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C H
3
OH
CH
3
(ii) H
2
O
2
/O
-
H
(D) (Optically active)
(i) B
2
H
6
Dil.NaOH
E
5. How will you synthesise?
(i) Acetamide from acetone (ii) Iodoform from acetic acid
6. What happens when?
(a) Sulphur is boiled with caustic soda solution forms two compounds A and B, A liberates I
2
gas from
KI. What are A and B write equations.
(b) Aluminium forms [AlF
6
]
3
but boron does not form [BF
6
]
3
.
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FACREC-02-(P-2-IITJEE)-11-12)CH2
7. Write down the hybridisation state of the central atom and indicate the shape.
(i) XeOF
2
(ii) PBr
3
Cl
2
(iii) XeF
6
(iv)
2
ICl
8. Glucose and fructose consists of aldehydic and ketonic functional groups respectively, yet Fehlings
reagent cannot be used to distinguish them. Why?
9. K
C
for N
2
O
4(g)
2NO
2(g)
is 0.00466 at 298 K. If a one litre container initially contained 0.8 mole of
N
2
O
4
, what would be the concentrations of N
2
O
4
and NO
2
at equilibrium? Also calculate equilibrium
concentration of N
2
O
4
and NO
2
if the volume is halved at the same temperature.
10. Fill in the blanks the missing products (one principal organic product in one blank)
(a)
- +
Anhy. AlCl i) OH i) H
3
ii) SOCl
2 ii) ClCH COO
2
OH
(b)
D / Ni
2
O
N H O
PART II
1. Three compounds A,B and C, all have the formula C
6
H
10
. All three compounds rapidly decolourise Br
2
in CCl
4
. Compound A gives a precipitate when treated with silver nitrate in ammonia, but compound B
and C do not. A and B both yield n-hexane when they are treated with excess hydrogen in presence
of palladium catalyst. Under these conditions C absorbs only one molar equivalent of H
2
and gives a
product with formula C
6
H
12
. When A is oxidised with hot basic KMnO
4
and the resulting solution
acidified, the only organic product that can be isolated is n-pentanoic acid. Similar oxidation of B
gives only propionic acid and similar treatment of C gives only adipic acid. Find A,B and C and give
the reactions involved.
2.
2 2 7
K Cr O solution being primary standard, a standard solution of it was prepared by dissolving 0.588g
of it in water whose volume was made to 500 mL by further dilution. 20 mL of this dichromate solution
was added to 200 mL sample of water containing
2
Fe
ions and the solution was made acidic by
adding sufficient dil.
2 4
H SO . The excess dichromate was back titrated with 4.5 mL 0.02 M oxalate ion
solution in acid medium. Calculate amount in ppm of iron in the sample assuming that entire iron is
present as
2
Fe
ion.
[MW of
2 2 7
K Cr O 294 and Fe= 56]
3. In order to prepare a linear saturated secondary alcohol having five carbon atoms an organic chemist
treated acetaldehyde and acetone in a dilute basic solution and got a compound (A). When he
analysed the product (A), he identified the alcoholic group to be present along with a carbonyl group.
In order to get rid of the carbonyl group he treated (A) with Zn amalgam and excess conc. HCl and
got (B). But, for his greatest astonishment, (B) decolourised Br
2
/H
2
O. Without being dis-heartened he
treated (B) with acidified water and got the product he wanted. Write a sample report involving all the
mechanisms and concepts in his reaction sequence.
4. At 25C, the emf of the cell
Pb | PbCl
2
.HCl (0.5 M) || HCl (0.5 M) | AgCl
(s)
| Ag is 0.49 volts and its temperature coefficient
4
dE
1.8 10 volt / degree
dT
. Calculate
(a) the entropy change when 1 gm mol of silver is deposited and
(b) the heat of formation of AgCl, if the heat of formation of lead chloride is 86000 cal.
FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 110016. Ph: 46106000/10/13/15 Fax : 26513942.
FACULTY RECRUITMENT TEST
CATEGORY-A
INTENATIONAL OLYMPIADS (SENIOR)
(CHEMISTRY)
PAPER II
Time: 60 Minutes. Maximum Marks: 40
Name:....................................................................................................
Subject: ................................................................................................
Marks:
Instructions:
Attempt all questions.
This question paper has two Parts, I and II. Each question of Part I carries 2 marks and of
Part II carries 5 marks.
Calculators and log tables are not permitted
PART I
1. Give chemical equations of the chemical reactions involved in the blast furnace for the extraction of
pig iron from roasted haematite.
2. A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and
phenylalanine. Glycine contributes 47.0% to the total weight of the hydrolysed products. The number
of glycine units present in the decapeptide is
3. In 1 L saturated solution of AgCl [K
sp
(AgCl) = 1.6 10
10
], 0.1 mol of CuCl [K
sp
(CuCl) = 1.0 10
6
] is
added. The resultant concentration of Ag
+
in the solution is 1.6 10
x
. The value of x is
4. An organic compound (A) of molecular formula C
5
H
8
when treated with sodium in liquid ammonia
followed by reaction with npropyl bromide yields (B), C
8
H
14
. A gives a ketone (C), C
5
H
10
O when
treated with dilute H
2
SO
4
and HgSO
4
. (B) on oxidation with alkaline KMnO
4
gives two isomeric
acids (D) and (E) C
4
H
8
O
2
. Give structures of compound (A) to (E) with proper reasoning.
5. At 37 C, G A for the following reaction at constant volume was found to be 15.7 kJ
1
mol
+
4
Glutamate + NH Glutamine
Another biological reaction is hydrolysis of ATP into ADP and Phosphate (P).
ATP ADP P +
FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 110016. Ph: 46106000/10/13/15 Fax : 26513942.
FACREC-02-(IO)-11-12)CH2
for which the G A value may be taken as 31.0 kJ
1
mol
+++++