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IIT-JEE-2009_Paper-I20%2620II%28Que-Sol-Key%29

# IIT-JEE-2009_Paper-I20%2620II%28Que-Sol-Key%29

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iit-jee solutions 2009
iit-jee solutions 2009

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IIT-JEE2009-Code-0-Questions and Solutions-Paper-I and II

2
Code
0

PART I : CHEMISTRYPAPER - I
SECTION I
Straight Objective Type
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of whichONLY ONE is correct.
For the benefit of 11
th
/12
th
Studying students, we have (*) marked the questions which are from 11
th
syllabus.You are advised to solve these questions in 100 minutes.
*1. Given that the abundances of isotopes
54
Fe,
56
Fe and
57
Fe are 5%, 90% and 5% respectively, the atomicmass of Fe is(A) 55.85 (B) 55.95(C) 55.75 (D) 56.05
Key. (B)Sol.
The atomic mass of an element is the average mass number of all its naturally occurring isotopes, theaveraging being done on the basis of their respective abundances. ThusAt. Mass of Fe =554905655755.95100
× + × + ×=
Hence (B)*2. The term that corrects for the attractive forces present in a real gas in the van der Waals equation is(A) nb (B)
22
anV (C)
22
anV
(D) –nb
Key. (B)Sol.
Vanderwaals’ equation for n moles of a real gas is
22
anP(Vnb)nRTV
+ =
The pressure correction factor
22
anVaccounts for the loss of pressure due to inward pull. ‘a’ is vanderwaals’constant for a gas and it is the measure of the strength of the vanderwaals’ intermolecular attraction.Hence
22
anV 3. Among the electrolytes Na
2
SO
4
, CaCl
2
, Al
2
(SO
4
)
3
and NH
4
Cl, the most effective coagulating agent forSb
2
S
2
sol is(A) Na
2
SO
4
(B) CaCl
2
(C) Al
2
(SO
4
)
3
(D) NH
4
Cl
Key. (C)Sol.
Sb
2
S
3
is a negatively charged colloid.
cation is responsible for its coagulation and the most effective is Al
2
[SO
4
]
3
1 mol can furnish 2
×
Al
3+
ioni.e. 6 moles of +ve charges which is the maximum in the given choicesHence (C)

IIT-JEE2009-Code-0-Questions and Solutions-Paper-I and II

3
4. The Henry’s law constant for the solubility of N
2
gas in water at 298 K is 1.0
×
10
5
atm. The mole fractionof N
2
in air is 0.8. The number of moles of N
2
from air dissolved in 10 moles of water at 298 K and 5 atmpressure is(A) 4.0
×
10
–4
(B) 4.0
×
10
–5
(C) 5.0
×
10
–4
(D) 4.0
×
10
–6

Key. (A)Sol.

2
N
p0.854atm
= × =
From Henry’s Law:
22
NHN
pK.X
=

2
5N5
4X410110
= = ××
This means 1 mole of solution will contain 4
×
10
–5
mole of N
2
and 1 – 4
×
10
–5

1 mole water.Thus, 1 mole of water is association with 4
×
10
–5
mole N
2

10 moles of water is associated with 4
×
10
–5
mole N
2
Hence (A)5. The reaction of P
4
with X leads selectively to P
4
O
6
. The X is(A) Dry O
2
(B) A mixture of O
2
and N
2
(C) Moist O
2
(D) O
2
in the presence of aqueous NaOH
Key. (B)Sol.
P
4
gives P
4
O
6
when oxygen is in limited supply. Hence a mixture of O
2
and N
2
is most suitable
4246
P3OPO
+
*6. The correct acidity order of the following is
OHOHClCOOHCOOHCH
3
(I)(II)(III)(IV)
(A) (III)
>
(IV)
>
(II)
>
(I) (B) (IV)
>
(III)
>
(I)
>
(II)(C) (III)
>
(II)
>
(I)
>
(IV) (D) (II)
>
(III)
>
(IV)
>
(I)
Key. (A)Sol.
CH
3
OHClCOOHCOOHCH
3
pKa=9.9pKa = 9.2pKa = 4.2pKa = 4.4

Carboxylic acids are more acidic than phenol. EWG exerts acid-strengthening effect while EDG exertsacid-weakening effect. The –I effect of Cl is dominating over its +R effect.
(A)7. Among cellulose, poly(vinyl chloride), nylon and natural rubber, the polymer in which the intermolecularforce of attraction is weakest is(A) Nylon (B) Poly(vinyl chloride)(C) Cellulose (D) Natural Rubber
Key. (D)

IIT-JEE2009-Code-0-Questions and Solutions-Paper-I and II

4
Sol.
Nylon and cellulose are Fibres. PVC is a thermoplastic while Natural Rubber is an elastomer. Theintermolecular foces of attraction can be graded asElastomer
<
Thermoplastic
<
Fibres.*8. The IUPAC name of the following compound is
OHBrCN
(A) 4-Bromo-3-cyanophenol (B) 2-Bromo-5-hydroxybenzonitrile(C) 2-Cyano-4-hydroxybromobenzene (D) 6-Bromo-3-hydroxybenzonitrile
Key. (B)Sol.
The priority order is:–CN
>
Br
>
–OHSo the compound is2-bromo 5-hydroxy benzo nitrile
SECTION – II
Multiple Correct Answer Type
This section contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A), (B), (C) and(D), out of which ONE OR MORE is/are correct.
9. The correct statement(s) regarding defects in solids is(are)(A) Frenkel defect is usually favoured by a very small difference in the sizes of cation and anion(B) Frenkel defect is a disolocation defect(C) Trapping of an electron in the lattice leads to the formation of F-centre(D) Schottky defects have no effect on the physical properties of solids
Key. (B, C)Sol.
Frenkel defect is usually favoured by a very large difference in the sizes of cation and anion. In Schottkydefect pairs of cations and anions left the crystal lattice as a result density decreases. Hence (B) and (C) arecorrect.10. The compound(s) that exhibit(s) geometrical isomerism is(are)(A) [Pt(en)Cl
2
] (B) [Pt(en)
2
]Cl
2
(C) [Pt(en)
2
Cl
2
]Cl
2
(D) [Pt(NH
3
)
2
Cl
2
]
Key. (C, D)Sol.
enentranscis(C)PtH
3
NClClNH
3
transcis(D)PtH
3
NH
3
NClClPtClenPtClClenCl
*11. The compound(s) formed upon combustion of sodium metal in excess air is(are)

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