The quantum effects can begin to dominate the properties of matter as size isreduced to nanoscale. These can affect the optical, electrical and magnetic behaviour of materials particularly as the particle size approaches the smaller end of the nanoscalewhich is due to the confinement of electrons within particles of dimension smaller thanthe bulk electron delocalization length, this process is being termed as quantumconfinement .
For other materials such as crystalline solids, as the size of their structuralcomponents decreases, there is much greater interface area within the material; this cangreatly affect both mechanical and electrical properties. For example, most metals aremade up of small crystalline grains; the boundaries between the grain slow down or arrestthe propagation of defects when the material is stressed, thus giving it strength. If thesegrains can be made very small, or even nanoscale in size, the interface area within thematerial greatly increases, which enhances its strength. For example, nanocrystallinenickel is as strong as hardened steel. Understanding surfaces and interfaces is a keychallenge for those working on nanomaterials, and one where new imaging and analysisinstruments are vital.
1.3 Nanomaterial Science
Nanomaterials are not simply another step in the miniaturization of materials.They often require very different production approaches. There are several processes tocreate nanomaterials, classified as ‘top-down’ and ‘bottom-up’. Although manynanomaterials are currently at the laboratory stage of manufacture, a few of them are being commercialized.Below we outline some examples of nanomaterials and the range of nanosciencethat is aimed at understanding their properties. As will be seen, the behaviour of somenanomaterials is well understood, whereas others present greater challenges.3