Chem 3 ICE Exercises Answer Key c!

e-γoT 2010
1. x: molarity of oxygen used up
M 2NO (g) + O2 (g)  2NO2 (g) a) [NO]EQ= 0.0200 – 2.2e-3 = 0.0178 M
I 0.0200 0.0300 0 b) [O2]EQ= 0.0300 – 1.1e-3 = 0.0289 M
C - 2x -x + 2x [NO 2]2EQ  2.2 e−32
c. K C = = =0.529
E 0.0200 - 2x 0.0300 - x 2x = 2.2e-3 [ NO ]2EQ [O 2 ]EQ 0.01782 0.0289

2.
P N2O4 (g)  2NO2 (g)
I y 0
y: initial partial pressure of N2O4 = (PNO2,EQ/2) + (PT - PNO2,EQ)
C - (x/2) +x
x: eqm partial pressure of NO2 at eqm PT = PNO2 + PN2O4 = 0.5
E 0.5 - x x
2
 P NO  x2
K P= =0.66= 2
x =0.3325 ,−0.9925
PN O 2
0.5−x 
4

0.3325
P N O converted  
2
percent d = 2
×100=
4
×100
P N O initial 0.3325
2
 4
0.5−0.3325
2
percent d =49.8 percent
P N O =0.5−0.3325=0.1675 atm P NO =0.3325 atm
3. 2 4 2

P H2 (g) + S (s)  H2S (g) x: partial pressure of H2S at eqm

(0.20)(0.08206) PH S x
I x(363)
disregard 0 K C =K P = 0.068=
2
x=0.38 atm=P H S
PH 2
5.96−x 2

C -x +x
E 5.96 - x x

4.
M N2O4 (g)  2NO2 (g)
I 1 1 x: molar conc'n of N2O4 used up x = 0.25, 2x = 0.50
C -x + 2x [ NO 2 ]2 1.52
K C= = =3.0
E 1 – x = 0.75 1 + 2x [ N 2 O 4 ] 0.75

6.
x: Partial Pressure of CO/Cl2 at eqm
P COCl2 (g)  CO(g) + Cl2 (g)
 P Cl  PCO  x2
I 0.124 0 0 K P= 2
0.0041= x=0.0206 ,−0.025
P COCl 2
0.124−x
C -x +x +x P COCl =0.124−0.0206=0.103 atm P Cl = PCO =0.0206 atm
2 2

E 0.124 - x x x ¿