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PH2130D/100
Royal Holloway and Bedford New College 2007
2006 -07
0 0
1/40
= = = = = = = = = = =
4 10-7 8.85 10-12 9.0 109 3.00 108 1.60 10-19 9.11 10-31 1.66 10-27 1.67 10-27 1.67 10-27 1.76 1011 6.63 10-34 1.05 10-34 1.38 10-23 5.67 10-8 8.31 6.02 1023 6.67 10-11 9.81 2.24 10-2 1.01 105
H m-1 F m-1 m F-1 m s-1 C kg kg kg kg C kg-1 Js Js J K-1 W m-2 K-4 J mol-1 K-1 mol-1 N m2 kg-2 m s-2 m3 N m-2
Speed of light in vacuum Elementary charge Electron (rest) mass Unified atomic mass constant Proton rest mass Neutron rest mass Ratio of electronic charge to mass Planck constant
c e me mu mp mn e/me h = h/2
= = = = = = = =
Boltzmann constant Stefan-Boltzmann constant Gas constant Avogadro constant Gravitational constant Acceleration due to gravity Volume of one mole of an ideal gas at STP One standard atmosphere
R NA G g
P0
page 1
PH2130
PART MARKS
ANSWER ONLY FIVE sections of Question One. You are advised not to spend more than 40 minutes answering Question One. The Fourier series for the function f ( x ) = x , which is defined over the interval L x L is x =
L 2L + 2 n =1 n 2 2
1.
(a)
{( 1) 1} cos ( n x / L ) .
n
Sketch the periodic function, and use the series to show that 2 1 1 1 1 = + + + + . 8 12 32 52 7 2 [4] (b)
, to convert
d 2 ( x ) 2m m 2 2 2 + 2 E 2 x ( x ) = 0 dx 2
into the dimensionless form:
d 2 + ( y 2 ) = 0. 2 dy
[4] (c) The following summation holds for the spherical harmonics
m = l
Y ( , )
m l
m =l
2l + 1 . 4
Y10 =
1 3 cos , 2
Y11 =
1 3 sin e i 2 2
[4]
What does this result say about the symmetry of filled p-orbitals?
(d)
TURN OVER
PH2130
PART MARKS
2 2 = 2 + 2 =0 x y
2
into two ordinary differential equations. Show all the steps carefully, but do not solve the resulting differential equations.
[4]
(e)
ln N ! N ln N N ,
to calculate the number of different ways that 100 footballs may be picked out of a box containing 150 identical balls. [4] (f) The function can written as a superposition of basis functions
( x ) = ai i ( x ) .
i =1 n
[4]
( x ) ( x ) dx =
b a i j b a
ij
TURN OVER
page 3
PH2130
PART MARKS
2.
(a)
What are the dimensions of and 0 ? Using x ( t ) = Ae pt is a trial solution to the differential equation, show that there are two solutions p+ and p given by p = 2 402 . 2
[2]
(b)
[4] (c) Obtain the given solutions for the following three cases: (a) 0 (b) 0
(c) 0 = / 2. x ( t ) = ( A + Bt ) et / . For each case sketch a typical solution, and identify critical damping, light damping, and heavy damping. [14]
TURN OVER
page 4
PH2130
PART MARKS
3.
F ( x) = 1/ a =0
for x a / 2 otherwise.
(a)
[2]
(b)
Write down the Maclaurins series (the Taylor series about x = 0 ) for a function g ( x ) , and hence show that lim g ( x ) F ( x ) dx = g ( 0 ) .
a 0
[6]
Comment on how this result is related to the properties of the Dirac delta function ( x ) .
[3]
(c)
[5]
f ( k ) = F ( x ) eikx dx.
Sketch f ( k ) and find a measure of its width k , and describe what happens to f ( k ) in the limit a 0.
[4]
TURN OVER
page 5
PH2130
PART MARKS
4.
(a)
Write down the auxiliary function of the following second order differential equation y + 4 y = 0, and hence find the general solution.
[3]
(b)
and compare how your solutions compare to this obtained in part (a).
[13]
(c)
Describe how the Frobenius technique is a powerful extension of the simple series solution for solving differential equations. Describe the type of solutions that can be obtained.
[4]
TURN OVER
page 6
PH2130
PART MARKS
5.
(a)
Write down the diffusion equation and the wave equation in one dimension. What is the essential difference between the solutions to these [4] equations?
We wish to solve the following equation 2 f f = . x 2 t (b) Verify that a solution to this equation is f ( x, t ) = 1 x 2 / 4t . e t [3]
Sketch the solution for different times t , for example t = 1, 10,100,... What does f ( x, t ) look like in the limit when t 0? (c) Suppose that the equation is modified to 2 f f f = , x 2 t t and the solution is of the form f ( x, t ) = g ( t ) 1 x2 / 4t e t Eq.1
[3] [3]
[6] [2]
Solve this differential equation and hence find the general solution to Eq. 1.
TURN OVER