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Dissertation 2001

Dissertation 2001

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Sulfinylamines of main-group elements have been used as excellent pre-cursors for the synthesis of substituted sulfur-nitrogen compounds, chain as well as ring molecules, and thus have been proven to be molecules of high synthetic potential.
Sulfinylamines of boron are hardly known with the exception of the two mono-substituted derivatives described by Haubold and co-workers
(W. Haubold, H. G. Fehlinger, G. Frey, Z. Naturforsch. 1980, 35b, 792 - 796).
Here, the results of recent developments in the chemistry of sulfinylamino-boranes are presented with emphasis on the subsumption of these results into existing knowledge.
Also, with the intention of finding alternative pathways to sulfinylaminobo-ranes some other new boron compounds have been synthesized.
Vibrational, mass spectroscopy and NMR (1H, 11B, 13C, 14N, 17O, 19F and 29Si) data are mostly given.
Sulfinylamines of main-group elements have been used as excellent pre-cursors for the synthesis of substituted sulfur-nitrogen compounds, chain as well as ring molecules, and thus have been proven to be molecules of high synthetic potential.
Sulfinylamines of boron are hardly known with the exception of the two mono-substituted derivatives described by Haubold and co-workers
(W. Haubold, H. G. Fehlinger, G. Frey, Z. Naturforsch. 1980, 35b, 792 - 796).
Here, the results of recent developments in the chemistry of sulfinylamino-boranes are presented with emphasis on the subsumption of these results into existing knowledge.
Also, with the intention of finding alternative pathways to sulfinylaminobo-ranes some other new boron compounds have been synthesized.
Vibrational, mass spectroscopy and NMR (1H, 11B, 13C, 14N, 17O, 19F and 29Si) data are mostly given.

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Categories:Types, Research, Science
Published by: Dr. Bernd Stange-Grüneberg on Mar 30, 2009
Copyright:Attribution Non-commercial

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02/01/2013

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Beitr\u00e4ge zur Chemie der Bor-Stickstoff-Verbindungen
Synthesen und Reaktionen von N- Sulfinylaminen des Bors
Wege zu geeignet en Vorst ufen
Dissertation
zur Erlangung des Grades eines
Dokt ors der Naturwissenschaften
der Abteilung f\u00fcr Chem ie
der Ruhr-Universit\u00e4t Bochum
vorgelegt von
Diplom -Chem iker
Bernd Stange
aus Wattenscheid
Bochum 2001
Refer en t:
Prof.em . Dr.m ult. Dr.h.c. A. Haas
Korr efer ent:
Prof. Dr. W. S. Sheldrick
Dr itt pr \u00fcfer :
Prof. Dr. M. Muhler
Tag der Disput at ion:
7. Februar 2001
Die vorliegende Arbeit wurde in der Zeit zwischen
Juni 1995und M\u00e4rz 1998am
Lehrst uhl f\u00fcr Anorganische Chem ie IIde r
Ruhr-Universit\u00e4t Bochumdurchgef\u00fchrt .
Meinem hochverehrten Lehrer,
Prof.em . Dr.m ult. Dr.h.c. A. Haas,
danke ich f\u00fcr die int eressant e Them enst ellung,
die imm erw\u00e4hrende Unterst\u00fctzung
und seine st et e Diskussionsbereitschaft
w\u00e4hrend der Anfertigung dieser Arbeit.

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