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CHAPTER 5
ATOMIC STRUCTURE
TEXT BOOK EXERCISE
Q1. i. Select the most suitable answer for the given one. The nature of the positive rays depends on (a) The nature of the electrode (b) The nature of the discharge tube (c) The nature of the residual gas (d) all of the above The velocity of photon is (a) Independent of its wavelength (b) Depends on its wavelength (c) Equal to square of its amplitude (d) Depends on its source The wave number of the light emitted by a certain source is 2 x 106 m. the wavelength of this light will be (a) 500nm (b) 500m (c) 200nm (d) 5 x 107 m Rutherfords model of an atom failed because (a) The atom did not have a nucleus an electron (b) It did not account for the attraction between protons and neutrons (c) It did not account for the stablility of the atom (d) There is actually no space between the nucleus and the electrons Bohr model of atom is contradicted by (a) Planck quantum theory (b) Paulis exclusion principle (c) Heisenbergs uncertainty principle (d) all of the above
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ii.
iii.
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Ans.
(x)c Q.2 Fill in the blanks with suitable words (i) B-particles are nothing but _______moving with a very high speed. (ii) The charge on one mole of electrons is ________coulombs. (iii) The mass of hydrogen atom is _________grams. (iv) The mass of one mole of electron is _________. (v) Energy is ________when electron jumps from higher to a lower orbit. (vi) The ionization energy of hydrogen atom can be given by formula ________. (vii) For d sub-shell, the azimuthal quantum number has a value of ________.
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(g) Ans.
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is
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Radius is inversely proportional to the number of protons in the nucleus (d) How do you come to know that the velocities of electrons in higher orbits are less than those in lower orbits of hydrogen atom? Ans. According to Bohr, since the electron keeps on revolving around the nucleus: Therefore, centrifugal force=Electrostatic force of attraction = or For H-atom,Z=1 r= Since, e, , and m are constant, therefore, the factor Therefore, r=constant x r= Hence, the radius of a moving electron is inversely proportional to the square of its velocity. The smaller the radius of the orbit, the higher is the velocity of electron. Hence, the velocities of electrons in higher orbits are less than those in lower orbits of hydrogen atom. (e) Justify that the distance gaps between different orbits go on increasing form the lower. Ans. We know that: r=0.529 x[n2] When n=1 r1=0.529 When n=2 r2=0.529 x4=2.11 When n=3 r3=0.529 x9=4.75 When n=4 r4=0.529 x16=8.4
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r=
is constant.
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When n=5 r5=0.529 x25=13.22 Distance between orbits are: r2 r1=(2.11 0.529) =1.581 r3 r2=(4.75 2.11) =2.64 r4 r3=(8.4 4.75) =3.65 r5 r4=(13.22 8.4) =4.82 From the data of radius difference, it is clear that the distance gaps between different orbits go on increasing from the lower to the higher orbits. Q8. Derive the formula for calculating the energy of an electron in nth orbit using Bohrs model. Keeping in view this formula explain the following: (a) The potential energy of the bounded electron is negative. Ans. According to Bohr, the energy of electron is calculated from the equation: En=- 2.178 x 10-18[] When n= , then En=0 Consider that an electron is present at an infinite distance from the nucleus, so there is no interaction between the two. The energy of this electron is zero. Now, suppose that the electron moves closer and closer to the nucleus. Since electron is negatively charged and nucleus is positively charged, no work needs to be done on the electron. The electron can move towards the nucleus by itself due to electrical attraction. Thus, work is done by the electron itself as it moves towards the nucleus. As a result, the potential energy falls, i.e. it become less than zero. Any value less than zero is negative. Hence, the potential energy of electron becomes more and more negative as the electron moves closer and closer towards the nucleus. (b) Total energy of the bounded electron is negative. Ans. When the electron is at infinite distance from the nucleus, there is no electrostatic interaction between the two. Therefore, the energy of the
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The energy of an electron is inversely proportional to n2 . As the value of n increases, the value of energy increases. The energy of higher orbits are always greater than those of the lower orbits. E5 >E4 >E3> E2 >E1 (d) The energy difference between adjacent levels goes on decreasing sharply. Ans. The energy difference between adjacent levels can be found as: E=E2 E1 =(- 328.09) (-1312.36) =984.27kJmol-1 E=E3 E2 =(- 145.82) (- 328.09) =182.27kJmol-1 E=E4 E3 =(- 82.023) (- 145.82) =63.797kJmol-1 E=E5 E4 =(- 52.49) (- 82.023) =29.533kJmol-1
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Hence, the size of He+ is much smaller than H-atom. This is because the nucleus of He+ has greater attraction for the electron as compared to Hatom which contains one proton in the nucleus. (b) Do you think that the size of li-2+ is even smaller than HE+ ? Justify with calculation. Ans. The size of He+ ion: The size of li-2+ ion: r=0.529 r=0.529 =0.2645 =0.1763
The size of li-2+ ion is much smaller than the size of He+ ion: Q12. (a) What are X-rays? What is their origin? How was the idea of atomic number derived from the discovery of X-rays? (b) How does the Bohrs model Justify the Moseleys equation? Q13. Point out the defects of Bohrs model. How these defects are partially covered by dual nature of electron and Heisenbergs uncertainty principle?
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Now,
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Now, =0.51 x 106 m-1 =5.1 x 105 m-1 =5.1 x 103 cm-1 (b) Convert this energy of the photon into ergs and calculate the wave length in cm, frequency in Hz and wave number in cm-1 . h=6.625x 10-34 js or 6.625 x 10-27 ergs. C=3 x 108 ms-1 or 3x 10 +10 cms-1 . Solution: E= 10-19 J =10-19 x 107 erg [1 j =107 erg] =10-12 erg =1.98 x 10-6 m=1.98 x10-6 x 102 cm=1.98 x 10-4 cm =5x105 m-1 =5 x 105 x 10-2 cm-1 =5x 103 cm-1 Q18. The formula for calculating the energy of an electron in hydrogen atom gives by Bohr, s model En = Calculate the energy of the electron in first orbit of hydrogen atom. The values of various parameters are same as provided in Q.19. Solution: n= E=? Formula: En =-2.178 x 10-18 [ ]J En=-2.178 x 10-18 [ ]J E=-2.178 x 10-18 J E=-2.18 x 10-18 J Q19. Bohrs equation for the radius of nth orbit of electron in hydrogen atom is rn =
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For
=3 r3 r2 =4.761 - 2.116 =Answer For n=9 r9 =0529(92)=42.849 n =10 r10=0.529 (102)=52.9 Distance traveled by the electron when it goes grom n=9 to n=10 r10 r9 =52.9 - 42.849 =10.051 Answer Q20. Answer the following questions, by performing the calculation s. (a) Calculate the energy of first five orbits of hydrogen atom an determine the energy differences between them. (b) Justify that energy difference between second and third orbits is approximately five times smaller than that between first and second orbits. (c) Calculate the energy of electron in He+ in first five orbits and justify that the energy differences are different from those of hydrogen atom. (d) Do you think that group of the spectral lines of He+ are at different places than those for hydrogen atom? Give reasons. Q21. Calculate the value of principal quantum number if an electron in hydrogen atom revolves in an orbit of energy - 0.242 x 10-18 j. Solution: E= - 242 x 10-18 j ; n=? Formula: E=- 2.178 x 10-18 n2= - 2.178 x 10-18 x n2=- 2.178 x 10-18x n2=
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=8.72 x 10-18 x =52.4944 x 102 kJ mol-1 =5249.44 kJ mol-1 Answer (e) The experimental values of ionization energy of H and He+ are 1331 kJ mol-1 and 5250 kJ mol-1 respectively. How do you compare your values with experimental values ? Q23. Calculate the wave number of the photon when the electron jumps from i. n=5 to n=2. ii. n=5 to n=1.] In which series of spectral lines and spectral regions these photons will appear. Solution: (i) n=5 to n =1 . =? Formula : =1.09678 x 107 [ =1.09678x 107[ =1.09678x 107[
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=1.09678x 107[
]m-1
=1.09678x 107m-1 =2.3x106 m-1 Answer The photon will appear in the Balmer series ii) n =5 to n= 1 Solution: n = 5 to n=1 ; =? Formula: =1.09678 x 107 [ ]m-1
=1.09678 x 107 m-1 Answer The photon will appear in the Lyman series. Q24. A photon of a wave number 102.70 x 105 m-1 is emitted when electron jumps form higher to n=1. (a) Determine the number of that orbit from where the electron falls. Solution: =102.70 x 105 ; n2=? Formula used: =1.09678 x 107 [ ]m-1 ]m-1
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= =16 n2 = =4 Answer (b) Indicate the name of the series to which this photon belongs. Ans. Since the electron falls from n=4 to n=1, therefore, the name of the series is Lyman series (d) If the electron will fall from higher orbit to n=2, then calculate the wave number of the photon emitted. Why this energy difference is so small as compared to that in part (a)? Solution: n1 =2 ; n2=4 =? Formula: =1.09678 x 107 [ =1.09678 x 107 [ ]m-1
]m-1
=1.09678 x 107 [ - ]m-1 =1.09678 x 107 [ ]m-1 =0.20565x 107 m-1 =0.20565x 105m-1 Answer Q25. (a) What is de Broglies wavelength of an electron in meters traveling at half a speed of light ? m =9.109 x 10-31 kg , c=3x 108 ms-1 Solution: M=9.109 x 10-31 kg : v= x3x 108 ms-1 =1.5x 108 ms-1 h =6.624 x 10-34 js Formula: = =
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