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Section 1. Chemical Product and Company Identification
Material Safety Data Sheet
and Safe Handling and Disposal Information
Date of issue
04/27/07
Product name
CITRUS CLEANER
Product code
0455

Emergency
Telephone
Numbers

Supersedes03/17/04
Product use
Cleaner. Degreaser
Zep Inc.
1310 Seaboard Industrial Blvd.
Atlanta, GA 30318
1-877-I-BUY-ZEP (428-9937)
www.zep.com
For MSDS Information:
Compliance Services 1-877-I-BUY-ZEP (428-9937)
For Medical Emergency
INFOTRAC: (877) 541-2016 Toll Free - All Calls
Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
D-LIMONENE; orange distillate; citrus terpene; cyclohexene, 1-methyl-
4-(1-methylethenyl)-, (R)-
5989-27-5
1 -5
Not established
MONOETHANOLAMINE; 2-aminoethanol; MEA
141-43-5
1 -5
OSHA PEL / ACGIH TLV (United States).
TWA: 3 ppm 8 hour(s).
OSHA /ACGIH (United States).
STEL: 6 ppm 15 minute(s).
ETHYLENE GLYCOL MONOBUTYL ETHER; 2-butoxyethanol; butyl
cellosolve
111-76-2
1 -5
ACGIH TLV (United States).
TWA: 20 ppm 8 hour(s).
OSHA PEL (United States). Skin
TWA: 50 ppm 8 hour(s).
DIPROPYLENE GLYCOL N-BUTYL ETHER; 1-(2-butoxy-1-methoxy)-
2-propanol; Glycol Ether DPNB
29911-28-2
1 -5
Not established
Section 2. Composition, Information on Ingredients
Name of hazardous ingredients
CAS #
% by Weight
Exposure Limits
Reactivity
Personal Protection
Fire Hazard
Health
Causes eye irritation. Inflammation of the eye is characterized by redness, watering and
itching.
Can cause gastrointestinal disturbances.
B021
HMIS

The substance may be toxic to blood, kidneys, lungs, liver, upper respiratory tract, skin, eyes, central nervous system (CNS). Overexposure of this product by inhalation or absorption can produce central nervous system depression resulting in headache, nausea and/or dizziness. Repeated or prolonged exposure to the substance can produce target organs damage.

Dermal contact. Eye contact. Inhalation.
Section 3. Hazards Identification
Routes of Entry
Acute EffectsAvoid breathing vapors, spray or mists. Over-exposure by inhalation may cause respiratory
irritation. Can cause central nervous system (CNS) depression.

Prolonged or repeated contact may dry skin and cause irritation. Skin inflammation is
characterized by itching, scaling, or reddening. Product may be dermal absorbed. May cause
skin sensitization.

Eyes
Skin
Inhalation
Ingestion
See Toxicological Information (section 11)
Chronic Effects
Carcinogenic Effects
Ingredients: Not listed as carcinogen by OSHA, NTP or IARC.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse health effects are lessened by
following all prescribed safety precautions, including use of proper personal protective equipment.

Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention
immediately.

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops.
If inhaled, remove to fresh air. If irritation persists, get medical attention.

Section 4. First Aid Measures

Eye Contact
Skin Contact
Inhalation

Ingestion
Page: 1/3
Printing date: 07/31/08
Material Safety Data Sheet
Product NameCITRUS CLEANER
Product code0455
12 0
Section 5. Fire Fighting Measures
Closed cup: >51\u00b0C (123.8\u00b0F).
(Tagliabue.)

Use dry chemical, CO2, water spray (fog) or foam. Cool closed containers exposed to fire with water. Wear special protective clothing and positive pressure, self-contained breathing apparatus.

Combustible liquid and vapor.
Flammability
Flash Point
Flammable Limits
Fire hazard
Fire-fighting procedures
Not determined.
COMBUSTIBLE.

Eliminate all ignition sources. Put on appropriate personal protective equipment (see section 8). Absorb with
an inert material and place in an appropriate waste disposal container. To clean the floor and all objects
contaminated by this material, use [***]. detergent. Finish cleaning by spreading water on the contaminated
surface and dispose of according to local and regional authority requirements.

Section 6. Accidental Release Measures
Spill Clean upStore and use away from heat, sparks, open flame or any other ignition source. Keep container tightly closed in a
cool, well-ventilated place. Store between the following temperatures: 40\u00b0F - 120\u00b0F (4.4\u00b0C - 49\u00b0C). Keep away
from food, drink and animal feeding stuffs. Keep out of the reach of children.
Keep away from heat, sparks and flame. Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray
or mists. Use only with adequate ventilation. Do not ingest. Wash thoroughly after handling.
Section 7. Handling and Storage
Handling
Storage
Section 8. Exposure Controls, Personal Protection

Use with adequate ventilation. Provide local exhaust ventilation to maintain airborne concentrations below
established exposure limits. Local exhaust ventilation is preferred because it prevents contaminant dispersion into the
work area by controlling it at its source.

Safety glasses.
For prolonged or repeated handling, use gloves. Recommended: Rubber
gloves. Neoprene gloves. Nitrile gloves.
Personal Protection
Eyes
Body
Respiratory
Protective Clothing (Pictograms)
Section 9. Physical and Chemical Properties

Physical State
pH
Boiling Point

Specific Gravity
Solubility

Liquid. (Thin liquid)
11.0 - 12.0
Not determined.
1.01 (Water = 1)
Soluble in water.

Color
Odor
Vapor Pressure
Vapor Density
Evaporation Rate
VOC (Consumer)
Clear. Orange.

Citrus
0.004 kPa (0.03 mm Hg) (at 20\u00b0C)
Not determined.
1 compared with Water

100.7 g/l (9.99%; 0.84 lb/gal.)
The product is stable.
Reactive with oxidizing agents.
Slightly reactive to reactive with acids. Keep away from heat, sparks and flame.
Will not occur.
carbon oxides (CO, CO2)
Section 10. Stability and Reactivity
Stability and Reactivity
Incompatibility
Hazardous Decomposition Products
Hazardous Polymerization
ORAL (LD50):\ue000 Acute: >5000 mg/kg [Rat].
DERMAL (LD50):\ue000 Acute: >5000 mg/kg [Rabbit].
Monoethanolamine:^[25,45,50,70
ORAL (LD50):\ue000 Acute: 1720 mg/kg [Rat.].
DERMAL (LD50):\ue000 Acute: >1000 mg/kg [Rabbit].
Ethylene Glycol Monobutyl Ether:^[25,45,50,70

ORAL (LD50):\ue000 Acute: 1746 mg/kg [Rat].
DERMAL (LD50):\ue000 Acute: 680 mg/kg [Rabbit].
VAPOR (LC50):\ue000 Acute: 450 ppm 4 hour(s) [Rat (Female)].

Section 11. Toxicological Information
Toxicity to Animals
Not available.
Section 12. Ecological Information
Biodegradable/OECDNot available.
Ecotoxicity
Waste must be disposed of in accordance with federal,
state and local environmental control regulations.

Code: D001
Classification: - (Hazardous waste.)
Origin: - (RCRA waste.)

Waste
Information
Waste Stream
Section 13. Disposal Considerations
Consult your local or regional authorities.
Page: 2/3
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