determinacion potenciometrica del potencial formal

ml k4[(fecn)6] fem

fem

fem

media fem

[ferri]

[ferro]

1
2
3
4

303.5
283.6
272.9
265.7

303.2
283.7
272.9
265.6

303.4
283.9
272.9
265.7

303.4 0.02741935 0.00806452

283.7
0.0265625
0.015625
272.9 0.02575758 0.02272727
265.7
0.025 0.02941176

5
6
7
8

259.9
254.8
250.4
247.6

259.9
254.8
250.5
247.7

259.9
254.8
250.5
247.6

259.9
254.8
250.5
247.6

0.02428571 0.03571429
0.02361111 0.04166667
0.02297297
0.0472973
0.02236842 0.05263158

otenciometrica del potencial formal E

ln(ferri/ferro)

[ferri]o

0.17

1.22377543
0.53062825
0.12516314
-0.16251893

Vo(ml)

5
30
0.02833333

V(ml)
[ferri]

[ferro]o

0.25

Vo(ml)
V(ml)
[ferro]
Eoferri/ferro

1
31
0.00806452
270.04

EoAg/AgCl referencia

-0.38566248
-0.56798404
-0.72213472
-0.85566611

210

Eoferri/ferro + E0Ag/AgCl/KCl (3M)

480.04

determinacin potenciomtrica del potencial

formal E
350.0
300.0
250.0
200.0
y = 26.786x + 270.04
R = 0.9995

150.0
100.0
50.0
0.0
-1

-0.5

0.5

1.5

determinacion voltamperometrica del coeficiente de difusion D

V(V/S)
0.02
0.05
0.1
0.15
0.2
0.25
0.3
0.4
0.5

A
[C]
D

ipc (mA)
-228.511
-361.787
-500.458
-601.675
-685.933
-752.293
-814.637
-913.106
-1009.466

Epc(mv)
0.228
0.23
0.228
0.226
0.226
0.224
0.224
0.224
0.224

0.085
0.00333333
269000
3.78829E-06 0.00194635
3.141592654

ipa(ma)
220.525
354.481
500.795
600.672
685.432
758.74
826.415
899.997
1026.42

Epa(mv)
0.302
0.302
0.306
0.308
0.308
0.31
0.312
0.308
0.31

ipc/ipa
-1.03621358
-1.02061041
-0.99932707
-1.0016698
-1.00073093
-0.99150302
-0.98574808
-1.0145656
-0.9834824

rica del coeficiente de difusion D

ipc (A)
-0.228511
-0.361787
-0.500458
-0.601675
-0.685933
-0.752293
-0.814637
-0.913106
-1.009466
0
0
-0.2
-0.4
ipc (mA)

1/2
Epc-Epa E0=1/2(Epc+Epa) V (V/S)
-0.074
0.265
0.14142136
-0.072
0.266
0.2236068
-0.078
0.267
0.31622777
-0.082
0.267
0.38729833
-0.082
0.267
0.4472136
-0.086
0.267
0.5
-0.088
0.268
0.54772256
-0.084
0.266
0.63245553
-0.086
0.267
0.70710678
0.267

-0.6
-0.8
-1
-1.2

y=

COEFICIENTE DE DIFUSION
0.1

0.2

0.3

0.4

y = -1.3707x - 0.0576
R = 0.997
V1/2 (V/S)

0.5

0.6

0.7

0.8