Micms Doc Admin

Benzyl alcohol
Safety Data Sheet

according to Regulation (EC) No. 453/2010 Revision date: 16/04/2012 Supersedes: 30/03/2011 Version: 2.1
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier : Benzyl alcohol : 603-057-00-5 : 202-859-9 : 100-51-6 : 01-2119492630-38-0001 : Benzene methanol, Phenylcarbinol, a-Hydroxytoluene, Phenylmethanol, (Hydroxymethyl)benzene, a-Toluenol Substance name EC index no EC no CAS No. REACH registration No. Synonyms 1.2. 1.2.1.
Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses : Industrial use,Professional use,Consumer use : ES1 : Manufacture of substances ES2 : Formulation of preparations (mixtures) ES3 : Industrial use of chemicals ES4 : Professional uses: Public domain (administration, education, entertainment, services, craftsmen) ES5 : Consumer uses: Private households (= general public = consumers) Most common technical function of the substance : Intermediate Use in laboratories Solvent Photosensitive agents and other photo-chemicals Viscosity adjustors Odour agents Flow improver
Main use category Use of the substance/preparation
1.2.2.
Uses advised against
No additional information available 1.3. Details of the supplier of the safety data sheet
EMERALD KALAMA CHEMICAL B.V. Havennr. 4322 - Montrealweg 15 3197 KH Rotterdam-Botlek - THE NETHERLANDS T +31 (0)888880500 - F +31 (0)888880520 purox.info@emeraldmaterials.com 1.4. Emergency telephone number Official advisory body / Company Emerald Kalama Chemical B.V.
SHEQ Dept. Emerald Kalama Chemical B.V. Rotterdam
Country THE NETHERLANDS
Address
Havennr. 4322 - Montrealweg 15 3197 KH Rotterdam-Botlek
Emergency number Chemtell (contract MIS0007388) 1-800-255-3924 (USA) +001-813-248-0585 (outside USA)
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 4 (Inhalation) H332 Acute Tox. 4 (Oral) H302 Eye Irrit. 2 H319 Full text of H-phrases: see section 16. Classification according to Directive 67/548/EEC or 1999/45/EC Xn; R20/22 Xi; R36 Full text of R-phrases: see section 16. Adverse physicochemical, human health and environmental effects Harmful if swallowed. Harmful by inhalation. Causes serious eye irritation.
16/04/2012
EN (English)
1/7
Benzyl alcohol
Safety Data Sheet
according to Regulation (EC) No. 453/2010
2.2.
Label elements :
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP)
GHS07
CLP Signal word Hazard statements (CLP)
: Warning : H302 - Harmful if swallowed H319 - Causes serious eye irritation H332 - Harmful if inhaled : P102 - Keep out of reach of children P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P270 - Do no eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Precautionary statements (CLP)
2.3.
Other hazards : Combustible. The product does not meet the PBT and vPvB classification criteria.
Other hazards not contributing to the classification
SECTION 3: Composition/information on ingredients

3.1. Name
Benzyl alcohol
Substances Product identifier

(CAS No.) 100-51-6 (EC no) 202-859-9 (EC index no) 603-057-00-5 (REACH-no) 01-2119492630-38-0001
%
100
Classification according to Directive 67/548/EEC

Xn; R20/22 Xi; R36
Name
Product identifier
Classification according to Regulation (EC) No. 1272/2008 [CLP]

Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319
Benzyl alcohol
(CAS No.) 100-51-6 (EC no) 202-859-9 (EC index no) 603-057-00-5 (REACH-no) 01-2119492630-38-0001
100
Full text of R-, H- and EUH-phrases: see section 16. 3.2. Mixtures
Not applicable
SECTION 4: First aid measures

4.1. Description of first aid measures : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Do not attempt to take action without suitable protective equipment Move the affected person away from the contaminated area and into the fresh air Take off contaminated clothes. : Remove to fresh air and keep at rest in a position comfortable for breathing Keep victim warm and rested If not breathing, give artificial respiration. Call a doctor immediately. : Wash with soapy water Remove all contaminated clothing and footwear If case of redness or irritation, call a doctor. : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutes minimum) If irritation persists, consult an eye specialist. : Rinse mouth out with water Never give anything by mouth to an unconscious person. Take medical advice immediately. First-aid measures general
First-aid measures after inhalation
First-aid measures after skin contact
First-aid measures after eye contact
First-aid measures after ingestion
4.2.
Most important symptoms and effects, both acute and delayed : Headache. Nausea. May cause drowsiness or dizziness. Loss of consciousness. Slightly irritating to the respiratory system. Cough. : May cause moderate irritation. Redness. Exposure may produce an allergic reaction. : Eye irritation. Redness.
EN (English) 2/7
Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact
16/04/2012
Benzyl alcohol
Safety Data Sheet
Symptoms/injuries after ingestion 4.3.
: Nausea. Vomiting. Headache. Disturbances of consciousness.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures

5.1. Extinguishing media : Dry powder Carbon dioxide (CO2) For a significant fire: Water spray Foam Dry powder. Suitable extinguishing media
5.2.
Special hazards arising from the substance or mixture : Vapours are explosive in air at temperatures higher than the flash point During combustion : Toxic fumes may be released (carbon oxides (CO and CO2)).
Fire hazard
5.3.
Advice for firefighters : Contain the extinguishing fluids by bunding. : Do not attempt to take action without suitable protective equipment Self-contained breathing apparatus Complete protective clothing.
Firefighting instructions Protection during firefighting
SECTION 6: Accidental release measures

6.1. 6.1.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel : Avoid contact with skin and eyes Keep away from ignition sources (including static discharges). Explosion-free electrical equipment and lighting with earth Consult an expert immediately.
Emergency procedures
6.1.2.
For emergency responders : Do not attempt to take action without suitable protective equipment For further information refer to section 8 Exposure controls/personal protection" ".
Protective equipment 6.2. Environmental precautions
Contain the spilled material by bunding. Do not discharge into drains or rivers. 6.3. Methods and material for containment and cleaning up : Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite kieselguhr, powdered limestone Put into a labelled container and provide safe disposal. Flame proof, lighting, electrical equipment and ventilation. No flames, No sparks. Eliminate all sources of ignition. : Wash non-recoverable remainder with large amounts of water. : Dispose of contaminated materials in accordance with current regulations.
For containment
Methods for cleaning up Other information 6.4. Reference to other sections
For further information refer to section 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling : Ensure good ventilation of the work station Avoid contact with skin and eyes Do not breathe vapours. Use personal protective equipment as required Flame proof, lighting, electrical equipment and ventilation. Keep away from ignition sources (including static discharges). : Do not drink, eat or smoke in the workplace Always wash hands after handling the product. Precautions for safe handling
Hygiene measures 7.2.
Conditions for safe storage, including any incompatibilities : Provide local exhaust or general room ventilation. Keep in fireproof place. : Keep in a cool, well-ventilated place away from heat Keep under inert gas Keep container tightly closed. Keep away from incompatible materials Avoid any contamination of the product by other substances.
EN (English) 3/7
Technical measures Storage conditions
16/04/2012
Benzyl alcohol
Safety Data Sheet
Incompatible materials Storage temperature Packaging materials 7.3. Specific end use(s)
: iron aluminium. : -12-50 C : Ordinary steel polyethylene.
Not applicable.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters Benzyl alcohol (100-51-6) DNEL/DMEL (Workers) Acute - systemic effects, dermal Acute - systemic effects, inhalation Long-term - systemic effects, dermal Long-term - systemic effects, inhalation DNEL/DMEL (General population) Acute - systemic effects, dermal Acute - systemic effects, inhalation Acute - systemic effects, oral Long-term - systemic effects,oral Long-term - systemic effects, inhalation Long-term - systemic effects, dermal 8.2. Exposure controls : Ensure good ventilation of the work station Flame proof, lighting, electrical equipment and ventilation. : Butyl-rubber protective gloves VITON gloves Breakthrough time (min) : > 480 Incompatible materials : Nitrile-rubber protective gloves neoprene/natural rubber Protective gloves made of latex. : Safety spectacles with side shields. : Protective clothing. : Gas mask with filter type A. : Take all necessary precautions to avoid the accidental release of the product outside, due to the rupture of containers or transfer systems. Appropriate engineering controls Hand protection
47 mg/kg bodyweight 450 mg/m 9,5 mg/kg bodyweight/day 90 mg/m 29 mg/kg bodyweight 40 mg/m 25 mg/kg bodyweight 5 mg/kg bodyweight/day 8,11 mg/m 5,7 mg/kg bodyweight/day
Eye protection Skin and body protection Respiratory protection Environmental exposure controls
SECTION 9: Physical and chemical properties

9.1. Colour Odour Odour threshold pH Melting point Boiling point Flash point Relat. evapor. rate comp. to butylacetate Flammability (solid, gas) Explosive limits Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Self ignition temperature Decomposition temperature Viscosity, kinematic
16/04/2012
Information on basic physical and chemical properties : Liquid : Colourless. : Mildly aromatic. : Not established. : No data available : -15,4 C (1013 hPa) (Handbook) : 205,3 C (1013 hPa) (Handbook) : 100,4 C (1013 hPa) (Handbook) : No data available : Non flammable.(expert statement) : LEL 1,3% / UEL 13% : 22,26 Pa (25 C) (Handbook) : No data available : 1,045 (20 C) (Handbook) : Material highly soluble in water. (> 1000 mg/l). Water: 40 g/l (25 C) (Handbook) : 1,05 (25 C) (Handbook) : 436 C (1013 hPa) (Handbook) : No data available : No data available
EN (English) 4/7
Physical state
Benzyl alcohol
Safety Data Sheet
Viscosity, dynamic Explosive properties Oxidising properties 9.2. Other information
: 5,84 mPa.s (25 C) : LEL 1,3% / UEL 13% : Not applicable. (expert statement).
Other properties
: Surface tension : 39 mN/m (20 C) (1 g/l) (OECD 115, EC A.5).
SECTION 10: Stability and reactivity

10.1. Reactivity To our knowledge, the product does not present any particular risk. 10.2. Chemical stability
Stable at ambient temperature and under normal conditions of use. 10.3. Possibility of hazardous reactions
Air contact may form hazardous compounds. : Benzaldehyde. 10.4. Conditions to avoid
No flames, No sparks. Eliminate all sources of ignition Air sensitive. 10.5. Incompatible materials
Air. Acids Oxidizing materials aluminium Iron Synthetic material. 10.6. Hazardous decomposition products
on contact with air. : Benzaldehyde.
SECTION 11: Toxicological information

11.1. Information on toxicological effects : Harmful if inhaled. Harmful if swallowed. Acute toxicity Benzyl alcohol (100-51-6) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard
1620 mg/kg No data available > 4178 mg/m (OECD 403) : Not classified (OECD 404) : Causes serious eye irritation. (OECD 405) : Not classified (OECD 406) : Not classified (Based on available data, the classification criteria are not met) : Not classified (Based on available data, the classification criteria are not met) : Not classified (Based on available data, the classification criteria are not met) : Not classified (Based on available data, the classification criteria are not met) : Not classified (Based on available data, the classification criteria are not met) : Not classified (Based on available data, the classification criteria are not met)
SECTION 12: Ecological information

12.1. Toxicity Benzyl alcohol (100-51-6) LC50 fish EC50 Daphnia EC50 other aquatic organisms NOEC (chronic) ErC50 (algae) 12.2. Persistence and degradability
460 mg/l/96h (OECD 203) 230 mg/l/48h (Daphnia magna) (OECD 202) 390 mg/l/24h (inhibition of microbial activity)(ISO 8192 / ISO DIS 9509) 51 mg/l/ 21 d (Daphnia magna) (OECD 211) 770 mg/l/72h (OECD 201)
Benzyl alcohol (100-51-6) Persistence and degradability

16/04/2012
Readily biodegradable (OECD 301C & 301A).

EN (English) 5/7
Benzyl alcohol
Safety Data Sheet
12.3.
Bioaccumulative potential
Benzyl alcohol (100-51-6) Log Pow 12.4. Mobility in soil
1,05 (25 C) (Handbook)
Benzyl alcohol (100-51-6) Mobility in soil 12.5. Results of PBT and vPvB assessment
No data available
Benzyl alcohol (100-51-6) Results of PBT assessment 12.6. Other adverse effects
The product does not meet the PBT and vPvB classification criteria
No additional information available
SECTION 13: Disposal considerations

13.1. Waste treatment methods : Dispose of in accordance with relevant local regulations. Waste treatment methods
SECTION 14: Transport information

In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA 14.1. UN number UN-No. 14.2. UN proper shipping name : UN 9003 (ADNR) : 9003 (ADNR)
Transport document description 14.3. Transport hazard class(es)
Class (ADNR) : 9 - Miscellaneous dangerous substances and articles 14.4. Packing group : Not applicable
Packing group (UN) 14.5. Environmental hazards
Other information 14.6. 14.6.1. 14.6.2. 14.6.3. Special precautions for user Overland transport Transport by sea Air transport
: No supplementary information available.
No additional information available No additional information available No additional information available 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information

15.1. 15.1.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations
No additional information available 15.1.2. National regulations
No additional information available 15.2. Chemical safety assessment
A chemical safety assessment has been carried out.
SECTION 16: Other information

Data sources : CSR (Chemical safety report). Full text of R-, H- and EUH-phrases: ------ Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (Oral) Category 4 ------ Eye Irrit. 2 Serious Eye Damage/Irritation Category 2
16/04/2012 EN (English) 6/7
Benzyl alcohol
Safety Data Sheet
--------------------------
H302 H319 H332 R20/22 R36
Harmful if swallowed Causes serious eye irritation Harmful if inhaled Harmful by inhalation and if swallowed. Irritating to eyes.
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
16/04/2012
EN (English)
7/7
Substance
Explanation of acronyms
ANNEX TO THE SAFETY DATA SHEET SDS Reference Benzyl alcohol Version Exposure scenario 1
SU: Sector of use PROC: Process category ERC: Environmental release category PPE: Personal protection equipment PC: Product category
1 Page1 of 4
1 Exposure scenario (1) Manufacture of substances : Benzyl alcohol Use descriptors related to the life cycle stage Name of contributing environmental scenario (1) and corresponding ERC List of names of contributing worker scenarios (2) and corresponding PROC SU8/9 PROC1/2/3/8b/9 ERC1 1. 1. 2. 3. 4. Manufacture of substances (ERC1) Use in closed process, no likelihood of exposure (PROC1) Use in closed, continuous process with occasional controlled exposure (PROC2) Use in closed batch process (synthesis or formulation) (PROC3) Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities (PROC8b) Transfer of substance or preparation into small containers (dedicated filling line, including weighing) (PROC9)
5.
2.1 Contributing scenario (1) controlling environmental exposure Product characteristic Amounts used Frequency and duration of use Environmental factors not influenced by risk management Other given operational conditions affecting environment exposure Technical conditions and measures at process level (source) to prevent release Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Liquid, 100 % substance in the product Number of sites : 1,8250 t/ year Emission per site : 300 days/year Continuous 300 days/year Dilution factor for surface water : 10 (by default) (Coastal zone : 100) There is practically no disposal or run-off into soil, wastewater, drains and sewers Local exhaust ventilation (Efficiency > 99.9 %) Practically no release to waste water and soil Store in original container. Keep container tightly closed. Store in dry, cool, well-ventilated area. Protect from sunlight Use only organic solvents for cleaning the equipment Wet scrubber are used to minimize the emission to air (Efficiency >98 %) Small spillages: Soak up small spill with inert solids. Use suitable disposal containers. Wash contaminated area with large amounts of water Significant spillages: Prevent liquid from entering sewers, watercourses, underground or low areas Take up liquid spill into inert absorbent material, e.g.: sand/earth Recycle or dispose of in compliance with current legislation
Substance
1 Page2 of 4
Organizational measures to prevent/limit release from site Conditions and measures related to municipal sewage treatment plant Conditions and measures related to external treatment of waste for disposal Conditions and measures related to external recovery of waste
Explosion-free electrical equipment and lighting with earth Remove ignition sources. All personnel are trained Size of the STP : 2000 m/day (by default) No release to the sewage treatment plant during manufacturing
All waste and organic cleaning solutions are disposed of by incineration

Not applicable
2.2 Contributing scenario (2) controlling worker exposure All Process Categories are covered by this contributing scenario as all Operational Conditions (OCs) and Risk Management Measures (RMMs) are identical. PROC1/2/3/8b/9 Product characteristic Product related conditions, e.g. the concentration of the substance in a mixture, the physical state of that mixture (solid, liquid; if solid: level of dustiness), package design affecting exposure: Amounts used Amounts used at a workplace (per task or per shift); note: sometimes this information is not needed for assessment of workers exposure Frequency and duration of use/exposure Duration per task/activity (e.g. hours per shift) and frequency (e.g. single events or repeated) of exposure Particular conditions of use, e.g. body parts potentially exposed as a result of the nature of the activity : Other given operational conditions: e.g. technology or process techniques determining the initial release of substance from process into workers environment; room volume, whether the work is carried out outdoors/indoors, process conditions related to temperature and pressure: Process design aiming to prevent releases and hence exposure of workers; this in particular includes conditions ensuring rigorous containment; performance of containment to be specified (e.g. by quantification of residual losses or exposure) Engineering controls, e.g. exhaust ventilation, 8 hours per day 230 days/year 65 t/ days Emission per site : 250 days/year Liquid, 100 % substance in the product
Human factors not influenced by risk management Body weight : 70 kg Respiration volume : 10 m / 8h per day (light activity)
Other given operational conditions affecting workers exposure Wear recommended personal protective equipment. All personnel are trained
Technical conditions and measures at process level (source) to prevent release Local exhaust ventilation
Technical conditions and measures to control dispersion from source towards the worker Direct contact with the substance can be practically
Substance
1 Page3 of 4
general ventilation; specify effectiveness of measure :
excluded as the substance is produced in closed systems and appropriate protective measures are in place All personnel are trained Wear recommended personal protective equipment. Store in a dry area (-12.2C / 50 C)
Organisational measures to prevent /limit releases, dispersion and exposure Specific organisational measures or measures needed to support the functioning of particular technical measures (e.g. training and supervision). Those measures need to be reported in particular for demonstrating strictly controlled conditions (to justify exposure based waiving) : Personal protection, e.g. wearing of gloves, face protection, full body dermal protection, goggles, respirator; specify effectiveness of measure; specify the suitable material for the PPE (where relevant) and advise how long the protective equipment can be used before replacement (if relevant) :
Conditions and measures related to personal protection, hygiene and health evaluation Wear recommended personal protective equipment. : Gas mask with filter type A Butyl-rubber protective gloves VITON gloves Safety spectacles with side shields Protective clothing Do not eat, drink or smoke when using this product All personnel are trained Always wash hands after handling the product Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
Exposure information and reference to its source
Information for contributing scenario 1 Environmental exposure has been calculated using EUSES v2.1 Exposure estimation Fresh water Marine water Sediment (freshwater) Sediment (marine water) Soil. STP Information for contributing scenario 2 Workers exposure estimation has been calculated using ECETOC TRA Only highest figures are presented here for the contributing scenarios for human health For all calculations, please refer to the CSR Workers exposure Long-term - systemic effects, dermal Long-term - systemic effects, inhalation Long-term- systemic effects, combined routes Exposure estimation 0,686 mg/kg bw/day 2,25 mg/m 1,01 mg/kg bw/day DNEL 9,5 mg/kg bodyweight/day 90 mg/m/day 9.5 mg/kg bw/day 0,0048 mg/l 0,000461 mg/l 0,0248 mg/kg 0,00238 mg/kg 0,0534 mg/kg 0 mg/l PNEC 1 mg/l 0,1 mg/l 5,27 mg/kg dwt 0,527 mg/kg dwt 0,456 mg/kg dwt 39 mg/l
Substance
1 Page4 of 4
Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Local exhaust ventilation No gloves or respiratory protection are required
Substance
1 Page1 of 4
1 Exposure scenario (2) Formulation of preparations (mixtures) Use descriptors related to the life cycle stage SU10 PC0/1/3/8/9a/9b/9c/14/15/18/19/20/21/23/24/26/27/28/29/30/31/32/34/35/39 PROC1/2/3/4/5/8a/8b/9/19 ERC2/3 1. 2. 1. 2. 3. 4. 5. 6. 7. 8. 9. Formulation of preparations (ERC2) Formulation in materials (ERC3) Use in closed process, no likelihood of exposure (PROC1) Use in closed, continuous process with occasional controlled exposure (PROC2) Use in closed batch process (synthesis or formulation) (PROC3) Use in batch and other process (synthesis) where opportunity for exposure arises (PROC4) Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) (PROC5) Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities (PROC8a) Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities (PROC8b) Transfer of substance or preparation into small containers (dedicated filling line, including weighing) (PROC9) Hand-mixing with intimate contact and only PPE available (PROC19)
Name of contributing environmental scenario (1) and corresponding ERC List of names of contributing worker scenarios (2) and corresponding PROC
2.1 Contributing scenario (1) controlling environmental exposure Formulation of preparations (ERC2) Formulation in materials (ERC3) Product characteristic Amounts used Liquid, 100 % substance in the product Number of sites : > 1 Annual amount used in region : 10% Annual amount used per site : 5250 t (ERC2) - 3010 t (ERC3) Emission per site : 300 days/year (ERC2) - 100 days/year (ERC3) Continuous 300 days/year (ERC2) - 100 days/year (ERC3) Dilution factor for surface water : 10 (by default) (Coastal zone : 100) There is practically no disposal or run-off into soil, wastewater, drains and sewers
Frequency and duration of use Environmental factors not influenced by risk management Other given operational conditions affecting environment exposure Technical conditions and measures at process level (source) to prevent release Technical onsite conditions and measures to reduce or limit
Local exhaust ventilation (Efficiency > 99.9 %) Practically no release to waste water and soil Store in original container. Keep container tightly closed. Store in dry, cool, well-ventilated area.
Substance
1 Page2 of 4
discharges, air emissions and releases to soil Organizational measures to prevent/limit release from site Conditions and measures related to municipal sewage treatment plant Conditions and measures related to external treatment of waste for disposal Conditions and measures related to external recovery of waste
Protect from sunlight Use only organic solvents for cleaning the equipment All personnel are trained
Size of the STP : 2000 m/day (by default)
All waste and organic cleaning solutions are disposed of by incineration.
Not applicable
2.2 Contributing scenario (2) controlling worker exposure Formulation of preparations (mixtures) All Process Categories are covered by this contributing scenario as all Operational Conditions (OCs) and Risk Management Measures (RMMs) are identical. PROC1/2/3/4/5/8a/8b/9/19 Product characteristic Product related conditions, e.g. the concentration of the substance in a mixture, the physical state of that mixture (solid, liquid; if solid: level of dustiness), package design affecting exposure: Amounts used Amounts used at a workplace (per task or per shift); note: sometimes this information is not needed for assessment of workers exposure Duration per task/activity (e.g. hours per shift) and frequency (e.g. single events or repeated) of exposure Particular conditions of use, e.g. body parts potentially exposed as a result of the nature of the activity : Other given operational conditions: e.g. technology or process techniques determining the initial release of substance 0.8 t/ days Emission per site : 250 days/year Liquid, 100 % substance in the product
Frequency and duration of use/exposure 8 hours per day 230 days/year
Human factors not influenced by risk management Body weight : 70 kg Respiration volume : 10 m / 8h per day (light activity)
Other given operational conditions affecting workers exposure Wear recommended personal protective equipment. All personnel are trained
Substance
1 Page3 of 4
from process into workers environment; room volume, whether the work is carried out outdoors/indoors, process conditions related to temperature and pressure: Technical conditions and measures at process level (source) to prevent release Process design aiming to prevent releases and hence exposure of workers; this in particular includes conditions ensuring rigorous containment; performance of containment to be specified (e.g. by quantification of residual losses or exposure) Engineering controls, e.g. exhaust ventilation, general ventilation; specify effectiveness of measure :
Substance release can be practically excluded. Formulation occurs to a large extent in closed systems.
Local exhaust ventilation No waste water is produced The incidental waste is collected in suitable containers and stored until disposal
Technical conditions and measures to control dispersion from source towards the worker Direct contact with the substance can be practically excluded as the substance is produced in closed systems and appropriate protective measures are in place Wear recommended personal protective equipment.
Organisational measures to prevent /limit releases, dispersion and exposure Specific organisational measures or measures needed to support the functioning of particular technical measures (e.g. training and supervision). Those measures need to be reported in particular for demonstrating strictly controlled conditions (to justify exposure based waiving) : Personal protection, e.g. wearing of gloves, face protection, full body dermal protection, goggles, respirator; specify effectiveness of measure; specify the suitable material for the PPE (where relevant) and advise how long the protective equipment can be used before replacement (if relevant) : 3 Store in a dry area (-12.2 C / 50 C)
Conditions and measures related to personal protection, hygiene and health evaluation Breathing apparatus Protective gloves Chemical goggles Protective clothing Do not eat, drink or smoke when using this product Always wash hands after handling the product Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. All personnel are trained.
Information for contributing scenario 1 Environmental exposure has been calculated using EUSES v2.1 Exposure estimation Fresh water 0,226 mg/l (ERC2) 0,0428 mg/l (ERC3) PNEC 1 mg/l
Substance
1 Page4 of 4
Marine water Sediment (freshwater) Sediment (marine water) Soil. STP
0,0226 mg/l (ERC2) 4,26E-03 mg/l (ERC3) 1,17 mg/kg (ERC2) 0,221 mg/l (ERC3) 0,117 mg/kg (ERC2) 0,022 mg/l (ERC3) 0,0767 mg/kg (ERC2) 0,0264 mg/l (ERC3) 2,21 mg/l (ERC2) 0,38 mg/l (ERC3)
0,1 mg/l 5,27 mg/kg dwt 0,527 mg/kg dwt 0,456 mg/kg dwt 39 mg/l
Information for contributing scenario 2 Workers exposure estimation has been calculated using ECETOC TRA Only highest figures are presented here for the contributing scenarios for human health For all calculations, please refer to the CSR Workers exposure Long-term - systemic effects, dermal Exposure estimation 1,41 mg/kg bodyweight/day (Industrial use) 1,41 mg/kg bodyweight/day (Professional use.) Long-term - systemic effects, inhalation Long-term - systemic effects, combined routes 4,51 mg/m (Industrial use) 22,5 mg/m (Professional use.) 2,05 mg/kg bodyweight/day (Industrial use) 4,62 mg/kg bodyweight/day (Professional use.) 90 mg/m 9,5 mg/kg bodyweight/day DNEL 9,5 mg/kg bodyweight/day
Local exhaust ventilation Hand-mixing with intimate contact and only PPE available (PROC19) : Wear gloves (Efficiency : 90%)
Substance
1 Page1 of 4
1 Exposure scenario (3) Industrial use of chemicals Use descriptors related to the life cycle stage SU3 PC 0 (PROC 5/7/8a/8b/9/10/13/14/15/19) - spERC ESVOC 3 (ERC4); spERC EFCC 4 (ERC4) PC 1 (PROC 5/7/8a/8b/9/10/12/13/14) - spERC ESVOC 5 (ERC4) PC 9a/b/c (PROC 5/7/8a/8b/9/10/13) - spERC ESVOC 5 (ERC4) PC 14 (PROC 5/8a/8b/9/15/23/24/25) - spERC ESVOC 5 (ERC4) PC 15 (PROC 5/8a/8b/9/15) - spERC ESVOC 5 (ERC4) PC 18 (PROC 7/8a/8b/9/10/13) - spERC ESVOC 5 (ERC4) PC 19 (PROC 1/2/3) - ERC6a PC 24 (PROC 18) - ERC7 PC 26 (PROC 5/6/7/8b/10/13/14) - ERC4 PC 30 (PROC 8a/8b) - ERC4 PC 32 (PROC 13) - ERC4 PC 34 (PROC 5/6/7/8a/8b/9/10/13/14) - spERC TEGEWA6 (ERC4) PC 35 (PROC 7/8a/8b/9/10/13) - spERC ESVOC 8 (ERC4, 6a) Industrial use of processing aids in processes and products, not becoming part of articles (ERC4) Industrial use of reactive processing aids (ERC6b) For the signification of the codes used, see the ECHA guidance chapter R.12 "Use descriptor system"
Name of contributing environmental scenario (1) and corresponding ERC
List of names of contributing worker scenarios (2) and corresponding PROC
2.1 Contributing scenario (1) controlling environmental exposure Industrial use of processing aids in processes and products, not becoming part of articles (ERC4) Industrial use of reactive processing aids (ERC6b) Product characteristic Amounts used Liquid <= 40 % substance in the product Number of sites : > 1 Annual amount used in region : 10% PC26 (ERC4) : 5t PC30 (ERC4) : 50t PC32 (ERC4) : 5t PC0 (spERC ESVOC 3) (ERC4) : 5t PC1,9a,9b,9c,14,15,18 (spERC ESVOC 5) (ERC4) : 510t PC35 (spERC ESVOC 8) (ERC4) : 100t PC0 (spERC EFCC 4) (ERC4) : 3000t PC34 (spERC TEGEWA 6) (ERC4): 5t PC19 (ERC6a) : 300t PC35 (spERC ESVOC 8) (ERC6b) : 100t PC24 (ERC7) : 5t Continuous PC26 (ERC4) : 1 days/year PC30 (ERC4) : 300 days/year PC32 (ERC4) : 1 days/year
Frequency and duration of use
Substance
1 Page2 of 4
spERC ESVOC 3 (ERC4) : 300 days/year spERC ESVOC 5 (ERC4) : 300 days/year spERC ESVOC 8 (ERC4) : 20 days/year spERC EFCC 4) (ERC4) : 220 days/year spERC TEGEWA 6 (ERC4): 220days/year ERC6a : 20 days/year spERC ESVOC 8 (ERC6b) : 20 days/year ERC7 : 20 days/year Environmental factors not influenced by risk management Other given operational conditions affecting environment exposure Technical conditions and measures at process level (source) to prevent release Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Organizational measures to prevent/limit release from site Conditions and measures related to municipal sewage treatment plant Conditions and measures related to external treatment of waste for disposal Conditions and measures related to external recovery of waste Dilution factor for surface water : 10 (by default) (Coastal zone : 100) Avoid release to the environment Local exhaust ventilation (Efficiency > 99.9 %) Practically no release to waste water and soil Store in original container. Store in dry, cool, well-ventilated area. Protect from sunlight Use only organic solvents for cleaning the equipment All personnel are trained Size of the STP : 2000 m/day (by default) Dispose of in accordance with relevant local regulations Not applicable
2.2 Contributing scenario (2) controlling worker exposure Product characteristic Product related conditions, e.g. the concentration of the substance in a mixture, the physical state of that mixture (solid, liquid; if solid: level of dustiness), package design affecting exposure: Amounts used Amounts used at a workplace (per task or per shift); note: sometimes this information is not needed for assessment of workers exposure Frequency and duration of use/exposure Duration per task/activity (e.g. hours per shift) and frequency (e.g. single events or repeated) of exposure 8 hours per day 230 days/year Not relevant Solid Liquid <= 40 % substance in the product
Human factors not influenced by risk management Particular conditions of use, e.g. body parts potentially exposed as a result of the nature of the Body weight : 70 kg Respiration volume : 10 m / 8h per day (light activity)
Substance
1 Page3 of 4
activity : Other given operational conditions affecting workers exposure Other given operational conditions: e.g. technology or process techniques determining the initial release of substance from process into workers environment; room volume, whether the work is carried out outdoors/indoors, process conditions related to temperature and pressure: Process design aiming to prevent releases and hence exposure of workers; this in particular includes conditions ensuring rigorous containment; performance of containment to be specified (e.g. by quantification of residual losses or exposure) Engineering controls, e.g. exhaust ventilation, general ventilation; specify effectiveness of measure : Specific organisational measures or measures needed to support the functioning of particular technical measures (e.g. training and supervision). Those measures need to be reported in particular for demonstrating strictly controlled conditions (to justify exposure based waiving) : Wear recommended personal protective equipment. All personnel are trained
Technical conditions and measures at process level (source) to prevent release Not applicable
Technical conditions and measures to control dispersion from source towards the worker Not applicable
Organisational measures to prevent /limit releases, dispersion and exposure Store in a dry area (-12.2 C / 50 C)
Conditions and measures related to personal protection, hygiene and health evaluation Personal protection, e.g. wearing of gloves, face protection, full body dermal protection, goggles, respirator; specify effectiveness of measure; specify the suitable material for the PPE (where relevant) and advise how long the protective equipment can be used before replacement (if relevant) : Breathing apparatus Protective gloves Chemical goggles Protective clothing Do not eat, drink or smoke when using this product Always wash hands after handling the product Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. All personnel are trained
Information for contributing scenario 1 Environmental exposure has been calculated using EUSES v2.1 See documents in appendix nr II Information for contributing scenario 2 Workers exposure estimation has been calculated using ECETOC TRA See documents in appendix nr II
Industrial. :
Substance
1 Page4 of 4
Local exhaust ventilation Industrial spraying (PROC7) : During spraying wear suitable respiratory equipment (Efficiency : 95%) Professional use (PROC23abc, 24abc, 25abc) : Solid (For a substance content : 100%) : Local exhaust ventilation No gloves or respiratory protection are required
Substance
1 Page1 of 4
1 Exposure scenario (4) Professional use Use descriptors related to the life cycle stage SU22 PC 0 (PROC 5/8a/8b/9/10/11/13/19) - ERC8a/8d PC 1 (PROC 5/8a/8b/9/10/11/13/19) - ERC8a/8d PC 9a/9b9/c (PROC 5/8a/8b/9/10/11/13/19) - ERC8a/8d PC 14 (PROC 8a/8b/9/10/11/13/19/23/24/25) - ERC8a/8d PC 15 (PROC 8a/8b/9/10/11/13/19) - ERC8a/8d PC 18 (PROC 5/8a/8b/10/11/13/19) - ERC8a/8d PC 21 (PROC 8a/8b/15) - ERC8a/8d PC 26 (PROC 5/6/8a/8b/11/13/14/19/21) - ERC8a/8d PC 30 (PROC 8a/8b) - ERC8a/8d PC 31 (PROC 8b/10/11) - ERC8a/8d PC 32 (PROC 8a/8b/9/10/11) - ERC48a/8d PC 35 (PROC 8a/8b/9/10/11/13/19) - ERC8a/8b/8d/8e 1. 2. 3. 4. Wide dispersive indoor use of processing aids in open systems (ERC8a) Wide dispersive indoor use of reactive substances in open systems (ERC8b) Wide dispersive outdoor use of processing aids in open systems (ERC8d) Wide dispersive outdoor use of reactive substances in open systems (ERC8e)
Name of contributing environmental scenario (1) and corresponding ERC
List of names of contributing worker scenarios (2) and corresponding PROC
For the signification of the codes used, see the ECHA guidance chapter R.12 "Use descriptor system"
2.1 Contributing scenario (1) controlling environmental exposure Wide dispersive indoor use of processing aids in open systems (ERC8a) Wide dispersive indoor use of reactive substances in open systems (ERC8b) Wide dispersive outdoor use of processing aids in open systems (ERC8d) Wide dispersive outdoor use of reactive substances in open systems (ERC8e) Product characteristic Amounts used <= 40 % substance in the product Number of sites : > 1 Annual amount used in region : 10% ERC8a PC0,1,9a,9b,9c,14,15,18,21,26,30,31,32,34,35 : 3685t ERC8b PC35 : 155t ERC8d PC0,1,9a,9b,9c,14,15,18,21,26,31,32,34,35 : 3625t ERC8e PC35 : 100t Fraction of the main local source : 0.002 Emission per site : 365 days/year Continuous 365 days/year Dilution factor for surface water : 10 (by default) (Coastal zone : 100) Not applicable Keep container closed when not in use Dispose of contaminated materials in accordance with current regulations
Frequency and duration of use Environmental factors not influenced by risk management Other given operational conditions affecting environment exposure Technical conditions and measures at process level (source) to prevent release
Substance
1 Page2 of 4
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Organizational measures to prevent/limit release from site Conditions and measures related to municipal sewage treatment plant Conditions and measures related to external treatment of waste for disposal Conditions and measures related to external recovery of waste
Keep container tightly closed. Avoid release to the environment All personnel are trained Size of the STP : 2000 m/day (by default) Dispose of in accordance with relevant local regulations Not applicable
2.2 2.2 Contributing scenario (2) controlling worker exposure Product characteristic Product related conditions, e.g. the concentration of the substance in a mixture, the physical state of that mixture (solid, liquid; if solid: level of dustiness), package design affecting exposure: Amounts used Amounts used at a workplace (per task or per shift); note: sometimes this information is not needed for assessment of workers exposure Frequency and duration of use/exposure Duration per task/activity (e.g. hours per shift) and frequency (e.g. single events or repeated) of exposure Particular conditions of use, e.g. body parts potentially exposed as a result of the nature of the activity : Other given operational conditions: e.g. technology or process techniques determining the initial release of substance from process into workers environment; room volume, whether the work is carried out outdoors/indoors, process conditions related to temperature and pressure: Process design aiming to prevent releases and hence exposure of workers; this in particular includes conditions ensuring rigorous containment; performance of containment to be specified (e.g. by quantification of residual losses or exposure) Engineering controls, e.g. exhaust ventilation, 8 hours per day 230 days/year Not relevant <= 40 % substance in the product
Human factors not influenced by risk management Body weight : 70 kg Respiration volume : 10 m / 8h par day (light activity)
Other given operational conditions affecting workers exposure Wear recommended personal protective equipment.
Technical conditions and measures at process level (source) to prevent release Not applicable
Technical conditions and measures to control dispersion from source towards the worker Not applicable
Substance
1 Page3 of 4
general ventilation; specify effectiveness of measure : Organisational measures to prevent /limit releases, dispersion and exposure Specific organisational measures or measures needed to support the functioning of particular technical measures (e.g. training and supervision). Those measures need to be reported in particular for demonstrating strictly controlled conditions (to justify exposure based waiving) : Personal protection, e.g. wearing of gloves, face protection, full body dermal protection, goggles, respirator; specify effectiveness of measure; specify the suitable material for the PPE (where relevant) and advise how long the protective equipment can be used before replacement (if relevant) : Store in a dry area (-12.2 C / 50 C)
Conditions and measures related to personal protection, hygiene and health evaluation Breathing apparatus Protective gloves Chemical goggles Protective clothing Do not eat, drink or smoke when using this product Always wash hands after handling the product Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. All personnel are trained
Information for contributing scenario 1 Environmental exposure has been calculated using EUSES v2.1 See documents in appendix nr II Information for contributing scenario 2 Workers exposure estimation has been calculated using ECETOC TRA See documents in appendix nr II
For a substance content < 5 % No local exhaust ventilation Non industrial spraying (PROC11) : During spraying wear suitable respiratory equipment. (Efficiency : 95%) Hand-mixing with intimate contact and only PPE available (PROC19) : Wear gloves. (Efficiency 90%) For a substance content >=5% - < 25% : No local exhaust ventilation (Exception : roller application or brushing indoors (PROC10) only in the presence of LEV for a work duration of 8 hours) Gloves (90 % efficiency) indoors and outdoors Non industrial spraying (PROC11) : During spraying wear suitable respiratory equipment. (Efficiency 95%) Maximum duration of 1 hour(s) for mixing/loading operations in non-dedicated facilities (PROC8a) and hand mixing (PROC19) For a substance content >= 25 % : No local exhaust ventilation (Exception : roller application or brushing indoors (PROC10) only in the presence of LEV for a work duration of
Substance
1 Page4 of 4
8 hours) Gloves (90 % efficiency) indoors and outdoors Non industrial spraying (PROC11) : During spraying wear suitable respiratory equipment. (Efficiency : 95 %) Maximum duration of 1 hour(s) for mixing/loading operations in non-dedicated facilities (PROC8a) and hand mixing (PROC19) Maximum duration of 4 hour(s) for roller application or brushing outdoors (PROC10) Solid (100%) : No LEV and no gloves required (PROC21/23abc/24abc/25abc)
Substance
1 Page1 of 3
1 Exposure scenario (5) Consumer use Use descriptors related to the life cycle stage Name of contributing environmental scenario (1) and corresponding ERC SU21 PC 0,1,9a,9b,9c,18,31,34 (ERC8a/8d) - PC 35 (ERC8a/8b/8d/8e) 1. 2. 3. 4. Wide dispersive indoor use of processing aids in open systems (ERC8a) Wide dispersive indoor use of reactive substances in open systems (ERC8b) Wide dispersive outdoor use of processing aids in open systems (ERC8d) Wide dispersive outdoor use of reactive substances in open systems (ERC8e) Other use : Building, construction (equalizers (powders), insulation foam (spray can)) (PC0) Adhesives, sealants (PC1) Coatings and paints, thinners, paint removers (PC9a) Fillers, putties, plasters, modelling clay (PC9b) Finger paints (PC9c) Ink and toners (PC18) Polishes and wax blends (PC31) Textile dyes, finishing and impregnating products; including bleaches and other processing aids (PC34) Washing and cleaning products (including solvent based products) (PC35)
List of names of contributing consumer scenarios (2) and corresponding PC and sub-product categories if applicable
1. 2. 3. 4. 5. 6. 7. 8. 9.
2.1 Contributing scenario (1) controlling environmental exposure Wide dispersive indoor use of processing aids in open systems (ERC8a) Wide dispersive indoor use of reactive substances in open systems (ERC8b) Wide dispersive outdoor use of processing aids in open systems (ERC8d) Wide dispersive outdoor use of reactive substances in open systems (ERC8e) Product characteristic Paste Liquid <= 50 % substance in the product Annual amount used in region : 10% ERC8a PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35: 3,685 t ERC8b PC35: 155 t ERC8d PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35: 3,625 t ERC8e PC35: 100t Fraction of the main local source : 0.002 Emission per site : 365 days/year Frequency and duration of use Environmental factors not influenced by risk management Other given operational conditions affecting Continuous,365 days/year Dilution factor for surface water : 10 (by default),(Coastal zone : 100) None
Amounts used
Substance
1 Page2 of 3
environment exposure Conditions and measures related to municipal sewage treatment plant Conditions and measures related to external treatment of waste for disposal Conditions and measures related to external recovery of waste Size of the STP : 2000 m/day (by default) Dispose of in accordance with relevant local regulations None
2.2 Contributing scenario (2) consumer end-use
Product characteristic Product related conditions, e.g. the concentration of the substance in a mixture, the physical state of that mixture (solid, liquid; if solid: level of dustiness), package design affecting exposure: - PC0: covered by PC1, PC9a (up to 25%) and PC9b (up to 5%) - PC1: <= 25% (glues/adhesives, epoxy resins; application of wood parquet glue with gloves); <= 5% (application of wood parquet glue without gloves) - PC9a: <= 5% (paints/coatings)/<= 25% (epoxy resin-based coatings) <= 50% (paint remover) - PC9b: <= 15% (application of two-component fillers, wall plasters) <= 25% (fillers/putty from tube, mix/load twocomponent fillers, fillers-putty from spray) - PC9c: <= 5% - PC18: <= 5% - PC31: <= 5% - PC34: <= 5% - PC35: <= 10% Liquid Amounts used Amounts used per event Frequency and duration of use/exposure Duration of exposure per event and frequency of events; please note: Tier 1 exposure assessment usually refers to external event exposure, without taking into account the duration and frequency of the event (see Guidance Chapter R.15) Particular conditions of use, e.g. body parts potentially exposed; population potentially exposed (adults, children) Other operational conditions e.g. room volume, air exchange rate, outdoor or indoor use : See documents in appendix nr II See documents in appendix nr II
Human factors not influenced by risk management See documents in appendix nr II
Other given operational conditions affecting consumers exposure See documents in appendix nr II
Conditions and measures related to information and behavioral advice to consumers
Substance
1 Page3 of 3
Safety advice to be communicated to consumers in order to control exposure, e.g. technical instruction, behavioral advice Personal protection, e.g. wearing of gloves, face protection, full body dermal protection, goggles, respirator; specify effectiveness of measure; specify the suitable material for the PPE (where relevant) and advise how long the protective equipment can be used before replacement (if relevant) : 3
Refer to the MSDS before handling or disposing.
Conditions and measures related to personal protection, hygiene and health evaluation
None
Information for contributing scenario 1 Environmental exposure has been calculated using EUSES v2.1 See documents in appendix nr II Information for contributing scenario 2 Consumers exposure estimation has been calculated using ConsExpo 4.1 See documents in appendix nr II
Acute Consumer Exposure Scenarios: All acute consumer exposure scenarios are safe with the exception of the wood parquet application scenario when using a concentration of 25% BzOH (i.e. RCR < 1 after comparison of the acute exposure estimates obtained in ConsExpo with the acute/short-term DNELs for BzOH)
Chronic Consumer Exposure Scenarios: All chronic consumer exposure scenarios are safe with (i.e. RCR < 1 after comparison of the chronic exposure estimates obtained in ConsExpos with the long-term DNELs for BzOH)
SAFETY DATA SHEET

In accordance with Regulation (EC) 1907/2006 (REACH), Annex II
BENZYL ALCOHOL
Created on November 30, 2010 Revised on March 30, 2011
ANNEX II
Exposure scenario 3 Industrial uses PC0 Workers
Route
Exposure concentrations
5.64 mg/kg bw/d 4.51 mg/m
3
Leading toxic end point / Critical effect

Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity
DNEL
Long-term systemic effects
Dermal Inhalation
9.5 mg/kg bw/d 90 mg/m

3
Combined routes
6.29 mg/kg bw/d
9.5 mg/kg bw/d
Please note that in the table above the highest exposure values obtained for dermal, inhalation and combined exposure, as calculated by use of ECETOC TRA for BzOH concentrations of up to 40%, are presented. These exposure values were not necessarily obtained in the same PROC.
Environment
Compartments ERC4 spERC ESVOC3 Freshwater Marine water Freshwater sediments Marine sediments spERC EFCC4 Freshwater Marine water Freshwater sediments Marine sediments Compartments 4.8E-03 mg/l 4.61E-04 mg/l 0.0248 mg/kg 2.38E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 4.7E-03 4.52E-03 4.7E-03 4.52E-03 PEC PNEC PEC/PNEC
4.8E-03 mg/l 4.61E-04 mg/l 0.0248 mg/kg 2.38E-03 mg/kg PEC
1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg PNEC
4.7E-03 4.52E-03 4.7E-03 4.52E-03 PEC/PNEC
ERC4 spERC ESVOC3 Agricultural soil 2.95E-03 mg/kg (30 days) Grassland spERC EFCC4 Agricultural soil (30 days) Grassland Compartments 2.95E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
6.46E-03 6.46E-03
0.0391 mg/kg 0.0619 mg/kg PEC
0.456 mg/kg 0.456 mg/kg PNEC
0.0857 0.1357 PEC/PNEC
ERC4 spERC ESVOC3
Page 1 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
STP spERC EFCC4 STP
1.05E-06 mg/l 0 mg/l
39 mg/l 39 mg/l
2.7E-08 0
Exposure scenario 4 Professional uses PC0 Workers

Route
3

DNEL
Dermal Inhalation

3
Combined routes
7.49 mg/kg bw/d
9.5 mg/kg bw/d
Please note that in the table above the highest exposure values obtained for dermal, inhalation and combined exposure, as calculated by use of ECETOC TRA for BzOH concentration of 40%, are presented. These exposure values were not necessarily obtained in the same PROC.
Environment
Compartments ERC8a* Freshwater Marine water Freshwater sediments Marine sediments ERC8d** Freshwater Marine water Freshwater sediments Marine sediments 0.0173 mg/l 1.72E-03 mg/l 0.0897 mg/kg 8.87E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.017 0.0168 0.017 0.0168 ----0.0176 mg/l 1.74E-03 mg/l 0.0908 mg/kg 8.98E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0172 0.017 0.0172 0.017 ----PEC PNEC PEC/PNEC Discussion
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35 ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Compartments ERC8a* Agricultural soil (30 days) Grassland ERC8d** Agricultural soil
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg 7.04E-03 mg/kg
0.456 mg/kg 0.456 mg/kg 0.456 mg/kg
0.0156 0.0073 0.0154
----
Page 2 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
(30 days) Grassland 3.32E-03 mg/kg 0.456 mg/kg 0.0073 -The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Compartments ERC8a* STP ERC8d** STP
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Exposure scenario 5 Consumer uses PC0 Environment

Compartments ERC8a* Agricultural soil (30 days) Grassland ERC8d** Agricultural soil (30 days) Grassland
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
6.46E-03 0.0073
---
Compartments
PEC
PNEC
PEC/PNEC
Discussion
Page 3 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
ERC8a* STP ERC8d** STP
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---

Route
0.856 mg/kg bw/d 4.51 mg/m
3

DNEL
Risk characterisatio n ratio

9.01x10 5.01x10 0.125
-2
Dermal Inhalation

3
-2
Combined routes
1.19 mg/kg bw/day
9.5 mg/kg bw/d
Environment
Compartments PEC PNEC 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg PEC/PNEC Discussion ERC4 - spERC ESVOC5* Freshwater Marine water Freshwater sediments Marine sediments 0.0263 mg/l 2.61E-03 mg/l 0.136 mg/kg 0.0135 mg/kg 0.0258 0.0256 0.0258 0.0256 -----
*This spERC was calculated with the total tonnage of the following product categories: PC1, PC9a, b, c, 14, 15, and 18 and therefore represents the worst case.
Compartments
PEC
PNEC
PEC/PNEC
Discussion
ERC4 - spERC ESVOC5* Agricultural soil 0.0106 mg/kg (30 days) Grassland 4.59E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0232 0.0101
---
Compartments
PEC
PNEC
PEC/PNEC
Discussion
ERC4 - spERC ESVOC5* STP 0.215 mg/l
39 mg/l
5.5E-03
--
Page 4 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Exposure scenario 4 Professional uses PC1 Workers Route Exposure concentrations 4.28 mg/kg bw/d 47.3 mg/m
3
Dermal Inhalation Combined routes
7.49 mg/kg bw/d
Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity
DNEL

3
Risk characterisatio n ratio 0.451 0.526 0.788
9.5 mg/kg bw/d
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
Page 5 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 5 Consumer uses PC1 Consumers Route Exposure concentrations 12.83 mg/kg bw/d 3 20.5 mg/m 0.771 mg/kg bw/d 17.21 mg/kg bw/d 0.0513 mg/kg bw/d 3 1.1 mg/m 0.0253 mg/kg bw/d 0.488 mg/kg bw/d Leading toxic end point / Critical effect Acute toxicity Acute toxicity Acute toxicity Acute toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio 0.44 0.513 -2 3.08x10 0.688 9x10
-3
Acute systemic effects
Dermal Inhalation Oral Combined
29 mg/kg bw/d 40 mg/m 25 mg/kg bw/d 25 mg/kg bw/d 5.7 mg/kg bw/d 8 mg/m
3 3
Dermal Inhalation Oral Combined routes
0.138 5.06x10 9.76x10

-3
5 mg/kg bw/d 5 mg/kg bw/d
-2
Please note, that in the table above the highest exposure values obtained for oral, dermal, inhalation and combined exposure, as calculated by use of ConsExpo, are presented, thus, representing a worst case for each route of exposure
Environment
Compartments ERC8a* Freshwater Marine water Freshwater sediments Marine sediments ERC8d** Freshwater Marine water Freshwater sediments 0.0173 mg/l 1.72E-03 mg/l 0.0897 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.017 0.0168 0.017 ---0.0176 mg/l 1.74E-03 mg/l 0.0908 mg/kg 8.98E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0172 0.017 0.0172 0.017 ----PEC PNEC PEC/PNEC Discussion
Page 6 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Marine sediments
8.87E-03 mg/kg
0.527 mg/kg
0.0168
--
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 3 Industrial uses PC9a Workers Route Exposure concentrations 0.856 mg/kg bw/d 3 4.51 mg/m 1.19 mg/kg bw/d ay Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 9.01x10 5.01x10 0.125
-2

3
9.5 mg/kg bw/d
Environment
Compartments PEC PNEC 1.02 mg/l 0.102 mg/l 5.27 mg/kg PEC/PNEC Discussion ERC4 - spERC ESVOC5* Freshwater Marine water Freshwater sediments 0.0263 mg/l 2.61E-03 mg/l 0.136 mg/kg 0.0258 0.0256 0.0258 ----
Page 7 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Marine sediments
0.0135 mg/kg
0.527 mg/kg
0.0256
--
* This spERC was calculated with the total tonnage of the following product categories: PC1, PC9a, b, c, 14, 15, and 18 and therefore represents the worst case.
Compartments
PEC
PNEC
PEC/PNEC
Discussion
0.456 mg/kg 0.456 mg/kg
0.0232 0.0101
---
Compartments
PEC
PNEC
PEC/PNEC
Discussion
39 mg/l
5.5E-03
--
Exposure scenario 4 Professional uses PC9a Workers Route Exposure concentrations 4.28 mg/kg bw/d 47.3 mg/m
3
7.49 mg/kg bw/d
DNEL

3
9.5 mg/kg bw/d
Environment
Compartments ERC8a* Freshwater Marine water Freshwater sediments Marine sediments ERC8d** Freshwater Marine water 0.0173 mg/l 1.72E-03 mg/l 1.02 mg/l 0.102 mg/l 0.017 0.0168 --0.0176 mg/l 1.74E-03 mg/l 0.0908 mg/kg 8.98E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0172 0.017 0.0172 0.017 ----PEC PNEC PEC/PNEC Discussion
Page 8 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Freshwater sediments Marine sediments
0.0897 mg/kg 8.87E-03 mg/kg
5.27 mg/kg 0.527 mg/kg
0.017 0.0168
---
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 5 Consumer uses PC9a Consumers Route Exposure concentrations 4.17 mg/kg bw/d 3 12.3 mg/m 0.0169 mg/kg bw/d 9.12 mg/kg bw/d 0.0114 mg/kg bw/d 3 0.0338 mg/m 9.25x10 mg/kg bw/d 0.025 mg/kg bw/d
-5
Dermal Inhalation Oral Combined Dermal Inhalation Oral Combined routes
Leading toxic end point / Critical effect Acute toxicity Acute toxicity Acute toxicity Acute toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity
DNEL
29 mg/kg bw/d 3 40 mg/m 25 mg/kg bw/d 25 mg/kg bw/d 5.7 mg/kg bw/d 8 mg/m
3
Risk characterisatio n ratio 0.144 0.308 -4 6.76x10 0.365 -3 2x10 4.23x10 1.85x10 5x10
-3 -3
-5
Please note, that in the table above the highest exposure values obtained for oral, dermal, inhalation and combined exposure, as calculated by use of ConsExpo, are presented, thus, representing a worst case for each route of exposure.
Page 9 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 3 Industrial uses PC9b Workers Route Exposure concentrations 0.856 mg/kg bw/d 3 4.51 mg/m Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose DNEL Risk characterisatio n ratio -2 9.01x10 5.01x10
-2
Dermal Inhalation

3
Page 10 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Combined routes
1.19 mg/kg bw/d ay
toxicity Repeated dose toxicity
9.5 mg/kg bw/d
0.125
Environment
Compartments
PEC
PNEC
PEC/PNEC
Discussion
0.456 mg/kg 0.456 mg/kg
0.0232 0.0101
---
Compartments
PEC
PNEC
PEC/PNEC
Discussion
39 mg/l
5.5E-03
--
Exposure scenario 4 Professional uses PC9b Workers Route Exposure concentrations 4.28 mg/kg bw/d 47.3 mg/m
3
7.49 mg/kg bw/d
DNEL

3
9.5 mg/kg bw/d
Page 11 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 5 Consumer uses PC9b Consumers Route Exposure concentrations Leading toxic end point / Critical effect Page 12 of 43 DNEL Risk characterisatio n ratio
SAFETY DATA SHEET

BENZYL ALCOHOL
15 mg/kg bw/d 3 38.6 mg/m 0.459 mg/kg bw/d 23.4 mg/kg bw/d 0.00821 mg/kg bw/d 3 0.229 mg/m 1.26x10 mg/kg bw/d 0.0935 mg/kg bw/d
-3
Acute toxicity Acute toxicity Acute toxicity Acute toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity
3
0.517 0.965 -2 1.84x10 0.936 -3 1.44x10 0.0286 2.52x10 0.0187

-4
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
Compartments ERC8a*
PEC
PNEC
PEC/PNEC
Discussion
Page 13 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
STP ERC8d** STP
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 3 Industrial uses PC9c Workers Route Exposure concentrations 0.856 mg/kg bw/d 3 4.51 mg/m 1.19 mg/kg bw/d ay Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 9.01x10 5.01x10 0.125
-2

3
9.5 mg/kg bw/d
Environment
Compartments
PEC
PNEC
PEC/PNEC
Discussion
0.456 mg/kg 0.456 mg/kg
0.0232 0.0101
---
Compartments
PEC
PNEC
PEC/PNEC
Discussion
39 mg/l
5.5E-03
--
Exposure scenario 4 Professional uses PC9c
Page 14 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Workers Route Exposure concentrations 4.28 mg/kg bw/d 47.3 mg/m

3
7.49 mg/kg bw/d
DNEL

3
9.5 mg/kg bw/d
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
Compartments ERC8a* STP ERC8d**
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l
39 mg/l
3.28E-03
--
Page 15 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
STP
0.126 mg/l
39 mg/l
3.23E-03
--
Exposure scenario 5 Consumer uses PC9c Consumers Route Exposure concentrations 1.25 mg/kg bw/d 3 2.97 mg/m n.a. 2.44 mg/kg bw/d 0.0103 mg/kg bw/d 3 0.0244 mg/m n.a. 0.0201 mg/kg bw/d Leading toxic end point / Critical effect Acute toxicity Acute toxicity Acute toxicity Acute toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio 0.0431 0.0743 n.a. 0.0976 -3 1.81x10 3.05x10 n.a. 4.02x10
-3 -3
Acute systemic effects Long-term systemic effects
3
n.a. not applicable Please note, that in the table above the highest exposure values obtained for oral, dermal, inhalation and combined exposure, as calculated by use of ConsExpo, are presented, thus, representing a worst case for each route of exposure.
Environment
Compartments ERC8a* Agricultural soil (30 days)
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg
0.456 mg/kg
0.0156
--
Page 16 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Grassland ERC8d** Agricultural soil (30 days) Grassland
3.33E-03 mg/kg
0.456 mg/kg
0.0073
--
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 3 Industrial uses PC14 Workers Route Exposure concentrations 0.274 mg/kg bw/d 4.51mg/m
3
0.699 mg/kg bw/da y
DNEL
9.5 mg/kg bw/d 3 90 mg/m 9.5 mg/kg bw/d
Risk characterisatio n ratio -2 2.88x10 5.01x10 7.36x10

-2
-2
Route
Exposure concentrations 0.283 mg/kg bw/d 2 mg/m

3
0.569 mg/kg bw/d
DNEL
Risk characterisatio n ratio -2 2,98x10 2.22x10 5.99x10

-2
-2
Please note, that in the table above the highest exposure values obtained for dermal, inhalation and combined exposure, as calculated by use of ECETOC TRA and assuming BzOH concentrations of 100% in solid matrices, are presented. These exposure values were not necessarily obtained in the same PROC.
Environment
Page 17 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Compartments
PEC
PNEC 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg
PEC/PNEC
Discussion
ERC4 - spERC ESVOC5* Freshwater Marine water Freshwater sediments Marine sediments 0.0263 mg/l 2.61E-03 mg/l 0.136 mg/kg 0.0135 mg/kg 0.0258 0.0256 0.0258 0.0256 -----
Compartments
PEC
PNEC
PEC/PNEC
Discussion
0.456 mg/kg 0.456 mg/kg
0.0232 0.0101
---
Compartments
PEC
PNEC
PEC/PNEC
Discussion
39 mg/l
5.5E-03
--
3
7.49 mg/kg bw/d
DNEL

3
9.5 mg/kg bw/d
Route

3
Dermal Inhalation
Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity
DNEL

3
Risk characterisatio n ratio 0.298 0.222
Page 18 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Combined routes
5.69 mg/kg bw/d
Repeated dose toxicity
9.5 mg/kg bw/d
0.599
Please note, that in the table above the highest exposure values obtained for dermal, inhalation and combined exposure, as calculated by use of ECETOC TRA and assuming BzOH concentrations of 100% in solid matrices, are presented. These exposure values were not necessarily obtained in the same PROC.
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Page 19 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Route
Exposure concentrations 0.274 mg/kg bw/d 4.51mg/m

3
0.699 mg/kg bw/da y aus PROC8a)
DNEL
Risk characterisatio n ratio -2 2.88x10 5.01x10 7.36x10

-2
-2
Environment
* This spERC was calculated with the total tonnage of the following product categories PC1, PC9a, b, c, 14, 15, and 18 and therefore represents the worst case.
Compartments
PEC
PNEC
PEC/PNEC
Discussion
0.456 mg/kg 0.456 mg/kg
0.0232 0.0101
---
Compartments
PEC
PNEC
PEC/PNEC
Discussion
39 mg/l
5.5E-03
--
3
Dermal Inhalation
Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose
DNEL

3
Risk characterisatio n ratio 0.451 0.526
Page 20 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Combined routes
7.49 mg/kg bw/d
toxicity Repeated dose toxicity
9.5 mg/kg bw/d
0.788
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 3 Industrial uses PC18
Page 21 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Workers Route Exposure concentrations 0.856 mg/kg bw/d 3 4.51 mg/m 1.19 mg/kg bw/d ay Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 9.01x10 5.01x10 0.125
-2

3
9.5 mg/kg bw/d
Environment
Compartments
PEC
PNEC
PEC/PNEC
Discussion
0.456 mg/kg 0.456 mg/kg
0.0232 0.0101
---
Compartments
PEC
PNEC
PEC/PNEC
Discussion
39 mg/l
5.5E-03
--
Exposure scenario 4 Professional uses PC18 Workers Route Exposure concentrations Leading toxic end point / Critical effect Page 22 of 43 DNEL Risk characterisatio n ratio
SAFETY DATA SHEET

BENZYL ALCOHOL

3
7.49 mg/kg bw/d

3
0.451 0.526 0.788
9.5 mg/kg bw/d
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Page 23 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Exposure scenario 5 Consumer uses PC18 Consumers Route Exposure concentrations 3 mg/kg bw/d 3 2.31 mg/m n.a. 3.93 mg/kg bw/d 0.00821 mg/kg bw/d 3 0.00634 mg/m n.a. 0.0108 mg/kg bw/d Leading toxic end point / Critical effect Acute toxicity Acute toxicity Acute toxicity Acute toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio 0.103 0.0578 n.a. 0.157 -3 1.44x10 7.93x10 n.a. 2.16x10
-3 -4
3
Environment
Compartments ERC8a* Agricultural soil (30 days) Grassland ERC8d**
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
Page 24 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Agricultural soil (30 days) Grassland
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 3 Industrial uses PC19 Workers Route Exposure concentrations 0.137 mg/kg bw/ d 3 1.35 mg/m 0.227 mg/kg bw/ d Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 1.44x10 1.5x10
-2

3
9.5 mg/kg bw/d
2.39x10
-2
Please note that in the table above the highest exposure values obtained for dermal, inhalation and combined exposure, as calculated by use of ECETOC TRA for a BzOH concentration of 100% are presented. These exposure values were not necessarily obtained in the same PROC.
Environment
Compartments ERC6a PC19 Freshwater Marine water Freshwater sediments Marine sediments Compartments ERC6a PC19 Agricultural soil (30 days) Grassland Compartments ERC6a PC19 0.194 mg/l 0.0194 mg/l 1 mg/kg 0.1 mg/kg PEC 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg PNEC 0.191 0.19 0.191 0.19 PEC/PNEC ----Discussion PEC PNEC PEC/PNEC Discussion
0.065 mg/kg 8.92E-03 mg/kg PEC
0.142 0.0196
--PEC/PNEC Discussion
Page 25 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
STP
1.9 mg/l
39 mg/l
0.0486
--
Exposure scenario 4 Professional uses PC21 Workers Route Exposure concentrations 0.685 mg/kg bw/d 3 45.1 mg/m 6.72 mg/kg bw/d ay Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 7.21x10 0.501 0.707

3
9.5 mg/kg bw/d
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
Page 26 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 3 Industrial uses PC24 Workers Route Exposure concentrations 0.274 mg/kg bw/d 3 4.51 mg/m 0.918 mg/kg bw/d Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 2.88x10 5.01x10 9.66x10
-2

3
9.5 mg/kg bw/d
-2
Please note, that in the table above the highest exposure values obtained for dermal and inhalation exposure, as calculated by use of ECETOC TRA for BzOH concentrations of up to 40%, are presented and combined exposure was estimated by addition of these exposure values.
Environment
Compartments ERC7 PC 24 Freshwater Marine water Freshwater sediments Marine sediments Compartments ERC7 PC 24 Agricultural soil (30 days) Grassland Compartments ERC7 PC 24 STP PEC 0.0127 mg/l 1.25E-03 mg/l 0.0656 mg/kg 6.47E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0124 0.0123 0.0124 0.0123 Discussion ----PEC PNEC PEC/PNEC Discussion
PNEC
PEC/PNEC
5.53E-03 mg/kg 3.19E-03 mg/kg PEC
0.0121 0.0070 PEC/PNEC
--Discussion
0.079 mg/l
39 mg/l
2.03E-03
--
Exposure scenario 3 Industrial uses PC26 Workers Page 27 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Route
Exposure concentrations 0.856 mg/kg bw/d 3 4.51 mg/m 1.19 mg/kg bw/d ay aus PROC10)
Dermal* Inhalation Combined routes
DNEL

3
Risk characterisatio n ratio -2 5.01x10 9.01x10 0.125

-2
9.5 mg/kg bw/d
Environment
Compartments ERC4 PC26 Freshwater Marine water Freshwater sediments Marine sediments Compartments ERC4 PC26 Agricultural soil (30 days) Grassland Compartments ERC4 PC26 STP PEC 0.0206 mg/l 2.04E-03 mg/l 0.0656 mg/kg 6.47E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0202 0.02 0.0202 ---PEC PNEC PEC/PNEC Discussion
PNEC
0.02 -PEC/PNEC Discussion
8.11E-03 mg/kg 3.42E-03 mg/kg PEC
0.0178 0.0075 PEC/PNEC
--Discussion
0.158 mg/l
39 mg/l
4.05E-03
--
3
7.54 mg/kg bw/d
DNEL

3
9.5 mg/kg bw/d
Please note that in the table above the highest exposure values obtained for dermal, inhalation and combined exposure, as calculated by use of ECETOC TRA for BzOH concentration of up to 40%, are presented. These exposure values were not necessarily obtained in the same PROC
Page 28 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Route

3
3.54 mg/kg bw/d
DNEL

3
Risk characterisatio n ratio 0.298 5.56x10 0.373

-2
9.5 mg/kg bw/d
Please note, that in the table above the highest exposure values obtained for dermal and inhalation exposure, as calculated by use of ECETOC TRA and assuming BzOH concentrations of 100% in solid matrices, are presented and combined exposure was estimated by addition of these exposure values which were obtained in PROC21.
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
Compartments ERC8a* STP ERC8d**
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l
39 mg/l
3.28E-03
--
Page 29 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
STP
0.126 mg/l
39 mg/l
3.23E-03
--
Exposure scenario 3 Industrial uses PC30 Workers Route Exposure concentrations 0.274 mg/kg bw/d 3 4.51 mg/m 0.699 mg/kg bw/ d Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 2.88x10 5.01x10 7.36x10
-2

3
9.5 mg/kg bw/d
-2
Environment
Compartments ERC4 PC30 Freshwater Marine water Freshwater sediments Marine sediments Compartments ERC4 PC30 Agricultural soil (30 days) Grassland Compartments ERC4 PC30 STP PEC 0.089 mg/l 8.89E-03 mg/l 0.46 mg/kg 0.0459 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg PNEC 0.0873 0.0871 0.0873 0.0871 Discussion ----PEC PNEC PEC/PNEC Discussion
PEC/PNEC
0.0305
mg/kg
0.0667 0.012 PEC/PNEC
--Discussion
5.48E-03 mg/kg PEC
0.842 mg/l
39 mg/l
0.0216
--
Exposure scenario 4 Professional uses PC30 Workers Route Exposure concentrations Leading toxic end point / Critical effect DNEL Risk characterisatio n ratio
Page 30 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
0.685mg/kg bw/d 45.1 mg/m

3
6.72 mg/kg bw/d

3
2.88x10 0.501 0.707
-2
9.5 mg/kg bw/d
Environment
Compartments ERC8a* Freshwater Marine water Freshwater sediments Marine sediments ERC8b** Freshwater Marine water Freshwater sediments Marine sediments 4.81E-03 mg/l 4.62E-04 mg/l 0.0249 mg/kg 2.39E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 4.71E-03 4.53E-03 4.71E-03 4.53E-03 ----0.0176 mg/l 1.74E-03 mg/l 0.0908 mg/kg 8.98E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0172 0.017 0.0172 0.017 ----PEC PNEC PEC/PNEC Discussion
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC30/35
Compartments ERC8a* Agricultural soil (30 days) Grassland ERC8b** Agricultural soil (30 days) Grassland
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
2.95E-03 mg/kg 2.95E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
6.46E-03 6.46E-03
---
Compartments ERC8a* STP ERC8b** STP
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 1.07E-04 mg/l
39 mg/l 39 mg/l
3.28E-03 2.74E-06
---
Page 31 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
3
7.49 mg/kg bw/d
DNEL

3
9.5 mg/kg bw/d
Please note that in the table above the highest exposure values obtained for dermal, inhalation and combined exposure, as calculated by use of ECETOC TRA for BzOH concentration of up to 40%, are presented. These exposure values were not necessarily obtained in the same PROC.
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
Compartments ERC8a*
PEC
PNEC
PEC/PNEC
Discussion
Page 32 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
STP ERC8d** STP
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 5 Consumer uses PC31 Consumers Route Exposure concentrations 12.5 mg/kg bw/d 3 0.202mg/m 0.0224 mg/kg bw/d 12.6 mg/kg bw/d 0.0251 mg/kg bw/d 3 0.00108 mg/m 4.9x10 mg/kg bw/d 0.0257 mg/kg bw/d
-4
DNEL
3
Risk characterisatio n ratio 0.431 -3 5.05x10 -4 8.96x10 0.504 -3 4.4x10 1.35x10 9.8x10
-4
-5
5.14x10
-3
Environment
Compartments ERC8a*
PEC
PNEC
PEC/PNEC
Discussion
Page 33 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Agricultural soil (30 days) Grassland ERC8d** Agricultural soil (30 days) Grassland
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Page 34 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Exposure scenario 3 Industrial uses PC32 Workers Route Exposure concentrations 0.274 mg/kg bw/d 3 4.51 mg/m 0.918 mg/kg bw/d Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 5.01x10 2.88x10 9.66x10
-2

3
9.5 mg/kg bw/d
-2
Please note, that in the table above the highest exposure values obtained for dermal and inhalation exposure, as calculated by use of ECETOC TRA for BzOH concentrations of up to 40%, are presented and combined exposure was estimated by addition of these exposure values.
Environment
Compartments ERC4 PC32 Freshwater Marine water Freshwater sediments Marine sediments Compartments ERC4 PC32 Agricultural soil (30 days) Grassland Compartments ERC4 PC32 STP PEC 0.0127 mg/l 1.25E-03 mg/l 0.0656 mg/kg 6.47E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0124 0.0123 0.0124 0.0123 Discussion ----PEC PNEC PEC/PNEC Discussion
PNEC
PEC/PNEC
5.52E-03 mg/kg 3.18E-03 mg/kg PEC
0.0121 0.0070 PEC/PNEC
--Discussion
0.079 mg/l
39 mg/l
2.03E-03
--
3
Dermal Inhalation Combined
7.49 mg/kg bw/d
Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose
DNEL

3
9.5 mg/kg bw/d
Page 35 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
routes
toxicity
Environment
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg 3.32E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0154 0.0073
---
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Page 36 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Exposure scenario 3 Industrial uses PC34 Workers Route Exposure concentrations 0.856 mg/kg bw/d 3 4.51 mg/m 1.19 mg/kg bw/d Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 9.01x10 5.01x10 0.125
-2

3
9.5 mg/kg bw/d
Environment
Compartments PEC PNEC 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg PNEC PEC/PNEC Discussion ERC4 spERC TEGEWA 6 PC 34 Freshwater Marine water Freshwater sediments Marine sediments Compartments 0.0192 mg/l 1.9E-03 mg/l 0.099 mg/kg 9.81E-03 mg/kg PEC 0.0188 0.0186 0.0188 0.0186 PEC/PNEC ----Discussion
ERC4 spERC TEGEWA 6 PC 34 Agricultural soil 7.63E-03 mg/kg (30 days) Grassland 4.26E-03 mg/kg Compartments PEC
0.0167 0.0093
--Discussion
PEC/PNEC
ERC4 spERC TEGEWA 6 PC 34 STP 0.144 mg/l 39 mg/l
3.68E-03
--
Page 37 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Exposure scenario 5 Consumer uses PC34 Consumers Route Exposure concentrations 1.6 mg/kg bw/d 3 0.0561 mg/m n.a. 1.6 mg/kg bw/d 1.6 mg/kg bw/d 0.016mg/m n.a. 1.6 mg/kg bw/d
3
DNEL
3
Risk characterisatio n ratio 0.055 -3 1.4x10 n.a. 0.064 0.281 2x10 n.a. 0.32
-3
Environment
Compartments ERC8a* Agricultural soil (30 days) Grassland ERC8d** Agricultural soil (30 days)
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg
0.456 mg/kg 0.456 mg/kg
0.0156 0.0073
---
7.04E-03 mg/kg
0.456 mg/kg
0.0154
--
Page 38 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Grassland
3.32E-03 mg/kg
0.456 mg/kg
0.0073
--
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 0.126 mg/l
39 mg/l 39 mg/l
3.28E-03 3.23E-03
---
Exposure scenario 3 Industrial uses PC35 Workers Route Exposure concentrations 0.856 mg/kg bw/d 3 4.51 mg/m 1.19 mg/kg bw/d Leading toxic end point / Critical effect Repeated dose toxicity Repeated dose toxicity Repeated dose toxicity DNEL Risk characterisatio n ratio -2 9.01x10 5.01x10 0.125
-2

3
9.5 mg/kg bw/d
Environment
Compartments PEC PNEC 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg PNEC PEC/PNEC Discussion ERC4 spERC ESVOC 8 Freshwater Marine water Freshwater sediments Marine sediments Freshwater Marine water Freshwater sediments Marine sediments Compartments 5.11E-03 mg/l 4.93E-04 mg/l 0.0264 mg/kg 2.55E-03 mg/kg 5.01E-03 4.83E-03 5.01E-03 4.83E-03 5.01E-03 4.83E-03 5.01E-03 4.83E-03 PEC/PNEC ---------
ERC6b spERC ESVOC 8 5.11E-03 mg/l 4.93E-04 mg/l 0.0264 mg/kg 2.55E-03 mg/kg PEC
Discussion
ERC4 - spERC ESVOC 8 Agricultural soil 3.42E-03 mg/kg (30 days)
0.456 mg/kg
7.49E-03
--
Page 39 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Grassland 3.55E-03 mg/kg ERC6b - spERC ESVOC 8 Agricultural soil 3.42E-03 mg/kg (30 days) Grassland 3.55E-03 mg/kg Compartments PEC
0.456 mg/kg
7.79E-03
--
7.49E-03 7.79E-03
--Discussion
PEC/PNEC
ERC4 (ESVOC 8) PC35 STP 3.16E-03 mg/l ERC6b (ESVOC 8) PC35 STP 3.16E-03 mg/l
39 mg/l 39 mg/l
8.1E-05 8.1E-05
---
3
7.49 mg/kg bw/d
DNEL

3
9.5 mg/kg bw/d
Environment
Compartments ERC8a* Freshwater Marine water Freshwater sediments Marine sediments ERC8b** Freshwater Marine water Freshwater sediments Marine sediments ERC8d*** Freshwater Marine water Freshwater sediments 0.0173 mg/l 1.72E-03 mg/l 0.0897 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.017 0.0168 0.017 ---0.0176 mg/l 1.74E-03 mg/l 0.0908 mg/kg 8.98E-03 mg/kg 4.81E-03 mg/l 4.62E-04 mg/l 0.0249 mg/kg 2.39E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0172 0.017 0.0172 0.017 4.71E-03 4.53E-03 4.71E-03 4.53E-03 --------PEC PNEC PEC/PNEC Discussion
1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg
Page 40 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Marine sediments ERC8e** Freshwater Marine water Freshwater sediments Marine sediments
8.87E-03 mg/kg 4.8E-03 mg/l 4.62E-04 mg/l 0.0248 mg/kg 2.39E-03 mg/kg
0.527 mg/kg
0.0168 4.71E-03 4.53E-03 4.71E-03 4.53E-03
------
1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ **PC30,35/ *** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Compartments ERC8a* Agricultural soil (30 days) Grassland ERC8b** Agricultural soil (30 days) Grassland ERC8d*** Agricultural soil (30 days) Grassland ERC8e** Agricultural soil (30 days) Grassland
PEC
PNEC
PEC/PNEC
Discussion
7.11E-03 mg/kg 3.33E-03 mg/kg 2.95E-03 mg/kg 2.95E-03 mg/kg
0.456 mg/kg 0.456 mg/kg 0.456 mg/kg 0.456 mg/kg
0.0156 0.0073 6.46E-03 6.46E-03
-----
0.0154 0.0073 6.46E-03 6.46E-03
-----
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ **PC30, 35/ *** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Compartments ERC8a* STP ERC8b** STP ERC8d*** STP ERC8e** STP
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 1.07E-04 mg/l 0.126 mg/l 6.92E-05 mg/l
39 mg/l 39 mg/l 39 mg/l 39 mg/l
3.28E-03 2.74E-06 3.23E-03 1.77E-06
-----
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ **PC30, 35/ *** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Exposure scenario 5 Consumer uses PC35 Consumers
Page 41 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Route
Exposure concentrations 3.07 mg/kg bw/d 3 0.18 mg/m 0.00344 mg/kg bw/d 3.07 mg/kg bw/d 3.06 mg/kg bw/d 0.136 mg/m
3
DNEL
3
Risk characterisatio n ratio 0.106 -3 4.5x10 -4 1.38x10 0.123 0.537 0.017 2.5x10 0.612
-4
0.00125 mg/kg bw/d 3.06 mg/kg bw/d
Environment
Compartments ERC8a* Freshwater Marine water Freshwater sediments Marine sediments ERC8b** Freshwater Marine water Freshwater sediments Marine sediments ERC8d*** Freshwater Marine water Freshwater sediments Marine sediments ERC8e** Freshwater Marine water Freshwater sediments Marine sediments 0.0173 mg/l 1.72E-03 mg/l 0.0897 mg/kg 8.87E-03 mg/kg 4.8E-03 mg/l 4.62E-04 mg/l 0.0248 mg/kg 2.39E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 4.71E-03 4.53E-03 4.71E-03 4.53E-03 4.71E-03 4.53E-03 4.71E-03 4.53E-03 --------0.0176 mg/l 1.74E-03 mg/l 0.0908 mg/kg 8.98E-03 mg/kg 4.81E-03 mg/l 4.62E-04 mg/l 0.0249 mg/kg 2.39E-03 mg/kg 1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg 0.0172 0.017 0.0172 0.017 0.017 0.0168 0.017 0.0168 --------PEC PNEC PEC/PNEC Discussion
1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg
1.02 mg/l 0.102 mg/l 5.27 mg/kg 0.527 mg/kg
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ **PC35/ *** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Page 42 of 43
SAFETY DATA SHEET

BENZYL ALCOHOL
Compartments ERC8a* Agricultural soil (30 days) Grassland ERC8b** Agricultural soil (30 days) Grassland ERC8d*** Agricultural soil (30 days) Grassland ERC8e** Agricultural soil (30 days) Grassland
PEC
PNEC
PEC/PNEC
Discussion
0.0156 0.0073 6.46E-03 6.46E-03
-----
0.0154 0.0073 6.46E-03 6.46E-03
-----
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ **PC35/ *** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35 worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Compartments ERC8a* STP ERC8b** STP ERC8d*** STP ERC8e** STP
PEC
PNEC
PEC/PNEC
Discussion
0.128 mg/l 1.07E-04 mg/l 0.126 mg/l 6.92E-05 mg/l
39 mg/l 39 mg/l 39 mg/l 39 mg/l
3.28E-03 2.74E-06 3.23E-03 1.77E-06
-----
The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ **PC35/ *** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35
Page 43 of 43

Micms Doc Admin

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Micms Doc Admin

Uploaded by

Copyright:

Available Formats

Benzyl alcohol

Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Main use category Use of the substance/preparation

Uses advised against

Country THE NETHERLANDS

SECTION 2: Hazards identification

CLP Signal word Hazard statements (CLP)

Precautionary statements (CLP)

Other hazards not contributing to the classification

SECTION 3: Composition/information on ingredients

Substances Product identifier

Classification according to Directive 67/548/EEC

Classification according to Regulation (EC) No. 1272/2008 [CLP]

SECTION 4: First aid measures

First-aid measures after inhalation

First-aid measures after skin contact

First-aid measures after eye contact

First-aid measures after ingestion

Symptoms/injuries after ingestion 4.3.

: Nausea. Vomiting. Headache. Disturbances of consciousness.

Indication of any immediate medical attention and special treatment needed

SECTION 5: Firefighting measures

Firefighting instructions Protection during firefighting

SECTION 6: Accidental release measures

Protective equipment 6.2. Environmental precautions

Methods for cleaning up Other information 6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

Hygiene measures 7.2.

Technical measures Storage conditions

: iron aluminium. : -12-50 C : Ordinary steel polyethylene.

SECTION 8: Exposure controls/personal protection

SECTION 9: Physical and chemical properties

Viscosity, dynamic Explosive properties Oxidising properties 9.2. Other information

: Surface tension : 39 mN/m (20 C) (1 g/l) (OECD 115, EC A.5).

SECTION 10: Stability and reactivity

on contact with air. : Benzaldehyde.

SECTION 11: Toxicological information

SECTION 12: Ecological information

Benzyl alcohol (100-51-6) Persistence and degradability

Readily biodegradable (OECD 301C & 301A).

Benzyl alcohol (100-51-6) Log Pow 12.4. Mobility in soil

1,05 (25 C) (Handbook)

No additional information available

SECTION 13: Disposal considerations

SECTION 14: Transport information

Transport document description 14.3. Transport hazard class(es)

Packing group (UN) 14.5. Environmental hazards

: No supplementary information available.

SECTION 15: Regulatory information

No additional information available 15.1.2. National regulations

No additional information available 15.2. Chemical safety assessment

A chemical safety assessment has been carried out.

SECTION 16: Other information

H302 H319 H332 R20/22 R36

All waste and organic cleaning solutions are disposed of by incineration

general ventilation; specify effectiveness of measure :

Exposure information and reference to its source

Guidance to DU to evaluate whether he works inside the boundaries set by the ES

Local exhaust ventilation No gloves or respiratory protection are required

Size of the STP : 2000 m/day (by default)

All waste and organic cleaning solutions are disposed of by incineration.

Frequency and duration of use/exposure 8 hours per day 230 days/year