PETROLERA AMERIVEN

July 9-11, 2002 Yagua, Venezuela

DISTILLATION AND LUBE OIL BASE WORKSHOP

Content

1. Petrolera Ameriven S.A.

2. Project Description

3. Upgrader Configuration

4. Distillation Unit

DISTILLATION AND LUBE OIL BASE WORKSHOP

Petrolera Ameriven Definition

Petrleos de Venezuela, S.A

Phillips Petroleum Company

ChevronTexaco Corporation

30%

40%

30%
Management Company

PETROLERA HAMACA, S.A.

Agent/Operator Company
PETROLERA AMERIVEN, S.A.

DISTILLATION AND LUBE OIL BASE WORKSHOP

Project Overview

PRODUCTION

UPGRADER

SHIPPING

DCO
250 MBOPD

SYNTHETIC CRUDE
180 MBOPD 26 API

Hamaca CO 190 MBOPD

8 - 9 API

BY-PRODUCTS

COKE 4. 000 MTPD

SULFUR 600 MTPD

DISTILLATION AND LUBE OIL BASE WORKSHOP

Project Location
STRATEGIC ASSOCIATIONS LOCATION
CARIBBEAN SEA

JOSE
PUERTO LA CRUZ

200 Km 36 / 20

Km 52

156 Km 42 / 20 134 Km 30 / 20

25 Km 26 / 12

65 Km 30 / 20

PTO

SINCOR

PETROZUATA

PDVSA 38 % TOTAL 47 % STATOIL 15 %

PDVSA 49.9 % CONOCO 50.1 %

PDVSA 30 % PHILLIPS 40 % TEXACO 30 %

PDVSA 41.67 % MOBIL 41.67 % VEBA 16.67 %

DISTILLATION AND LUBE OIL BASE WORKSHOP

Major Lines
JOSE
20 D 42 DCO 30 DCO

PTO
20D 20 D 30 DCO

FROM/TO OCN

COB
16 DILUENT 36DILUTED CRUDE OIL

MULTIPHASE PUMPS

BLOCKS H/M

EXISTING

PADS

PADS

PADS

PADS

NEW

DISTILLATION AND LUBE OIL BASE WORKSHOP

Upstream Facilities

JOSE H/M - BLOCKS P.T.O.

..
MPP STATION WELL PAD 16

BITOR ELECTRICAL SUB-STATION

42 EQUITY PIPELINE

WATER INJECTION 36 34.5 Kv 8

DEHYDRATION PLANT SLUG CATCHER

DILUENT 30 DILUENT

D.C.O
WATER TREATMENT GAS

ELECTRICAL SUB-STATION

AMERIVEN OWNED

NEW INSTALATIONS PDVSA OWNED

LAGOON

GAS PLANT

16

CENTRO OPERATIVO BARE (COB)

GAS LINE TO COLORADITO

DISTILLATION AND LUBE OIL BASE WORKSHOP

COB Dehydration Facility

..
MPP STATION WELL PAD 16 DILUENT FROM COA

PTO P.L.C. / JOSE

Oily Water to Treatment Plant

From Electrical Sub. Station

WATER INJECTION

Water from Treatment Plant

36

SLUG CATCHER

T-1

H-100 SM-100 54-T-11 S-100 S-101 54-T-12 S-102

T-3 T-2

SE-100

DEHYDRATED CRUDE OIL

H-101 SM-101

SE-101

H-102 SM-102 S-103

SE-102

GAS TO KNOCK DRUM AND FLARE

GAS TO TREATMENT

DISTILLATION AND LUBE OIL BASE WORKSHOP

Jose Industrial Condominium (JIC)

CARIBBEAN SEA
N

INDUSTRIAL SERVICE PLANTS

SOLIDS HANDLING
(COMMON)
S-8 S-7

PETROCHEM. COMPLEX

CRYOGENIC COMPLEX
CRUDE Shipping
S-5 S-4 S-3

Petrozuata Sincor
178 ha. 214 ha.

S-6

Gas Station Pig Launching CONDOMINIUM BITOR

S-2 219 ha.

PETROCHEMICAL Expansion
455 ha.

AREA Reserved Area

Strategic Associations

Cerro Ameriven Negro I

128 ha. 161 ha. 109 ha.

CIED PALMICHAL
Commercial Support Natl Guard JIC Access Control

Strategic Associations

TANK FARM

S-1 30 ha.

Rmulo Betancourt Highway

DISTILLATION AND LUBE OIL BASE WORKSHOP

Hamaca Project Upgrader 3D Model

DISTILLATION AND LUBE OIL BASE WORKSHOP

Hamaca Project Upgrader Delayed Coker

DISTILLATION AND LUBE OIL BASE WORKSHOP

Hamaca Project Upgrader Tank Farm

DISTILLATION AND LUBE OIL BASE WORKSHOP

Hamaca Project Upgrader Administration Building & Main Pipe Rack

DISTILLATION AND LUBE OIL BASE WORKSHOP

Upgrader Configuration
Natural Gas
Naphtha Diluent 58 Naphtha Diluent

HPU 2x 85*
H2 COMMERCIAL CRUDE

Diluted Crude

248

A T M 248

Distillate LVGO C3 C4-645

LOH 60
Reactor Effluent

HSU

180 MBPSD
25.9 API 23.3% Residue

190 MBPSD Hamaca Crude

HAMACA CRUDE FIELD * (MMSCFD)

V A C 165

HVGO

DCU/ GP 62

HCGO

GOH 55
Sour Water

1000+ Residuum MVGO

Coke 4040 ST/D

Rich MDEA

2x ARU 3x SWSU 3x SRU 1x TGTU

Sulfur 600 MT/D

Lean MDEA

Stripped Sour Water

DISTILLATION AND LUBE OIL BASE WORKSHOP

Diluted Crude Oil Characteristics

API Total Sulfur, wt% Acid Number, mg KOH/g Water content, vol% Salt content, lb/1000 bbl 16.0 3.16 2.44 1.0 96.9 4,577 3.3 63 249

Total Nitrogen, ppmw

Iron, ppmw Nickel, ppmw Vanadium, ppmw

DISTILLATION AND LUBE OIL BASE WORKSHOP

Crude Preheating Cold Train

Diluent Naphtha To Storage Atm. Tower Overhead 10-E-002A-J MVGO LGO To 10-EA-002 LGO PA HVGO FROM 10-E-017

10-E-007A-D

To 10-C-004 10-E-001A-C Diluted Crude 61-P-001A-B

TC

10-E-005

10-E-008

Dilute Crude 10-E-009 10-E-010

10-E-004A-C 10-E-006A-D To Flushing oil Tank and Vacuum Residue Blend

To GOH or Storage To LOH or Storage To Atm Tower

HGO from 10-E-016

FC

DISTILLATION AND LUBE OIL BASE WORKSHOP

Desalting
Stripped Sour Water 10-E-011A/B
FC CW

To Waste Water Treatment

10-E-012

10-V-002A

LC

10-V-002B

LC

Dilute Crude

Mixing Valve

Mixing Valve

Desalted Crude
Mud Wash Mud Wash

FC FC

FC

10-P-018A

10-P-017A

10-V-003A

LC

10-V-003B

LC

Mixing Valve

Mixing Valve

Mud Wash Mud Wash FC

FC

10-P-017B/C

10-P-018B/C

DISTILLATION AND LUBE OIL BASE WORKSHOP

Crude Preheating Hot Train

To 10-C001 To 10-C-004

LP Steam 10-E-015A-L MVGO PA

Desalted Crude

HGO PA 10-E-016A-C 10-E-018A-C To 10-C-001

10-C-002

10-E-014A-B 10-H-001 HVGO PA HGO PA To 10-E-008 10-E-017A-L To 10-E-007 Vacuum Residue To 10-E-009 HVGO PA

10-P-002A-B

DISTILLATION AND LUBE OIL BASE WORKSHOP

Distillation Tower

10-V-001
38

Diluent Naphtha
35

25 24 22

Sour Water to SW Stripper

Light Distillate Stripper

To LOH

Distillate to Light Oil Hydrotreater

17

15

From 10-C-002 From 10-H-001

10-C-001 To Vacuum Heater

DISTILLATION AND LUBE OIL BASE WORKSHOP

Atmospheric Tower Characteristics

Diameter Height Internals Stripping section Rectification Section 20-6 183-0 Tan. to Tan. 38 trays. 6 two-pass sieve trays. 32 valve trays.

Feed.
Inlet temperature Operating Pressure (abs). Top Flash Zone Bottom

Tangential nozzle/vapor horn.

678 F

9 psi. 14 psi. 15 psi.

DISTILLATION AND LUBE OIL BASE WORKSHOP

Vacuum Tower Characteristics

Diameter
Height Internals Stripping section Rectification Section Feed.

42-0/19-0
144-0 Tan. to Tan.

6 two-pass sieve trays. 4 packing sections.

Tangential nozzle/Vapor horn.

Inlet temperature
Operating Pressure (abs). Top Flash Zone Bottom

743 F

57 mmHg. 65 mmHg. 95 mmHg

DISTILLATION AND LUBE OIL BASE WORKSHOP

Intermediate Product Specifications Product

Diluent Naphtha

Specifications
TBP cut point range: 200 345F Vapor Pressure at storage temp: 10 psia max. RVP: 5 psi (approx). BPSD: 55,273 min. TBP (98%): 800F max. TBP cut point range: 680 790 F TBP (98%): Report Metals: 2.0 ppmw max. CCR: 0.5 wt% max. BPSD required: 38,765 TBP cut range 1000 F + Na content: 10 ppmw max.
DISTILLATION AND LUBE OIL BASE WORKSHOP

Combined Distillate MVGO HVGO

Vacuum Residue

CDU Streams Qualities and Production Rates

BPSD Diluent Naphtha Combined Distillate MVGO HVGO Vacuum Residue / MVGO Blend Vacuum Residue API 47.0 26.8 16.8 12.5 Total Sulfur, wt. % 0.06 2.1 3.2 3.5 4.3 4.5 1000 + F. TBP 200 F 345 F. 345 F 680 F. 680 F 790 F. 790 F 1000 F

55,273
31,811 5,000 38,765 54,510 62,000

5.3 2.2

DISTILLATION AND LUBE OIL BASE WORKSHOP

Crude Characteristics
Extra Heavy Crude Oil Flow, MBPD API Total Sulfur, wt% Total Nitrogen, ppmw Commercial Crude Oil

190
8.6 3.9

180
25.9 1.6

5810
78 308

2481
42 153

Nickel, ppmw
Vanadium, ppmw

DISTILLATION AND LUBE OIL BASE WORKSHOP

Crude Characteristics
Composition, LV % Propane I-Butane N- Butane Lt. Naphtha (C5-180 F) Extra Heavy Crude Oil 0.0 0.0 0.0 0.0 0.3 4.4 Commercial Crude Oil 0.5 0.5 1.0 4.2 9.0 17.7

Hvy Naphtha (180-345 F)

Kerosene (345-525 F)

Diesel (525-680 F)
Gas Oil (680-1000 F) Residuum (1000+ F)

10.2
30.4 54.7

18.3
25.4 23.3

DISTILLATION AND LUBE OIL BASE WORKSHOP

Treatment Units
Plant Train Numbers 02 Spec.

Amine Reg. Sour Water Stripper Sulfur Recovery Tail Gas Treatment

Rich Amine: 0,3 mol H2S/mol MDEA Lean Amine: 0,01 mol H2S/mol MDEA 1750 GPM
(Stripped Water: Max. 45 ppm NH3)

03

03

600 MTD, Sulfur Rec.: 99,9 wt% (Licensed by Stork-Comprimo) Max. 250 ppmv of SO2 (Licensed by Stork-Comprimo)

01

DISTILLATION AND LUBE OIL BASE WORKSHOP

Delayed Coker
Process Specifications Capacity, MBD: Feed: TPR: Cycles, hours: Heaters: 62 Vaccum Residue (1000 oF +) 1,05 18 02

Fuel:
Accelerat. Media: Decoking Facilities:

Fuel Gas
HP Steam Steam-Air Decoking On line Spalling

DISTILLATION AND LUBE OIL BASE WORKSHOP

Delayed Coker
Mechanical Specifications Coke Drums: Drums Diameter, ft: 04 29

Drums Pressure, psig:

Fractionator Diameter, ft: Number of trays: Type of trays: Wash Zone:

15 (25 max.)
19 18 Valve 2 spray chambers 3 rows of shed trays

Coke removal facilities at bottom of fractionator and blowdown drum.

DISTILLATION AND LUBE OIL BASE WORKSHOP

Light Oil Hydrotreater

Recycle Gas Compressor Knockout Drum To Relief Header

Makeup Hydrogen from Hydroprocessing Support Unit LCGO/Naphtha From Gas Plant/Delayed Coker

Lean Amine Recycle Gas Scrubber

Recycle Gas Heater Recycle Gas Compressor

Rich Amine

Coker Light Ends To Relief Header Combined Distillate From Crude Unit Purge Light Naphtha from Crude Unit

Flash Drum Offgas to Hydroprocessing Support In-Serie Reactor Train Separator Flash Drum

Feed Surge Drum

Sour Water to Non-Phenolic Header

LVGO from Vacuum Unit

Flash Drum Liquid to Hydroprocessing Support Unit

DISTILLATION AND LUBE OIL BASE WORKSHOP

Gas Oil Hydrocracker

Makeup Hydrogen From Hydroprocessing Support Unit Recycle Gas Heater

Recycle Gas Compressor Knockout Drum To Relief Header

Lean Amine Recycle Gas Scrubber

HVGO from Vacuum Unit

Recycle Gas Compressor

Rich Amine

To Relief Header HCGO from Delayed Coking Unit Feed Surge Drum

Flash Drum offgas to Hydroprocessing Support Unit Parallel Reactor Train Separator

Flash Drum

Sour Water to SW Stripper

Stripper Feed to Hydroprocessing Support Unit

DISTILLATION AND LUBE OIL BASE WORKSHOP

Hydroprocessing Support Unit

Light Ends to LPG Scrubber and Deethanizer Columns for LPG

Feed from Gas Oil Hydrocracker Unit

34

30 30 To Fuel Gas Scrubber

To Fuel Gas Scrubber

27

15

16 Feed from Light Oil Hydrotreater Unit

Stripper Column To SW Stripper

Debut. Column Sour Water To SW Stripper Naphtha Splitter Column

Sour Water To SW Stripper

Light Naphtha to Commercial Crude Blending

Stripper Bottoms To Commercial Crude Blending

Heavy Naphtha to Commercial Crude Blending

Diluent Naphtha Make Up To Crude Unit

DISTILLATION AND LUBE OIL BASE WORKSHOP