Expt 2: CrO42- – Cr2O72- Equilibrium System Pre-Lab Sheet C30910

Objective:
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Schematic Diagram: (flowchart of procedure)

Data:
Part I. Chromate-Dichromate Equilibrium
Solution Color
K2CrO4
K2Cr2O7
K2CrO4 + NaOH + HCl
K2Cr2O7 + NaOH + HCl
K2CrO4 + HCl + NaOH
K2Cr2O7 + HCl + NaOH
Part II. Chromate-Dichromate Equilibrium with Barium chromate
Solution Color
K2CrO4 + NaOH + Ba(NO3)2 (A)
K2Cr2O7 + HCl +Ba(NO3)2 (B)
(A)+ HCl
(B)+ NaOH
K2Cr2O7 + Ba(NO3)2
K2CrO4 + Ba(NO3)2
Part III. Chromate-Dichromate Equilibrium with acids and bases
Solution Color Solution Color
K2CrO4 + CH3COOH K2Cr2O7 + CH3COOH
K2CrO4 + Ca(OH)2 K2Cr2O7 + Ca(OH)2
K2CrO4 + HNO3 K2Cr2O7 + HNO3
K2CrO4 + H2SO4 K2Cr2O7 + H2SO4
K2CrO4 + KOH K2Cr2O7 + KOH
K2CrO4 + C2H5OH K2Cr2O7 + C2H5OH
K2CrO4 + NH3 K2Cr2O7 + NH3