• Embed Doc
  • Copy Link
  • Readcast
  • Collections
  • 2
    CommentGo Back
Download
 
t (min)20406080100120x (mmol)0.20.40.60.81
 

II:
""""        """"
L’eau de Javel et l’eau de Dakin
: 
      :
51
 
:
ClO
(
aq
)−
 / 
Cl
(
aq
)−
O
2
(
g
)
 / 
 H 
2
O
(
l
)
.
  :
R=8,314u.S.I
    
25°C:
 
K
e
= 1,00.10
-14
 
                
ClO
(
aq
)−
  
Cl
(
aq
)−
 
 Na
(
aq
)+
 
 HO
(
aq
)−
.       
                      "    " 
liqueur de Dakin
1
(  :     .                     : 
)(2)()(
22
gaqaq
OClClO
+→
−−
      
5
      
(S
0
)
    
V = 250ml
 
(S
1
)
.        
V
1
= 20,0ml
 
(S
1
)
        
T = 300 K 
      
t
   
P(t)
 .    .       
V
0
.   
t = 0 min
P
0
:
1.1
(       .
12  
(       
010203
,,
nnn
    
ClO
(
aq
)−
Cl
(
aq
)−
O
2
(
g
)
 
112
( 
 
n
02
 
n
03
   .
212
( 
n
0
           
n
03

n
0
 
312
(   
 x
 f 
        . 
13
(       
x(t)
   : 
( )
T  RV Pt P t  x
..)()(
00
−=
 
14
(          
x(t)
   
1
)( 
114
(  
v(t)
   
t214
(              . 
314
(     
(S
0
)
    :
0
2 1( )
5,0.10 .
aqS
ClO mol L
− − −
=
.  
n
01
 
.          . 
 
 
2
. : """                 
(S
2
)
  
3
 NaHCO
        
3,00.10 
-1
mol.L
-1
 
3,00.10 
-2 
mol.L
-1
.
12
(         
ClO
(
aq
)−
 .  
K 
 A
1
   . 
22
( 
pH 

(S 
2 
 )

10,3 pH 
1
= 

 pK 
 A
1
=
 7,3 
. 
[ ]
[ ]
 HAClO
−

[ ]
 HA
   
ClO
(
aq
)−
.   
32
(    
 HCO
3
(
aq
)−
 / 
CO
3
(
aq
)
2
−
 
K 
 A
2

 pK 
 A
2
=
10,3 .
.  
 HCO
3
(
aq
)−

 HO
(
aq
)−
 
(S 
2 
 )
.
132
(     
 HCO
3
(
aq
)−
 HO
(
aq
)−
. 
232
(    
K 

K 
 A
2
K 
e
  . 
42
( 
142
(   
pH 
 
pH
2
= 9,3
. 
242
( 
pH
   
pH

(S
2
)
.
342
(   
[ ]
[ ]
 HAClO
−
. 
442
(                  . 
1
( :     .
1.1
    
2 2
 /  / 
ClO ClO H O
− −
 
22 2
2 22 4 4
لاإ ةآأ 
ClO H e Cl H O H O O H e
− + − −+ −
+ + → + → + +
 
12(112(
 
n
02
 
n
03
   : 
ClO
-
    ""               
O
2
Cl
-
           .
 
212
( 
   
n
0
      )   (: 
  
O
2
  
1/5
:
0 0 003
5 5 .
n PV n RT 
= =
 
13
(    : 
0 00 00 000 0
( ) ( ) ( ) ( )( )( ) ( ), ( )( ( ) )( )
T T 
n t n x t x t n t nPV P t V  x t 
و 
T T  
ٍ و 
V V  
 RT RT P t P V  x t 
و 
 RT 
= +
⇒
= −= − = =−=
 
0 00 0 0 0
..
PV PV n RT n RT 
=
⇒
=
 
 
14
(            
x(t)
   
1
 
114
(      : 
214
(           . 
                  .          . 
314
(     
(S
0
)
    : 
0
2 1( )
5,0.10 .
aqS
ClO mol L
− − −
=
 
•
: 
n
0
= 0,2 mmol =2.10
-4
mol
•
   :
01
2( )3 40 ( ) 0 0
5,0.10. . .20.10 2.105 5
aqSaqS
ClOn ClO V V mol
−−− − −
= = = =
 
2
. : """
12
(       
ClO
(
aq
)−
 
  
HClO 
 
2 331
.
aq aqéq éq Aaqéq
 HClO H O H O ClO H O ClOK  HClO
+ −+ −
 →+ +← 
=
 
22
(: 
( )( )
1
( ) ( )1 1( ) ( )( )( )( )10,3 7,33 3( ) ( )( )
log log1010 10 10 .
 A
aq aqéq éq A Aaq aqéq éqaqéqpH pK aqéqaqéqaq aqéqéqaqéq
ClO ClO pH pK pH pK  HClO HClOClO HClOClOClO HClO HClO
− −−−−−−
= + ⇔ = −
  ⇒
=
= = ⇔ =
  ) ( 
of 00

Leave a Comment

You must be to leave a comment.
Submit
Characters: ...
02 / 05 / 2010This doucment made it onto the Rising List!
PHYTANJA فيزياء طنجة

التمرين II : " ماء جافيل وماء" داكين L’eau de Javel et l’eau de Dakin

reply04 / 02 / 2009
You must be to leave a comment.
Submit
Characters: ...