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coPC13svt

coPC13svt

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Published by Ja Maa

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Published by: Ja Maa on Jun 19, 2013
Copyright:Attribution Non-commercial

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06/19/2013

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18
 
1023  :.  –
7 
5,0
 
1
 
5,70 5,70
 
:
2.
 
2.2.
 
- +3 6 3(aq) 2 (l) 3 5 3 (aq) 3 (aq)
C H O + H O C H O + H O
 
2.1.
:
2.3.
 
éq
x
 
3éq
x 1,81.10
mol 
::
+f 3 éq
n (H O )=x
:
+f 330
n (H O )
 f  
 H O
:
+ -pHf 3 éq 3 0 0
n (H O )=x .V 10 .V
 H O
:
-pHéq 0
x 10 .V
:.
-2,44 3éq
x 10 .0,5 1,81.10
mol 
2.
.
 
A
 pK 
-3 6 3(aq) 3 5 3 (aq)
C H O / C H O
:
+3 3 5 33 6 3
H O C H OC H O
 f f   A f  
 K 
   
 
 
- +3 6 3(aq) 2 (l) 3 5 3 (aq) 3 (aq)
C H O + H O C H O + H O
 
 
0
0 0
.
C
 0 0
éq
x
 
0 0
.
C
– 
 
éq
x
 
éq
x
 
éq
x
 x
m
.
a
C
– 
 
x
max
x
m
x
m
 
 
 
28
 
1023  :.  –
5,0 1 5,0 5,70 
:
2+3A+0 3
H OK =C - H O
 
: .
234A1 3
3,62.10K = 1,36.1010 3,623.10
 
:
A A
 pK =- log
 :.
4A
 pK =- log(1,36.10 ) 3,87
 
1.
 
2.1
.
:
- -3 6 3(aq) (aq) 3 5 3 (aq) 2 (l)
C H O + HO C H O + H O
.
2.2
.
A
C
:
:
A A B B,E
C .V =C .V
 
:
B B,EA
C .VC =
 A
 :.
-22A
2.10 .28,3C = 5,66.10 mol/L10
 
: :
A
C =100
:
A
C=100.C
 .
 
:.
-2
C=100.5,66.10 =5,66 mol/L
.
2.3
.
::
3 6 3
C.M(C H O )P=
ρ
 : .
3
5,66.90P= 0,45 45%1,13.10
 "
  
 
-1
g.L
 
-1
g.mol
".
3.
 
3.1
.
 
x
 ::
1/2
xx(t )=2
:
f 1/2
x 2.x(t )
 
 
 
38
 
1023  :.  –
5,70 5,0 
1/2
.x(t )
 
1/2
t
 
:
-31/2
.x(t ) 0,96.10 mol
 
:
-3 3
x 2.0,96.10 1,92.10
mol 
.
3.2
.
 
t=22,5 s
::
1 dxv= .V dt
 
t=22,5 s
: 
-2 -3
dx 1,8 0,82,42.10 10 mol/sdt 45 3,8
:
-5 3 -1 -13
1 dx 1v= . = .2,42.10 2,42.10 mol.s .Ldt10.10
 
3.3
.
 .) (
1 
5,05,70
 
5,0
 
5,0 
2: 
1
.
 
18675
Re
1.1.
 
18675
Re
:
57
 

 
8
.
1..
 
18675
Re
:
186 186 075 76 -1
Re Os+ e
 
-
β
.
2
.
.1.
 
18675
Re
:
:
1/2
ln2=
 
 :.
1/2
ln2 0,693,630,19 0,19
t jours
..
 
1
 N 
 

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