM3-P143 (2011). 69. T Gnanavel, M A M Yajid, Z Saghi, Y Peng, B J Inkson, M R J Gibbs and G Mbus Electron beam nanofabrication of ferromagnetic nanostructures in TEM, Appl Phys A: Mat Sci Proc, 102(1) (2011) 205-211. 70. J R A Godinho, S Piazolo, M C Stennett and N C Hyatt Sintering of CaF2 pellets as nuclear fuel analog for surface stability experiments, J Nucl Mats, 419(1-3) (2011) 46-51. 71. V Goian, S Kamba, S Greicius, D Nuzhnyy, S Karimi and I M Reaney Terahertz and infrared studies of antiferroelectric phase transition in multiferroic Bi0.85Nd0.15FeO3, J Appl Phys, 110(7) (2011) 074112. 72. S Goulart-Santos, R D Mancosu, C Godoy, A Matthews and A Leyland Influence of surface hardening depth on the cavitation erosion resistance of a low alloy steel, J ASTM Intl, 8(9) (2011) ISSN: 1546-962X pp12. 73. I Grammenos and P Tsakiropoulos Study of the role of Hf, Mo and W additions in the microstructure of Nb-20Si silicide based alloys, Intermetallics, 19(10) (2011) 1612-1621.
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74. N H Green, Q Huang, B M Corfe, J P Bury and S MacNeil NF-B is activated in oesophageal fibroblasts in response to a paracrine signal generated by acid-exposed primary oesophageal squamous cells, Intl J Expl Pathology: mechanisms and models of disease, 92(5) (2011) 345-356. 75. W Guan, A Lockwood, B J Inkson and G Mbus A piezoelectric goniometer inside a transmission electron microscope goniometer, Microscopy and Microanalysis, 17(5) (2011) 827-833. 76. W Guan and G Mbus Differential tilt between two specimen parts by an all piezo-electric miniaturised goniometer, Proc Microsc Conf (MC2011), DGE publ, W Jger et al, eds, Kiel, Germany, IM6-P180 (2011). 77. J N Hart, N L Allan and F Claeyssens Ternary silicon germanium nitrides: A class of tunable band gap materials, Phys Rev B (Condensed Matter and Materials Physics), 84 (2011) 245209. 78. J W Haycock 3D cell culture: a review of current approaches and techniques, Methods in Molecular Biology, 695 (2011) 1-15. 79. T J Hayward, A D West, K J Weatherill, T Schrefl, I G Hughes and D A Allwood Nanomagnetic engineering of the properties of domain wall atom traps, J Appl Phys, 110 (2011) 123918. 80. V Hearnden, S MacNeil and G Battaglia Tracking nanoparticles in three-dimensional tissueengineered models using confocal laser scanning microscopy, Methods in Molecular Biology, 695 (2011) 41-51. 81. G L Hill, E Bailey, M C Stennett, N C Hyatt, E M Maddrell, P F McMillan and J A Hriljac High-pressure and-temperature ion exchange of aluminosilicate and gallosilicate natrolite, J Am Chem Soc, 133(35) (2011) 13883-13885. 82. J Hlinka, J Pokorny, S Karimi and I M Reaney Angular dispersion of oblique phonon modes in BiFeO3 from micro-Raman scattering, Phys Rev B (Condensed Matter and Materials Physics), 83(2) (2011) 020101. 83. M Holcombe, S Adra, M Bicak, S Chin, S Coakley, AI Graham, J Green, C Greenough, D Jackson, M Kiran, S MacNeil, A Maleki-Dizaji, P McMinn, M Pogson, R Poole, E Qwarnstrom, F Ratnieks, MD Rolfe, R Smallwood, T Sun and D Worth Modelling Complex Biological Systems Using an Agent-based Approach, Integrative Biology (2011). 84. A Howe Simple approaches for solidification and diffusive homogenisation, Ironmaking and Steelmaking, 38(7) (2011) 534-539. 85. G Hrkac, J Dean and D A Allwood Nanowire spintronics for storage class memories and logic, Phil Trans of the Royal Society A. Mathematical, Physical and Engineering Sciences, 369(1948) (2011) 3214-3228.
86. H Hussein, M Ojovan and H Kinoshita Immobilisation of BaSO 4: Phases and microstructure of OPC-BaSO4 system cured at an elevated temperature, Proc WM11 Conference, 27th February - 3rd March 2011, Phoenix, Arizona, WM 11012, 11 p (2011). 87. Hussein, H Kinoshita and M Ojovan Immobilisation of BaSO4: The effect of fine BaSO4 powder on the microstructure and strength of OPC- BaSO4 cured at an elevated temperature, Proc NUWCEM2011, 1st Int Symp on Cement-based Materials for Nuclear Wastes, (O212) 10 p, Avignon, France 11-14.10.2011. 88. Y Iqbal, A Manan and I M Reaney Low loss Sr1CaxLa4Ti5O17 microwave dielectric ceramics, Mat x Res Bulletin, 46(7) (2011) 1092-1096. 89. M H Ismail, R Goodall, H A Davies and I Todd Porous NiTi alloy by metal injection moulding/ sintering of elemental powders: Effect of sintering temperature, Mat Lett, 70(3) (2011) 142-145. 90. J W Jacobs and S J Matcher Digital phase stabilization for improving sensitivity and degree of polarization accuracy in polarization sensitive optical coherence tomography Proc SPIE 7889, 788938 (2011) doi:10.1117/12.874509. 91. T Jarvis, W Voice and R Goodall The bonding of nickel foam to Ti-6Al-4V using Ti-Cu-Ni braze alloy, Mat Sci Eng A: Structural Materials Properties Microstructure and Processing, 528(6) (2011) 25922601. 92. A Javed, N A Morley and M R J Gibbs Effect of growth parameters on the structure and magnetic properties of thin polycrystalline Fe films fabricated on Si < 1 0 0 > substrates, Appl Surf Sci, 257(13) (2011) 5586-5590. 93. A Javed, N A Morley, T Szumiata and M R J Gibbs A comparative study of the microstructural and magnetic properties of < 1 1 0 > textured thin polycrystalline Fe100-xGax (10 <= x <= 35) films, Appl Surf Sci, 257(14) (2011) 5977-5983. 94. M Jepson, X Liu, D Bell, D Ferranti, B J Inkson and C Rodenburg Resolution limits of secondary electron dopant contrast in helium ion and scanning electron microscopy, Microscopy and Microanalysis, 17(4) (2011) 637-642. 95. A C Johnson, S A Hayes and F R Jones The role of matrix cracks and fibre/matrix debonding on the stress transfer between fibre and matrix in a single fibre fragmentation test, Composites Part A: Applied Science and Manufacturing, 43(1) (2011) Available online. 96. R L Johnson-Wilke, D S Tinberg, C B Yeager, Y Han, I M Reaney, I Levin, D D Fong, T T Fister and S Trolier-Mckinstry Tilt transitions in compressively strained AgTa0.5Nb0.5O3 thin films, Phys Rev B (Condensed Matter and Materials Physics), 84(13) (2011) 134114.
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97. N G Jones and M Jackson On mechanism of flow softening in Ti-5Al- 5Mo-5V-3Cr, Mat Sci Technol, 27(6) (2011) 1025-1032. 98. R Kaewkhaw, A M Scutt and J W Haycock Anatomical site influences the differentiation of adipose-derived stem cells for Schwann-cell phenotype and function, Glia, 59(5) (2011)734-749. 99. K Kalantari, I Sterianou, S Karimi, M C Ferrarelli, S Miao, D C Sinclair and I M Reaney Ti-doping to reduce conductivity in Bi0.85Nd 0.15FeO3 ceramics, Advanced Functional Materials, 21(19) (2011) 37373743. 100. K Kanie, J Sekiguchi, X B Zeng, G Ungar and A Muramatsu Phospholipids with a stimuliresponsive thermotropic liquid-crystalline moiety, Chemical Communications, 47(24) (2011) 68856887. 101. P Kapranos The Challenge of introducing Environmental Issues into the teaching of Engineering Materials A story of Reflective Teaching and Inquiry Based Learning, 3rd Int. Materials Education Symposium, 7th-8th April 2011, Cambridge, UK. 102. D K Kasaragod, Z Lu and S J Matcher A comparative study of the optical back-scattering properties of collagen fibers in bovine tendon and cartilage, J Biomed Opt, 16 (2011) 080501. 103. D K Kasaragod, Z H Lu, J Jacobs and S J Matcher Theoretical framework for the analysis of optical anisotropy in birefringent biological tissues with polarization-sensitive optical coherence tomography Proc SPIE 8091 (2011) DOI: 10.1117/12.889208. 104. A S Khan, K R Hassan, S F Bukhari, F S L Wong and I U Rehman Structural and in vitro adhesion analysis of a novel covalently coupled bioactive composite, Journal of Biomedical Materials Research. Part B: Applied Biomaterials, 100B(1) (2011) 239-248. 105. C C Khaw, K B Tan, C K Lee and A R West Phase equilibria and electrical properties of pyrochlore and zirconolite phases in the Bi2O3-ZnO-Ta2O5 system, J Euro Ceram Soc, 32(3) (2011) 671-680. 106. A Kohn, J Dean, A Kovacs, A Zeltser, M J Carey, D Geiger, G Hrkac, T Schrefl and D A Allwood Exchange-bias in amorphous ferromagnetic and polycrystalline antiferromagnetic bilayers: Structural study and micromagnetic modelling, J Appl Phys, 109(8) (2011) 083924. 107. E Krajewska, C Lewis, C Staton, A Macgowan and S Macneil New insights into induction of early-stage neovascularization in an improved tissue-engineered model of psoriasis, J Tissue Engineering and Regenerative Medicine, 5(5) (2011) 363-374.
108. S Krohns, P Lunkenheimer, S Meissner, A Reller, B Gleich, A Rathgeber, T Gaugler, H U Buhl, D C Sinclair and A Loidl The route to resourceefficient novel materials, Nature Materials, 10(12) (2011) 899-901. 109. N Krstajic, D T D Childs, S J Matcher, D Livshits, A Shkolnik, I Krestnikov and R A Hogg Swept-Source Laser Based on Quantum-Dot Semiconductor Optical Amplifier-Applications in Optical Coherence Tomography, IEEE Photonics Technology Letters 23(11) (2011) 739-741. 110. N Krstajic, D Childs, N Peyvast, D Kasaragod, S J Matcher, I Krestnikov and R Hogg Evaluation of a swept-laser optical coherence tomography light source based on a novel quantum-dot based semiconductor optical amplifier Proc SPIE 8091 (2011) DOI: 10.1117/12.889247. 111. N Krstajic, D Childs, R Smallwood, R E Hogg and S J Matcher Common path Michelson interferometer based on multiple reflections within the sample arm: sensor applications and imaging artefacts, Meas. Sci Tech, 22(2) (2011) 027002. 112. N Krstaji, R Hogg and S J Matcher Common path Fourier domain optical coherence tomography based on multiple reflections within the sample arm, Opt Commun, 284(12) (2011) 3168-3172. 113. N Krstaji, R E Richard Hogg and S J Matcher Common path FDOCT based on multiple reflections within the sample arm, Proc. SPIE 7889, 78892K (2011) doi:10.1117/12.874669. 114. Y Lei, I M Reaney, Y C Liu, Y S Yin and G H Chen Microwave dielectric properties and microstructures of RETiNbO6 (RE=La, Sm and Y), Adv Mater Res, 197-198 (2011) 285-289. 115. I Levin, M C Tucker, H Wu, V Provenzano, C L Dennis, S Karimi, T Comyn, T Stevenson, R I Smith and I M Reaney Displacive phase transitions and magnetic structures in Nd-substituted BiFeO3, Chem Mat, 23(8) (2011) 2166-2175. 116. D Li, X Tian, G Hu, Q Zhang, P Wang, P Sun, G Zhou, X Meng, J Yang, J Wu, B Jin, S Zhang, X Tao and Y Tian Synthesis, crystal structures, photophysical properties, and bioimaging of living cells of bis--diketonate phenothiazine ligands and its cyclic dinuclear complexes, Inorganic Chemistry, 50(17) (2011) 7997-8006. 117. M Li, D C Sinclair and A R West Extrinsic origins of the apparent relaxorlike behavior in CaCu3Ti4O12 ceramics at high temperatures: A cautionary tale, J Appl Phys, 109(8) (2011) 084106. 118. Y Li, G Zhang, X Zeng, J Cheng, M Gheorghe and S Elias A modified estimation of distribution algorithm for numeric optimization, Bio-Inspired Computing: Theories and Applications (BIC-TA), Sixth Intl Conf, Penang, (2011) 114-119. 119. Z Li and P Tsakiropoulos Study of the effect of Ti and Ge in the microstructure of Nb-24Ti-18Si-5Ge in situ composite, Intermetallics, 19(9) (2011) 12911297.
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120. Z Li and P Tsakiropoulos The effect of Ge and Ti additions on the microstructures and properties of Nb-18Si based alloys, Mat Res Soc Symp Proc, 1295 (2011) 379-384. 121. F Liu, M Prehm, X Zeng, G Ungar and C Tschierske Two- and three-dimensional liquid-crystal phases from axial bundles of rodlike polyphiles: segmented cylinders, crossed columns, and ribbons between sheets, Angewandte Chemie (International Edition), 50(45) (2011) 10599-10602. 122. X Liu, Z Wang and Zhang Molten salt synthesis and characterization of titanium carbide-coated graphite flakes for refractory castable applications, Intl J Appl Ceram Technol: ceramic product development and commercialization, 8(4) (2011) 911-919. 123. A J Lockwood, K Anantheshwara, M S Bobji and B J Inkson Friction-formed liquid droplets, Nanotechnology, 22(10) (2011) 105703. 124. A J Lockwood, A Padmanabhan, R J T Bunyan and B J Inkson Nanoscale deformation of MEMS materials, Mat Res Soc, 1297 (2011) pp6. 125. A J Lockwood, J Wedekind, R S Gay, J J Wang, M S Bobji, B Amavasai, M Howarth, G Moebus and B J Inkson NanoLAB Triboprobe: Characterizing Dynamic Wear, Friction and Fatigue at the Nanoscale, Mat Res Soc, 1297 (2011) 95-100. 126. Z H Lu, D K Kasaragod and S J Matcher Optic axis determination by fibre-based polarization-sensitive swept-source optical coherence tomography, Phys Med Biol, 56(4) (2011) 1105-1122. 127. Z H Lu, D K Kasaragod and S J Matcher Performance comparison between 8- and 14-bitdepth imaging in polarization-sensitive sweptsource optical coherence tomography, Biomed Opt Express, 2(4) (2011) 794-804. 128. Z Lu, D K Kasaragod and S J Matcher A method to calibrate phase fluctuation in polarization sensitive swept-source optical coherence tomography, J Biomed Opt, 16 (2011) 070502. 129. Z Lu, D K Kasaragod and S J Matcher Polarization-sensitive optical coherence tomography measurements using continuous polarization modulation with arbitrary phase modulation amplitude, J Biomed Opt, 16 (2011) 070502. 130. Z Lu, D K Kasaragod and S J Matcher A method to calibrate phase fluctuation in polarization-sensitive swept-source optical coherence tomography, Proc SPIE 8091 (2011) DOI: 10.1117/12.889613. 131. Z H Lu, D K Kasaragod and S J Matcher Performance comparison between 8 and 14 bitdepth imaging in polarization-sensitive sweptsource optical coherence tomography, Proc. SPIE 7889, 78892F (2011) doi:10.1117/12.874605.
132. Z H Lu, D H K Kasaragod and S J Matcher Optic axis determination by fiber-based polarizationsensitive swept-source optical coherence tomography Proc SPIE 7889, 78890W (2011) doi:10.1117/12.875081. 133. A Ma, B Zhao, A J Bentley, A Brahma, S MacNeil, F L Martin, S Rimmer and N J Fullwood Corneal epithelialisation on surface-modified hydrogel implants - Artificial cornea, J Mat Sci -Materials in Medicine, 22(3) (2011) 663-670. 134. L Ma and W M Rainforth A Study of Biolox delta Subject to Water Lubricated Reciprocating Wear, Tribology International, 43(10) (2011) 1872-1881. 135. S MacNeil, S Bains, C Johnson, J M Ide, C Factor, G Jestin, N Fretellier and S K Morcos Gadolinium contrast agent associated stimulation of human fibroblast collagen production, Investigative Radiology, 46(11) (2011) 711-717. 136. S MacNeil, J Shepherd and L Smith Production of tissue-engineered skin and oral mucosa for clinical and experimental use, Methods in Molecular Biology, 695 (2011) 129-153. 137. A Mangera, A Bullock, S MacNeil and C R Chapple comparative investigation of seven candidate scaffolds for the production of an autologous tissue engineered connective tissue for use in stress urinary incontinence and pelvic organ prolapsed, Neurourology and Urodynamics, 30(6) (2011) 868-870. 138. A Mangera, A J Bullock, C R Chapple and S Macneil Are biomechanical properties predictive of the success of prostheses used in stress urinary incontinence and pelvic organ prolapse? A systematic review, Neurourology and Urodynamics, (2011) Available online. 139. A Mangera, A J Bullock, S MacNeil and C R Chapple Creating a tissue engineered prosthesis for stress urinary incontinence and pelvic organ prolapse, which scaffold?, British Journal of Surgery, 98(4/5) (2011) Conference Proceedings. 140. A Mangera, AJ Bullock, S MacNeil and C R Chapple Engineering a novel tissue engineered autologus prosthesis for use in stress urinary incontinence (SUI) and pelvic organ prolapse (POP) repair, British Journal of Surgery, 98(6) (2011) E6. 141. A Mangera, AJ Bullock, S MacNeil and C R Chapple Increasing collagen production and contraction with ascorbate in a tissue engineered autologus prosthesis for use in the treatment of stress urinary incontinence (SUI) and pelvic organ prolapse (POP), British Journal of Surgery, 98(6) (2011) E7. 142. A Mangera, AJ Bullock, S MacNeil and C R Chapple The effect of scaffold restraint on the properties of tissue engineered prostheses being developed for use in stress urinary incontinence (SUI) and pelvic organ prolapse (POP), European Urology, 10(2) (2011) 291.
Materials Science & Engineering, The University of Sheffield
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143. N Mas, D I Woodward, P A Thomas, A Varez and A R West Structural characterisation of ferroelectric Ag2Nb4O11 and dielectric Ag2Ta4O11, J Mater Chem, 21(8) (2011) 2715-2722. 144. N Mas, D I Woodward, A Varez and A R West Polymorphism, structural characterisation and electrical properties of Na2Nb4O11, J Mater Chem, 21(32) (2011)12096-12102. 145. N Mas, X Yue, T Goto and A R West Frequencydependent electrical properties of ferroelectric BaTi2O5 single crystal, J Appl Phys, 109(2) (2011) pp8. 146. S J Matcher Practical aspects of OCT imaging in tissue engineering, Methods Mol Biol, 695 (2011) 261-280. 147. S J Matcher Oximetry, in Handbook of Biophotonics, Ed Jrgen Popp, Valery V Tuchin, Arthur Chiou, Stefan H Heinemann, Wiley-VCH (2011). 148. A Matthews The UK surface engineering market, T Met Finish, 89(2) (2011) 69-70. 149. F Maxim, P M Vilarinho, P Ferreira, I M Reaney and I Levin Kinetic study of the static hydrothermal synthesis of BaTiO3 using titanate nanotubes precursors, Cryst Growth Des, 11(8) (2011) 33583365. 150. J McGann and M I Ojovan The Synthesis of Graphite-Glass Composites Intended for the Immobilisation of Waste Irradiated Graphite, J Nucl Mater, 413 (2011) 47-52. 151. V Melissinaki, A A Gill, I Ortega, M Vamvakaki, A Ranella, C Fotakis, M Farsari and F Claeyssens Direct laser writing of polylactide 3D scaffolds for Neural Tissue Engineering Applications, Biofabriction, 3 (2011) 045005. 152. R J Milne, A J Lockwood and B J Inkson Size-dependent deformation mechanisms of Al nanopillars, J Phys D: Applied Physics, 44(48) (2011) 485301. 153. L Miranda, K Boulahya, M Hernando, D C Sinclair, F Jimenez-Villacorta, A Varela, J M Gonzalez-Calbet and M Parras StructureComposition-Property Relationships of 6H-BaTi1CoyO3-delta (0.1 <= y <= 0.4), Chem Mat, 23(4) y (2011) 1050-1060. 154. M Mirsaneh, B E Hayden, S Miao, J Pokorny, S Perini, E Furman, M T Lanagan, R Ubic and I M Reaney High throughput synthesis and characterization of the PbnNb 2O5+n (0.5 < n < 4.1) system on a single chip, Acta Mat, 59(5) (2011) 2201-2209. 155. M Mirsaneh, I M Reaney, Y Han, I Sterianou and O P Leisten Low sintering temperature high permittivity glass ceramic composites for dielectric loaded microwave antennas, Adv Appl Ceram, 110(7) (2011) 387-393.
156. G Mbus, Z Saghi, U M Bhatta, and I M Ross Aberration corrected TEM of irradiation induced atomic hopping processes on various ceria surfaces observed in-situ, Proc Microsc Conf (MC2011), DGE publ, W Jger et al, eds, Kiel, Germany, IM2-P119 (2011). 157. G Mbus, Z Saghi, D C Sayle, U M Bhatta, A Stringfellow and T X T Sayle Dynamics of Polar Surfaces on Ceria Nanoparticles Observed In Situ with Single-Atom Resolution, Adv Funct Mats, 21(11) (2011) 1971-1976. 158. N A Morley, D Dhandapani, A Rao, H Al Qahtani, M R J Gibbs, M Grell, D Eastwood and B K Tanner Polymeric spin-valves at room temperature, Synthetic Metals, 161(7-8) (2011) 558-562. 159. C Morrison, L Saharan, G Hrkac, T Schrefl, Y Ikeda, K Takano, J J Miles and T Thomson Inter/ intra granular exchange and thermal activation in nanoscale granular magnetic materials, Appl Phys Lett, 99(13) (2011) 132507 pp3. 160. C Murray-Dunning, S L McArthur, T Sun, R McKean, A J Ryan and J W Haycock Threedimensional alignment of schwann cells using hydrolysable microfiber scaffolds: strategies for peripheral nerve repair, Methods in Molecular Biology, 695 (2011) 155-166. 161. R Nazir, N Iqbal, A S Khan, A Akram, A Asif, A A Chaudhry, I U Rehman and R Hussain Rapid synthesis of thermally stable hydroxyapaptite, Ceram Intl, 38(1) (2011) 457-462. 162. M I Ojovan, G A Varlackova, Z I Golubeva and O N Burlaka Long-term field and laboratory leaching tests of cemented radioactive wastes, J Hazard Mater, 187 (2011) 296-302. 163. M I Ojovan and W E Lee Glassy wasteforms for nuclear waste immobilisation, Metal Mater Trans A, 42(4) (2011) 837-851. 164. M I Ojovan and W E Lee Glassy and glass composite nuclear wasteforms, Ceram Trans, 227 (2011) 203-216. 165. M I Ojovan Rydberg Matter Clusters: Theory of Interaction and Sorption Properties, J Clust Sci, (2011) 1-12. 166. M I Ojovan (Editor) Handbook of advanced radioactive waste conditioning technologies, ISBN 1 84569 626 3. Woodhead Publishing Series in Energy No 12, Oxford, 512 (2011). 167. M I Ojovan Radioactive waste characterisation and selection of conditioning technologies, in: Handbook of advanced radioactive waste conditioning technologies. Edited by M I Ojovan. p. 1-16, Woodhead, Oxford (2011). 168. M I Ojovan P P Poluektov and V A Kascheev Super-deep HLW self-disposal option, Proc. WM11 Conference, 27th February 3rd March 2011, Phoenix, Arizona, WM 11065, 10 p (2011).
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169. M I Ojovan, G A Varlakova, Z I Golubeva and O N Burlaka Leaching of radionuclides from cementitious wasteforms in laboratory and field conditions, Proc NUWCEM2011, 1st Int Symp on Cement-based Materials for Nuclear Wastes. (P38) 6 p, Avignon, France 11-14.10.2011. 170. M Z Omar, H V Atkinson and P Kapranos Thixotropy in semi solid steel slurries under rapid compression, Metal Mat Trans A, 42A (2011) 2011 2807. 171. D S G Ong, J S Ng, Y L Goh, C H Tan, S Zhang and J P R David InAlAs avalanche photodiode with type-II superlattice absorber for detection beyond 2 m, IEEE Transactions on Electron Devices, 58(2) (2011) 486-489. 172. R A M Osman and A R West Electrical characterization and equivalent circuit analysis of (Bi1.5 Zn0.5)(Nb0.5Ti1.5)O-7 Pyrochlore, a relaxor ceramic, J Appl Phys, 109(7) (2011) 074106. 173. E J Palmeire, P Cizek, F Bai, R M Poths, J Turner, B P Wynne and W M Rainforth The Use of Fe-30% Ni and Fe-30% Ni-Nb Alloys as Model Systems for Studying the Microstructural Evolution during the Hot Deformation of Austenite, Mater Manuf Process, 26(1) (2011) 127-131. 174. E Pamula, J Kokoszka, K Cholewa-Kowalska, M Laczka, L Kantor, L Niedzwiedzki, G C Reilly, J Filipowska, W Madej, M Kolodziejczyk, G Tylko and A M Osyczka Degradation, Bioactivity, and Osteogenic Potential of Composites Made of PLGA and Two Different Sol-Gel Bioactive Glasses, Annals of Biomed Eng, 39(8) (2011) 2114-2129. 175. L B Parsons and R Goodall Testing the fracture behaviour of chocolate, Physics Education, 46(1) (2011) 50-56. 176. J M Patterson, A J Bullock, S MacNeil and C R Chapple Methods to reduce the contraction of tissue-engineered buccal mucosa for use in substitution urethroplasty, 60(4) (2011) 856-861. 177. A J Pearson, S A Boden, D M Bagnall, D G Lidzey and C Rodenburg Imaging the bulk nanoscale morphology of organic solar cell blends using helium ion microscopy, Nano Letters: a journal dedicated to nanoscience and nanotechnology, 11(10) (2011) 4275-4281. 178. C Pegoraro, S MacNeil and G Battaglia Polymersome macromolecule delivery across intact human skin, Tech Proc of NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2011 3: 428431. 179. X Peng, A Matthews and S Xue, Plasma-based processes and thin film equipment for nano-scale device fabrication, J Mater Sci, 46(1) (2011) 1-37. 180. Y Peng, T Cullis, I Luxmoore and B Inkson Electrical properties of individual CoPt/Pt multilayer nanowires characterized by in situ SEM nanomanipulators, Nanotech, 22(24) (2011) 245709.
181. V Percec, S D Hudson, M Peterca, P Leowanawat, E Aqad, R Graf, H W Spiess, X Zeng, G Ungar and P A Heiney Self-repairing complex helical columns generated via kinetically controlled self-assembly of dendronized perylene bisimides, J Am Chem Soc, 133(45) (2011) 18479-18494. 182. V Percec, M Peterca, T Tadjiev, X Zeng, G Ungar, P Leowanawat, E Aqad, M R Imam, B M Rosen, U Akbey, R Graf, S Sekharan, D Sebastiani, H W Spiess, P A Heiney and S D Hudson Selfassembly of dendronized perylene bisimides into complex helical columns, J Am Chem Soc, 133(31) (2011) 12197-12219. 183. J D Plummer, R Goodall, I A Figueroa, I Todd A study of mechanical homogeneity in as-cast bulk metallic glass by nanoindentation, J Non-Cryst Solids, 357(3) (2011) 814-819. 184. J D Plummer and I Todd Implications of elastic constants, fragility, and bonding on permanent deformation in metallic glass, Appl Phys Lett, 98(2) (2011) 021907 pp3. 185. J Pokorny, U M Pasha, L Ben, O P Thakur, D C Sinclair and I M Reaney Use of Raman spectroscopy to determine the site occupancy of dopants in BaTiO3, J Appl Phys, 109(11) (2011) 114110. 186. J Poole, S MacNeil and S Rimmer Semicontinuous emulsion polymerization of butyl methacrylate and 1, 3-butadiene in the presence of cyclodextrins and cytocompatibility of dicarboxylic acid telechelic oligo(butyl methacrylate)s derived from ozonolysis of the latexes, Macromol Chem Phys, 212(18) (2011) 2043-2051. 187. M Prehm, F Liu, X Zeng, G Ungar and C Tschierske Axial-bundle phases - New modes of 2D, 3D, and helical columnar self-assembly in liquid crystalline phases of bolaamphiphiles with swallow tail lateral chains, J Am Chem Soc, 133(13) (2011) 4906-4916. 188. D Quigley, C L Freeman, J H Harding and P M Rodger Sampling the structure of calcium carbonate nanoparticles with metadynamics, J Chem Phys, 134(4) (2011) 044703. 189. I M Reaney, D I Woodward and C A Randall Displacive phase transitions and intermediate structures in perovskites, J Am Ceram Soc, 94(7) (2011) 2242-2247. 190. N Reeves-Mclaren, M C Ferrarelli, Y Tung, D C Sinclair and A R West Synthesis, structure and electrical properties of Cu3.21Ti1.16Nb2.63O12 and the CuOx-TiO2-Nb2O5 pseudoternary phase diagram, J Solid State Chem, 184(7) (2011) 1813-1819. 191. N Reeves-McLaren, R I Smith and A R West Lithium-Ion Conduction Pathways in Complex Lithium Spine Is Li2MGe3O8 (M = Ni or Zn), Chem Mat, 23(15) (2011) 3556-3563.
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Publications
192. R Risti, E Babi, D Paji, K Zadro, I A Figueroa, H A Davies, I Todd, A Kurumovi and M Stubiar Mechanical and magnetic properties of Cu55Hf45Ti metallic glasses, Solid State Comm, 151(14-15) x x (2011) 1014-1017. 193. R Risti, E Babi, M Stubiar, A Kurumovi, J R Cooper, I A Figueroa, H A Davies, I Todd, L K Varga and I Bakonyi Simple correlation between mechanical and thermal properties in TE-TL (TE = Ti,Zr,Hf;TL = Ni,Cu) amorphous alloys, J Non-Cryst Solids, 357(15) (2011) 2949-2953. 194. C Rodenburg, X Liu, M A E Jepson, S A Boden and G Brambilla Surface morphology of silica nanowires at the nanometer scale J Non-Cryst Solids, 357(15) (2011) 3042-3045. 195. P B Rose, D I Woodward, M I Ojovan, N C Hyatt and W E Lee Crystallisation of a simulated borosilicate high-level waste glass produced on a full-scale vitrification line, J Non-Cryst Solids, 357(15) (2011) 2989-3001. 196. R M Rumney, A Sunters, G C Reilly and A Gartland Application of multiple forms of mechanical loading to human osteoblasts reveals increased ATP release in response to fluid flow in 3D cultures and differential regulation of immediate early genes, J Biomech, 45(3) (2011) 540-554. 197. Y Safaei-Naeini, F Golestani-Fard, F Khorasanizadeh, M Aminzare and S Zhang Low temperature molten salt synthesis of nano crystalline MgAl2O4 powder, Iranian J Mat Eng, 8(3) (2011) 23-28. 198. L Saharan, C Morrison, J J Miles, T Thomson, T Schrefl and G Hrkac Angle dependence of the switching field of recording media at finite temperatures, J Appl Phys, 110 (2011) 103906. 199. P Sarker, J Shepherd, K Swindells, I Douglas, S MacNeil, L Swanson and S Rimmer Highly branched polymers with polymyxin end groups responsive to Pseudomonas aeruginosa, Biomacromolecules, 12(1) (2011) 1-5. 200. T X Sayle, B J Inkson, A Karakoti, A Kumar, M Molinari, G Mbus, S C Parker, S Seal and D C Sayle Mechanical properties of ceria nanorods and nanochains; the effect of dislocations, grainboundaries and oriented attachment, Nanoscale 3(4) (2011) 1823-1837. 201. L Scelsi, A Hodzic, C Soutis, S A Hayes, S Rajendran, M A AlMaadeed and R Kahraman A review on composite materials based on recycled thermoplastics and glass fibres, Plastics Rubber and Composites, 40(1) (2011) 1-10. 202. L Schulz, L Nuccio, M Willis, P Desai, P Shakya, T Kreouzis, V K Malik, C Bernhard, F L Pratt, N A Morley, A Suter, G J Nieuwenhuys, T Prokscha, E Morenzoni, W P Gillin and A J Drew Engineering spin propagation across a hybrid organic/inorganic interface using a polar layer, Nature Materials, 10(1) (2011) 39-44.
203. M Selim, A J Bullock, K A Blackwood, C R Chapple and S MacNeil Developing biodegradable scaffolds for tissue engineering of the urethra, British Journal of Urology (BJU) Intl, 107(2) (2011) 296-302. 204. Z Shamsudin, A Hodzic, C Soutis, R J Hand, S A Hayes and I P Bond Characterisation of thermo-mechanical properties of MgO-Al 2O3SiO2 glass ceramic with different heat treatment temperatures, J Mat Sci, 46(17) (2011) 5822-5829. 205. J Shepherd, P Sarker, S Rimmer, L Swanson, S MacNeil and I Douglas Hyperbranched poly(NIPAM) polymers modified with antibiotics for the reduction of bacterial burden in infected human tissue engineered skin, Biomat, 32(1) (2011) 258267. 206. A T Sidambe, I A Figueroa, H Hamilton and I Todd Improved Processing of Titanium Alloys by Metal Injection Moulding, IOP Conf Ser: Mat Sci and Eng, 26 (2011) 012005. 207. A T Sidambe, I A Figueroa, H G C Hamilton and I Todd Taguchi optimization of mim titanium sintering, Intl J of Powder Metallurgy, 47 (2011) 21-28. 208. L Smith ands MacNeil State of the art in noninvasive imaging of cutaneous melanoma, Skin Res Tech, 17(3) (2011) 257-259. 209. L E Smith, V Hearnden, Z Lu, R Smallwood, K D Hunter, S J Matcher, M H Thornhill, C Murdoch and S MacNeil Evaluating the use of optical coherence tomography for the detection of epithelial cancers invitro, J Biomed Optics, 16(11) (2011) 116015. 210. J Squire, E R Maddrell, N C Hyatt and M C Stennett Developing the plutonium disposition option: Ceramic processing concerns, Ceram Trans, 227 (2011) 241-249. 211. M Steeper, M Jackson, P Madin and K Ridal Advances in metal manufacturing technologies, Ironmaking and Steelmaking, 38(4) (2011) 241-249. 212. M C Stennett, I J Pinnock and N C Hyatt Rapid synthesis of Pb-5(VO4)(3)I, for the immobilisation of iodine radioisotopes, by microwave dielectric heating, J Nuclear Materials, 414(3) (2011) 352-359. 213. L Sun, K Muszka, B P Wynne and E J Palmiere The effect of strain path reversal on high-angle boundary formation by grain subdivision in a model austenitic steel, Scripta Mat, 64(3) (2011) 280-283. 214. T Szumiata, K Brzzka, M Gawroski, B Grka, A Javed, N A Morley and M R J Gibbs Structural and magnetic ordering in Fe-Ga thin films examined by Mssbauer spectrometry, Acta Physica Polonica. Series A: General Physics, Physics of Condensed Matter, Optics and Quantum Electrodynamics, 119(1) (2011) 21-23.
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215. S L Tan, S Zhang, W M Soong, Y L Goh, L J J Tan, J S Ng, J P R David, I P Marko, A R Adams, S J Sweeney and J Allam GaInNAsSb/GaAs photodiodes for long-wavelength applications, IEEE Elect Dev Lett, 32(7) (2011) 919-921. 216. D Tian, X Zeng and J Keane Core-generating approximate minimum entropy discretization for rough set feature selection in pattern classification, Intl J Approx Reason, 52(6) (2011) 863-880. 217. D S Tinberg, R L Johnson-Wilke, D D Fong, T T Fister, S K Streiffer, Y S Han, I M Reaney and S Trolier-McKinstry Octahedral tilt transitions in relaxed epitaxial Pb(Zr1-xTix)O-3 films, J Appl Phys, 109(9) (2011) 094104. 218. R Torchio, S Pascarelli, O Mathon, C Marini, S Anzellini, P Centomo, C Meneghini, S Mobilio, N A Morley and M R J Gibbs Structure and magnetism in compressed iron-cobalt alloys, High Pressure Research, 31(1) (2011) 148-152. 219. P Tsakiropoulos, K Zelenitsas and N Vellios Study of the effect of Al, Cr and Sn additions on the microstructure and properties of Nb silicide based alloys, MRS Proc, 1295 (2011) 367-372. 220. G Ungar, C Tschierske, V Abetz, R Holyst, M A Bates, F Liu, M Prehm, R Kieffer, X Zeng, M Walker, B Glettner and A Zywocinski Selfassembly at different length scales: Polyphilic star-branched liquid crystals and miktoarm star copolymers, Adv Funct Mats, 21(7) (2011) 1296-1323. 221. G A Varlakova, A T Dyakonova, A I Netrusov and M I Ojovan Microbiological Activities on Cementitious Waste Forms in a Shallow-Ground Repository, J Mater Sci Eng, B1 (2011) 591-596. 222. G A Varlakova, A T Dyakonova, A I Netrusov and M I Ojovan Microbiological activities in a shallowground repository with cementitious wasteforms, Proc NUWCEM2011, 1st Int Symp on Cement-based Materials for Nuclear Wastes, (P39) 10 p, Avignon, France 11-14.10.2011. 223. P Viswanathan, S Chirasatitsin, G Reilly, A Engler and G Battaglia 3D cell instructive scaffolds to direct stem cell fate, Tech Proc 2011 NSTI Nanotech Conf and Expo, NSTI-Nanotech (2011) 3: 256-259. 224. N G Walker, AR Mistry, L E Smith, P C Eves, G Tsaknakis, S Forster, S M Watt and S Macneil A Chemically Defined Carrier for the Delivery of Human Mesenchymal Stem/Stromal Cells to Skin Wounds, Tissue Eng. Part C. Methods, 18(2) (2011) 143-155. 225. N Wang, B Robaye, A Agrawal, G Reilly, J M Boeynaems and A Gartland Deletion of the P2Y13 receptor leads to reduced bone turnover and protection from ovariectomy-induced bone loss, Bone, 48 (2011) S227. 226. A T White and C K Chong Rotational invariance in the three-dimensional lattice Boltzmann method is dependent on the choice of lattice, J Computational Physics, 230(16) (2011) 6367-6378.
227. H Wu and A R West Thermally-Induced Homogeneous Racemization, Polymorphism, and Crystallization of Pyroglutamic Acid, Cryst Growth Des, 11(8) (2011) 3366-3374. 228. B Xiao, E J Palmiere, A A Howe and H C Carey Multi-Pass Simulation of Heavy Plate Rolling Including Intermediate Forced Cooling, J Iron and Steel Res Intl, 18 (2011) 506-510. 229. W Xie, G Mbus and S Zhang Molten salt synthesis of silicon carbide nanorods using carbon nanotubes as templates, J Mat, 21(45) (2011) 1832518330. 230. F Yan, S Miao, I Sterianou, I M Reaney, M O Lai, L Lu, W D Song Multiferroic properties and temperature-dependent leakage mechanism of Sc-substituted bismuth ferrite-lead titanate thin films, Scripta Mat, 64(5) (2011) 458-461. 231. T Yasuda, T Shimizu, R Liu, G Ungar and T Kato Electro-Functional Octupolar pi-Conjugated Columnar Liquid Crystals, J Am Chem Soc, 133(34) (2011) 13437-13444. 232. J Ye, S Zhang and W E Lee Novel low temperature synthesis and characterisation of hollow silicon carbide spheres, Micro Meso Mats, 152(1) (2011) 25-30. 233. B S Yilbas, S S Akhtar, A Matthews and C Karatas Laser remelting of zirconia surface: Investigation into stress field and microstructures, Mater Manu Proc, 26(10) (2011) 1277-1287. 234. B S Yilbas, S S Akhtar, A Matthews, C Karatas and A Leyland Microstructure and Thermal Stress Distributions in Laser Carbonitriding Treatment of Ti-6Al-4V Alloy, J Manu Sci and Eng, 133(2) (2011)021013. 235. X Zeng, R Kieffer, B Glettner, C Nrnberger, F Liu, K Pelz, M Prehm, U Baumeister, H Hahn, H Lang, G A Gehring, C H M Weber, J K Hobbs, C Tschierske and G Ungar Complex multicolor tilings and critical phenomena in tetraphilic liquid crystals, Science, 331(6022) (2011) 1302-1306. 236. Q L Zhang, N Maso, Y Liu, H Yang and A R West Voltage-dependent low-field resistivity of CaTiO3:Zn ceramics, J Mater Chem, 21(34) (2011) 12894-12900. 237. Z Zhou, W M Rainforth, M H Gass, A Bleloch, A P Ehiassarian and P E Hovsepian C/CrC nanocomposite coating deposited by magnetron sputtering at high ion irradiation conditions, J Appl Phys, 110(7) (2011) 073301. 238. Z Zhou, I M Ross, L Ma, W M Rainforth, A P Ehiasarian and P Hovsepian Wear of hydrogen free C/Cr PVD coating against Al2O3 at room temperature, Wear, 271(9) (2011) 2150-2156.
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PhD Awards
Eng D
Adrian Covill Novel encapsulants for intermediate level waste in the UK nuclear industry. Supervisor Prof N C Hyatt.
Mohd Sobri Idris Synthesis and characterisation of lithium nickel manganese cobalt oxide as cathode material. Supervisor: Prof A R West. Timur Tadjiev Crystal structures of helical columnarconjugated systems and biodegradable polyester. Supervisor: Prof G Ungar. Wie Xie Molten salt synthesis and characterisation of novel carbide materials. Supervisors: Dr S Zhang and Dr G Moebus. Zhaoxia Zhou Oxidation and wear of TiAIN/VN multilayer PVD Hard Coatings. Supervisor: Prof W M Rainforth.
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Sponsors 8
DeWalt/Black and Decker UK Limited DGP Group Doncasters plc Dormer Tools Ltd Dow Corning Ltd Dowding and Mills Ltd DSTL DSM, Gelen, The Netherlands DTI Dynamic Ceramic EADS (UK and Germany) Egide UK Ekspan Ltd, Sheffield Engineering and Physical Sciences Research Council (EPSRC) Environment Agency EU-ALFA Programme European Regional Development Fund Objective 1 EU-Framework VII Initiative EU-INTAS Programme EU-NVOTO Programme European Synchrotron Radiation Facility European Owens Corning First Subsea Ltd Firth Rixon plc, Rotherham Flow Science Inc. Furlong Charitable Research Foundation GEC-Marconi Research Centre General Electric (ex Rare Earth Products (GE) Ltd, Widnes) George Greensmith and Co Ltd, Sheffield Glass Technology Services (GTS) Glass Training Ltd Government of Iran Government of Libya Government of Malaysia Government of Mexico Government of Pakistan Government of Spain Government of Thailand Government of Turkey
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Sponsors
Health and Safety Laboratory Hereans Electro-Nite UK Ltd Hitatchi Global Storage Technologies Holset Turbochargers Hydro Aluminium Innoval Technology Ltd Institute of Materials, Minerals and Mining Intercytex Limited International Atomic Energy Agency International Centre for Diffraction Data, USA Ion Coat Ltd Ironmongers Company Johnson Matthey plc K B Alloys Inc Keronite Ltd King Mongkuts University, Thailand Kirkstall Ltd Lawrence Livermore Laboratory Leverhulme Trust London and Scandinavian Metallurgical Co Ltd, Rotherham Lynwood Products Magnesium Electron Ltd Magnox Electric plc Maharashra Institute of Technology, India Mandeville of London Ltd Materialise BV Merck Ltd METRIC (N8 Molecular Engineering Research Centre) Metalysis Limited Minelco Minerals Ministry of Defence Mitsubishi Heavy Industries, Japan Morgan Advanced Ceramics Morgan Electroceramics Ltd National Environmental Research Council National Institute for Health Research (NIHR) National Nuclear Laboratory National Physical Laboratory National Synchrotron Light Source NGF Europe Ltd Nippon Sheet Glass Novelis Nuclear Decommissioning Authority (NDA) Nuclear Energy Corporation of South Africa Nuclear Technology Education Consortium
Orla Protein Technologies Osaka Institute of Technology, Japan Outokumpu Stainless Owens Corning Fibreglass RV, Belgium Particle Physics and Astronomy Research Council (PPARC) Pilkington plc Plasso Technology Ltd POSCO, Pohang Steel Company, Korea Powerwave Ltd Ilika Technology Precision Products Ltd PSI, Hailsham, East Sussex Q Coat Ltd Qinetiq Plc, Farnborough Qinetiq, Malvern Qinetiq MAST Innovative Reference Metals Company Inc., USA regeNer8 Renold Chain Ltd The Research Council UK (RCUK) Research Institute for Solid State Physics, Budapest, Hungary Rolls-Royce plc Reiter Automotive Management AG Royal Society of Chemistry Rutherford Appleton Laboratory Sabic, The Netherlands SAIT, Samsung Advanced Institute of Technology Sandvik Osprey Sarantel Ltd Sellafield Limited Sheffield Forgemasters Group, Sheffield SIDERAR, Argentina Silberline, Leven, UK Siemens Industrial Turbines Ltd Siemens VAI plc SIRIM, Malaysia Sumitomo Metal Industries, Ibaraki, Japan Symmetry Medical Synchrotron Radiation Source Tata Iron and Steel Company Ltd, India Tata Steel plc Tata Aluminium Rolled Products Tata, Construction and Industrial Tata Engineering Steels Ltd, Rotherham Tata, Research, Development and Technology (Tata Teesside Technology Centre) Tata Research Development and Technology, Ijmuiden (Netherlands) Tata Rail
8
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Materials@Sheffield 2012
Tata, Research, Development and Technology (Tata Swinden Technology Centre) Tata Steel Strip Products Technical Fibre Products, Kendal, UK Technology Strategy Board (TSB) Technology Strategy Consultants Tecvac Ltd Thai Government Thermometrics
Sponsors 8
The Royal Society The Wellcome Trust Timet Timken Inc Tinsley Wire, Sheffield Top Box Toyobo Limited, Japan TWI UNAM, Mexico City United States Air Force United States Department of Energy University of Malaysia University of Sheffield, Proof of Concept Fund USA Center for Nuclear Waste Regulatory Analyses Vesuvius Premier Wallwork Heat Treatment Ltd WBB plc White Rose Consortium Worshipful Company of Ironmongers WRAP (Waste and Resources Action Plan, UK Government) Wuhan Iron and Steel Company (WISCO) Yorkshire Forward York Pharma
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Materials@Sheffield 2012
Grants
Prof S MacNeil
Dr S J Matcher Dr S A Hayes Em Prof F R Jones Dr Z Liu Dr A Leyland Prof A Matthews Prof I M Reaney Prof M R Gibbs Dr E J Palmiere Dr S J Matcher Prof I M Reaney Dr F Claeyssens Prof N C Hyatt Prof W M Rainforth Prof S MacNeil Dr R Goodall Prof I Todd Dr P A Bingham Prof R J Hand Prof N C Hyatt Prof J W Haycock
Industrial Secondment Develop the casting of polymer adhesive/ carrier films Novel Efficiency-Enhancing Duplex Treatments for Turbines (NEET) New Perovskite Materials with Large Field-Induced Electromechanical Strains Effect of segregation elements and hot deformation on abnormal grain growth in GO-Silicon Steel KTA 200nm SLD High temperature multi-layer actuators for diesel fuel injection systems METRC STP Stage 2 Award SmartKem Ltd EMMI Comparison of sterilisation methodologies on tissue recellularisation CDE Micro-Truss Blast Resistance MBM ash in fibre glass insulation KTA proof of concept To develop, evaluate and test a new marketable bioactive coating LANDSCAPE AWARD - Engineering Tissue Engineering and Regenerative Medicine ~ E-TERM To develop and commercially produce bio-derived compostable biopolymer A high contrast emission diagnostic tool for early non-invasive cancer detection The development of direct manufacturing process for low cost titanium coil springs
21,000.00
53,625.00
595,500.00 30,703.00
POSCO EPSRC EPSRC SMARTKEM LTD EUROPEAN COMMISSION TISSUE REGENIX DEFENCE SCIENCE AND TECHNOLOGY LABORATORY EPSRC KNOWLEDGE TRANSFER PARTNERSHIP EPSRC TECHNOLOGY STRATEGY BOARD EPSRC EPSRC
20,003.00 12,516.40
49,343.00
127,218.00
Prof S MacNeil
37,722.00
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Materials@Sheffield 2012
Grants
Awarding Body
Grant Holder/s Prof S MacNeil Dr S J Matcher Prof S MacNeil Prof B J Inkson Prof I M Reaney Prof W M Rainforth Dr P A Bingham Prof R J Hand
Project Title Evaluation of a novel biocompatible polypyrrole nanoparticle optical contrast agent for OCT imaging CA-RoboCom Unilever PhD - factors in abrasive tooth cleaning - Consumables Domain wall - Defect interactions in ferroelectric thin films SRNL Modelling Development Stage 1 Development and testing of neurophillic scaffold materials for peripheral nerve repair WASTEKIT Biomedical implant with Exceptional Resistance to Tribo-bio-corrosion and Inherent antimicrobial properties (BERTI) MAGNETISM YOU CAN RELY ON
37,134.00
5,000.00
EPSRC SAVANNAH RIVER NUCLEAR SOLUTIONS, LLC NUFFIELD FOUNDATION EUROPEAN COMMISSION TECHNOLOGY STRATEGY BOARD EPSRC EUROPEAN COMMISSION EUROPEAN OFFICE OF AEROSPACE TISSUE REGENIX ROYAL HALLAMSHIRE HOSPITAL TRUST EPSRC DOBENECKTECHNOLOGIESTIFTUNG EPSRC EPSRC (KTA Fund)
393,648.00
25,532.00
Prof J W Haycock
1,440.00
Prof N C Hyatt Dr A Leyland Prof A Matthews Dr T Hayward Dr R Goodall Prof P Tsakiropoulos Dr S A Hayes
33,036.00
76,511.00
698,103.00
Accelerated Metallurgy
444,967.00
Self healing inkjet composites Comparison of sterilisation methodologies on tissue recellularisation CONTINUATION Developing tissue engineered materials for pelvic floor repair The atomic resolution chemical structure of defects in multiferroic oxides MERCURY - PROBEAM EQUIPMENT Anchorless selective laser melting (ASLM) of high temperature metals Kickstart Funding for co-electrolysis using Solid Oxide Fuel Cells Equipment funding for Thermal Conductivity Rig and High Temperature X-ray Diffractometer
6,263.60
Prof S MacNeil
4,929.00
Prof S MacNeil Prof I M Reaney Prof I Todd Prof W M Rainforth Prof I Todd Prof D C Sinclair Dr R Elder (CBE) Prof W M Rainforth Prof D C Sinclair
58,000
69
Materials@Sheffield 2012
Highlights 2011
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Had an invited visit to Grallar Artcraft (a glassware manufacturer) in Ktahya, Turkey, 6th-9th January. Attended the Indo-UK Civil Nuclear Collaboration Review Meeting, Mamallapuram, India, 6th-9th March. Gave an invited lecture, Towards stronger silicate glasses: a review of research into the mechanical properties of glasses, at iecam 26 Cam Sempozyum (26th iecam Glass Symposium, Istanbul, Turkey, 27th May. Gave an invited lecture, Mechanical properties of glasses, waste glass composition development and characterisation, at the 10th Anniversary Glass Trend meeting in Zandvoort, The Netherlands, 7th-9th June. Acted as an external PhD examiner at the University of Aalborg, Denmark. The thesis submitted by Martin Jensen was entitled Inhomogeneity in glass forming melts. The defence took place on 30 September 2011. Attended the first Research Coordination meeting of the collaborative research project Treatment of Irradiated Graphite to Meet Acceptance Criteria for Waste Disposal held at the IAEA Vienna, 28th-30th November. Prof John Harding Presented a paper, Controlling crystal growth with organic molecules in aqueous systems, at the RCS Materials Chemistry Meeting, Manchester, July. Presented a review on simulating the nucleation and growth of calcium carbonate at a WUN workshop Mineralisation in corals, York, July. Organised the annual Summer School in Molecular Simulation in Belfast and gave 4 lectures there as part of the course, July. Gave two invited presentations (one on Surface Science and Nanotechnology; the other on Simulation Methods) at an International Summer School Nanotechnology and Virtual Reality, St Poelten, Austria,July. Gave an Invited TalkSimulation on the edge: the trials and tribulations of modelling interfaces at the Annual General Meeting of CCP5, Bath, September. Organised a Symposium, Nucleation and Growth of Biological and Biomimetic Materials, at the MRS Fall Meeting, Boston, November, and presented papers and posters. Prof John Haycock Gave an invited departmental seminar, Bioengineering peripheral nerve, biomaterials and stem cells, at the Medical School University of Manchester, February. Gave an invited talk, Adipose-derive stem cells for nerve repair, to the Thai Stem Cell Meeting at the University of Sheffield, March. Gave an invited talk, Bioengineering peripheral nerve, to the Kroto Research Institute Annual Symposium, May. Gave an invited talk, Rapid fabrication of bioactive surfaces, to the Polymer Centre University of Sheffield, July. Gave an invited talk, Fabrication of a medical device nerve guide, to the Regener8 Annual Symposium, Manchester, September.
Gave an invited talk, Controlling biological function using polymer interfaces and surfaces, to the SSBII, Port Sunlight, October. Gave an invited talk to the Bioreactors for Tissue Engineering meeting, University of Keele. November. Gave an invited talk, Developing an immunocompetent 3D skin model for sensitization testing, at the Colipa Skin Tolerance Workshop, Brussels, Belgium, March. Gave an invited talk, Paracrine signalling communication of skin cells and inflammatory detection, to the Quasi-Vive Bioreactor Annual Meeting, Saarbrucken, Germany, May. Gave 3 talks at the Tissue Engineering and Regenerative Medicine International Society (TERMIS) European Chapter Grenada, Spain, July: Development of a paracrine skin model for irritant detection Adipose-derived stem cells for peripheral nerve repair Polymer microfiber scaffolds for peripheral nerve repair Gave 2 talks at the European Society for Biomaterials (ESB), Dublin, Ireland. September: Bioengineering peripheral nerve using nerve guidance conduits Stem cells for nerve repair Gave an invited talk, Strategies for repairing peripheral nerve. to the Department of Surgery, University of Umea, Sweden. November. Gave an Invited talk, Stem cells and nerve guide channels for repairing injured nerve, to the Ludvik Boltzman Institute, Vienna, Austria, November. Prof John Haycocks and Prof Nick Williams (Chemistry) work on anti-inflammatory dip and dry surfaces for biomaterials was featured in latest quarterly BBSRC Business magazine as both a front cover and 2-page article. The work involved the design and synthesis of highly adhesive and self-assembling molecules conjugated to anti-inflammatory peptides. Dr John Hinton Was awarded an Outstanding Poster Award for The Effect of High Temperature Grain Refinement on the Isothermal Ferrite Grain Growth Kinetics in Steel S460 at the 4th Recrystallization and Grain Growth Conference held in Sheffield in July 2010. Presented a paper at the 6th International Conference on High Strength Low Alloy Steels (HSLA Steels 2011) in Beijing, China, June.
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Visiting Prof Andy Howe, in his Tata Steel role, organised and co-hosted Tata Steels University Challenge event at Warwick on 11th January 2011 with strategic partner universities (Prof Mark Rainforth representing Sheffield). Wish-lists from the company were fielded for discussion with the represented Universities to help identify topics/ capabilities for short term assistance and for configuring the next round of PhD proposals. Prof Neil Hyatt was appointed to the Chair in Radioactive Waste Management from January 2011.
Highlights 2011
Emeritus Professor Frank R Jones Is Presidents invited Fellow of the Royal Aeronautical Society (FRAeS). Was also invited to be Honorary Professor at Deakin University, Victoria, Australia. Was OCE (Office of the Chief Executive) Distinguished Visiting Scientist at CSIRO (Commonwealth Science and Industry Research Organisation) Melbourne, Australia, September 2010-May 2011, where he continued his work on Self Healing Resins for use as matrices for composite materials. He was based in the Materials Science and Engineering (CMSE) laboratories, hosted by Dr Phil Casey and Dr Russell Varley. Was an invited keynote speaker at the Carbon Fibres Workshop organised by the Victorian Centre for Advanced Materials Manufacturing (VCAMM) and Deakin University held in Geelong. December 2010. He also gave a series of lectures: Smart Self -Sensing and Self -Healing Composites; Molecular engineering of Interfaces and Interphases in Fibre Composites; From Atoms to Aeroplanes and Automobiles Towards Multi-scale Modelling and Design of Composites. Gave research seminars at the Mawson Institute of University of South Australia, Adelaide; Deakin University, Geelong; RMIT, Melbourne; Australian Composites Structures Society and Composites Research Centre (CRC), at the CRC/ DSTO laboratory in Melbourne. Dr Plato Kapranos acted as external examiner on a PhD thesis at the Technical University of Mondragon, Spain. The theme of the work was An investigation on the reasons behind the lack of commercial applications of semi-solid manufacturing technologies in the European automotive market, based on the factors of productivity, competitiveness, quality and cost. Whilst there, he also spent one day carrying out experimental lab work on thixoforming low alloy steels, with his colleagues at Mondragon. Dr Hajime Kinoshita Completed a book chapter, Development of ceramic matrices for high level radioactive wastes, for the Handbook of advanced radioactive waste conditioning technologies. The book has been published in January 2011 from Woodhead Publishing, UK. Was invited to give a series of lectures on the pre-disposal technologies for radioactive wastes at the IAEAs training course in radioactive waste management to the participants selected by IAEA world widely, Clausthal, Germany12th-16th September. Gave an invited lecture, Ceramics or cements? Alternative cement systems and beyond at GLOBAL 2011, 11th-16th December, Makuhari, Japan, the special focus of which was he Fukushima Daiichi accident following the devastating earthquake and consequent tsunami attacked east Japan on 11th March.
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Prof Beverley J Inkson and Dr Lockwood have had an active collaboration with Prof M S Bobji and group at the Department of Mechanical Engineering, Indian Institute of Science (IISc), Bangalore India. Research exchange visits to India in July and visits of Prof Bobji and G Vikram to Sheffield in July and September/October have been funded by a joint NanoLAB-IISc UKIERI British Council NanoBALLS project. Has developed collaborations with China, and hosted academic visitors Prof Yong Peng, Lanzhou University Jan-Feb 2011, and Prof Xiang Kong from the Institute of Materials for Mobile Energy, Shanghai Jiao Tong University, June. Organised the meeting Nanoscale Effects in Tribology, (NET 2011), Sheffield, June 2011. This meeting attracted over 50 attendees, and was supported by the EPSRC, IOM3, IMechE, IET, NanoKTN, IOP, MaterialsKTN, HealthcareKTN and Nanofactory. Gave an invited talk, Squashing, sliding and melting Real-time dynamics of moving nanomaterials, at the In-situ Microscopy Workshop, Universitt Gttingen, Germany, November 2010. Gave an invited talk at the Institute of Physics Workshop Small Scale Tribology, London, May. Prof Inkson attended the EU-funded Trends in Nanotribology conference, at the International Centre for Theoretical Physics, Trieste, Italy, September, giving a talk Friction in action: nanoscale tribology inside electron microscopes. Is a Director of the RCUK Basic Technology Research Programme in Nanorobotics. Is Chair of the EPSRC UK NanoFIB Network: Nanoprocessing and nanoanalysis of materials using Focused Ion Beams. Is Deputy-Chair of the Nanomaterials Nanotechnology Committee of the IOMMM. and
Is a member of the EPSRC Peer Review College and also a member of the Editorial Advisory Board of the Elsevier Journal Materials Characterisation as well as a member of Scientific Programme Committee for the European Microscopy Congress (EMC 2012) and Chair of the Advances in Ion Microscopy Symposium. Was assessor for the German Research Foundation (DFG) and Netherlands Organisation for Scientific Research (NWO).
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Dr Michael Krzyzanowski Presented on new developments related to modelling of FSW process at the International Conference KomPlasTech 2011 in Katowice, Poland, supported among other by ECCOMAS (European Community on Computational Methods in Applied Science). He was involved in the International Scientific Committee and presented a paper co-authored with Prof W M Rainforth. Dr Feng Liu was chosen by the 6 participating laboratories of the European Science Foundations project SCALES to represent the Project at the event Frontiers in Chemistry: From Molecules to Systems held in Paris, 21st May with a poster entitled Complex Mesophases and Tiling Patterns in Self-Assembled Polyphiles. Speakers at this prestigious event included four Nobel laureates. Prof S MacNeil Gave the following presentations: Translational research in tissue engineering skin and other epithelial tissues, Specialised Medicine Research Afternoon. Medical School, Sheffield, 13th January. Applications of mechanical engineering to tissue engineering, Mechanical Engineering Research Day, Sheffield, 17th January. Tissue engineering from the lab to the clinic, Aston University, Birmingham, 4th March. Scaffolds for tissue engineering of skin and other epithelial tissues, Bristol University, 11th March.
Dr Steve Matcher Attended Biomedical Optics, Imaging, and Biophotonics conference (BIOS) 21st-26th 26 January in San Francisco. He gave a presentation Optic axis determination by fibre-based polarization-sensitive swept-source optical coherence tomography, and also a poster presentation, Performance comparison between 8 and 14 bit-depth imaging in polarization-sensitive swept-source optical coherence tomography. Attended European Conferences on Biomedical Optics (ECBO) 22nd-26th May in Munich, May. He gave a presentation, A method to calibrate phase fluctuation in polarization-sensitive swept-source optical coherence tomography, and also A theoretical framework for the analysis of optical anisotropy in birefringent biological tissues with polarization-sensitive optical coherence tomography. Also presented poster, Evaluation of a swept-laser optical coherence tomography light source based on a novel quantumdot based semiconductor optical amplifier. Prof Allan Matthews Was invited to write an editorial feature on Surface Engineering and a review article on Knowledge Transfer for Public Service Review: UK Science and Technology which is a pioneering publication addressing the key issues affecting the funding, application and success of the countrys science, research and technology base. Examined the the PhD Thesis of Xiao Ma (a former undergraduate student in the Department) at the University of Twente in The Netherlands on 11th February. The thesis title was Surface Quality of Aluminium Extrusion Products. He also visited the Tribology Laboratory of Prof D Schipper. Attended the Society of Vacuum Coaters Techcon Conference in Chicago USA, 16th-20th April. He participated in Conference Planning Meetings and co-hosted (with Dr B Sproul) a Technology Forum Breakfast on Tribological Coatings, as well as presenting a half-day Short Course on Tribological Coatings. He was co-author (with Dr John Eichler and Dr Adrian Leyland) of the Poster Paper A Comparative Study of Impact Testing Techniques and Results for Carbon Based Coatings. He also co-chaired the Tribological Coatings session at the conference. Attended the International Conference on Metallurgical Coatings and Thin Films (ICMCTF), held in San Diego, USA, 30th April3rd May together with PhD Students, Po-Jen Chu, Chen-Jui Liang and Omeniyi Fasuba. Their papers (co-authored with Dr Aleksey Yerokhin) were Effect of (Poly)Phosphate Anion Structure on Characteristics of Pulsed DC PEO Coatings on Ti, for Dye Sensitised Solar Cell Applications, Effects of Coating Morphology on in-situ Impedance Spectra of Plasma Electrolytic Oxidation Process and Galvanic Corrosion Behaviour of Al-Based Coatings in 0.6M NaCl Solution. Dr Adrian Leyland was also a coauthor on the last paper. Allan and Adrian were also co-authors (with research collaborators from Tecvac Ltd) on three other papers, An Investigation into the Effect of Triode Plasma Oxidation (TPO) on the Properties of Ti-6Al-4V, An Investigation into the Tribological Performance of PVD Coatings on High Thermal Conductivity Cu Alloy Substrates and The
Materials Science & Engineering, The University of Sheffield
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Biomaterials for tissue engineering and wound healing, Phillips, Eindhoven, The Netherlands, 25th March. 3D skin models to study infection and wound healing assisted by use of bioreactors for noninvasive imaging, 3rd Annual Quasi-Vivo User Group Meeting, Saarbrucken, Germany, 28th May. Biomaterials and tissue engineering for wound healing, 1st UK-India Symposium on Materials in the Eye, Ravenhall, UK, 25th July. Simplifying the Transfer of Cultured Limbal Stem Cells from the Lab to the Patient, The Cornea and Tissue Engineering, JSPS Sponsored Research Symposium, Cardiff University, 18th August.
Biomaterials Technologies for Tissue Engineering: Scientific and Clinical Impact, 24th European Conference on Biomaterials, European Society for Biomaterials, Dublin, 4th September. Biomaterials and tissue engineering for wound healing, University of Adelaide, 10th October. Tissue engineering of skin and biomaterials for wound healing, Invited talk at first annual meeting of Australian Collaborative Centre for Chronic wounds, Brisbane, 12th October.
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Highlights 2011
Effect of an Intermediate Electroless Ni-P Layer Prior to PVD Treatment. Attended and presented an Invited Plenary paper, Enhanced Tribo-contact Performance Using Plasma-Assisted Surface Engineering Processes, at the 6th China International Conference on Surface Engineering in Xian, China, 10th-13th May. He also Chaired a Plenary session at the Conference. Whilst in China, Allan visited Yanshan University in Qiuhuangdao, where he met Prof Yulin Yang, the VicePresident (who is one of Allans former PhD Students) and his colleagues. Presented a paper, Plasma-Based Surface Engineering for Automotive Applications, at the IMechE Conference Are you Slip-Sliding Away Your Profits? The conference was held at the University of Leeds on 11th April. Was awarded the Gold Medal at the IOM3 Premier Awards Dinner, at Carlton House Terrace, 12th July. The award is given for a company, team or individual who has made a significant contribution to the industrial application of materials. During his 35-year career in surface engineering, he has been instrumental in transferring laboratory-based technologies to industry. Prof Matthews established the UK Research Centre in Surface Engineering, which has developed coatings and surface treatments that are widely used in industry. His pioneering research on environmentally friendly plasma assisted vacuum deposition processes has prolonged the lives of cutting tools and improved productivity. He has pioneered vacuum plasma processes for the aerospace industry. Matthews work on plasma electrolytic deposition techniques has application in prosthetics and lightweight vehicle structures. Presented a talk, Industry Trends and Growing Markets in the UK, at the Surface Engineering Associations Annual Conference, in Meriden, 14th October. Spoke at Functional Surfaces, an IoP sponsored Seminar in Leeds, 14th November. The title of the talk was Enhancing Surface Functionality by Using Nanocomposite Coatings. Dr Guenter Mbus Gave an invited Departmental Seminar, 3D Imaging of Nanoobjects: time and energy resolved electron microscopy, at the University of Exeter, Department of Physics, 11th March 2011. Organised, together with the Royal Microscopical Society (RMS), the two-day workshop TEM & TOM III, 11th-12th April 2011, in Sheffield, Mappin Hall, including 4 presentations by group members Dr T Gnanavel, Dr U Bhatta, Dr W Guan, and Dr J Ghatak. Attended, on invitation, the workshop on Current topics in TEM: Tomography and Plasmonics in Tegernsee, Germany from 27th-29th July 2011, and gave an invited talk about Model based atomic resolution (and some other) tomographies. Chaired a session on Advances in imaging and spectroscopy at the Electron Microscopy and Analysis Group conference of the Institute of Physics (EMAG2011) in Birmingham, 5th-9th September 2011,
including 3 papers presented by group members Dr T Gnanavel, Dr W Guan and Dr U Bhatta. Attended the Microscopy Conference (MC2011) of the German Society for Electron Microscopy in Kiel, Germany, 29th Aug. 2nd Sept 2011 and presented 3 papers: Tomographic Nanofabrication with electron beams. Differential tilt between two specimen parts by an all piezo-electric miniaturised goniometer.
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Aberration corrected TEM of irradiation induced atomic hopping processes on various ceria surfaces onserved in-situ. Dr Krzysztof Muszka Attended the SIMULIA UK Regional Users Meeting in Crewe. Co-presented an Overview of Strain Path Effects (co-authors B P Wynne, E J Palmiere, W M Rainforth) at Tata Research Seminar, Swindon Technology Centre, Rotherham. Presented a paper, Influence of strain path changes on microstructure inhomegeneity and mechanical behaviour of wire drawing products at the 7th Pacific Rim International Conference on Advanced Materials and Processing, PRICM, Cairns, Australia. Presented a paper at the 13th International Conference on Metal Forming 2012 in Toyohashi, Japan. Presented a paper, Multiscale modelling of the mechanical response of dislocation structures developed using high straining at low deformation temperatures, at TMS 2011, Annual Meeting and Exhibition in Sand Diego, USA. Presented a paper at the 6th International Conference on High Strength Low Alloy Steels HSLA2011 in Beijing, China. Prof John Parker Attended a conference in Accra, Ghana, 15th-20th January, jointly organised by the Association of Commonwealth Universities and British Council; in the latter case the emphasis was on AKTPs, a scheme mirroring the British Knowledge Transfer Partnerships but with African Associates. Was an invited guest at the Central Glass and Ceramic Research Institute (a unit of CSIR), Kolkata, India, 3rd-5th August. He also presented an invited lecture, Modelling the optical absorption spectrum of glass at the International Conference on Specialty Glass and Optical Fiber: Materials, Technology and Devices, ICGF-2011, organised as part of their diamond jubilee celebrations. Gave a plenary lecture, Glass: colouring our view of life at the Lomonosov International Conference on the Chemistry of Glasses and Glass-forming Melts, 4th-8th September, organised at Lady Margaret Hall, the University of Oxford by the Society of Glass Technology in celebration of the 300th anniversary of the birth of Mikhail Vasilievich Lomonosov.
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Prof Mark Rainforth Presented the Opening Plenary, Design of Material Microstructure Through Optimum Processing, at the Swedish/Indian Workshop on Advanced Materials, Kolkata, India (2011). Attended the Wear of Materials Conference, USA in April and presented Wear of hydrogen free C/Cr PVD coatings and attended the WOM Inc steering committee. As part of his role as Visiting Professor visited Graz Technical University, June 2011 and delivered an MSc Course in the Austrian Centre for Electron Microscopy on Advanced Characterisation Techniques. Is Vice Chair of the forthcoming European Microscopy Congress (EMC 2012). Prof Ian M Reaney Gave invited talks: Intermediate Structures in Perovskites, Electronic Materials and their Applications, Florida, USA. Planar defects and phase transitions in RE-doped Bi Ferrite ceramics, Oak Ridge National Laboratory, STEM Group, Tennessee, USA.
at the Institute of Metal Research (IMR), Chinese Academy of Science, Shenyang, China. The main theme of the forum was Materials Challenges for Safety and Reliability, and the Symposium was divided into four topics, Design and fabrication of high-performance materials, Characterization and evaluation of advanced materials, Property and performance of advanced materials and Applications of advanced materials, including plenary presentations by 18 invited speakers. Attended Academic Council Meeting at the COMSATS University, Islamabad, Pakistan. Examined PhD thesis at the University of Aberdeen, Scotland. Dr Gwen Reilly Co-authored Poster with Jennifer E Edwards, Low magnitude, high frequency vibration modulates mesenchymal progenitor differentiation, which was presented at the 57th Annual meeting of the Orthopaedic Research Society, Long Beach, California, by Jennifer Edwards. Co-authored Poster with Robin Delaine-Smith and Sheila Macneil, Osteogenic media and fluid shear forces can induce osteogenic differentiation in dermal fibroblasts, which was presented at the 57th Annual meeting of the Orthopaedic Research Society, Long Beach, California, by Robin Delaine-Smith. Co-authored Poster with Mohsen Shaeri, S Philips and D Athey, Mechanical stimulation of mesenchymal stem cells in 3D scaffolds using oscillating fluid flow, which was presented at the 29th Annual meeting of the Society for Physical Regulation in Biology and Medicine, Miami Beach, USA by Mohsen Shaeri. Gave an invited lecture, Mechanobiology of Bone Tissue Engineering, at the Notre Dame University in London, Workshop on Interdisciplinary Biomedical Research. Gave a conference oral presentation, Cell membrane mechanosensors mediate in vitro matrix production: the role of the glycocalyx and the primary cilium, at the University of Oxford, MediTech: Advances in Biomechanics and Mechanobiological modelling. Co-authored Poster with William van Grunsven and Russell Goodall, Porous metal implants for enhanced bone in growth and stability, which was presented at the Tissue and Cell Engineering Society UK by William van Grunsven. Was Publication Committee Chair of the European Society of Biomechanics. A member of the International Editorial Review Board of the European Cells and Materials. Dr Conny Rodenburg Gave an invited talk, Energy selective secondary electron detection for the characterisation of polymerblends, at the Microscopy and Microanalysis conference, Nashville, USA, August. Gave a presentation, Energy selective secondary electron detection for the characterisation of polymer-blends, at the extraordinary seminar at the Fraunhofer Insititute for Nondestructive Testing IZFP, Dresden, Germany, August.
Materials Science & Engineering, The University of Sheffield
Highlights 2011 10
Intermediate Structures in Perovskites, German Physical Society Meeting, Dresden, Germany. Planar defects and phase transitions in RE-doped Bi Ferrite ceramics, TEM Workshop, Electron Microscopy; Exploring Materials on the Atomic Scale, Darmstadt.
Glass ceramics and metallisations in antenna applications, GHz Glass Ceramics Workshop, Darmstadt, Germany. Microwave Dielectric ceramics for mobile phone networks, University of Birmingham Seminar Programme, Birmingham, UK. Was external examiner for PhD Examinations: Rob Noble, University of Southampton, Department of Chemistry, June.
Ronald Mikkenie, University of Twente, Twente, Holland, June. Frederic Aguesse, Imperial College, Department of Materials, December. Study Visits: Department of Ceramics and Glass, University of Aveiro, April and July. National Institute of Standards and Technology, June.
Pennsylvania State University, Pennsylvania, USA, June. Dr Ihtesham ur Rehman Invited talk, FTIR and Raman spectroscopy of Biomaterials, characterisation of Advanced materials made simple, invited by Thermo Fischer at Warwick University. Represented the Department at the the 4th World Materials Research Institute Forum, which was held
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Highlights 2011
Dr Alfred Sidambe Attended the Euro PM 2011 Congress and Exhibition in Powder Metallurgy in Barcelona, Spain, 9th-12th October. He presented a paper, Fatigue Behaviour of Ti6Al4V and CP-Ti Components Processed By Metal Injection Moulding. Prof Derek Sinclair Attended Zing Conference Solid State Chemistry: New Functional Materials, Structures and Electrical Properties in Sharm el Sheikh, Egypt, 2nd February. Gave invited talks at Electronic Materials and Applications (EMA 2011, Florida) and Materials Science and Technology (MS & T 2011, Ohio). Both meetings were organised by the American Ceramic Society. Gave an invited seminar at the Center for Electronic Correlations and Magnetics at the University of Augsburg, Germany. Was also an invited guest lecturer to China in October 2011 to give a series of lectures (7 in total) on Solid State Chemistry and/or Electroceramics to Undergraduate and Postgraduate students in Xian (Key Laboratory of the Ministry of Education for Electronic Materials Research, Jiaotong University and The School of Material Science and Engineering, Northwestern Polytechnical University); Shenzhen (The College of Chemistry and Chemical Engineering, Shenzhen University); Shanghai (The Key Laboratory of Inorganic Coating Materials and Artificial Crystal Research Centre at the Shanghai Institute of Ceramics, Chinese Academy of Sciences); and Beijing (The College of Chemistry and Molecular Engineering, Beijing University; The Institute of Inorganic Chemistry, College of Chemistry and Molecular Engineering, Beijing University, The School
Dr Karl Travis Spent the month of August working at Swinburne University, Australia, as a Visiting Fellow in the Department of Mathematics, Faculty of Engineering. While at Swinburne, Karl initiated 3 collaborative projects: a project involving CSIRO modelling the separation of gas mixtures using nano-engineered graphitic filters, a project aimed at understanding the existence of a liquid state and a collaboration with Applied Physics Department at RMIT on obtaining the thermal conductivity of brines at elevated temperature and pressures using atomistic simulation. Gave two Departmental seminars, one at Swinburne, Modelling Phase Equilibria using Dissipative Particle Dynamics, the other at RMIT, Configurational and Kinetic Thermostats for use in Equilibrium and nonEquilibrium Atomistic Simulations. Dr Travis and James Miller attended a workshop, Non-equilibrium Processes: The last 40 Years and the Future held in Obergurgl, Tirol, Austria, 29th August-2nd September. Karl gave a presentation, Fragmentation of Liquid Droplets, while James gave a poster presentation, Modeling non-equilibrium properties in nuclear waste vitrification. The meeting was organised to honour the enormous contributions made by Denis Evans in the field of non-equilibrium Statistical Mechanics and to celebrate his 60th Birthday. Dr Travis and Dr Henry Foxhall attended the Materials Research Society XXXV International Symposium: Scientific Basis for Nuclear Waste Management meeting in Buenos Aires, Argentina 2nd-7th October. Karl gave a presentation, Deep Borehole Disposal of Higher Burn-up Spent Nuclear Fuels, while Henry gave a presentation, Topological analysis of accumulated radiation damage from multiple molecular dynamics recoil cascades. The highlight of the meeting was a trip to the Atucha Nuclear Power Plant where there was a once-in-a-lifetime chance to stand inside a reactor core. Dr Ignacio Figueroa Vargas, was named as a Runner-up for The 2009 James Clerk Maxwell Young Writers Prize for papers published during the year in Philosophical Magazine and Philosophical Magazine Letters. Ignacio was nominated by co-author, Professor Hywel Davies, for his paper, High Glass Formability for Cu-Hf-Ti Alloys with Small Additions of Y and Si [Ref I A Figueroa, H A Davies and I Todd, Phil Mag 89, 2355-2368 (2009). Prof Tony West Gave contributed talks at the Dielectrics Group meeting in Canterbury in April 2011 and at the British Association for Crystal Growth conference at University College London in July. Was a member of the Chemistry panel that visited Uppsala University in May 2011 to evaluate the Universitys research in Chemistry as part of the project Quality and Renewal 2011. He was a member of the international advisory panel for the European conference on solid state chemistry, Lund, Sweden, September 2011.
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Organised and chaired his own conference on solid state chemistry in Lanzarote, February 2012. He gave a plenary lecture at the European meeting on ferroelectrics, Bordeaux, France, June 2011 and organised a session at the Institute of Physics dielectrics conference, Canterbury, April 2011. Emeritus Professor Peter Wright was awarded the Galileo Galilei Award for Energy Conversion by Ion Conduction at the 12th International Symposium on Polymer Electrolytes (ISPE-12) in Padua, Italy. This is a new Galileo Galilei award.
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Retired Staff
Research has included a number of themes based around structure, crystallisation and optical properties. Current major topics are glass colour and how specific ions can act as probes for local structure associated with segregation such as complex formation or fictive temperature behaviour. A particular interest is the modelling of absorption spectra as an aid to composition design for glass makers particularly when using high fractions of recycled glass. An ongoing interest is how the formation of nanocrystals within a matrix can influence the environment of dopant ions and produce specific optical effects.
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Dr Michael I Ojovan
MSc PhD DSc FRANS FMRS MSGT Reader in Materials Science and Waste Immobilisation Research interests focus on physics of metastable states, structure and properties of disordered systems and Rydberg matter, radiation-induced effects in solids. Recent work has included analysis of durability and long term performance of nuclear waste immobilising glasses and glass-composite materials, development of nuclear waste processing techniques including thermochemical decontamination and self-sustaining immobilisation.
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Materials Science and Engineering The University of Sheffield Sir Robert Hadfield Building Mappin Street Sheffield S1 3JD United Kingdom Tel: +44 (0)114 222 5941 Fax: +44 (0)114 222 5943 www.shef.ac.uk/materials
Every effort has been made to ensure the accuracy of the information given in this publication. However, the university reserves the right to make changes.