Iit-Jee 2012 Fst1 p1 Solns

SOLUTIONS
TO

B-MAT FULL TEST-I
FOR OUR STUDENTS
TOWARDS
IIT-JOINT ENTRANCE EXAMINATION, 2012

PAPER I & II

CHEMISTRY - PHYSICS - MATHEMATICS
1
Brilliant Tutorials Pvt. Ltd. IIT/B.MAT1/CPM/P(I)/Solns
CHEMISTRY
TEST-I
PART-I
SECTIONI
Single Correct Choice Type

1. (B) For 3d orbital, n = 3 and = 2
Number of angular nodes (nodal plane) = = 2
Number of spherical nodes = n 1 = 3 2 1 = 0

2. (D)
P
P
0
reaction
reaction
T
E
nF
T
G
S

=

( )
1 3
JK 6 . 231 10 2 . 1 96500 2

= =

3. (C)
OH
H
2
OH
H O
Cl
H
O
Cl
Cl
Cl
H
H
Cl
O
Cl
Cl
O
Cl
Cl
O

O
Cl
OH
Cl
O
OH
Cl
COOH

4. (B) Let initially volume of solution = 100 ml.
mass of solution = 1.8 100 = 180 g mass of solute = 0.24 180 = 43.2 gm.
Let amount of water added be x.

2 2
H O H O
M xgm, V x ml. = =
On dilution, mass of solute remains same.
( ) 2 . 43 x 180
100
9
= + .
300 x = density of diluted solution = gm/cc 2 . 1
400
480
300 100
300 180
= =
+
+

5. (D)

6. (D) 3 moles of Phenyl hydrazine are used.
2

7. (D)
) aq ( Cl CH
3
+ OH

) aq ( OH CH
3
+
Cl
Initial concentration 0.05 0.1 0 0
Equilibrium concentration ~0 0.1 0.05 0.05 0.05
As equilibrium constant is very large the reaction will be almost 100% complete.

SECTIONII
Multiple Correct Choice Type

8. (A, B, D)

9. (A, C)
[ ]
3
4
Fe FeCl
+
is
5 0
3d 4s , Cl
is a weak field ligand. Hence, hybridization of Fe is

3
sp .
This is a tetrahedral complex. It is paramagnetic species having 5 unpaired electrons.
[ ]
2
4
NiCl is
3
sp hybridized. Paramagnetic Ni
+2
is 3d
8
4s
0
. It has 2 unpaired electrons.

10. (A, C)

11. (A, B, C, D)
(A) Tischenko reaction
(B)

CH
3
COOH +
CH
2
NN
CH
3
COO
+ CH
3
NN CH
3
COOCH
3
+ N
2

(C)

CH
3
CCl + C
2
H
5
OH CH
3
COOC
2
H
5
+ HCl
O

(D) Claisen condensation.

SECTIONIII
Paragraph Type
Paragraph for Question Nos. 12 to 13
12. (C) If water is used then
3 3 2 2 1 1
V N V N V N = +

3
V
6 . 5
8 . 16
2
6 . 5
6 . 33
2
6 . 5
6 . 5
= +
or,
3
14
V
3
=
litre. 67 . 0
3
2
4
3
14
V
w
= = =

13. (D)
2 2 2 2
O
2
1
O H O H +
Moles of 7 2
2 . 11
6 . 33
2
2 . 11
6 . 5
O H
2 2
= + =
3
Moles of
2
7
O
2
=
Volume of O
2
at STP L 4 . 78 4 . 22
2
7
= =


14. (B) Radius of sphere = R
Radius of octahedral void = r
In close packed arrangement r = 0.414 R

15. (D) In fcc arrangement of anions effective number of anions in an unit cell is

1 1
8 6 4
8 2

+ =

Since cation and anion have 4 : 4 coordination, no. of cations per unit cell must also
be 4.
In otherwords, the cations occupy the alternate tetrahedral voids.

16. (C) For bcc lattice Z = 2; a = 400 pm = 400 10
10
cm
density =
3 30 3 23 30
0
ZM 2 100
a N 10 (400) 6.02 10 10

=

2
1
2 10
64 6.02 10
=

2000
385.28
=
= 5.19 g/cm
3

SECTION IV
Integer Type

17. Total work done = Area of circle A Area of circle B
= 25 20 = 5 unit.
Ans. 5

18. Rate = [ ] [ ]
2
2
H O PhCHO
Ans. 4

19. In solid state SO
3
exists as

S
O
S
O
O
S
O
O
O
O
O
O

Ans. 6
4

20. O = C = C = C = O
All bonds are covalent not co-ordinate covalent (dative) bonds
Ans. 0

21. DMSO is polar solvent benzoic acid will dissociate only.
Ans. 0

22.
N
N
N
N

Ans. 4

23. 1 PO H , 2 PO H , 1 BO H , 3 PO H
2 3 3 3 3 3 4 3

Ans. 7

5
PHYSICS
PART-II
SECTIONI
24. Balancing torque about hinge
53 sin
2
2
kxl
iBl
=
k
iBl
x
8
5
=
Energy Stored =
2
2
1
kx
k
l B i
2 2 2
128
25
=
(C)

25. K W W W W
spring N f g
= + + +
( ) ) (
2
1
2
1
0 ) 37 cos 50 . 5 . 0 ( 37 sin 50
2 2 2
0
i f m
x
m
v v m kx dx x x
m
= +

(At the point of max. elongation v = 0)
0 5 10 30
2 2
=
m m m
x x x

m m
x x 5 10 30 + =
30 15 =
m
x
2 =
m
x m
(C)

26. r
R
i
B
in
|
\
|
=
2
0
2
=
R
ldr r
R
i
0
2
0
2
4
0
li
=
(A)

27.
20
1
) 25 (
1 1
+
v
cm 100 = v
4
25
100
=
|
\
|
= m
0
1 1 1 1 1
2 2
= = +
dt
dx
x dt
dy
y f x y

0
2
0
2
2
v m v
x
y
v
i
=
|
|
\
|
=
cm/s 2
, 0
=
m
v
s cm v m v
m m i
/ 32
, 0
2
,
= =
2 32
,
+ = + =
m m i i
v v v

= cm/s 30
cm/s 34 4 30
0 0 ,
= = = v v v
i i

(B)
6
28. gh a
dt
dh
x 2
2
= |
\
|

=
0 2 2
0
2
] ) ( [
R
t
gh
dh h R R
dt a

g a
R
t
15
2 7
2 / 5
=

h
dh x
O
R

(C)

29. Q = dr r
R
r
dr r
R
R
R
2
2
2
2 /
0
4 1 2 . . 4
(
+ =
24
11
6
3 3
R R
+
3
8
5
R =
(C)

30.

40 cm
B
5cm
A
5cm
f = 20cm
5cm
A
40 cm
5cm
4cm
10cm
3cm
B

For B,
20
1
36
1 1
=
v

45 = v cm

8 4
5
36
45 I
u
v
m =
= =
10 = I
A B= 2 5 ) 5 ( ) 5 (
2 2
= +
(B)

SECTIONII
31. 18
20
T
=
V
V

6
20
T
=
+ V
V

Solving 40 = V km/hr
T = 9 min
(B), (C)

32. Till reaches angle of repose
f = mg sin , N = mg cos
c
f mg. =
7
For exceeding angle of repose
f = mg cos , N = mg cos
( )
2
1 + =
c
f mg cos
(A, D)

33. Between 0 = t to 2 = t + + , speeding up
2 = t to 4 = t + , speeding down
4 = t to 5 = t , speeding up
(A, C)

34. k =
0

k
dt
d
=
0

=
t
t
k
k
dt
k
d
0 0
0
0 0
ln
1

[ ]
kt
e
k
= 1
0

kt
e
dt
d

= =
0

(A, C)
SECTION III
Paragraph Type
Paragraph for Question Nos. 35 & 36
35. Using

B B A A
V P V P = ( )

0
0
0 0
16 .
32
) 2 .( V
P
V P =
( )
= 16 ) 2 ( 32

3
5
=
(A)

36.
1
2
1
Q
Q
=
In isobaric process
T nC Q
p
=
(
\
|
+ =
nR
V P
nR
V P
R R
f
n
i i
f f
2
= [ ]
i i f f
V P V P
f
\
| +
2
2

[ ]
0 0 1
2
5
2
2
V P V P V P
f
Q Q
i i f f DA
= |
\
| +
= =
[ ]
0 0 2
8
5
2
2
V P V P V P
f
Q Q
i i f f BC
= |
\
| +
= =

4
3
=
(C)
8
37. As there is no ext. force
0 =
cm
a 0 =
cm
V 0 =
cm
x if
1
x and
2
x and displacement of
1
m and
2
m then,

2
0
2 1
x
x x = + (i)

2 1 2 2 1 1
2mx mx x m x m = = (ii)

3
0
1
x
x =
(A)

38. As momentum will be same for both,

m
p
K
2
2
=
1
2
1
2
2
1
= =
m
m
K
K

(A)

39. WD by spring force on B = KE of B.
) (
2
1
) 2 (
2
1
2
1
2
0
2
2
2
1
x k v m mv = + and
2 1
2v v =

6
) 2 (
2
1
2
0 2
2
kx
v m =
(B)
SECTION IV
Integer Type
40. ,
0
N
N
P
A
=
0
0
N
N N
P
B
=

A B
P P 15 =

0 0
0
15
N
N
N
N N
=

N N 16
0
=
Ans.: (4)

41. Energy of electron in nth orbit
2
n
2
Z Rhc
E ,
n
=
R Rydberg constant of hydrogen atom.
E = E
3
E
2
= 47.2 eV
= Z
2
Rhc
1 1
4 9
(
(

=
2
5
Z Rhc
36

9
Z
2
=
36 47.2
5Rhc
But Rhc = 13.6 eV.

=
36 47.2
5 13.6

= 25 or Z = 5
ionization energy = Z
2
Rhc
Hence
0
hc
25Rhc 340.0 eV = =

34 8
0
19 19
hc 6.6 10 3 10
340 1.6 10 34 16 10

= =

= 36 10
10
m
= 36
= 4n
n = 9
Ans: (9)

42. Given
2
10I
dt
dI
L =

=
t
dt
I
dI
L
0
2
25 . 1
5 . 2
10
2 = t ms
Ans.: (2)

43. For an adiabatic process,
dV P dU dQ + = [ ] 0 = dQ
or 0 ] [ = + + dV P bPV a d
or 0 = + + dV P dP bV dV bP
or 0 ) 1 ( = + + dP bV dV P b
or 0 ) 1 ( = + +
P
dP
b
V
dV
b
or = + + P b V b log log ) 1 ( constant
=
+ b b
P V
1
constant
or =
+
b
b
PV
1
constant

b
b 1 +
= 33 . 1
3
4
= =
[] = 1
Ans.: (1)

10
44.
2 2 1 1
r r = (i)
As separation between teeth remain
constant

1
2
r2
r1

2
2
1
1
2 2 r
N
r
N

= (ii)
From (i) and (ii)

1
2
2
1
N
N
=

20
40
4
1
2
1 2
= =
N
N
= 8
Ans.: 8

45.
(
\
|
=
20
1
10
1
1
1
5 . 1 1
f
40 = f
2
40 20
40
=
+
=
+
=
f u
f
m
Ans.: 2

46.
0
0
4
4
I
I
I
P
= =
+ + = cos . 2
0 0 0 0
I I I I

D
d y
.
2
3
2
2
1
cos
= =

d
D
y
3
2
2

=
x = 3
Ans.: 3

11
MATHEMATICS
PART - III
SECTION I
47. (C)
dx
dy
dy dx dy
d
dy dx dx
d
dx
y d
|
|
\
|
=
|
|
\
|
=
/
1
/
1
2
2

( )
2
2
3
/
1
dy
x d
dy dx
=
The given equation becomes
0
3
2
2
= +
|
|
\
|
dy
dx
y
dy
dx
dy
x d

0
2
2
2
=
|
|
\
|
dy
dx
y
dy
x d
.

48. (B)
|
|
\
|
|
|
\
|
=
1
2
1
2
ae
be
ae
be
m m
BC AB

1
1
1
2
2
2
2
2
2
=
|
|
|
|
\
|
+
+
=
a
b
b
a
a
b

ABCD is a square.

A
(ae
1
,0)
C
(ae
1
,0)
D (0,be
2
)
B (0,be
2
)

Area ( ) ( )
2 1 2 1
2 2 2
2
1
e abe be ae = =
( )
2 2
2
2 2
2
2 2
2 2 b a
a
b a
b
b a
ab + =
+ +
= .

49. (C) Any normal to x y 4
2
= is
3
2 m m mx y = .
It passes through (9, 6).
0 6 7
3
= m m 3 , 2 , 1 = m
1
1
= m , 2
2
= m , 3
3
= m
0
11
= a , 0
22
= a , 6
33
= a .

50. (C)
r
n
r
r
n
r k
r
r
r
r
r
k
C C C C C + + + + =
+
=
+
...
2 1

r
n
r
r
r
r
r
r
C C C C + + + + =
+ +
+
+
...
2 1
1
1

r
n
r
r
r
r
C C C + + + =
+
+
+
...
2
1
2

1
1
+
+
=
r
n
C
12
( )

=
+
+
=
n
r
r
n
C n f
0
1
1

1
1
2
1
1
1
...
+
+ + +
+ + + =
n
n n n
C C C
1 2
1
=
+ n

( ) 31 . 11 . 3 1023 1 2 9
10
= = = f
Hence, number of divisors ( ) ( ) ( ) 8 1 1 1 1 1 1 = + + + = .

51. (B) Put t x 2 cos = .
( )dt t t e I
t
cos 3 sin 2 2
2 / 1
2 / 1
2
+ =

( ) ( )dt t e dt t e
t t
cos 3 2 sin 2 2
2 / 1
2 / 1
2
2 / 1
2 / 1
2

+ =
dt t e
t
cos 12
2 / 1
0
2
=
dt t e
t
cos 12
2 / 1
0
2
=
( )
(
\
|
+ = + = 2
2
1
sin
2
1
cos 2
5
12
sin cos 2
5
12
2 / 1
0
2
e t t e
t
.

52. (C) Let
7
5
log
5 = x and
5
7
log
7 = y
7 log log
5 5
= x

5 log
1
5 log
log
7
7
7
=
x

y x
7 7 7
log 5 log log = =
y x = .

53. (A) ( ) 1 5
2 3
+ = x x x x f
( ) 5 2 3 '
2
+ = x x x f
( ) ( ) 5 3 1 + = x x
Sign scheme for ( ) x f ' is

+ +
1 5/3

13
Graph of ( ) x f y = is as shown.
It is clear from the graph that
2 1 , 0 1 , 2 3 < < < < < < .
[ ] [ ] [ ] ( ) ( ) ( ) 3 1 1 + + = + + .
3 =

y
x

3

1 2 5/3
2
1

SECTION II
54. (A, B, C)
( ) [ ] [ ] x x x f =

( )

=
elsewhere , 0
, 1 , , 1 N a a a x

55. (A, C)
Let k a j a i a a

3 2 1
+ + =

i a k a j a

3 1
=

2
3
2
1
a a + =
Similarly,
2
3
2
2
a a i a + =

and
2
2
2
1
a a k a + =

( )
2
2
3
2
2
2
1
2
2 2 a a a a p

= + + = .
The rectangle is a square.
Area
2
a
= .

56. (B, D)
( ) ( ) ( ) ( ) ( ) ( ) n m x n m x x x f
n m
+ + =

2 2 1 '
1 1

The critical points are
n m
n m
x
+
+
=
2
, 2 , 1 .
For the given condition, 1 m and 1 n must be odd.

57. (A, B, C, D)
One of the bisectors makes an angle
2 2
+
=

+ with
the x-axis, and the other one makes an angle
2
90
+
+ with
the x-axis.

()/2

Let
2
+
= .
14
Then
|
\
| +
+ =
2
90 cos = sin and
|
\
| +
+ =
2
90 sin = cos .
If
|
\
| +
=
+
+ =
2
cos ,
2
90 ( ) = = sin 90 cos .

SECTION III
Paragraph Type
Paragraph for Question Nos. 58 & 59
58. (A)

59. (B)

Sol.: nPB PA =
( ) ( ) [ ]
2 2 2 2 2
y a x n y a x + + = +
( ) 0 2
1
1
2
2
2
2 2
= +
|
|
\
|
+
+ + = a ax
n
n
y x S

2
2
2
2 2
1
1
2 0 a
n
n
a a S
A
+
|
|
\
|
+
+ + =
0
1
4
1
1
1 2
2
2 2
2
2
2
<
=
|
|
\
|
+
+ =
n
n a
n
n
a , since 1 0 < < n .
A lies inside the circle.

2
2
2
2 2
1
1
2 0 a
n
n
a a S
B
+
|
|
\
|
+
+ =
0
1
4
1
1
1 2
2
2
2
2
2
>
=
|
|
\
|
+
=
n
a
n
n
a
B lies outside the circle.
0
1
4
2
2 2
>
=
n
n a
S
A
, since 1 > n .
0
1
4
2
2
<
=
n
a
S
B

A lies outside the circle and B lies inside the circle.


60. (D)

61. (C)
15
62. (B)
Sol.:

|
\
|
|
\
|
|
\
|
= +
7
5
cos
7
3
cos
7
cos 8 1 4 4 8
2 3
x x x x x x
Put 1 = x .

|
\
|
|
\
|
|
\
|
=
14
5
cos 2
14
3
cos 2
14
cos 2 8 7
2 2 2

8
7
14
5
cos
14
3
cos
14
cos =

.
Replacing x by
x
1
in the given equation, we get
0 8 4 4
2 3
= + x x x having roots
7
3
sec ,
7
sec

and
7
5
sec

.
Put 1 1 sec tan
2 2 2
= = = x y in this equation to obtain the equation having roots
7
3
tan ,
7
tan
2 2

and
7
5
tan
2

.
( ) ( ) 2 4 4
2 2
= x x x ( ) ( )
2
2
2
2 2
2 16 4 = x x x
( ) ( ) ( )
2 2
1 16 3 1 = + y y y 0 7 35 21
2 3
= + y y y
The equation 0 7 35 21
2 3
= + x x x has roots
7
3
tan ,
7
tan
2 2

and
7
5
tan
2

.
Replacing x by
x
1
in this equation, we get
0 1 21 35 7
2 3
= + x x x having roots
7
3
cot ,
7
cot
2 2

and
7
5
cot
2

.

= =
|
\
|
|
\
|
3
1
2
3
1
2
7
1 2
cot
7
1 2
tan
r r
r r
( ) ( ) 105 5 21 = = .

SECTION IV

Integer Type
63. ( )

=
=
20
0 k
k
k
x A x f
( ) ( ) ( ) ( ) ( ) x f x f x f x f x f
r
r 6 2
6
0
... + + + + =
=

( ) ( )

= = =
+ + + =
20
0
6
20
0
20
0
...
k
k
k
k
k
k
k
k
k
x A x A x A

( ) ( )
6
1 0
... 1 7 + + + + = x A A ( ) + + + + + + ... ... 1
12 2 2
2
x A ( )
120 20 20
20
... 1 + + + x A
( ) ( ) ( ) 7 7 7
14
14
7
7 0
x A x A A + + =
( )
14
14
7
7 0
7 x A x A A + + =
7 = n
Ans. 7
16
64. Let the roots be , .
q p = = + ,
Now, and are primes and p is odd. This is possible only when one of the roots is 2.
Let 2 =
p = + 2 and q = 2
35 = + q p 33 3 = 11 = .
Ans. 9

65. Let p and 1 + p be removed.

( )
( )
4
105
2
1 2
2
1
=
+
+
n
p
n n

0 206 8 103 2
2
= + p n n
Since n and p are integers, n must be even.
Let k n 2 =

( )
4
1 103
2
k
k p

+ =
Since p is an integer, k 1 must be divisible by 4.
Let 1 4 + = t k . Then 1 95 16
2
+ = t t p .
Now, n p < 1
2 8 1 95 16 1
2
+ < + t t t
6 = t

2
5 2 50 = = n
No. of odd divisors ( ) 3 2 1 = + = .
Ans. 3

66. DRs of the line are given by k i
k j i

2
4 3 2
2 1 1

+ = . Hence the D.Rs are 2, 0, 1
Putting 0 = z in the equations of the two planes, we get
2 , 5 = = y x .
Hence, a point on the line can be taken as ( ) 0 , 2 , 5 .
The required shortest distance
( )
2

2
1 0 0
1 0 2
0 2 5
=
+
=
k i k
.
Ans. 2
17
67.
2
cos 4
2
cos
2
sin
2
cos 4
2
cos
2
cos
2
sin 4
2
2 1
C
R
C B A
R
C B A
R r r = + = + .
Similarly,
2
cos 4
2
3 2
A
R r r = + and
2
cos 4
2
1 3
B
R r r = + .
( ) C B A R c b a sin sin sin 2 + + = + +

2
cos
2
cos
2
cos 8
C B A
R =
or
2
cos
2
cos
2
cos 64 4
2 2 2 2 2
C B A
R s =

2
cos
2
cos
2
cos 16
2 2 2 3 2
C B A
R s R = .
Ans. 4

68. Let the radius be r.
( ) 0 , 1 r C + =
Equation of circle is ( )
2 2 2
1 r y r x = +
( ) ( )
2 2 2
4 1 1 2 r x r x r x = + + + +

C (1,0)

( ) ( ) 0 1 2 1 2
2
= + + r x r x
0 = D ( ) ( ) 1 2 4 1 4
2
+ = r r
0 4
2
= r r r = 4.
Ans. 4

69.

=
= =

|
\
|
|
|
\
|
|
\
|
|
|
\
|
|
\
|
=
n
r
n
r
n
r
n
n
r
n
n
r
n n
r
n
I
1
6
1
3
1
2
1
1 1
lim

12
7
1
0
6
1
0
3
1
0
2
=
|
|
\
|
|
|
\
|
=

dx x
dx x dx x
.
Ans. 7

Iit-Jee 2012 Fst1 p1 Solns

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Iit-Jee 2012 Fst1 p1 Solns

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SOLUTIONS

is a weak field ligand. Hence, hybridization of Fe is

But Rhc = 13.6 eV.

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