and integrating over volume, we get the time average total energy as2
ǫω
2
V A
20
(14)Assuming that the field energy is due to a photon with energy
ω
, we have
ω
=2
ǫω
2
V A
20
A
0
=
2
ωǫV
(15)We want to reexpressed this in terms of photon flux
I
ω
≡
NcV
√
µ
r
ǫ
r
(16)which is defined as the number of photon per unit time per unit area. Sub-stituting the
V
in (15) using this expression, we get
A
0
=
I
ω
√
µ
r
ǫ
r
2
ωǫNc
1
/
2
(17)Note that the direction of
A
0
is determined by the polarization of the field,which we will denote by
ˆa
. So now the vector potential is given by
A
(
x
,t
) =
ˆa
I
ω
√
µ
r
ǫ
r
2
ωǫNc
1
/
2
be
−
iωt
+
b
†
e
iωt
(18)where we have made a dipole approximation
e
k
·
x
≈
1.Now we have obtained the expression for the vector potential, and readyto calculate the interaction Hamiltonian. We first write the interactionHamiltonian in the second quantized Hamiltonian as given by
H
1
=
lm
l
|
H
1
|
m
a
†
l
a
m
(19)where
l
and
m
are the site-basis eigenstates. The matrix element is
l
|
H
1
|
m
=
qm
0
A
·
l
|
p
|
m
(20)Now we assume that the field is polarized in the
ˆz
direction. Then thematrix element becomes
l
|
H
1
|
m
=
q
√
µ
r
ǫ
r
2
NωǫcI
ω
1
/
2
(
be
−
iωt
+
b
†
e
iωt
)
×
l
ˆ
p
z
m
0
m
(21)3
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