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Table Of Contents

Quantities, Units and Conversions
3 REFERENCES
Fundamentals of Solubility
1 INTRODUCTION
3 THERMODYNAMICS OF SOLUBILITY
4 SOLUBILITY OF GASES IN LIQUIDS
5 SOLUBILITY OF LIQUIDS IN LIQUIDS
6 SOLUBILITY OF SOLIDS IN LIQUIDS
8 REFERENCES
2 FUNDAMENTAL CONCEPTS
5 KINETICS OF APPROACH TO EQUILIBRIUM
6 SUMMARY OF RATE-DETERMINING MECHANISMS
7 ACKNOWLEDGEMENT
3 THE SOLUTION COMPONENTS
4 DEGASSING THE SOLVENT
5 EXPERIMENTAL METHODS
7 TREATMENT OF DATA
8 STANDARDS
9 SUMMARY AND RECOMMENDATIONS
10 REFERENCES
2 MANOMETRIC METHODS
3 GRAVIMETRIC METHODS
4 INVERSE GAS CHROMATOGRAPHY
5 MISCELLANEOUS
6 CONCLUSIONS
7 REFERENCES
1 SOLUBILITY OF GASES IN MOLTEN SALTS
2 SOLUBILITY OF GASES IN MO LTEN METALS
1 SIEVERTS METHOD
2 EQUILIBRATE–QUENCH–ANALYZE METHOD
3 GRAVIMETRIC METHOD
6 REFERENCES
Liquids
I INTRODUCTION
2 THE SYNTHETIC METHOD
3 THE ANALYTICAL METHOD
4 MISCELLANEOUS METHODS
5 SAMPLE PURITY
6 TEST SYSTEMS
1 GENERAL REVIEW OF METHODS
2 ANALYTICAL METHODS
3 SYNTHETIC METHODS
4 ‘COMBINATORIAL’ METHODS
5 SUMMARY OF EXPERIMENTAL DIFFICULTIES
4 SUMMARY, CONCLUSIONS AND RECOMMENDATIONS
5 REFERENCES
2 PHASE DIAGRAM CONSTRUCTION (THEORY)
1 METHODS BASED ON PHASE SEPARATION
3 INDIRECT METHODS
Special Systems
2 BASIC EQUATIONS AND NOMENCLATURE
4 STATIC METHODS
5 RECIRCULATION METHODS
6 FLOW METHODS
7 SATURATION (TRANSPIRATION) METHODS
8 DEW- AND BUBBLE-POINT METHODS
9 SUPERCRITICAL FLUID CHROMATOGRAPHY
3 CONCLUDING REMARKS
4 REFERENCES
1 SAMPLE PROBLEMS
2 KINETIC PROBLEMS
3 PHASE DIAGRAMS
4 METHODS
INDEX
P. 1
The Experimental Determination of Solubilities

The Experimental Determination of Solubilities

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Published by Wiley
The most useful experimental methods for all types of solubility measurements

The importance of solubility phenomena has been long recognized throughout science. For example, in medicine, the solubility of gases in liquids forms the basis of life itself; in the environment, solubility phenomena influence the weathering of rocks, the creation of soils, the composition of natural water bodies and the behaviour and fate of many chemicals. However, until now, no systematic critical presentation of the methods for obtaining solubilities has been given.

Divided into five sections the author has concentrated on the fundamental thermodynamic and kinetic background necessary for a full understanding of solubility phenomena. The major types of solubility determinations according to the physical state of the solute: gases, liquids and solids; whilst the final section deals with those technologically important areas whose traditions are sufficiently different to justify their separate presentation.

 Each chapter aims to be comprehensive but not encyclopaedic, with coverage of the reliable methods in the particular area; Illustrations have been included to enable the novice investigator quickly develop apparatus of their own Where appropriate, contributors have included sets of data to enable workers to properly assess the quality of their apparatus, technique and data
The most useful experimental methods for all types of solubility measurements

The importance of solubility phenomena has been long recognized throughout science. For example, in medicine, the solubility of gases in liquids forms the basis of life itself; in the environment, solubility phenomena influence the weathering of rocks, the creation of soils, the composition of natural water bodies and the behaviour and fate of many chemicals. However, until now, no systematic critical presentation of the methods for obtaining solubilities has been given.

Divided into five sections the author has concentrated on the fundamental thermodynamic and kinetic background necessary for a full understanding of solubility phenomena. The major types of solubility determinations according to the physical state of the solute: gases, liquids and solids; whilst the final section deals with those technologically important areas whose traditions are sufficiently different to justify their separate presentation.

 Each chapter aims to be comprehensive but not encyclopaedic, with coverage of the reliable methods in the particular area; Illustrations have been included to enable the novice investigator quickly develop apparatus of their own Where appropriate, contributors have included sets of data to enable workers to properly assess the quality of their apparatus, technique and data

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Publish date: Nov 14, 2003
Added to Scribd: Jun 05, 2013
Copyright:Traditional Copyright: All rights reservedISBN:9780470864272
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