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MATERIALS HANDBOOK com

MATERIALS HANDBOOK com

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Published by FENEC

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Published by: FENEC on Jun 17, 2009
Copyright:Attribution Non-commercial

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1
Materials, Their Propertiesand Uses
Part
 
ABLATIVES.
Materials used for the outward dissipation of extreme-ly high heats by mass removal. Their most common use is as anexternal heat shield to protect supersonic aerospace vehicles fromanexcessive buildup of heat caused by air friction at the surface. Theablative material must have a low thermal conductivity in order thatthe heat may remain concentrated in the thin surface layer. As thesurface of the ablator melts or sublimes, it is wiped away by the fric-tional forces that simultaneously heat newly exposed surfaces. Theheat is carried off with the material removed. The less material thatis lost, the more efficient is the ablative material. The ablative mater-ial also should have a high thermal capacity in the solid, liquid, andgaseous states; a high heat of fusion and evaporation; and a high heatof dissociation of its vapors. The ablative agent, or
ablator,
is usuallya carbonaceous organic compound, such as a phenolic plastic. As thedissociation products are lost as liquid or vapor, the char is held inplace by the refractory reinforcing fibers, still giving a measure of heat resistance. The effective life of an ablative is short, calculated inseconds per millimeter of thickness for the distance traveled in theatmosphere.Single ablative materials seldom have all the desirable factors, andthus composites are used. Phenolic or epoxy resins are reinforced withasbestos fabric, carbonized cloth, or refractory fibers, such as asbestos,fused silica, and glass. The refractory fibers not only are incorporatedfor mechanical strength, but also have a function in the ablativeprocess, and surface-active agents may be added to speed the rate of evaporation. Another composite,
polyarylacetylene (PAA)
reinforcedwith carbon fiber fabric, proved superior to carbon-reinforced phenolicin tests to develop an alternative ablative and insulative material fornozzle components of solid rocket motors. Favoring the PAAis its high(90%) char yield, lower weight loss and erosion, greater moisture resis-tance, and more stable ablation.
 Ablative paint,
for protecting wood-work, may be organic silicones which convert to silica at temperaturesabove 2000°F (1093°C).Metals can resist temperatures higher than their melting point by
convection cooling,
or
thermal cooling,
which is heat protectionby heat exchange with a coolant. Thus, tungsten can be arc-melted ina copper kettle which is cooled by circulating water. The containermetal must have high thermal conductivity, and the heat must bequickly carried away and stored or dissipated. When convection cool-ing is difficult or not possible, cooling may be accomplished by a heatsink.
Heat-sink cooling
depends on the heat absorption capabilityof the structural material itself or backed up by another material of higher heat absorption. Copper, beryllium, graphite, and berylliumoxide have been used. Aheat-sink material should have high thermal
2
ABLATIVES